Macrocycles: construction, chemistry, and nanotechnology applications
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, NJ
Wiley
2011
|
| Ausgabe: | 1. publ. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | XII, 596 S. Ill. |
| ISBN: | 9780470714621 9780470714638 9780470980200 |
Internformat
MARC
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| 245 | 1 | 0 | |a Macrocycles |b construction, chemistry, and nanotechnology applications |c Frank Davis ; Séamus Higson |
| 250 | |a 1. publ. | ||
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| 300 | |a XII, 596 S. |b Ill. | ||
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Datensatz im Suchindex
| _version_ | 1804143611735965696 |
|---|---|
| adam_text | Contents
Preface
xi
1
Introduction
1
1.1
Simple
Ring Compounds
1
1.2
Three-Dimensional Aliphatic Carbon Structures
3
1.3
Annulenes
5
1.4
Multi-Ring Aromatic Structures
9
1.5
Porpyrins and Phthalocanines
10
1.6
Conclusions
13
References
14
2
Cyclophanes
16
2.1
Introduction
16
2.2
Cyclophanes with One Aromatic System and Aliphatic Chain
16
2.2.1
Properties of the cyclophanes
17
2.2.2
Chemistry of the cyclophanes
18
2.2.3
Synthesis of the cyclophanes
19
2.3
Cyclophanes with More than One Aromatic Ring
20
2.4
Napthalenophanes and Other Aromatic Systems
25
2.5
Cyclophanes Containing Heteroaromatic Systems
28
2.6
Ferrocenophanes
28
2.7
Conclusions
30
Bibliography
30
References
30
3
Crown Ethers, Cryptands and Other Compounds
34
3.1
Introduction
34
3.2
Crown Ethers
35
3.3
Simple Complexes with Crown Ethers
37
3.4
Azacrowns, Cyclens and Cyclams
42
3.5
Crowns Containing Other
Heteroatoms
50
3.6
Lariat and Bibracchial Crown Ethers
50
3.7
Cryptands
54
3.8
Spherands
56
3.9
Combined and Multiple Systems
60
vi
Contents
3.10
Applications
of
Crown
Ethers and Related Compounds
67
3.11
Conclusions
70
Bibliography
70
References
70
4
Calixarenes
77
4.1
Introduction
77
4.2
History
77
4.3
Structures of Calixarenes
80
4.4
Chemical Modification of Calixarenes
82
4.4.1
Modification of the hydroxyls
82
4.4.2
Replacement of the hydroxyls
86
4.4.3
Reaction of the rings
88
4.4.4
Reactions of the bridging groups
89
4.4.5
Modification of the upper rim
90
4.5
Complexes with Calixarenes
95
4.6 ß/5
and Multicalixarenes
98
4.7
Oxacalixarenes, Azacalixarenes and Thiacalixarenes
104
4.8
Resorcinarenes: Synthesis and Structure
107
4.9
Cavitands and Carcerands
113
4.10
Conclusions
116
Bibliography
116
References
117
5
Heterocalixarenes and Calixnaphthalenes
126
5.1
Introduction
126
5.2
Calixnaphthalenes
126
5.3
Tropolone-Based
Macrocycles
133
5.4
Calixfurans
134
5.5
Calixpyrroles
138
5.5.1
Introduction
138
5.5.2
Chemical modification of the calixpyrroles I46
5.5.3
Confused calixpyrroles
152
5.5.4
Substituted calixpyrroles
153
5.5.5
Strapped calixpyrroles
158
5.5.6
Modification of the pyrrole units
160
5.5.7
Sensing and other applications of calix^Jpyrroles
161
5.5.8
Calixpyrroles including nonpyrrole units
163
5.6
Calixindoles, Calixpyridines and Calixthiophenes
172
5.7
Conclusions
180
Bibliography
183
References
183
6
Cyclodextrins
190
6.1
Introduction
190
Contents
vii
6.2
Complex
Formation
by Cyclodextrins
195
6.3
Cyclodextrins of Other Sizes
207
6.4
Modification Reactions of Cyclodextrins
208
6.4.1
Modification of the 6-hydroxyls
209
6.4.2
Modification of the
2-
or 3-positions
211
6.5
Selectivity of Cyclodextrins
217
6.6
Multiple Cyclodextrin Systems
219
6.6.1
Bis and multi-cyclodextrins
219
6.7
Polymeric Cyclodextrins
229
6.7.1
Covalently linked cyclodextrin polymers
