Strategies for the immobilization of transition metal complexes on various carrier materials and their catalytic application:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
München
Verl. Dr. Hut
2011
|
| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Anorganische Chemie
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 175 S. Illustrationen, Diagramme |
| ISBN: | 9783868537703 |
Internformat
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| 245 | 1 | 0 | |a Strategies for the immobilization of transition metal complexes on various carrier materials and their catalytic application |c Christian Erich Fischer |
| 250 | |a 1. Aufl. | ||
| 264 | 1 | |a München |b Verl. Dr. Hut |c 2011 | |
| 300 | |a 175 S. |b Illustrationen, Diagramme | ||
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Datensatz im Suchindex
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|---|---|
| adam_text | IMAGE 1
INDEX
INDEX
I. INTRODUCTION 1
1 . SUPPORT MATERIALS - AN OVERVIEW 3
1.1 SILICEOUS SUPPORT MATERIALS 3
1.2 POLYMERIC SUPPORT MATERIALS 6
1.3 NANOTUBES AS SUPPORT MATERIALS 7
1.4 METAL-ORGANIC FRAMEWORKS (MOFS) AND ZEOLITES AS SUPPORT MATERIALS 8
2. IMMOBILIZATION OF NITRILE LIGATED TRANSITION-METAL COMPLEXES 11
2.1 NITRILE LIGATED TRANSITION-METAL COMPLEXES 11
2.2 IMMOBILIZATION METHODS 14
3. CATALYSTS FOR THE POLYMERIZATION OF ISOBUTENE 17
3.1 INDUSTRIAL PRODUCTION AND PROPERTIES OF POLYISOBUTENE 17
3.2 NITRILE LIGATED TRANSITION-METAL COMPLEXES AS HOMOGENEOUS CATALYSTS
FOR THE
POLYMERIZATION OF ISOBUTENE 17
3.3 SUPPORTED NITRILE LIGATED TRANSITION-METAL COMPLEXES AS CATALYSTS
FOR ISOBUTENE
POLYMERIZATION 18
4. OBJECTIVES OF THIS WORK 18
5. REFERENCES 19
II. IMMOBILIZATION OF TRANSITION METAL COMPLEXES BEARING WEAKLY
COORDINATING
ANIONS AS CATALYSTS FOR THE POLYMERIZATION OF ISOBUTENE 25
1. IMMOBILIZATION STRATEGIES FOR MCM-41 27
1.1 DIRECT ANCHORING OF THE WCA ONTO THE SUPPORT 27
1.1.1 SYNTHESIS OF MCM41-BCU AND MCM41-BCE 27
1.1.2 CATALYTIC RESULTS OF MCM41-BCU AND MCM41-BCE 28
1.1.3 STRUCTURAL CHARACTERIZATION OF MCM41-BCU AND MCM41-BCE 31
1.1.4 CONCLUSION 38
1.2 ANCHORING OF THE WCA ONTO THE SUPPORT USING A LINKER MOLECULE 38
1.2.1 SYNTHESIS OF MCM41-LAB-CUL AND MCM41-LAB-CU2 38
1.2.2 RESULTS AND DISCUSSION OF MCM41-LAB-CUL AND MCM41-LAB-CU2 40
1.2.3 LAB-[CU(PHCN) 5][B(C6F5)4]2 - A HOMOGENEOUS MODEL CATALYST 40
1.2.4 CONCLUSION 41
2. MODIFICATION OF SILSESQUIOXANE STRUCTURES 42
3. IMMOBILIZATION ON POLYMERIC SUPPORT MATERIALS 43
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1010075349
DIGITALISIERT DURCH
IMAGE 2
INDEX
3.1 IMMOBILIZATION ON WANG RESIN 44
3.2 IMMOBILIZATION ON POLY(VINYL ALCOHOL) (PVA) 44
3.3 IMMOBILIZATION ON POLY(ETHYL VINYL ETHER) (PEVE) 45
3.4 IMMOBILIZATION ON POLY(ETHYL ACRYLATE) (PEA) 46
3.5 CONCLUSION 47
4. CREATION OF METAL ORGANIC FRAMEWORKS (MOF) AS CATALYSTS 47
5. OTHER HETEROGENEOUS CATALYSTS 5
6. EXPERIMENTAL 52
7. REFERENCES *
M. SYNTHESIS AND CHARACTERIZATION OF BENZONITRILE LIGATED TRANSITION
METAL COMPLEXES
[M(PHCN) 6][B(C6F5)4]2 (M = MN-CO) AND [M(PHCN)5][B(C6F5)4]2
(M = NI-ZN) AS CATALYSTS FOR THE HOMOPOLYMERIZATION OF ISOBUTENE 61
1. BACKGROUND 3
2. RESULTS AND DISCUSSION 64
