Polymer electrolytes: fundamentals and applications
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Oxford [u.a.]
Woodhead Publ.
2010
|
| Ausgabe: | 1. publ. |
| Schriftenreihe: | Woodhead Publishing in materials
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | XVI, 623 S. Ill., graph. Darst. |
| ISBN: | 9781845697723 |
Internformat
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| 245 | 1 | 0 | |a Polymer electrolytes |b fundamentals and applications |c ed. by César Sequeira and Diogo Santos |
| 250 | |a 1. publ. | ||
| 264 | 1 | |a Oxford [u.a.] |b Woodhead Publ. |c 2010 | |
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Datensatz im Suchindex
| _version_ | 1804145680634085376 |
|---|---|
| adam_text | Contents
Contributor contact details
xi
Preface
xv
Part I Types and development of polymer electrolytes
1
1
Introduction to polymer electrolyte materials
3
С. А. С
Sequeira
and D.
Μ. Ε
Santos, Technical
University of Lisbon, Portugal
1.1
Introduction
3
1.2
Categories of polymer electrolytes
5
1.3
Structure and its implications
17
1.4
Conductivity measurements
20
1.5
Applications in practical devices
39
1.6
Conclusions
51
1.7
References
52
2
Ceramic polymer electrolytes
62
J. S. Syzdek, Warsaw University of Technology, Poland
2.1
Introduction
62
2.2
Experimental approaches
67
2.3
First composites
-
conductive fillers
70
2.4
Development of insulating fillers
72
2.5
Impact of the filler surface on the transport properties
75
2.6
Interfacial
concerns
77
2.7
Other types of ceramic-polymer systems
80
2.8
Conclusions
82
2.9
Acknowledgements
83
2.10
References
84
©
Woodhead Publishing Limited,
2010
vi
Contents
3
Polymer electrolytes based on natural polymers
95
A. Pawlicka and J. P.
Donoso,
Universidade de São
Paulo,
Brazil
3.1
Introduction
95
3.2
Grafted natural polymer-based solid polymer electrolytes
97
3.3
Plasticized natural polymer-based solid polymer
electrolytes
103
3.4
Other natural polymer-based systems
110
3.5
Magnetic resonance spectroscopy of polymer electrolytes
obtained from natural polymers
112
3.6
Conclusions and future trends
123
3.7
References
124
4
Composite polymer electrolytes for electrochemical
devices
129
F. Alloin and
С
Iojoiu, LEPMI
CNRS,
Grenoble
Institute of Technology, France
4.1
Introduction
129
4.2
Composite electrolytes for lithium batteries: introduction
130
4.3
Solid polymer electrolytes
131
4.4
Composite polymer electrolytes based on poly(ethylene
oxide) and clays
132
4.5
Composite polymer electrolytes based on poly(ethylene
oxide) and non-ionic fillers
137
4.6
Gel polymer electrolytes
148
4.7
Composite electrolytes for proton exchange membrane
fuel cells
151
4.8
Composite polymer electrolytes based on metal oxides
156
4.9
Hygroscopic solid inorganic proton conductor composite
polymer electrolytes
160
4.10
Self-humidifying composite electrolytes
164
4.11
Future trends
166
4.12
Sources of further information and advice
167
4.13
References
168
5
Lithium-doped hybrid polymer electrolytes
176
V.
de Zea Bermudez,
University of
Trás-os-Montes e
Alto Douro, Portugal, and M. M. Silva,
University of
Minho, Portugal
5.1
Introduction
176
5.2
Ionic conductivity
178
5.3
Thermal properties
182
5.4
Electrochemical stability
184
©
Woodhead Publishing Limited,
2010
Contents
vii
5.5
Spectroscopic
studies
185
5.6
Electrochromic
displays
207
5.7
Conclusion
209
5.8
References
210
6
Hybrid inorganic-organic polymer electrolytes
219
V.
di Noto, E. Negro and
S.
