Preparation of highly functionalized aryl and heteroaryl organometallics by C-H activation of aromatics and heterocycles using new hindered TMP-amide bases of Zn, Al, Mn, Fe and La:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin ; Bochum ; Dülmen ; London ; München ; Paris
Europ. Univ.-Verl.
2010
Berlin ; Bochum ; Dülmen ; London ; München ; Paris Munich Univ. Press |
| Schriftenreihe: | Chemistry
1 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 354 S. 22 cm |
| ISBN: | 9783865151216 |
Internformat
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| 245 | 1 | 0 | |a Preparation of highly functionalized aryl and heteroaryl organometallics by C-H activation of aromatics and heterocycles using new hindered TMP-amide bases of Zn, Al, Mn, Fe and La |c Stefan Wunderlich |
| 264 | 1 | |a Berlin ; Bochum ; Dülmen ; London ; München ; Paris |b Europ. Univ.-Verl. |c 2010 | |
| 264 | 1 | |a Berlin ; Bochum ; Dülmen ; London ; München ; Paris |b Munich Univ. Press | |
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Datensatz im Suchindex
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| adam_text | TABLE OF CONTENTS / INTRODUCTION 1.1 GENERAL OVERVIEW 1.2 PREPARATION OF
ORGANOMETALLIC REAGENTS 1.2.1 OXIDATIVE INSERTION 1.2.2 HALOGEN-METAL
EXCHANGE 1.2.3 DIRECTED METALATION 2 OBJECTIVES 3 DIRECTED ZINCATION OF
FUNCTIONALIZEDAROMATICS AND HETEROAROMATICS USING TMP,ZN-2MSCH-2LICL 3.1
INTRODUCTION 1 1 2 2 5 7 12 14 14 3.2 PREPARATION OF THE ZN-REAGENT 60
15 3.3 METALATION OF HETEROAROMATICS 19 3.4 METALATION OF HETEROCYCLES
BEARING SENSITIVE FUNCTIONALITIES 23 3.5 METALATION OF FUNCTIONALIZED
AROMATICS 26 3.6 LARGER SCALE EXPERIMENTS 31 4 FUNCTIONALIZATION
OF3,6-DICHLOROPYRIDAZINE (71) 33 4.1 INTRODUCTION 33 4.2 MONO- AND
BIS-FUNCTIONALIZATION OF 3,6-DICHLOROPYRIDAZINE (71) 34 4.3 SYNTHESIS OF
ANNELATED HETEROCYCLES 36 5 DIRECTED ZINCATION OF FUNCTIONALIZED A
ROMATICS AND HETEROAROMATICS USING TMP 2 ZN-2MGCL 2 -2LICL (60) AND
MICROWAVE IRRADIATION 38 5.1 INTRODUCTION 38 5.2 PREPARATION OF
FUNCTIONALIZED AROMATICS 39 5.3 PREPARATION OF FUNCTIONALIZED
HETEROAROMATICS 44 6 BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/1004285965 DIGITALISIERT DURCH 8.3 ALUMINATION OF
AROMATICS BEARING EFFICIENT DIRECTING GROUPS 66 8.4 METALATION OF
AROMATIC AND HETEROCYCLIC ETHERS 69 8.5 UNUSUAL SUBSTITUTION PATTERNS 72
9 DIRECTED METALATION OF AROMATICS AND HETEROAROMATICS USING TMP 3
LA-3MGCL 2 -SLICL 76 9.1 INTRODUCTION 76 9.2 PREPARATION OF THE LA-BASES
77 9.3 PREPARATION OF FUNCTIONALIZED ORGANOLANTHANUM REAGENTS 79 9.4
PRELIMINARY EXPERIMENTS FOR THE LA-CATALYZED ACYLATION OF ORGANOZINC
REAGENTS_ 86 10 DIRECTED MANGANATION OF FUNCTIONALIZED AROMATICS AND
HETEROCYCLES USING TMP 2 MN-2MGCL 2 -4LICL 89 10.1 INTRODUCTION 89 10.2
PREPARATION OF THE BASE 89 10.3 PREPARATION OF FUNCTIONALIZED
ARYL-MANGANESE SPECIES 92 10.4 PREPARATION OF FUNCTIONALIZED
HETEROARYL-MANGANESE REAGENTS 100 11 DIRECTED FERRATION OF
FUNCTIONALIZED AROMATICS USING TMP 2 FE-2MGCL 2 -4LICL _103 11.1
INTRODUCTION 103 11.2 PREPARATION OF THE HINDERED FE-TMP BASE 181 104