2.1 SYNTHESIS OF COMPOUNDS [M(PHCN)6]TB(C 6F5)4]2 (M = MN (1), FE (2)
AND CO (3))
AND [M(PHCN) 5][B(C6F5)4]2 (M = NI (4), CU(5), ZN (6)) 64
2.2 SPECTROSCOPIC ANALYSIS 64
2.3 THERMOGRAVIMETIC ANALYSIS 66
2.4 X-RAY STRUCTURE ANALYSIS OF [CU(PHCN) 5][B(C6F5)4]2 (5) 67
3. HOMOPOLYMERIZATION OF ISOBUTENE WITH COMPOUNDS 1-6 68
4. CONCLUSION 70
5. OUTLOOK 72
6. EXPERIMENTAL 73
6.1 MEASUREMENTS AND PREPARATION 73
6.2 GENERAL SYNTHESIS OF [M(PHCN) 6][B(C6F5)4]2 (M = MN (1), FE (2) AND
CO (3)) AND
[M(PHCN) 5] [B(C6F5)4]2 (M = NI (4) AND ZN (6)) 74
7. REFERENCES 75
IV. ORGANIC-INORGANIC NANOTUBE HYBRIDS: ORGANOSILICA-NANOTUBES
CONTAINING
ETHANE, ETHYLENE AND ACETYLENE GROUPS 79
1. INTRODUCTION 81
2. RESULTS AND DISCUSSION 82
2.1 SYNTHESIS AND CHARACTERIZATION OF ORGANOSILICA NANOTUBES 82
IMAGE 3
INDEX
2.2 GRAFTING OF GLYCINE ON ESNT 87
3. CONCLUSION 90
4. EXPERIMENTAL 90
5. REFERENCES 93
V. VIBRATIONAL SPECTROSCOPIC STUDY OF SILICA BASED NANOTUBES 97
1. BACKGROUND 99
2. INFRARED SPECTRA OF SIO2 BASED NANOTUBES 100
2.1 INFRARED SPECTRA OF SIO2 NANOTUBES 100
2.2 INFRARED SPECTRA OF ETHANESILICA NANOTUBES (ETSNT) 101
2.3 INFRARED SPECTRA OF ETHYLENESILICA NANOTUBES (ESNT) 103
2.4 INFRARED SPECTRA OF BROMINATED ETHYLENESILICA NANOTUBES (BR-ESNT)
106
2.5 INFRARED SPECTRA OF GLYCINE SUBSTITUTED NANOTUBES (GLY-ESNT) 107
2.6 INFRARED SPECTRA OF ACETYLENESILICA NANOTUBES (ASNT) 109
2.7 CHARACTERISTIC SIGNALS IN IR SPECTRA OF ORGANOSILICA-NANOTUBES 110
2.8 CALCULATION OFFEREE CONSTANTS OF SILICA BASED NANOTUBES 112
3. CONCLUSION 113
4. EXPERIMENTAL 114
5. REFERENCES 114
VI. SYNTHESIS OF MCM-41 SUPPORTED DIOXOMOLYBDENUM(VI) COMPLEXES BEARING
ETHOXYCARBONYL-BIPYRIDINE LIGANDS AND THEIR CATALYTIC PROPERTIES IN THE
EPOXIDATION OF 1-OCTENE 117
1. BACKGROUND 119
2. RESULTS AND DISCUSSION 120
2.1 SYNTHESIS AND CHARACTERIZATION OF THE HOMOGENEOUS COMPLEXES LA-5A
120
2.2 SYNTHESIS AND CHARACTERIZATION OF THE HETEROGENEOUS COMPLEXES LB-5B
121
2.3 CATALYTIC RESULTS 123
2.4 NMR-STUDIES OF CATALYSTS LA AND LB 126
3. CONCLUSION 130
4. EXPERIMENTAL 131
4.1 MEASUREMENTS AND PREPARATION 131
4.2 SYNTHESIS OF THE HOMOGENEOUS COMPLEXES LA-5A 132
4.3 IMMOBILIZATION OF THE HOMOGENEOUS COMPLEXES ONTO MCM-41 133
IMAGE 4
INDEX
AA CATALYTIC OXIDATION REACTIONS 134
5. REFERENCES 134
V N. SUMMARY 139
VIII. ZUSAMMENFASSUNG 149
IX. APPENDIX 159
|
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| bvnumber | BV037271234 |
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| discipline | Chemie / Pharmazie |
| edition | 1. Aufl. |
| format | Thesis Book |
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| id | DE-604.BV037271234 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:54:55Z |
| institution | BVB |
| isbn | 9783868537703 |
| language | English |
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| physical | 175 S. Illustrationen, Diagramme |
| publishDate | 2011 |
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| publisher | Verl. Dr. Hut |
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| series2 | Anorganische Chemie |
