Artificial receptors for chemical sensors:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2011
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XV, 469 S. Ill., graph. Darst. |
| ISBN: | 9783527323579 |
Internformat
MARC
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| 016 | 7 | |a 994010664 |2 DE-101 | |
| 020 | |a 9783527323579 |c GB. : ca. EUR 129.00 (freier Pr.), ca. sfr 204.00 (freier Pr.) |9 978-3-527-32357-9 | ||
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| 245 | 1 | 0 | |a Artificial receptors for chemical sensors |c ed. by Vladimir M. Mirsky... |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2011 | |
| 300 | |a XV, 469 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
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IMAGE 1
CONTENTS
PREFACE XI LIST OF CONTRIBUTORS X I II
1 QUANTITATIVE CHARACTERIZATION OF AFFINITY PROPERTIES OF IMMOBILIZED
RECEPTORS 1 VLADIMIR M. M/RSFCY 1.1 INTRODUCTION 1
1.2 MEASUREMENTS UNDER EQUILIBRIUM CONDITIONS 3 1.3 KINETIC MEASUREMENTS
7
1.4 ANALYSIS OF TEMPERATURE DEPENDENCIES 10 1.5 EXPERIMENTAL TECHNIQUES
22 REFERENCES 14
2 SELECTIVITY OF CHEMICAL RECEPTORS 17 HANS-JOERG SCHNEIDER AND ANATOLY
K. YATSIMIRSKY 2.1 INTRODUCTION 17
2.2 SOME GENERAL CONSIDERATIONS ON SELECTIVITY 18 2.3 CORRELATION
BETWEEN SELECTIVITY AND AFFINITY 21 2.4 CROWN ETHER AND CRYPTAND
COMPLEXES: HOLE SIZE FITTING AND OTHER EFFECTS 24
2.5 RECOGNITION OF TRANSITION AND HEAVY METAL IONS 29 2.6 RECOGNITION
VIA ION PAIRING 31
2.7 HYDROGEN BONDED COMPLEXES AND SOLVENT EFFECTS 37 2.8 LEWIS ACID
RECEPTORS 41
2.8.1 ASSOCIATIONS WITH TRANSITION METAL COMPLEXES 41 2.8.2 ASSOCIATIONS
WITH OTHER LEWIS ACIDS 45 2.9 COMPLEXES WITH STACKING AND VAN DER WAALS
INTERACTIONS 46 2.10 MULTIFUNCTIONAL RECEPTORS FOR RECOGNITION OF
COMPLEX
TARGET MOLECULES 48
ARTIFICIAL RECEPTORS FOR CHEMICAL SENSORS. EDITED BY V.M. MIRSKY AND A.
YATSIMIRSKY COPYRIGHT 2011 WILEY-VCH VERLAG GMBH & CO. KGAA, WEINHEIM
ISBN: 978-3-527-32357-9
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/994010664
DIGITALISIERT DURCH
IMAGE 2
VI CONTENTS
2.10.1 COMPLEXATION OF AMINO ACIDS AND PEPTIDES 48
2.10.2 COMPLEXATION OF NUCLEOTIDES AND NUCLEOSIDES 54 2.11 CONCLUSIONS
60
REFERENCES 61
3 COMBINATORIA! DEVELOPMENT OF SENSING MATERIALS 67 RADISIAV A.
POTYRAILO 3.1 INTRODUCTION 67
3.2 GENERAL PRINCIPLES OF COMBINATORIAL MATERIALS SCREENING 68 3.3
OPPORTUNITIES FOR SENSING MATERIALS 69 3.4 DESIGNS OF COMBINATORIAL
LIBRARIES OF SENSING MATERIALS 71 3.5 DISCOVERY AND OPTIMIZATION OF
SENSING MATERIALS USING
DISCRETE ARRAYS 73
3.5.1 RADIANT ENERGY TRANSDUCTION SENSORS 73 3.5.2 MECHANICAL ENERGY
TRANSDUCTION SENSORS 79 3.5.3 ELECTRICAL ENERGY TRANSDUCTION SENSORS 84
3.6 OPTIMIZATION OF SENSING MATERIALS USING GRADIENT ARRAYS 92
3.6.1 VARIABLE CONCENTRATION OF REAGENTS 92 3.6.2 VARIABLE THICKNESS OF
SENSING FILMS 93 3.6.3 VARIABLE 2D COMPOSITION 94 3.6.4 VARIABLE
OPERATION TEMPERATURE AND DIFFUSION LAYER THICKNESS 95
3.7 EMERGING WIRELESS TECHNOLOGIES FOR COMBINATORIAL SCREENING OF