11.3 ALKYLATION REACTIONS CATALYZED BY IMPURITIES 106 11.4 REACTIVITY
VERSUS ELECTROPHILES 108 11.5 PREPARATION OF FUNCTIONALIZED ARYL-(FE)
COMPOUNDS 109 11.6 PRELIMINARY EXPERIMENTS ABOUT A NI-CATA YZED
ALKYLATION OF ORGANOZINC REAGENTS 114 12 SUMMARY AND OUTLOOK 116 12.1
DIRECTED ZINCATIONS 116 12. PREPARATION OF THE REAGENT {TMP 2 FE} (190)
132 13.3 TYPICAL PROCEDURES 133 TYPICAL PROCEDURE FOR THE ZINCATION OF
POLYFUNCTIONALIZED AROMATICS AND HETEROCYCLES USING TMP 2 ZN-2MGCL 2
-2LICL (60) OR [(TBU)N(IPR)] 2 ZN-2MGCL 2 -2LICL (87) (TP 1) 133 TYPICAL
PROCEDURE FOR THE PREPARATION OF THE ZINCATED 3,6-DICHLOROPYRIDAZINE
(72) USING TMP 2 ZN-2MGCL 2 -2LICL(60)(TP2) 133 TYPICAL PROCEDURE FOR
THE ZINCATION OF POLYFIMCTIONALIZED AROMATICS AND HETEROCYCLES WITH TMP
2 ZN-2MGCL 2 -2LICL (60) USING MICROWAVE IRRADIATION (TP 3) 133 TYPICAL
PROCEDURE FOR THE ZINCATION OF POLYFUNCTIONALIZED AROMATICS AND
HETEROCYCLES WITH TMPMGCLLICL (40) USING ZNCL 2 (TP 4) 134 TYPICAL
PROCEDURE FOR THE ZINCATION OF POLYFUNCTIONALIZED AROMATICS WITH
TMPMGCLLICL (40) USING ET 3 AL (TP 5) 134 TYPICAL PROCEDURE FOR THE
ALUMINATION OF FUNCTIONALIZED AROMATICS AND HETEROAROMATICS USING
ALUMINUM BASES (TP 6) [ 134 TYPICAL PROCEDURE FOR THE LANTHANATION OF
FUNERIONALIZED AROMATICS AND HETEROAROMATICS USING TMP 3 LA-3MGCL 2
-5LICL (143
|
| any_adam_object | 1 |
| author | Wunderlich, Stefan 1980- |
| author_GND | (DE-588)14201012X |
| author_facet | Wunderlich, Stefan 1980- |
| author_role | aut |
| author_sort | Wunderlich, Stefan 1980- |
| author_variant | s w sw |
| building | Verbundindex |
| bvnumber | BV036894670 |
| ctrlnum | (OCoLC)706857744 (DE-599)DNB1004285965 |
| dewey-full | 547.2 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.2 |
| dewey-search | 547.2 |
| dewey-sort | 3547.2 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| indexdate | 2024-07-09T22:50:22Z |
| institution | BVB |
| isbn | 9783865151216 |
| language | English |
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| physical | 354 S. 22 cm |
| publishDate | 2010 |
| publishDateSearch | 2010 |
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| publisher | Europ. Univ.-Verl. Munich Univ. Press |
| record_format | marc |
| series | Chemistry |
| series2 | Chemistry |
| spelling | Wunderlich, Stefan 1980- Verfasser (DE-588)14201012X aut Preparation of highly functionalized aryl and heteroaryl organometallics by C-H activation of aromatics and heterocycles using new hindered TMP-amide bases of Zn, Al, Mn, Fe and La Stefan Wunderlich Berlin ; Bochum ; Dülmen ; London ; München ; Paris Europ. Univ.-Verl. 2010 Berlin ; Bochum ; Dülmen ; London ; München ; Paris Munich Univ. Press 354 S. 22 cm txt rdacontent n rdamedia nc rdacarrier Chemistry 1 Zugl.: München, Univ., Diss., 2010 Funktionelle Gruppe (DE-588)4155684-7 gnd rswk-swf Tetramethylpiperidin 2,2,6,6- (DE-588)7716476-3 gnd rswk-swf Metallierung (DE-588)4169596-3 gnd rswk-swf Aromatische Verbindungen (DE-588)4129374-5 gnd rswk-swf Metallamide (DE-588)4289738-5 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Aromatische