Isotopic analysis: fundamentals and applications using ICP-MS
Gespeichert in:
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| Format: | Buch |
| Sprache: | English |
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Weinheim
Wiley-VCH
2012
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| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XXI, 529 S. graph. Darst. |
| ISBN: | 9783527328963 |
Internformat
MARC
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| 084 | |a PHY 115f |2 stub | ||
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| 245 | 1 | 0 | |a Isotopic analysis |b fundamentals and applications using ICP-MS |c ed. by Frank Vanhaecke ... |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2012 | |
| 300 | |a XXI, 529 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Isotopes | |
| 650 | 4 | |a Inductively coupled plasma mass spectrometry | |
| 650 | 0 | 7 | |a Isotopenhäufigkeit |0 (DE-588)4162584-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Isotopieeffekt |0 (DE-588)4162585-7 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a ICP-Massenspektrometrie |0 (DE-588)4280345-7 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4143413-4 |a Aufsatzsammlung |2 gnd-content | |
| 689 | 0 | 0 | |a Isotopenhäufigkeit |0 (DE-588)4162584-5 |D s |
| 689 | 0 | 1 | |a ICP-Massenspektrometrie |0 (DE-588)4280345-7 |D s |
| 689 | 0 | |5 DE-604 | |
| 689 | 1 | 0 | |a Isotopieeffekt |0 (DE-588)4162585-7 |D s |
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| 700 | 1 | |a Vanhaecke, Frank |4 edt | |
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| 999 | |a oai:aleph.bib-bvb.de:BVB01-024507426 | ||
Datensatz im Suchindex
| _version_ | 1804148519982858240 |
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| adam_text | IMAGE 1
V
CONTENTS
PREFACE X V
LIST O F CONTRIBUTORS X I X
1 THE ISOTOPIC COMPOSITION O F THE ELEMENTS 1
FRANK VANHAECKE A N D KURT KYSER 1.1 ATOMIC STRUCTURE 1
1.2 ISOTOPES 2
1.3 RELATION BETWEEN ATOMIC STRUCTURE A N D NATURAL ABUNDANCE OF
ELEMENTS A N D ISOTOPES 3 1.4 NATURAL ISOTOPIC COMPOSITION O F THE
ELEMENTS 5
1.4.1 ELEMENTS WITH RADIOGENIC NUCLIDES 7
1.4.1.1 RADIOACTIVE DECAY 7
1.4.1.2 ELEMENTS WITH RADIOGENIC NUCLIDES 9 1.4.2 EFFECTS CAUSED BY NOW
EXTINCT RADIONUCLIDES 13 1.4.3 MASS-DEPENDENT ISOTOPE FRACTIONATION 13
1.4.3.1 ISOTOPE FRACTIONATION IN PHYSICAL PROCESSES 15
1.4.3.2 ISOTOPE FRACTIONATION IN CHEMICAL REACTIONS 16 1.4.4
MASS-INDEPENDENT ISOTOPE FRACTIONATION 20 1.4.5 INTERACTION O F COSMIC
RAYS WITH TERRESTRIAL MATTER 23 1.4.6 HUMAN-MADE VARIATIONS 24
REFERENCES 26
2 SINGLE-COLLECTOR INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY 31 FRANK