SENSING MATERIALS 97 3.8 SUMMARY AND OUTLOOK 102
REFERENCES 104
4 FLUORESCENT CYCLODEXTRINS AS CHEMOSENSORS FOR MOLECULE DETECTION IN
WATER 113 HIROSHI IKEDA
4.1 INTRODUCTION 113
4.2 PYRENE-APPENDED CYCLODEXTRINS 114 4.2.1 PYRENE-APPENDED
Y-CYCLODEXTRINS AS MOLECULE SENSORS 214 4.2.2 PYRENE-APPENDED
7-CYDODEXTRIN AS A BICARBONATE SENSOR 225 4.2.3 BIS-PYRENE-APPENDED
Y-CYCLODEXTRINS 116 4.3 FLUOROPHORE-AMINO ACID-CD TRIAD SYSTEMS 228
4.3.1 DANSYL-LEUCINE-APPENDED CDS 228 4.3.2 DANSYL-VALINE-APPENDED AND
DANSYL-PHENYLALANINE-APPENDED
CDS 122
4.4 MOLECULAR RECOGNITION BY REGIOISOMERS OF DANSYL-APPENDED CDS 223
4.4.1 6-0, 2-O, AND 3-O-DANSYL-Y-CDS 223 4.4.2 6-0, 2-0, AND
3-0-DANSYL-SS-CDS 225
4.5 TURN-ON FLUORESCENT CHEMOSENSORS 225 4.6 EFFECT OF PROTEIN
ENVIRONMENT ON MOLECULE SENSING 127 4.7 CD-PEPTIDE CONJUGATES AS
CHEMOSENSORS 228
IMAGE 3
CONTENTS VIL
4.8 IMMOBILIZED FLUORESCENT CD ON A CELLULOSE MEMBRANE 230
4.9 CONCLUSION 132
REFERENCES 232
5 CYCLOPEPTIDE DERIVED SYNTHETIC RECEPTORS 235 STEFAN KUBIK 5.1
INTRODUCTION 235
5.2 RECEPTORS FOR CATIONS 238
5.3 RECEPTORS FOR ION PAIRS 249
5.4 RECEPTORS FOR ANIONS 150
5.5 RECEPTORS FOR NEUTRAL SUBSTRATES 257 5.6 CONCLUSION 260
REFERENCES 262
6 BORONIC ACID-BASED RECEPTORS AND CHEMOSENSORS 269 XIAOCHUAN YANG,
YUNFENG CHENG, SHANJIN, AND BINGHE WANG 6.1 INTRODUCTION 269
6.2 DE NOVO DESIGN 272
6.3 COMBINATORIAL APPROACHES 277 6.4 TEMPLATE DIRECTED SYNTHESIS 282
REFERENCES 285
7 ARTIFICIAL RECEPTOR COMPOUNDS FOR CHIRAL RECOGNITION 291 THOMAS J.
WENZEL AND NGOC H. PHAM 7.1 INTRODUCTION 292
7.2 CYDODEXTRINS 292
7.2.1 ALKYLATED CYDODEXTRINS 292 7.2.2 ACYLATED AND MIXED
ACYLATED/ALKYLATED CYDODEXTRINS 294 7.2.3 CARBAMOYLATED CYDODEXTRINS 194
7.2.4 2-HYDROXYPROPYLETHER CYDODEXTRINS 195 7.2.5
TERT-BUTYLDIMETHYLSILYL CHLORIDE-SUBSTITUTED CYCLODEXTRINS 195 7.2.6
ANIONIC CYCLODEXTRINS 196
7.2.7 CATIONIC CYCLODEXTRINS 197 7.2.8 MISCELLANEOUS CYCLODEXTRINS 198
7.3 CROWN ETHERS 200
7.3.1 L,L'-BINAPHTHALENE-BASED CROWN ETHERS 202 7.3.2 CARBOHYDRATE-BASED
CROWN ETHERS 202 7.3.3 TARTARIC ACID-BASED CROWN ETHERS 204 7.3.4 CROWNS
ETHERS WITH PHENOL MOIETIES 206 7.3.5 CROWN ETHERS WITH PYRIDINE
MOIETIES 208 7.4 CALIXARENES 209
7.5 CALIX^JRESORCINARENES 228
7.6 MISCELLANEOUS RECEPTOR COMPOUNDS 225 7.7 METAL-CONTAINING RECEPTOR
COMPOUNDS 235 REFERENCES 237
IMAGE 4
VIII CONTENTS
8 FULLERENE RECEPTORS BASED ON CALIXARENE DERIVATIVES 249
PAVEL LHOTAK AND ONDFEJ KUNDRAT 8.1 INTRODUCTION 249
8.2 CALIXARENES 251
8.3 SOLID STATE COMPLEXATION BY CALIXARENES 252 8.4 COMPLEXATION IN
SOLUTION 257
8.5 CALIXARENES AS MOLECULAR SCAFFOLDS 263 8.6 OUTLOOK 268
REFERENCES 269
9 CUANIDINIUM BASED ANION RECEPTORS 273 CARSTEN SCHMUCK AND HANNES YACU
KUCHELMEISTER 9.1 INTRODUCTION 273
9.2 INSTRUCTIVE HISTORICAL EXAMPLES 275 9.3 RECENT ADVANCES IN INORGANIC
ANION RECOGNITION 283 9.4 ORGANIC AND BIOLOGICAL PHOSPHATES 287 9.5
POLYCARBOXYLATE BINDING 292
9.6 AMINO ACID RECOGNITION 297
9.7 DIPEPTIDES AS SUBSTRATE 301
9.8 POLYPEPTIDE RECOGNITION 303
9.9 CONDUSION 322
REFERENCES 313