Verbindungen (DE-588)4129374-5 s Funktionelle Gruppe (DE-588)4155684-7 s Metallierung (DE-588)4169596-3 s Metallamide (DE-588)4289738-5 s Tetramethylpiperidin 2,2,6,6- (DE-588)7716476-3 s DE-604 Chemistry 1 (DE-604)BV036894668 1 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020809797&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Wunderlich, Stefan 1980- Preparation of highly functionalized aryl and heteroaryl organometallics by C-H activation of aromatics and heterocycles using new hindered TMP-amide bases of Zn, Al, Mn, Fe and La Chemistry Funktionelle Gruppe (DE-588)4155684-7 gnd Tetramethylpiperidin 2,2,6,6- (DE-588)7716476-3 gnd Metallierung (DE-588)4169596-3 gnd Aromatische Verbindungen (DE-588)4129374-5 gnd Metallamide (DE-588)4289738-5 gnd |
| subject_GND | (DE-588)4155684-7 (DE-588)7716476-3 (DE-588)4169596-3 (DE-588)4129374-5 (DE-588)4289738-5 (DE-588)4113937-9 |
| title | Preparation of highly functionalized aryl and heteroaryl organometallics by C-H activation of aromatics and heterocycles using new hindered TMP-amide bases of Zn, Al, Mn, Fe and La |
| title_auth | Preparation of highly functionalized aryl and heteroaryl organometallics by C-H activation of aromatics and heterocycles using new hindered TMP-amide bases of Zn, Al, Mn, Fe and La |
| title_exact_search | Preparation of highly functionalized aryl and heteroaryl organometallics by C-H activation of aromatics and heterocycles using new hindered TMP-amide bases of Zn, Al, Mn, Fe and La |
| title_full | Preparation of highly functionalized aryl and heteroaryl organometallics by C-H activation of aromatics and heterocycles using new hindered TMP-amide bases of Zn, Al, Mn, Fe and La Stefan Wunderlich |
| title_fullStr | Preparation of highly functionalized aryl and heteroaryl organometallics by C-H activation of aromatics and heterocycles using new hindered TMP-amide bases of Zn, Al, Mn, Fe and La Stefan Wunderlich |
| title_full_unstemmed | Preparation of highly functionalized aryl and heteroaryl organometallics by C-H activation of aromatics and heterocycles using new hindered TMP-amide bases of Zn, Al, Mn, Fe and La Stefan Wunderlich |
| title_short | Preparation of highly functionalized aryl and heteroaryl organometallics by C-H activation of aromatics and heterocycles using new hindered TMP-amide bases of Zn, Al, Mn, Fe and La |
| title_sort | preparation of highly functionalized aryl and heteroaryl organometallics by c h activation of aromatics and heterocycles using new hindered tmp amide bases of zn al mn fe and la |
| topic | Funktionelle Gruppe (DE-588)4155684-7 gnd Tetramethylpiperidin 2,2,6,6- (DE-588)7716476-3 gnd Metallierung (DE-588)4169596-3 gnd Aromatische Verbindungen (DE-588)4129374-5 gnd Metallamide (DE-588)4289738-5 gnd |
| topic_facet | Funktionelle Gruppe Tetramethylpiperidin 2,2,6,6- Metallierung Aromatische Verbindungen Metallamide Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020809797&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV036894668 |
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