VANHAECKE 2.1 MASS SPECTROMETRY 31
2.2 THE INDUCTIVELY COUPLED PLASMA ION SOURCE 32
2.3 BASIC OPERATING PRINCIPLES O F MASS SPECTROMETERS 34
2.3.1 MASS SPECTROMETER CHARACTERISTICS 34
2.3.1.1 MASS RESOLUTION 34
ISOTOPIC ANALYSIS: F U N D A M E N T A L S A N D APPLICATIONS USING I C
P - M S , FIRST EDITION. EDITED BY F R A N K V A N H A E C K E A N D
PATRICK DEGRYSE. 2012 WILEY-VCH VERLAG G M B H & CO. KGAA, W E I N H E
I M . PUBLISHED 2012 BY WILEY-VCH VERLAG G M B H & CO. KGAA
HTTP://D-NB.INFO/1017774900
IMAGE 2
VI CONTENTS
2.3.1.2 ABUNDANCE SENSITIVITY 35
2.3.1.3 MASS SPECTRAL RANGE 36
2.3.1.4 SCANNING SPEED 36
2.3.2 QUADRUPOLE FILTER 36
2.3.3 DOUBLE-FOCUSING SECTOR FIELD MASS SPECTROMETER 38 2.3.4
TIME-OF-FLIGHT ANALYZER 43
2.3.5 COMPARISON O F CHARACTERISTICS 45
2.4 QUADRUPOLE-BASED ICP-MS 45
2.5 SAMPLE INTRODUCTION STRATEGIES IN ICP-MS 4 7
2.6 SPECTRAL INTERFERENCES 50
2.6.1 COOL PLASMA CONDITIONS 51
2.6.2 MULTIPOLE COLLISION/REACTION CELL 52
2.6.2.1 OVERCOMING SPECTRAL INTERFERENCE VIA CHEMICAL RESOLUTION 53
2.6.2.2 OVERCOMING SPECTRAL INTERFERENCE VIA COLLISIONAL DECELERATION A
N D KINETIC ENERGY DISCRIMINATION 5 5 2.6.3 HIGH MASS RESOLUTION WITH
SECTOR FIELD ICP-MS 55
2.7 MEASURING ISOTOPE RATIOS WITH SINGLE-COLLECTOR ICP-MS 56 2.7.1
ISOTOPE RATIO PRECISION 5 7
2.7.1.1 POISSON COUNTING STATISTICS 5 7
2.7.1.2 ISOTOPE RATIO PRECISION WITH SINGLE-COLLECTOR ICP-MS 5 8 2.7.2
DETECTOR ISSUES 62
2.7.2.1 ELECTRON MULTIPLIER OPERATING PRINCIPLES 62 2.7.2.2 DETECTOR
DEAD TIME 62
2.7.3 INSTRUMENTAL MASS DISCRIMINATION 66
REFERENCES 68
3 MULTI-COLLECTOR INDUCTIVELY COUPLED PLASMA
MASS SPECTROMETRY 7 7 MICHAEL WIESER, JOHANNES SCHWIETERS, A N D CHARLES
DOUTHITT 3.1 INTRODUCTION 77
3.2 EARLY MULTI-COLLECTOR MASS SPECTROMETERS 78
3.3 VARIABLE MULTI-COLLECTOR MASS SPECTROMETERS 79 3.4 MASS RESOLUTION
AND RESOLVING POWER 81
3.5 THREE-ISOTOPE PLOTS FOR MEASUREMENT VALIDATION 84
3.6 DETECTOR TECHNOLOGIES FOR MULTI-COLLECTION 87
3.7 CONCLUSION 90
REFERENCES 91
4 ADVANCES IN LASER ABLATION-MULTI-COLLECTOR INDUCTIVELY COUPLED PLASMA
MASS SPECTROMETRY 93 TAKAFUMI HIRATA 4.1 PRECISION O F ISOTOPE RATIO
MEASUREMENTS 93
4.2 STABLE SIGNAL INTENSITY PROFILES: WHY SO IMPORTANT? 94
4.3 SIGNAL SMOOTHING DEVICE 99
IMAGE 3
CONTENTS VII
4.4 MULTIPLE ION COUNTING 101
4.5 ISOTOPE FRACTIONATION DURING LASER ABLATION A N D
IONIZATION 102
4.6 STANDARDIZATION O F THE ISOTOPE RATIO DATA 107
ACKNOWLEDGMENTS 108 REFERENCES 108
5 CORRECTION O F INSTRUMENTAL MASS DISCRIMINATION FOR ISOTOPE RATIO
DETERMINATION WITH MULTI-COLLECTOR INDUCTIVELY COUPLED PLASMA MASS
SPECTROMETRY 113 JURIS MEIJA, LU YANG, ZOLTAN MESTER, AND RALPH E.