10 ARTIFICIAL RECEPTORS BASED ON SPREADER-BAR SYSTEMS 329 THOMAS HIRSCH
REFERENCES 332
11 POTENTIAL OF APTAMERS AS ARTIFICIAL RECEPTORS IN CHEMICAL SENSORS 333
BETTINA APPEL, SABINE MUELLER, AND SABINE STINGEL 11.1 INTRODUCTION 333
11.2 GENERATION AND SYNTHESIS OF APTAMERS 334 11.2.1 SELECTION OF
APTAMERS FROM COMBINATORIAL LIBRARIES (SELEX) 334 11.2.2 SELEX
VARIATIONS 336
11.2.2.1 SELEX USING MODIFIED OLIGONUDEOTIDE LIBRARIES 336 11.2.2.2
PHOTOSELEX 336 11.2.2.3 AUTOMATED SELEX 337 11.2.3 ALTERNATIVE
APPROACHES FOR SELECTION OF APTAMERS
FROM COMBINATORIAL LIBRARIES 338 11.2.3.1 CAPILLARY ELECTROPHORESIS
TECHNIQUES 338 11.2.3.2 AFM TECHNIQUES 339 11.2.4 SYNTHESIS OF APTAMERS
AND STABILIZATION 339
11.2.4.1 CHEMICAL SYNTHESIS OF APTAMERS 339 11.2.4.2 STABILIZATION OF
APTAMERS 340 11.3 APTAMER ARRAYS 341
11.4 TECHNIQUES FOR READOUT OF LIGAND BINDING TO THE APTAMER 343
IMAGE 5
CONTENTS IX
11.4.1 CONFORMATIONAL EFFECTS 343
11.4.2 APTAZYMES 344 11.4.3 METHODS OF SENSING 345 11.4.3.1 OPTICAL
SENSING 345 11.4.3.2 ELECTROCHEMICAL SENSING 350 11.4.3.3 ACOUSTIC
SENSING 353 11.4.3.4 QUARTZ CRYSTAL MICROBALANCE BASED SENSING 354
11.4.3.5 CANTILEVER BASED SENSING 354 11.5 OUTLOOK/SUMMARY 354
REFERENCES 355
12 CONDUCTING POLYMERS AS ARTIFICIAL RECEPTORS IN CHEMICAL SENSORS 361
ULRICH LANGE, NATALIYA V. ROZNYATOVSKAYA, QINGLI HAO, AND VLADIMIR M.
MIRSKY 12 A INTRODUCTION 361
12.2 TRANSDUCERS FOR ARTIFICIAL RECEPTORS BASED ON CONDUCTING POLYMERS
362 12.3 INTRINSIC SENSITIVITY OF CONDUCTING POLYMERS 366 12.3.1
SENSITIVITY TO PH CHANGES 366 12.3.2 AFFINITY TO INORGANIC IONS 368
12.3.3 AFFINITY TO GASES AND VAPORS 368 12.4 CONDUCTING POLYMERS
MODIFIED WITH RECEPTOR GROUPS 369 12.4.1 CONDUCTING POLYMERS WITH
RECEPTOR GROUPS ATTACHED TO THE MONOMER 369
12.4.1.1 RECEPTORS FOR IONS 369 12.4.1.2 RECEPTORS FOR
ORGANIC/BIOORGANIC MOLECULES 382 12.4.2 CONDUCTING POLYMERS DOPED WITH
RECEPTOR 382 12.4.3 MOLECULAR IMPRINTING OF CONDUCTING POLYMERS 383
12.5 CONCLUSION 383
REFERENCES 384
13 MOLECULARLY IMPRINTED POLYMERS AS ARTIFICIAL RECEPTORS 392 FLORIAN
MEIER AND BORIS MIZAIKOFF 13.1 INTRODUCTION 392
13.2 FUNDAMENTALS OF MOLECULAR IMPRINTING 393 13.2.1 WHAT ARE MIPS? 393
13.2.2 APPROACHES TOWARD MOLECULAR IMPRINTED POLYMERS 394 13.2.2.1
NONCOVALENT IMPRINTING (SELF-ASSEMBLY APPROACH) 394
13.2.2.2 COVALENT IMPRINTING (PREORGANIZED APPROACH) 395 13.2.2.3
SEMI-COVALENT IMPRINTING 395 13.2.2.4 ADVANTAGES AND DISADVANTAGES OF
DIFFERENT IMPRINTING APPROACHES 396
13.2.3 REAGENTS AND SOLVENTS IN MOLECULAR IMPRINTING TECHNOLOGY 396
13.2.3.1 FUNCTIONAL MONOMERS 396 13.2.3.2 CROSSLINKERS 397
IMAGE 6
X CONTENTS
13.2.3.3 RADICAL INITIATORS 401
13.2.3.4 SOLVENTS 402 13.2.4 HOW ARE MIPS PREPARED? 404 13.3 POLYMER
FORMATS AND POLYMERIZATION METHODS FOR MIPS 405 13.3.1 BULK POLYMERS 405
13.3.2 MICRO- AND NANOBEADS 407 13.3.3 MIP FILMS AND MEMBRANES 408
13.3.4 COMPARISON OF MIP FORMATS PREPARED BY DIFFERENT POLYMERIZATION
METHODS 422 13.4 EVALUATION OF MIP PERFORMANCE - IMPRINTING EFFKIENCY
