Chemical sensors: 3 Fundamentals of sensing materials: polymers and other materials
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York
Momentum Press
2010
|
| Ausgabe: | 1. ed. |
| Schriftenreihe: | Sensors technology series
Sensor technology series |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIX, 382 S. Ill., graph. Darst. |
| ISBN: | 1606502301 9781606502303 |
Internformat
MARC
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| 020 | |a 1606502301 |9 1-60650-230-1 | ||
| 020 | |a 9781606502303 |9 978-1-60650-230-3 | ||
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| 245 | 1 | 0 | |a Chemical sensors |n 3 |p Fundamentals of sensing materials: polymers and other materials |c ed. by Ghenadii Korotcenkov |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a New York |b Momentum Press |c 2010 | |
| 300 | |a XIX, 382 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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Datensatz im Suchindex
| _version_ | 1804147987886112768 |
|---|---|
| adam_text | Contents
Preface to Chemical Sensors: Fundamentals of Sensing Materials
xi
Preface to Volume
3:
Polymers and Other Materials
xiii
About the Editor
xv
Contributors
xvii
1
Polymers in Chemical Sensors
1
B. Adhikari
P.
Kar
1
Introduction
1
2
What Are Polymers?
3
3
Parameters of Polymers Promising for Chemical Sensor Application
4
4
Synthesis of Polymers
7
5
Deposition of Polymers
9
6
Functionalization of Polymers
13
6.1
Structure Modification
13
6.2
Surface Modification
14
6.3
Composition Modification
15
7
Polymers in Chemical Sensors
16
7.1
Optical and Fiber Optic Polymer-Based Sensors
20
7.2
Conductometric Gas Sensors
27
7.3
SAW and QCM Polymer-Based Sensors
40
7.4
Electrochemical Polymer-Based Sensors
45
7.5
Chemically Sensitive FET-Based Sensors
57
8
Outlook
61
9
Acknowledgments
61
References
62
vi
.
CONTENTS
Molecular
Imprinting (Templating)
—
A Promising Approach for Design
of Polymer-Based Chemical Sensors
77
G. Korotcenkov
B. K. Cho
1
Introduction
77
2
General Principles of Molecular Imprinting (Templating)
79
3
Methods of Imprinting (Templating)
80
3.1
In-Block Imprinted Polymers
80
3.2
In Situ Imprinted Polymers
82
3.3
Polymer-Imprinted Beads
82
4
Components of Imprinting Technology
83
4.1
Target Molecules
83
4.2
The Imprinting Matrix
85
4.3
Cross-Linkers
86
4.4
Solvents
(Porogens)
88
4.5
Initiators
89
5
МІР
Preparation Methods
89
6
Combination of MIPs and Monomolecular Host Molecules
91
7
Control of the Imprinting Effect
92
8
Application of Imprinting Polymers in Chemical Sensors
92
8.1
Advantages of MIP-Based Chemical Sensors
92
8.2
Detection Principles Used in
МІР
Chemical Sensors
93
8.3
Interfacing the
МІР
with the Transducer
99
8.4
Factors Controlling the Sensing Characteristics of MIPs-Based
Chemical Sensors
101
8.5
Micro- and Nanofabricated MIPs
103
9
Outlook
106
10
Acknowledgments
108
References
109
Calkarene-Based Materials for Chemical Sensors
117
H. M. Chawla
N.
Pant
S. Kumar
D. StC. Bkck
N.
Kumar
1
Introduction
117
CONTENTS
·
vii
2
Molecular
Receptors and Generation of Signal for Sensing Target Species
119
3
Calixarenes and Thiacalixarenes
120
4
Synthesis of
Са1іх[и]
arenes
123
4.1
Base-Catalyzed Condensation Reactions
123
4.2
Acid-Catalyzed Condensation Reactions
124
5
Synthesis of Thiacalix
[и]
arenes
(Sulfur-Bridged Calixarenes)
124
6
Physical Properties of Calixarenes and Tetrathiacalixarenes
127
6.1
Melting points
127
6.2
Solubilities and pKa Values
127
7
Spectral Properties and Characterization of Calixarenes
128
7.1
Infrared Spectra
128
7.2
Ultraviolet Spectra
128
7.3
NMR Spectra
129
8
Conformational Structures of Calixarenes and Thiacalixarenes
129
9
Conformational Characterization of Calixfwjarenes
132
10
Calixarenes as Materials for Chemical Sensors
132
11
Calixarene-Based Materials for Recognition of Alkali and Alkaline Earth
Metal Ions
133
12
Calixarene-Based Materials for Recognition of Transition and Heavy-
Metal Ions
137
13
Calixarene-Based Materials as Dual Probes for Sensing and Extraction
139
14
Calixarene-Based Materials for Sensing
Lanthanides
and Actinides
139
15
Sensor Materials Based on Polymeric Calixarenes
143
16
Naked-Eye Sensing: Calixarene-Based Chromogenic Materials for Sensing
Ions and Molecules
143
17
Calixarene-Based Electroactive Sensing Materials
156
18
Calixarene-Based Materials for Sensing Anions
161
18.1
Calixarene-Based Electron-Deficient or Positively Charged
Anion
Receptors
161
18.2
Calixarene-Based Neutral
Anion
Receptors
165
18.3
Calixarene-Based Ditopic Molecular Receptors
175
19
Calixarene-Based Sensor Materials for Neutral Molecules and Biological
Amines
176
20
Calixarene-Based Materials for Gas Sensors
179
21
Outlook
181
viii
· CONTENTS
22 Acknowledgments 181
References
182
4
Biological and Biomimetic Systems in Chemical Sensors
201
Я
Jelinek
S.