| spelling | Fischer, Christian Erich 1980- Verfasser (DE-588)143614045 aut Strategies for the immobilization of transition metal complexes on various carrier materials and their catalytic application Christian Erich Fischer 1. Aufl. München Verl. Dr. Hut 2011 175 S. Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Techn. Univ., Diss., 2010 Katalysator (DE-588)4029919-3 gnd rswk-swf Isobuten (DE-588)4162474-9 gnd rswk-swf Zeolith M41S (DE-588)4608084-3 gnd rswk-swf Polymerisation (DE-588)4046704-1 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf Immobilisierung (DE-588)4123417-0 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Übergangsmetallkomplexe (DE-588)4131837-7 s Immobilisierung (DE-588)4123417-0 s Zeolith M41S (DE-588)4608084-3 s Katalysator (DE-588)4029919-3 s Polymerisation (DE-588)4046704-1 s Isobuten (DE-588)4162474-9 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=021184198&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Fischer, Christian Erich 1980- Strategies for the immobilization of transition metal complexes on various carrier materials and their catalytic application Katalysator (DE-588)4029919-3 gnd Isobuten (DE-588)4162474-9 gnd Zeolith M41S (DE-588)4608084-3 gnd Polymerisation (DE-588)4046704-1 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd Immobilisierung (DE-588)4123417-0 gnd |
| subject_GND | (DE-588)4029919-3 (DE-588)4162474-9 (DE-588)4608084-3 (DE-588)4046704-1 (DE-588)4131837-7 (DE-588)4123417-0 (DE-588)4113937-9 |
| title | Strategies for the immobilization of transition metal complexes on various carrier materials and their catalytic application |
| title_auth | Strategies for the immobilization of transition metal complexes on various carrier materials and their catalytic application |
| title_exact_search | Strategies for the immobilization of transition metal complexes on various carrier materials and their catalytic application |
| title_full | Strategies for the immobilization of transition metal complexes on various carrier materials and their catalytic application Christian Erich Fischer |
| title_fullStr | Strategies for the immobilization of transition metal complexes on various carrier materials and their catalytic application Christian Erich Fischer |
| title_full_unstemmed | Strategies for the immobilization of transition metal complexes on various carrier materials and their catalytic application Christian Erich Fischer |
| title_short | Strategies for the immobilization of transition metal complexes on various carrier materials and their catalytic application |
| title_sort | strategies for the immobilization of transition metal complexes on various carrier materials and their catalytic application |
| topic | Katalysator (DE-588)4029919-3 gnd Isobuten (DE-588)4162474-9 gnd Zeolith M41S (DE-588)4608084-3 gnd Polymerisation (DE-588)4046704-1 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd Immobilisierung (DE-588)4123417-0 gnd |
| topic_facet | Katalysator Isobuten Zeolith M41S Polymerisation Übergangsmetallkomplexe Immobilisierung Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=021184198&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT fischerchristianerich strategiesfortheimmobilizationoftransitionmetalcomplexesonvariouscarriermaterialsandtheircatalyticapplication |