STURGEON 5.1 HISTORICAL INTRODUCTION 113
5.2 MASS BIAS IN MC-ICP-MS 114
5.3 SYSTEMATICS O F MASS BIAS CORRECTION MODELS 115
5.3.1 EXTERNAL GRAVIMETRIC CALIBRATION 116 5.3.2 INTERNAL DOUBLE-SPIKE
CALIBRATION 117 5.3.3 INTERNAL CALIBRATION (INTER-ELEMENT) 117 5.3.4
EXTERNAL BRACKETING CALIBRATION (INTER-ELEMENT) 117
5.4 LOGIC O F CONVENTIONAL CORRECTION MODELS 118
5.5 PITFALLS WITH SOME CORRECTION MODELS 119
5.5.1 LINEAR LAW 119
5.5.2 EXPONENTIAL VERSUS THE POWER LAW 120
5.6 INTEGRITY O F THE CORRECTION MODELS 120
5.6.1 RUSSELL S LAW 120
5.6.2 DISCRIMINATION EXPONENT 121
5.6.3 DISCRIMINATION FUNCTION 122
5.6.4 SECOND-ORDER TERMS 124
5.7 THE REGRESSION MODEL 124
5.8 CALIBRATION WITH DOUBLE SPIKES 126
5.8.1 CAVEAT O F THE MODEL CHOICE 129
5.9 CALIBRATION WITH INTERNAL CORRECTION 130
5.9.1 INTRA-ELEMENTAL CORRECTION 130
5.9.2 INTER-ELEMENTAL CORRECTION 130
5.10 UNCERTAINTY EVALUATION 131
5.10.1 UNCERTAINTY MODELING A N D THE DOUBLE SPIKES 132 5.11 CONCLUSION
133
REFERENCES 134
6 REFERENCE MATERIALS IN ISOTOPIC ANALYSIS 139
JOCHEN VOGL AND WOLFGANG PRITZKOW 6.1 INTRODUCTION 139
6.2 TERMINOLOGY 140
6.3 DETERMINATION O F ISOTOPE A M O U N T RATIOS 145
6.4 ISOTOPIC REFERENCE MATERIALS 149
IMAGE 4
VIII CONTENTS
6.4.1 GENERAL 149
6.4.2 HISTORICAL DEVELOPMENT 149
6.4.3 REQUIREMENTS FOR ISOTOPIC REFERENCE MATERIALS 151 6.5 PRESENT
STATUS, RELATED PROBLEMS, A N D SOLUTIONS 153
6.5.1 PRESENT STATUS 153
6.5.2 RELATED PROBLEMS 154
6.5.3 SOLUTION 156
6.6 CONCLUSION A N D OUTLOOK 157
REFERENCES 158
7 QUALITY CONTROL IN ISOTOPE RATIO APPLICATIONS 165
THOMAS MEISEL
7.1 INTRODUCTION 165
7.2 TERMINOLOGY A N D DEFINITIONS 168
7.3 MEASUREMENT UNCERTAINTY 174
7.3.1 INFLUENCE QUANTITIES 177
7.3.1.1 SAMPLING 177
7.3.1.2 SAMPLE PREPARATION 177
7.3.1.3 ISOTOPE A M O U N T RATIO DETERMINATION 177 7.3.1.4 DATA
PRESENTATION WITH ISOTOPE NOTATION 179 7.3.2 EXAMPLE O F UNCERTAINTY
BUDGET ESTIMATION W H E N USING ISOTOPE DILUTION 180
7.3.3 ALTERNATIVE APPROACH 181
7.3.4 HOW TO ESTABLISH METROLOGICAL TRACEABILITY 181 7.3.5 METHOD
VALIDATION 182
7.3.5.1 LIMITS O F DETECTION, O F DETERMINATION, AND O F QUANTITATION
182 7.3.5.2 INTER-LABORATORY STUDIES 184 7.4 CONCLUSION 185
REFERENCES 185
8 DETERMINATION O F TRACE ELEMENTS AND ELEMENTAL SPECIES
USING ISOTOPE DILUTION INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY 189
KLAUS C. N E U M A N N 8.1 INTRODUCTION 189
8.2 FUNDAMENTALS 190
8.2.1 PRINCIPLES O F ISOTOPE DILUTION MASS SPECTROMETRY 190 8.2.2
ELEMENTS ACCESSIBLE TO ICP-IDMS ANALYSIS 194 8.2.3 SELECTION O F SPIKE
ISOTOPE A N D OPTIMIZATION O F ITS A M O U N T 195 8.2.4 UNCERTAINTY
BUDGET A N D LIMIT O F DETECTION 199
8.3 SELECTED EXAMPLES O F TRACE ELEMENT DETERMINATION VIA ICP-IDMS 200