Kolusbeva
1
Introduction
201
2 Polymers and Polymer/Biomolecule
Assemblies
202
2.1
Conductive
Polymers 202
2.2
Luminescent Conjugated Polymers
205
3
Membranes in Chemical Sensors
210
3.1
Chemical Membranes
210
3.2
Biological Membranes
213
4
Biomimetic Systems for Molecular and Ionic Recognition
219
4.1
Biological Receptors and Channels
219
4.2
Synthetic Receptors
221
4.3
Biomimetic Enzyme-Based Sensors
223
4.4
Nanobiosensors
225
4.5
Other Biomimetic Sensors
232
5
Monolayers and Films
242
5.1
Self-Assembled Monolayers
242
5.2
Langmuir-Blodgett Films
244
6
Challenges and Limitations of Biosensors
247
7
Conclusions and Outlook
248
References
248
5
Novel Semiconductor Materials for the
Development
of Chemical Sensors
263
N.
Chaniotakis
N.
Sofikiti
V Vamvakaki
1
Introduction
263
2
The Silicon Era
—
Classical Semiconductors in Chemical Sensing
265
3
Fundamentals of Sensor Development
269
4
Surface Chemistry of Semiconductors in Chemical Sensing
269
5
Band Gap Theory and Its Relationship to Sensor Design
271
6
Pinning of the Surface Fermi Level
272
CONTENTS · ix
7 New Semiconductor Substrates 273
7.1 Diamond 274
7.2 Silicon Carbide 277
7.3 Gallium Nitride and HI-Nitrides 279
8
Nanosemiconductor Structures
in Chemical Sensors 281
9
Forecasting the Future
283
References
284
6
Ion Conductors and Their Applications in Chemical Sensors
291
R
V.Kumar
C. Schwandt
1
Introduction
291
1.1
Solid Electrolytes
292
1.2
Chemical Sensors
293
2
Ionic Conduction in Solids
294
3
Oxygen Ion—Conducting Solid Electrolytes
296
3.1
Zirconia-Based Solid Electrolytes
297
3.2
Defect Chemistry of Stabilized Zirconia
304
3.3
Preparation of Stabilized Zirconia
305
3.4
Oxygen Sensors Based on Stabilized Zirconia
308
4
Proton-Conducting Solid Electrolytes
319
4.1
High-Temperature Proton-Conducting Solid Electrolytes
319
4.2
Defect Chemistry of Substituted Perovskites
320
4.3
Preparation of Substituted Perovskites
323
4.4
Hydrogen Sensors Based on Substituted Perovskites
324
4.5
Low-Temperature Proton-Conducting Solid Electrolytes
330
5
Metal Ion-Conducting Solid Electrolytes
332
5.1
Defect Chemistry and Preparation of
ß-Aluminas 332
5.2
Sensors Based on
ß-Aluminas 337
6
Outlook and Future Trends
343
References
344
7
Sensor Materials: Selection Guide
351
G. Korotcenkov
1
Acceptable Materials for Chemical Sensors
351
2
Which Metal Oxides Are Better for Gas Sensors?
358
χ
·
CONTENTS
3
Choosing a Polymer for a Chemical Sensor Application
362
4
Technological Limitations in Sensing Material Applications
362
5
Future Trends
363
6
Toward a Theory of Chemical Sensors
368
7
Summary
370
8
Acknowledgments
370
References
370
|
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| illustrated | Illustrated |
| indexdate | 2024-07-09T23:59:58Z |
| institution | BVB |
| isbn | 1606502301 9781606502303 |
| language | English |
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| spelling | Korotcenkov, Ghenadii Verfasser aut Chemical sensors 3 Fundamentals of sensing materials: polymers and other materials ed. by Ghenadii Korotcenkov 1. ed. New York Momentum Press 2010 XIX, 382 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Sensors technology series Sensor technology series (DE-604)BV039146504 3 Erscheint auch als Online-Ausgabe 1-60650-232-8 Erscheint auch als Online-Ausgabe 978-1-60650-232-7 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024164443&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Korotcenkov, Ghenadii Chemical sensors |
| title | Chemical sensors |
| title_auth | Chemical sensors |
| title_exact_search | Chemical sensors |
| title_full | Chemical sensors 3 Fundamentals of sensing materials: polymers and other materials ed. by Ghenadii Korotcenkov |
| title_fullStr | Chemical sensors 3 Fundamentals of sensing materials: polymers and other materials ed. by Ghenadii Korotcenkov |
| title_full_unstemmed | Chemical sensors 3 Fundamentals of sensing materials: polymers and other materials ed. by Ghenadii Korotcenkov |
| title_short | Chemical sensors |
| title_sort | chemical sensors fundamentals of sensing materials polymers and other materials |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024164443&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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