Dynamic Stereochemistry of Chiral Compounds: Principles and Applications
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Cambridge
Royal Society of Chemistry
2007
|
| Schlagworte: | |
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| Beschreibung: | A comprehensive overview of fundamental concepts of asymmetric synthesis along with in-depth discussion, This book provides an overview of fundamental concepts of asymmetric synthesis highlighting the significance of stereochemical and stereodynamic reaction control. Topics include kinetic resolution (KR), dynamic kinetic resolution (DKR), dynamic kinetic asymmetric transformation (DYKAT), and dynamic thermodynamic resolution (DTR). In-depth discussions of asymmetric synthesis with chiral organolithium compounds, atropisomeric biaryl synthesis, self-regeneration of stereogenicity (SRS), chiral amplification with chiral relays and other commonly used strategies are also provided. Particular emphasis is given to selective introduction, interconversion and translocation of central, axial, planar, and helical chirality. A systematic coverage of stereochemical principles and stereodynamic properties of chiral compounds guides the reader through the book and establishes a conceptual linkage to asymmetric synthesis, molecular devices that resemble the structure and stereomutations of propellers, bevel gears, switches and motors, and topologically chiral assemblies such as catenanes and rotaxanes. Racemization and diastereomerization reactions of numerous chiral compounds are discussed as well as the principles, scope and compatibility of commonly used analytical techniques. Details of analytical methods are provided and discussed as well as topics relating to the design of fascinating topologically chiral assemblies and molecular technomimetic devices in the context of dynamic stereochemistry. Strategies and recent developments that address important synthetic challenges are presented and highlighted with hundreds of examples, applications and detailed mechanisms. This exceptional book includes: - More than 550 figures, schemes and tables illustrating mechanisms of nume++ rous asymmetric reactions and stereomutations of chiral compounds - Technical drawings illustrating the conceptual linkage between macroscopic devices such as turnstiles, ratchets, brakes, bevel gears or knots and molecular analogs - More than 3000 references to encourage further reading and facilitate additional literature research - A comprehensive glossary with stereochemical definitions and terms which facilitate understanding and reinforce learning This book will be of particular interest to undergraduates, graduates and professionals working and researching in the fields of organic synthetic chemistry and analytical chemistry |
| Beschreibung: | 1 Online-Ressource (532 p.) 164 b&w, ill |
| ISBN: | 1847558097 9781847558091 |
| DOI: | 10.1039/9781847558091 |
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| doi_str_mv | 10.1039/9781847558091 |
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| id | DE-604.BV037195433 |
| illustrated | Not Illustrated |
| indexdate | 2024-08-01T11:43:57Z |
| institution | BVB |
| isbn | 1847558097 9781847558091 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-021109795 |
| oclc_num | 873741348 |
| open_access_boolean | |
| owner | DE-12 DE-384 DE-473 DE-BY-UBG DE-703 DE-29 DE-19 DE-BY-UBM DE-91 DE-BY-TUM DE-739 DE-355 DE-BY-UBR DE-20 DE-Aug4 DE-1046 DE-1047 DE-1102 DE-1050 DE-859 DE-M347 DE-92 DE-898 DE-BY-UBR DE-863 DE-BY-FWS DE-862 DE-BY-FWS DE-128 DE-54 DE-22 DE-BY-UBG DE-150 DE-155 DE-BY-UBR DE-210 DE-2070s DE-634 DE-526 DE-860 DE-70 DE-B768 |
| owner_facet | DE-12 DE-384 DE-473 DE-BY-UBG DE-703 DE-29 DE-19 DE-BY-UBM DE-91 DE-BY-TUM DE-739 DE-355 DE-BY-UBR DE-20 DE-Aug4 DE-1046 DE-1047 DE-1102 DE-1050 DE-859 DE-M347 DE-92 DE-898 DE-BY-UBR DE-863 DE-BY-FWS DE-862 DE-BY-FWS DE-128 DE-54 DE-22 DE-BY-UBG DE-150 DE-155 DE-BY-UBR DE-210 DE-2070s DE-634 DE-526 DE-860 DE-70 DE-B768 |
| physical | 1 Online-Ressource (532 p.) 164 b&w, ill |
| psigel | ZDB-1-RSE ZDB-1-RSE ZDB-1-RSE |
| publishDate | 2007 |
| publishDateSearch | 2007 |
| publishDateSort | 2007 |
| publisher | Royal Society of Chemistry |
| record_format | marc |
| spellingShingle | Wolf, Christian Dynamic Stereochemistry of Chiral Compounds Principles and Applications Chiralité Stéréochimie Chirality Chirale Verbindungen (DE-588)4348527-3 gnd Stereochemie (DE-588)4129569-9 gnd Asymmetrische Synthese (DE-588)4135603-2 gnd Organische Chemie (DE-588)4043793-0 gnd |
| subject_GND | (DE-588)4348527-3 (DE-588)4129569-9 (DE-588)4135603-2 (DE-588)4043793-0 |
| title | Dynamic Stereochemistry of Chiral Compounds Principles and Applications |
| title_auth | Dynamic Stereochemistry of Chiral Compounds Principles and Applications |
| title_exact_search | Dynamic Stereochemistry of Chiral Compounds Principles and Applications |
| title_full | Dynamic Stereochemistry of Chiral Compounds Principles and Applications Christian Wolf |
| title_fullStr | Dynamic Stereochemistry of Chiral Compounds Principles and Applications Christian Wolf |
| title_full_unstemmed | Dynamic Stereochemistry of Chiral Compounds Principles and Applications Christian Wolf |
| title_short | Dynamic Stereochemistry of Chiral Compounds |
| title_sort | dynamic stereochemistry of chiral compounds principles and applications |
| title_sub | Principles and Applications |
| topic | Chiralité Stéréochimie Chirality Chirale Verbindungen (DE-588)4348527-3 gnd Stereochemie (DE-588)4129569-9 gnd Asymmetrische Synthese (DE-588)4135603-2 gnd Organische Chemie (DE-588)4043793-0 gnd |
| topic_facet | Chiralité Stéréochimie Chirality Chirale Verbindungen Stereochemie Asymmetrische Synthese Organische Chemie |
| url | https://doi.org/10.1039/9781847558091 |
| work_keys_str_mv | AT wolfchristian dynamicstereochemistryofchiralcompoundsprinciplesandapplications |