Lavina,
University of
Padova,
Italy, and M. Vittadello, City University
of New York, USA
6.1
Introduction
219
6.2
Fundamentals of polymer electrolytes
220
6.3
Overview of hybrid inorganic-organic polymer electrolytes
221
6.4
Methods
254
6.5
The real component of the conductivity spectra in the
framework of the jump relaxation model and polymer
segmental
motion
266
6.6
Conclusions
272
6.7
Acknowledgements
273
6.8
References
273
7
Using nuclear magnetic resonance spectroscopy
in polymer electrolyte research
278
S. Abbrent, University of South Bohemia, Czech Republic,
and S. Greenbaum, Hunter College of the City University
of New York, USA
7.1
Introduction
278
7.2
Nuclei possibility
279
7.3
Liquid state nuclear magnetic resonance
281
7.4
Solid state nuclear magnetic resonance
282
7.5
Relaxation processes
291
7.6
Diffusion measurements
295
7.7
Magic angle spinning
299
7.8
Double resonance experiments
300
7.9
Two-dimensional methods
304
7.10
Exchange nuclear magnetic resonance
305
7.11
Electrophoretic nuclear magnetic resonance
307
7.12
Conclusions
308
7.13
References
309
8
Molecular dynamics simulations of Li ion and
H-conduction in polymer electrolytes
314
D. Brandell, Uppsala University, Sweden
8.1
Introduction
314
©
Woodhead Publishing Limited,
2010
viii Contents
8.2
Computational chemistry
315
8.3
The molecular dynamics methodology
316
8.4
L^-conducting poly(ethylene oxide)-based electrolytes
for batteries
325
8.5
Polymer electrolytes for fuel cells: perfluorosulphonic
acid systems
329
8.6
Conclusions and future trends
336
8.7
References
337
9
Characterisation and modelling of multivalent
polymer electrolytes
340
M. J. C.
Plancha,
Laboratório Nacional de Energia
e
Geologia,
Portugal
9.1
Introduction
340
9.2
Polymer-complex formation
342
9.3
Ionic transport properties
344
9.4
Morphological and crystallographic structures:
characteristics and influence on ionic transport
properties
358
9.5
Ionic association: influence on ionic transport
properties
365
9.6
Phase diagrams: crystallinity and conductivity
367
9.7
Conclusions
373
9.8
References
373
Part II Applications
379
10
Polymer electrolytes for dye-sensitized solar
cells
381
J.
N.
de Freitas,
J.
E. Benedetti,
F. S.
Freitas,
A. F.
Nogueira
and M. A. de Paoli,
University of
Campinas
- UNICAMP,
Brazil
10.1
Introduction
381
10.2
Polymer electrolytes
384
10.3
Plasticized and gel polymer electrolytes
390
10.4
Additives in the polymer electrolytes
402
10.5
Stability of polymer electrolyte-based dye-sensitized
solar cells
417
10.6
Up-scaling: towards commercialization of polymer
electrolyte-based dye-sensitized solar cells
421
10.7
Conclusions and future trends
423
10.8
Acknowledgements
424
10.9
References
424
©
Woodhead Publishing Limited,
2010
Contents
їх
11
Solid polymer electrolytes for supercapacitors
431
A. B.
Samui
and P.
Sivaraman,
Naval Materials Research
Laboratory, India
11.1
Introduction
431
11.2
Solid electrolytes
432
11.3
Conduction in solid electrolytes
433
11.4
Solid electrolytes in supercapacitors
439
11.5
Conducting polymer electrodes
442
11.6
Activated carbon electrodes
447
11.7
Cation exchange membrane-based supercapacitors
451
11.8
Current research activities
456
11.9
Applications
463
11.10
Conclusions
463
11.11
List of abbreviations
464
11.12
References
466
12
Polymer electrolytes for electrochromic devices
471
X.
Fu,
College of Chemistry and Chemical Engineering
Southwest University, P.R. China
12.1
Introduction
471
12.2
Electrochromic effect and electrochromic devices
472
12.3
Electrolytes for electrochromic devices
474
12.4
Polymer matrix
475
12.5
Classification of polymer electrolytes
477
12.6
Proton-conducting polymer electrolytes and alkaline
polymer electrolytes
500
12.7
New type of polymer electrolyte
506
12.8
References
513
13
Hyperbranched polymer electrolytes for high
temperature fuel cells
524
T.