229
6.7.2
Noncovalently linked cyclodextrin polymers
231
6.8
Cyclodextrins Combined with Other Macrocyclic Systems
231
6.9
Therapeutic Uses of Cyclodextrins
235
6.10
Other Uses of Cyclodextrins
238
6.11
Conclusions
243
Bibliography
244
References
244
7
Cyclotriveratylenes and Cryptophanes
255
7.1
Introduction
255
7.2
Synthesis of Cyclotnveratrylenes
255
7.3
Modification of Cyclotriveratrylenes
263
7.4
Synthesis of Optically Active Cyclotriveratrylenes
268
7.5
Modification of the Bridging Groups
269
7.6
Modification of the Aromatic Rings with Organometallic Groups
273
7.7
Selective Binding Applications of Cyclotriveratrylenes
276
7.8
Analogues of CTV
287
7.9
Synthesis and Structure of Cryptophanes
289
7.10
Modification of Cryptophanes
299
7.11
Complexes with Cryptophanes
303
7.12
Cryptophane-Xenon Complexes
308
7.13
Other Uses of Cryptophanes
312
7.14
Hemicryptophanes
ЗІЗ
7.15
Conclusions
315
Bibliography
316
References
316
8
Cucurbiturils
325
8.1
Introduction
325
8.2
Complexation Behaviour of Simple Cucurbiturils
328
8.2.1
CucurbitfSJuril
328
8.2.2
Cucurbittójuril
331
8.2.3
Cucurbitpjuril
339
8.2.4
Cucurbit^uril
346
8.2.5
CucurbittlOJuril
351
viii Contents
8.3
Modification
of Cucurbiturils
354
8.4
Uses
of
Cucurbiturils
361
8.5
Hemicucurbiturils
366
8.6
Conclusions 368
Bibliography 368
References 368
9
Rotaxanes and Catenanes
381
9.1
Introduction 381
9.2
Rotaxanes
382
9.2.1
Synthesis using statistical methods
382
9.2.2
Rotaxanes containing cyclodextrins, cucurbiturils and calixarenes
383
9.2.3
Rotaxanes based on
π
-electron interactions
388
9.2.4
Other synthetic methods for rotaxane synthesis
392
9.2.5
Rotaxanes as molecular machines
409
9.2.6
Thin films of rotaxanes
421
9.2.7
Polyrotaxanes
427
9.3
Catenanes 430
9.3.1
Synthesis using statistical and directed methods
431
9.3.2
Catenates and catenanes via metal templates
432
9.3.3
Catenanes based on
π
-electron interactions
450
9.3.4
Catenanes based on amide hydrogen-bonding interactions
474
9.3.5
Catenanes containing other macrocyclic units
479
9.3.6
Switchable catenanes
485
9.3.7
Catenanes on surfaces
493
9.3.8
Polycatenanes and catenated polymers
496
9.3.9
Natural catenanes
501
9.4
Conclusions
504
Bibliography
504
References
505
10
Other Supramolecular Systems, Molecular Motors, Machines and Nanotechnological
Applications
518
10.1
Introduction
518
10.2
Other Molecular Systems
518
10.2.1
Aromatic and cyclacene compounds
518
10.2.2
Other cavitands
520
10.2.3
Pretzelanes, bonnanes and [l]rotaxanes
525
10.2.4
Trefoil knots
526
10.2.5
Solomon links and Borromean rings
539
10.2.6
Other systems
546
10.3
Molecular Devices, Motors and Machines
549
10.3.1
Molecular and supramolecular switches
550
10.3.2
Molecular motion
555
Contents
¡χ
10.3.3 Light
harvesting
565
10.3.4 Ion
channels
566
10.3.5
Other uses of interlinked systems
567
10.4
Conclusions
567
Bibliography
570
References
570
Index
576
Macrocycles
Construction,
Chemistry and
Nanotechnology Applications
Dr
FRANK DAVIS, Cranfield University, UK
Professor
SÉAMUS
HIGSON, Cranfield University, UK
Macrocyclic molecules contain rings made up of seven or more atoms. They provide
building blocks for synthesizing precise two or three dimensional structures
-
an
important goal in nanotechnology. For example, they can be used to develop nanosized
reaction vessels, cages, switches and shuttles, and have potential as components in
molecular computers as switches, nano-valves and logic gates. They also have
applications as catalysts and sensors.