8.3.1 TRENDS IN ICP-IDMS TRACE ANALYSIS 200
IMAGE 5
CONTENTS | IX
8.3.2 DIRECT DETERMINATION O F TRACE ELEMENTS IN SOLID SAMPLES
VIA LASER ABLATION A N D ELECTROTHERMAL VAPORIZATION ICP-IDMS 201 8.3.3
REPRESENTATIVE EXAMPLES O F TRACE ELEMENT DETERMINATION VIA ICP-IDMS 203
8.3.3.1 DETERMINATION O F TRACE AMOUNTS O F SILICON IN BIOLOGICAL
SAMPLES 203
8.3.3.2 TRACE ELEMENT ANALYSIS O F FOSSIL FUELS 205 8.3.3.3 TRACE
ELEMENT ANALYSIS VIA ON-LINE PHOTOCHEMICAL VAPOR GENERATION 207 8.3.3.4
DETERMINATION O F TRACE AMOUNTS O F PLATINUM
GROUP ELEMENTS 208 8.3.3.5 DETERMINATION O F ULTRA-TRACE AMOUNTS O F
TRANSURANIUM ELEMENTS 211 8.3.4 ICP-IDMS IN ELEMENTAL SPECIATION 212
8.3.4.1 PRINCIPLES O F ICP-IDMS IN ELEMENTAL SPECIATION 212 8.3.4.2
SPECIES-SPECIFIC ICP-IDMS 214 8.3.4.3 SPECIES-UNSPECIFIC ICP-IDMS 221
REFERENCES 230
9 CEOCHRONOLOGICAL DATING 2 3 5
MARTINA A. ELBURG
9.1 GEOCHRONOLOGY: PRINCIPLES 235
9.1.1 SINGLE PHASE A N D ISOCHRON DATING 235
9.1.2 CLOSURE TEMPERATURE 237
9.2 PRACTICALITIES 240
9.2.1 ISOBARIC OVERLAP 240
9.2.2 ICP-MS VERSUS TIMS FOR GEOCHRONOLOGY 241 9.3 VARIOUS ISOTOPIC
SYSTEMS 242
9.3.1 U/TH-PB 242
9.3.1.1 LA-ICP-MS U - P B DATING O F ZIRCON 244 9.3.1.2 LASER ABLATION
U/TH-PB DATING O F OTHER PHASES 254 9.3.1.3 SOLUTION P B - P B DATING
257
9.3.2 L U - H F SYSTEM 257
9.3.2.1 L U - H F ISOCHRONS WITH GARNET 258
9.3.2.2 L U - H F O N PHOSPHATES 259
9.3.2.3 ZIRCON H F ISOTOPIC MODEL AGES 259 9.3.3 RE(-PT)-OS SYSTEM 261
9.3.3.1 RE-OS MOLYBDENITE DATING 262 9.3.3.2 RE-OS DATING O F BLACK
SHALES 262
9.3.3.3 PT-RE-OS ON MANTLE PERIDOTITES 263 9.4 SYSTEMS FOR WHICH ICP-MS
ANALYSIS BRINGS FEWER ADVANTAGES 265 ACKNOWLEDGMENTS 266
REFERENCES 266
IMAGE 6
X CONTENTS
1 0 APPLICATION O F MULTIPLE-COLLECTOR INDUCTIVELY COUPLED PLASMA
MASS SPECTROMETRY TO ISOTOPIC ANALYSIS IN COSMOCHEMISTRY 275 MARK
REHK AMPER, MARIA SCHDNBACHLER, AND RASMUS ANDREASEN 10.1 INTRODUCTION
275
10.2 EXTRATERRESTRIAL SAMPLES 276
10.2.1 INTRODUCTION 276
10.2.2 CLASSIFICATION O F METEORITES 277 10.2.3 CHONDRITIC METEORITES
279
10.2.4 NON-CHONDRITIC METEORITES 281 10.3 ORIGIN O F COSMOCHEMICAL
ISOTOPIC VARIATIONS 281 10.3.1 RADIOGENIC ISOTOPE VARIATIONS FROM THE
DECAY O F LONG-LIVED RADIOACTIVE NUCLIDES 282
10.3.2 RADIOGENIC ISOTOPE VARIATIONS FROM THE DECAY O F EXTINCT
RADIOACTIVE NUCLIDES 282 10.3.3 NUCLEOSYNTHETIC ISOTOPE ANOMALIES 283
10.3.4 MASS-DEPENDENT ISOTOPE FRACTIONATION 284 10.3.5 COSMOGENIC
ISOTOPE ANOMALIES 284
10.4 USE O F MC-ICP-MS IN COSMOCHEMISTRY 285
10.4.1 SPECIFIC ADVANTAGES O F MC-ICP-MS 286 10.4.2 ANALYTICAL
PROCEDURES 287
10.5 APPLICATIONS O F MC-ICP-MS IN COSMOCHEMISTRY 289 10.5.1
NUCLEOSYNTHETIC ISOTOPE ANOMALIES 289 10.5.2 LONG-LIVED RADIOACTIVE
DECAY SYSTEMS 293 10.5.2.1 THE 87RB-87SR DECAY SYSTEM 293