Ітон,
Mie
University, Japan
13.1
Introduction
524
13.2
Hyperbranched polymer electrolytes with a sulfonic acid
group at the periphery
525
13.3
Hyperbranched polymer electrolyte with a phosphonic
acid group at the periphery
537
13.4
Conclusions
547
13.5
References
548
14
Polymer electrolytes as solid solvents and their
applications
550
L. Ye and Z. Feng, Beijing Institute of Technology, China
14.1
Introduction
550
©
Woodhead Publishing Limited,
2010
χ
Contents
14.2
Structure
of
lithium ion
battery
552
14.3
Advantages of polymer electrolytes in lithium ion
batteries
552
14.4
Main properties of polymer electrolytes
554
14.5
Solid polymer electrolytes applied in lithium ion batteries
557
14.6
Gel polymer electrolytes in lithium ion batteries
566
14.7
Composite polymer electrolytes in lithium ion batteries
570
14.8
Polymer electrolytes in other battery types
572
14.9
Conclusions
577
14.10
Acknowledgments
578
14.11
References
578
15
Hybrid polymer electrolytes for electrochemical
devices
583
F. L.
de Souza,
Federal University of ABC, Brazil,
and E. R.
Leite,
Federal University of
São
Carlos, Brazil
15.1
Introduction
583
15.2
Physicochemical properties of hybrid polyelectrolytes
587
15.3
General discussion
595
15.4
Applications
596
15.5
Conclusions
598
15.6
Acknowledgments
599
15.7
References
599
Index
603
©
Woodhead Publishing Limited,
2010
WOODHEAD PUBLISHING IN
Polymer electrolytes are electrolytic materials that are widely used in batteries,
fuel cells and other applicationssuch as supercapacitors, and photoelectrochemical
and electrochromic devices. Polymer electrolytes: fundamentals and applications
provides an important review of this class of ionic conductors, their properties
and applications.
Part I reviews the various types of polymer electrolyte compounds, with chapters
on ceramic polymer electrolytes, natural polymer-based polymer electrolytes,
composite polymer electrolytes, lithium-doped hybrid polymer electrolytes, and
hybrid inorganic-organic polymer electrolytes. There are also chapters on ways of
characterising and modelling polymer electrolytes. Part II discusses applications
such as solar cells, supercapacitors, electrochromic and electrochemical devices,
fuel cells and batteries.
With its distinguished editors and international team of contributors, Polymer
electrolytes: fundamentals and applications will be a standard reference tool for all
those researching and using polymer electrolytes in such areas as battery and fuel
cell technology for automotive and other applications.
Dr César
Sequeira
and
Dr Diogo
Santos both work in the Department of
Chemical and Biological Engineering at the prestigious
Instituto
Superior
Técnico
in the Technical University of Lisbon, Portugal. Both are internationally known for
their research on the electrochemical properties of materials.
Woodhead Publishing Limited
Abington Hall,
Cranta
Park
Great Abington
Cambridge CB21 6AH
UK
www.woodheadpublishing.com
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| spelling | Polymer electrolytes fundamentals and applications ed. by César Sequeira and Diogo Santos 1. publ. Oxford [u.a.] Woodhead Publ. 2010 XVI, 623 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Woodhead Publishing in materials Polyelectrolytes Polyelektrolyt (DE-588)4175165-6 gnd rswk-swf Polyelektrolyt (DE-588)4175165-6 s DE-604 Sequeira, César A. C. 1943- Sonstige (DE-588)121454592 oth Erscheint auch als Online-Ausgabe 978-1-84569-977-2 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=022544247&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=022544247&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
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| subject_GND | (DE-588)4175165-6 |
| title | Polymer electrolytes fundamentals and applications |
| title_auth | Polymer electrolytes fundamentals and applications |
| title_exact_search | Polymer electrolytes fundamentals and applications |
| title_full | Polymer electrolytes fundamentals and applications ed. by César Sequeira and Diogo Santos |
| title_fullStr | Polymer electrolytes fundamentals and applications ed. by César Sequeira and Diogo Santos |
| title_full_unstemmed | Polymer electrolytes fundamentals and applications ed. by César Sequeira and Diogo Santos |
| title_short | Polymer electrolytes |
| title_sort | polymer electrolytes fundamentals and applications |
| title_sub | fundamentals and applications |
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