Macrocycles: Construction, Chemistry and Nanotechnology Applications is an essential
introduction to this important class of molecules and describes how to synthesize them,
their chemistry, how they can be used as nanotechnology building blocks, and their
applications. A wide range of structures synthesized over the past few decades are
covered, from the simpler cyclophanes and multi-ring aromatic structures to vases, bowls,
cages and more complex multi-ring systems and
3D
architectures such as pumpkins ,
interlocking chains and knots. Some of the molecular classes covered include simple
ring compounds, three dimensional aliphatic carbon structures, annulenes, multi-ring
aromatic structures, porphyrins and phthalocyanines, cyclophanes, crown ethers,
cryptands, spherands, calixarenes, resorcinarenes, cavitands, carcerands,
heterocalixarenes, calixnaphthalenes, cyclodextrins, cyclotriveratylenes, cryptophanes,
cucurbiturils, rotaxanes and catenanes.
Macrocycles: Construction, Chemistry and Nanotechnology Applications distills the
essence of this important topic for undergraduate and postgraduate students, and
for researchers in other fields who are interested in getting a general insight into this
increasingly important class of molecules.
Enjoyed this book?
Why not tell others about it
and write a review on your
favourite online bookseller.
ISBN
978-0-470-71463-8
Ψ
WILEY
9 780470 714638
|
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| id | DE-604.BV036896550 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:50:25Z |
| institution | BVB |
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| language | English |
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| physical | XII, 596 S. Ill. |
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| publisher | Wiley |
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| spelling | Davis, Frank Verfasser aut Macrocycles construction, chemistry, and nanotechnology applications Frank Davis ; Séamus Higson 1. publ. Hoboken, NJ Wiley 2011 XII, 596 S. Ill. txt rdacontent n rdamedia nc rdacarrier Makrocyclische Verbindungen (DE-588)4168678-0 gnd rswk-swf Makrocyclische Verbindungen (DE-588)4168678-0 s DE-604 Higson, Séamus Verfasser aut Erscheint auch als Online-Ausgabe, EPUB 978-1-119-99029-1 Erscheint auch als Online-Ausgabe, PDF 978-1-119-98993-6 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020811635&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020811635&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Davis, Frank Higson, Séamus Macrocycles construction, chemistry, and nanotechnology applications Makrocyclische Verbindungen (DE-588)4168678-0 gnd |
| subject_GND | (DE-588)4168678-0 |
| title | Macrocycles construction, chemistry, and nanotechnology applications |
| title_auth | Macrocycles construction, chemistry, and nanotechnology applications |
| title_exact_search | Macrocycles construction, chemistry, and nanotechnology applications |
| title_full | Macrocycles construction, chemistry, and nanotechnology applications Frank Davis ; Séamus Higson |
| title_fullStr | Macrocycles construction, chemistry, and nanotechnology applications Frank Davis ; Séamus Higson |
| title_full_unstemmed | Macrocycles construction, chemistry, and nanotechnology applications Frank Davis ; Séamus Higson |
| title_short | Macrocycles |
| title_sort | macrocycles construction chemistry and nanotechnology applications |
| title_sub | construction, chemistry, and nanotechnology applications |
| topic | Makrocyclische Verbindungen (DE-588)4168678-0 gnd |
| topic_facet | Makrocyclische Verbindungen |
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