10.5.2.2 THE 147SM-143ND DECAY SYSTEM 293 10.5.2.3 THE 176LU-176HF DECAY
SYSTEM 294 10.5.2.4 THE U/TH-PB DECAY SYSTEMS 295 10.5.3 EXTINCT
RADIOACTIVE DECAY SYSTEMS 297
10.5.4 STABLE ISOTOPE FRACTIONATION 300
10.5.5 COSMOGENIC ISOTOPE VARIATIONS 306 10.6 CONCLUSION 307
ACKNOWLEDGMENTS 308 REFERENCES 308
11 ESTABLISHING THE BASIS FOR USING STABLE ISOTOPE RATIOS
O F METALS AS PALEOREDOX PROXIES 3 1 7 LAURA E. WASYLENKI 11.1
INTRODUCTION 317
11.2 ISOTOPE RATIOS O F METALS AS PALEOREDOX PROXIES 319
11.2.1 MOLYBDENUM ISOTOPE RATIOS A N D GLOBAL OCEAN PALEOREDOX 320
11.2.2 CR ISOTOPE RATIOS AND PALEOREDOX CONDITIONS O F THE ATMOSPHERE
329
IMAGE 7
CONTENTS XI
11.2.3 U R A N I U M ISOTOPE RATIOS A N D MARINE PALEOREDOX 338
11.3 DIAGENESIS: A CRITICAL AREA FOR FURTHER WORK 344
REFERENCES 346
12 ISOTOPES AS TRACERS O F ELEMENTS ACROSS T H E
GEOSPHERE-BIOSPHERE INTERFACE 351 KURT KYSER 12.1 DESCRIPTION O F THE
GEOSPHERE-BIOSPHERE INTERFACE 351 12.2 ELEMENTS THAT TYPIFY THE
GEOSPHERE-BIOSPHERE INTERFACE 354 12.3 MICROBES AT THE INTERFACE 355
12.4 ELEMENT TRACING IN ENVIRONMENTAL SCIENCE A N D EXPLORATION O F
METAL DEPOSITS 356 12.5 ISOTOPES AS INDICATORS O F PALEOENVIRONMENTS 360
12.6 TRACING THE GEOSPHERE EFFECT ON VEGETATION A N D ANIMALS 360 12.7
TRACING IN THE MARINE ENVIRONMENT 364
12.8 FUTURE DIRECTIONS 367
REFERENCES 368
13 ARCHEOMETRIC APPLICATIONS 373
PATRICK DEGRYSE
13.1 INTRODUCTION 373
13.2 CURRENT APPLICATIONS 375
13.2.1 LEAD 375
13.2.2 STRONTIUM 377
13.2.2.1 INORGANICS: GLASS A N D IRON 377 13.2.2.2 ORGANICS: SKELETAL
MATTER 378 13.2.3 NEODYMIUM 379
13.2.4 O S M I U M 379
13.3 NEW APPLICATIONS 380
13.3.1 COPPER 380
13.3.2 TIN 380
13.3.3 ANTIMONY 380
13.3.4 BORON 381
13.4 CONCLUSION 382
REFERENCES 382
14 FORENSIC APPLICATIONS 391
MARTIN RESANO A N D FRANK VANHAECKE 14.1 INTRODUCTION 391
14.1.1 WHAT IS FORENSICS? 391
14.1.2 THE ROLE O F ICP-MS IN FORENSICS 391
IMAGE 8
XII CONTENTS
14.2 FORENSIC APPLICATIONS BASED O N ICP-MS ISOTOPIC ANALYSIS 393
14.2.1 CRIME SCENE INVESTIGATION 393
14.2.2 NUCLEAR FORENSICS 396
14.2.3 FOOD AUTHENTICATION 399
14.2.4 MONITORING ENVIRONMENTAL POLLUTION 404 14.2.5 OTHER APPLICATIONS
408
14.3 FUTURE OUTLOOK 411
ACKNOWLEDGMENTS 412 REFERENCES 412
15 NUCLEAR APPLICATIONS 4 1 9
SCOTT C. SZECHENYI AND MICHAEL E. KETTERER 15.1 INTRODUCTION 419
15.2 RATIONALE 419
15.3 PROCESS CONTROL AND MONITORING IN THE NUCLEAR INDUSTRY 422
15.4 ISOTOPIC STUDIES O F THE DISTRIBUTION O F U A N D P U IN T H E
ENVIRONMENT 424
15.5 NUCLEAR FORENSICS 429
15.6 PROSPECTS FOR FUTURE DEVELOPMENTS 431
ACKNOWLEDGMENT 431 REFERENCES 432
16 THE U S E O F STABLE ISOTOPE TECHNIQUES FOR STUDYING MINERAL AND
TRACE ELEMENT METABOLISM IN HUMANS 4 3 5 THOMAS WALCZYK 16.1 ESSENTIAL
