Radical reactions in aqueous media:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Cambridge
Royal Society of Chemistry
2009
|
| Schriftenreihe: | RSC Green chemistry
v. 4 |
| Schlagworte: | |
| Online-Zugang: | BHS01 BSB01 BTU01 BTW01 DMM01 FAN01 FAW01 FAW02 FHA01 FHD01 FHM01 FHN01 FHR01 FKE01 FLA01 FWS01 FWS02 HWR01 LCO01 SAB01 SAM01 SBG01 SBR01 SND01 TUM01 UBA01 UBG01 UBM01 UBR01 UBT01 UBW01 UER01 UPA01 Volltext |
| Beschreibung: | This book describes carbon-hydrogen bond formations in aqueous media via radical reactions with a specific focus on Hydrogen Atom Transfer, Chemists are now moving away from volatile, environmentally harmful, and biologically incompatible organic solvents. With its low cost, ready availability, and capacity to remove environmentally unfriendly by-products, water is an obvious replacement. Recent advances in free radical chemistry in water have expanded the versatility and flexibility of homolytic carbon-hydrogen, carbon-carbon, carbon-halogen, carbon-nitrogen bond formations in aqueous media. This textbook highlights the substantial progress which has been made in the last decade to "tame" the reactive free radical species in aqueous phase reactions. It describes carbon-hydrogen bond formations in aqueous media via radical reactions with a specific focus on HAT (Hydrogen Atom Transfer). Suitable for students of chemistry, industrial chemists and academic researchers, it combines extensive knowledge of free radical chemistry with the latest innovations and creative applications. Divided into five main areas, it covers the: generation of carbon centred free radicals; radical initiators; solubility of substrate; suitability of free radical hydrogen donors, and HAT reactions in aqueous media. The book describes radical reactions in organic and aqueous media and their applications in total synthesis, DNA structural probing, isotope labelling, living polymerization and various other applications. It shows that, armed with an elementary knowledge of kinetics and some common sense, it is possible to harness radicals into tremendously powerful tools for solving synthetic problems. Written with the needs of students in mind, it offers just the right level of detail for undergraduate study. All the basic principles and facts on each topic area are presented in a concise yet++ comprehensive style that is appropriate for both core and specialist courses. It provides a step-wise introduction, taking students from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes. Case studies are used to illustrate reactions in landmark synthesis and problems, with outlined answers, test the reader's understanding. There are also suggestions for further reading |
| Beschreibung: | 1 Online-Ressource 109 b&w, halftones |
| ISBN: | 1849730768 9781849730761 |
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| 500 | |a This book describes carbon-hydrogen bond formations in aqueous media via radical reactions with a specific focus on Hydrogen Atom Transfer, Chemists are now moving away from volatile, environmentally harmful, and biologically incompatible organic solvents. With its low cost, ready availability, and capacity to remove environmentally unfriendly by-products, water is an obvious replacement. Recent advances in free radical chemistry in water have expanded the versatility and flexibility of homolytic carbon-hydrogen, carbon-carbon, carbon-halogen, carbon-nitrogen bond formations in aqueous media. This textbook highlights the substantial progress which has been made in the last decade to "tame" the reactive free radical species in aqueous phase reactions. It describes carbon-hydrogen bond formations in aqueous media via radical reactions with a specific focus on HAT (Hydrogen Atom Transfer). Suitable for students of chemistry, industrial chemists and academic researchers, it combines extensive knowledge of free radical chemistry with the latest innovations and creative applications. Divided into five main areas, it covers the: generation of carbon centred free radicals; radical initiators; solubility of substrate; suitability of free radical hydrogen donors, and HAT reactions in aqueous media. The book describes radical reactions in organic and aqueous media and their applications in total synthesis, DNA structural probing, isotope labelling, living polymerization and various other applications. It shows that, armed with an elementary knowledge of kinetics and some common sense, it is possible to harness radicals into tremendously powerful tools for solving synthetic problems. Written with the needs of students in mind, it offers just the right level of detail for undergraduate study. All the basic principles and facts on each topic area are presented in a concise yet++ | ||
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Datensatz im Suchindex
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| callnumber-sort | QD 3169 W3 |
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| ctrlnum | (OCoLC)873742495 (DE-599)GBVNLM00369366X |
| dewey-full | 546.22 541.3422 |
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| dewey-ones | 546 - Inorganic chemistry 541 - Physical chemistry |
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| dewey-search | 546.22 541.3422 |
| dewey-sort | 3546.22 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Electronic eBook |
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| id | DE-604.BV037195558 |
| illustrated | Not Illustrated |
| indexdate | 2025-02-20T06:47:18Z |
| institution | BVB |
| isbn | 1849730768 9781849730761 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-021109920 |
| oclc_num | 873742495 |
| open_access_boolean | |
| owner | DE-12 DE-384 DE-473 DE-BY-UBG DE-703 DE-29 DE-19 DE-BY-UBM DE-91 DE-BY-TUM DE-739 DE-355 DE-BY-UBR DE-20 DE-Aug4 DE-1046 DE-1047 DE-1102 DE-1050 DE-859 DE-M347 DE-92 DE-898 DE-BY-UBR DE-863 DE-BY-FWS DE-862 DE-BY-FWS DE-128 DE-54 DE-22 DE-BY-UBG DE-150 DE-155 DE-BY-UBR DE-210 DE-2070s DE-634 DE-526 DE-860 DE-70 DE-B768 |
| owner_facet | DE-12 DE-384 DE-473 DE-BY-UBG DE-703 DE-29 DE-19 DE-BY-UBM DE-91 DE-BY-TUM DE-739 DE-355 DE-BY-UBR DE-20 DE-Aug4 DE-1046 DE-1047 DE-1102 DE-1050 DE-859 DE-M347 DE-92 DE-898 DE-BY-UBR DE-863 DE-BY-FWS DE-862 DE-BY-FWS DE-128 DE-54 DE-22 DE-BY-UBG DE-150 DE-155 DE-BY-UBR DE-210 DE-2070s DE-634 DE-526 DE-860 DE-70 DE-B768 |
| physical | 1 Online-Ressource 109 b&w, halftones |
| psigel | ZDB-1-RSE |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | Royal Society of Chemistry |
| record_format | marc |
| series2 | RSC Green chemistry |
| spellingShingle | Perchyonok, Tamara Radical reactions in aqueous media Water chemistry Hydrogen bonding Chemical reactions Free radical reactions Free radicals (Chemistry) |
| title | Radical reactions in aqueous media |
| title_auth | Radical reactions in aqueous media |
| title_exact_search | Radical reactions in aqueous media |
| title_full | Radical reactions in aqueous media Tamara Perchyonok ; Series edited by James H. Clark, George A. Kraus |
| title_fullStr | Radical reactions in aqueous media Tamara Perchyonok ; Series edited by James H. Clark, George A. Kraus |
| title_full_unstemmed | Radical reactions in aqueous media Tamara Perchyonok ; Series edited by James H. Clark, George A. Kraus |
| title_short | Radical reactions in aqueous media |
| title_sort | radical reactions in aqueous media |
| topic | Water chemistry Hydrogen bonding Chemical reactions Free radical reactions Free radicals (Chemistry) |
| topic_facet | Water chemistry Hydrogen bonding Chemical reactions Free radical reactions Free radicals (Chemistry) |
| url | http://www.rsc.org/publishing/ebooks/2009/9781849730006.asp |
| work_keys_str_mv | AT perchyonoktamara radicalreactionsinaqueousmedia AT clarkjamesh radicalreactionsinaqueousmedia AT krausgeorgeandrew radicalreactionsinaqueousmedia |