ELEMENTS 435
16.2 STABLE ISOTOPIC LABELS VERSUS RADIOTRACERS 436 16.3 QUANTIFICATION
O F STABLE ISOTOPIC TRACERS 438
16.4 ISOTOPE LABELING TECHNIQUES 442
16.5 CONCEPTS O F USING TRACERS I N STUDIES O F ELEMENT METABOLISM IN H
U M A N S 444
16.5.1 OVERVIEW 444
16.5.2 FECAL BALANCE STUDIES (SINGLE ISOTOPIC LABEL) 444 16.5.3 FECAL
BALANCE STUDIES (DOUBLE ISOTOPIC LABEL) 445 16.5.4 PLASMA APPEARANCE 446
16.5.5 URINARY MONITORING 447
16.5.6 COMPARTMENTAL MODELING 447
16.5.7 TISSUE RETENTION 448
16.5.8 ELEMENT TURNOVER STUDIES 449
16.5.9 ISOTOPE FRACTIONATION EFFECTS 450 16.6 ICP-MS IN STABLE
ISOTOPE-BASED METABOLIC STUDIES 451 16.6.1 MEASUREMENT PRECISION 451
16.6.2 MASS SPECTROMETRIC SENSITIVITY 454
IMAGE 9
CONTENTS XIII
16.6.3 MEASUREMENT ACCURACY A N D QUALITY CONTROL 454
16.7 ELEMENT-BY-ELEMENT REVIEW 458
16.7.1 CALCIUM 458
16.7.2 IRON 462
16.7.3 ZINC 464
16.7.4 MAGNESIUM 469
16.7.5 SELENIUM 471
16.7.6 COPPER 474
16.7.7 MOLYBDENUM 476
ACKNOWLEDGMENTS 477 REFERENCES 478
17 ISOTOPIC ANALYSIS VIA MULTI-COLLECTOR INDUCTIVELY COUPLED PLASMA MASS
SPECTROMETRY IN ELEMENTAL SPECIATION 4 9 5 VLADIMIR N. EPOV, SYLVAIN
BERAIL, CHRISTOPHE PECHEYRAN, DAVID AMOUROUX, A N D OLIVIER F.X. DONARD
17.1 INTRODUCTION 495
17.2 ADVANTAGE O F ON-LINE VERSUS OFF-LINE SEPARATION O F ELEMENTAL
SPECIES 497
17.3 COUPLING CHROMATOGRAPHY WITH MC-ICP-MS 498 17.3.1 INSTRUMENTATION:
LC, GC, HPLC, AND IC COUPLED WITH MC-ICP-MS 498 17.3.1.1 LIQUID
CHROMATOGRAPHY 500
17.3.1.2 GAS CHROMATOGRAPHY 500 17.3.2 ACQUISITION, MASS BIAS
CORRECTION, AND DATA TREATMENT STRATEGY 503 17.3.2.1 SIGNAL ACQUISITION
503
17.3.2.2 MASS BIAS CORRECTION 504 17.3.2.3 DATA TREATMENT STRATEGY 504
17.3.3 CONSEQUENCES O F THE TRANSIENT NATURE O F THE SIGNAL 507 17.3.3.1
SHAPE A N D WIDTH O F THE PEAK 507
17.3.3.2 DRIFT O F THE ISOTOPE RATIOS DURING PEAK ELUTION 507 17.4
ENVIRONMENTAL A N D OTHER APPLICATIONS 509
17.4.1 MERCURY 509
17.4.2 LEAD 511
17.4.3 SULFUR 511
17.4.4 ANTIMONY 512
17.4.5 HALOGENS 512
17.5 CONCLUSION A N D FUTURE TRENDS 513
REFERENCES 515
INDEX 5 1 9
|
| any_adam_object | 1 |
| author2 | Vanhaecke, Frank |
| author2_role | edt |
| author2_variant | f v fv |
| author_facet | Vanhaecke, Frank |
| building | Verbundindex |
| bvnumber | BV039657925 |
| classification_rvk | VG 9800 VK 5640 |
| classification_tum | CHE 254f PHY 115f PHY 541f |
| ctrlnum | (OCoLC)755072996 (DE-599)BVBBV039657925 |
| dewey-full | 541.388 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.388 |
| dewey-search | 541.388 |
| dewey-sort | 3541.388 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| format | Book |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV039657925 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:08:26Z |
| institution | BVB |
| isbn | 9783527328963 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-024507426 |
| oclc_num | 755072996 |
| open_access_boolean | |
| owner | DE-703 DE-11 DE-91G DE-BY-TUM DE-92 DE-29 |
| owner_facet | DE-703 DE-11 DE-91G DE-BY-TUM DE-92 DE-29 |
| physical | XXI, 529 S. graph. Darst. |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Isotopic analysis fundamentals and applications using ICP-MS ed. by Frank Vanhaecke ... Weinheim Wiley-VCH 2012 XXI, 529 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Isotopes Inductively coupled plasma mass spectrometry Isotopenhäufigkeit (DE-588)4162584-5 gnd rswk-swf Isotopieeffekt (DE-588)4162585-7 gnd rswk-swf ICP-Massenspektrometrie (DE-588)4280345-7 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Isotopenhäufigkeit (DE-588)4162584-5 s ICP-Massenspektrometrie (DE-588)4280345-7 s DE-604 Isotopieeffekt (DE-588)4162585-7 s Vanhaecke, Frank edt Erscheint auch als Online-Ausgabe, EPUB 978-3-527-65050-7 Erscheint auch als Online-Ausgabe, PDF 978-3-527-65051-4 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024507426&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Isotopic analysis fundamentals and applications using ICP-MS Isotopes Inductively coupled plasma mass spectrometry Isotopenhäufigkeit (DE-588)4162584-5 gnd Isotopieeffekt (DE-588)4162585-7 gnd ICP-Massenspektrometrie (DE-588)4280345-7 gnd |
| subject_GND | (DE-588)4162584-5 (DE-588)4162585-7 (DE-588)4280345-7 (DE-588)4143413-4 |
| title | Isotopic analysis fundamentals and applications using ICP-MS |
| title_auth | Isotopic analysis fundamentals and applications using ICP-MS |
| title_exact_search | Isotopic analysis fundamentals and applications using ICP-MS |
| title_full | Isotopic analysis fundamentals and applications using ICP-MS ed. by Frank Vanhaecke ... |
| title_fullStr | Isotopic analysis fundamentals and applications using ICP-MS ed. by Frank Vanhaecke ... |
| title_full_unstemmed | Isotopic analysis fundamentals and applications using ICP-MS ed. by Frank Vanhaecke ... |
| title_short | Isotopic analysis |
| title_sort | isotopic analysis fundamentals and applications using icp ms |
| title_sub | fundamentals and applications using ICP-MS |
| topic | Isotopes Inductively coupled plasma mass spectrometry Isotopenhäufigkeit (DE-588)4162584-5 gnd Isotopieeffekt (DE-588)4162585-7 gnd ICP-Massenspektrometrie (DE-588)4280345-7 gnd |
| topic_facet | Isotopes Inductively coupled plasma mass spectrometry Isotopenhäufigkeit Isotopieeffekt ICP-Massenspektrometrie Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024507426&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT vanhaeckefrank isotopicanalysisfundamentalsandapplicationsusingicpms |