414 13.4.1 BINDING CAPACITY AND BINDING AFFINITY 424 13.4.2 BINDING
SELECTIVITY 418
13.5 MIPS MIMICKING NATURAL RECEPTORS 420 13.5.1 COMPARISON OF MIPS AND
ANTIBODIES 422 13.5.2 MIPS AS ARTIFICIAL ANTIBODIES IN
PSEUDO-IMMUNOASSAYS 422 13.5.3 MIPS AS CATALYSTS WITH ENZYMATIC ACTIVITY
425 13.5.4 QUANTITATIVE DATA ON THE BINDING PROPERTIES OF MIPS 427
13.6 CONCLUSIONS AND OUTLOOK 427 REFERENCES 430
14 QUANTITATIVE AFFINITY DATA ON SELECTED ARTIFICIAL RECEPTORS 439
ANATOLY K. YATSIMIRSKY AND VLADIMIR M. MIRSKY 14.1 STRUCTURES OF
RECEPTORS 449
REFERENCES 458
INDEX 461 |
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| id | DE-604.BV036890005 |
| illustrated | Illustrated |
| indexdate | 2024-07-20T10:54:43Z |
| institution | BVB |
| isbn | 9783527323579 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-020805212 |
| oclc_num | 703893424 |
| open_access_boolean | |
| owner | DE-11 DE-634 DE-19 DE-BY-UBM |
| owner_facet | DE-11 DE-634 DE-19 DE-BY-UBM |
| physical | XV, 469 S. Ill., graph. Darst. |
| publishDate | 2011 |
| publishDateSearch | 2011 |
| publishDateSort | 2011 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Artificial receptors for chemical sensors ed. by Vladimir M. Mirsky... Weinheim Wiley-VCH 2011 XV, 469 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chemischer Sensor (DE-588)4259288-4 gnd rswk-swf Modellverbindung (DE-588)4327521-7 gnd rswk-swf Rezeptor (DE-588)4049722-7 gnd rswk-swf Chemischer Sensor (DE-588)4259288-4 s Rezeptor (DE-588)4049722-7 s Modellverbindung (DE-588)4327521-7 s DE-604 Mirsky, Vladimir M. (DE-588)129439320 edt text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3294473&prov=M&dok%5Fvar=1&dok%5Fext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020805212&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Artificial receptors for chemical sensors Chemischer Sensor (DE-588)4259288-4 gnd Modellverbindung (DE-588)4327521-7 gnd Rezeptor (DE-588)4049722-7 gnd |
| subject_GND | (DE-588)4259288-4 (DE-588)4327521-7 (DE-588)4049722-7 |
| title | Artificial receptors for chemical sensors |
| title_auth | Artificial receptors for chemical sensors |
| title_exact_search | Artificial receptors for chemical sensors |
| title_full | Artificial receptors for chemical sensors ed. by Vladimir M. Mirsky... |
| title_fullStr | Artificial receptors for chemical sensors ed. by Vladimir M. Mirsky... |
| title_full_unstemmed | Artificial receptors for chemical sensors ed. by Vladimir M. Mirsky... |
| title_short | Artificial receptors for chemical sensors |
| title_sort | artificial receptors for chemical sensors |
| topic | Chemischer Sensor (DE-588)4259288-4 gnd Modellverbindung (DE-588)4327521-7 gnd Rezeptor (DE-588)4049722-7 gnd |
| topic_facet | Chemischer Sensor Modellverbindung Rezeptor |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3294473&prov=M&dok%5Fvar=1&dok%5Fext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020805212&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT mirskyvladimirm artificialreceptorsforchemicalsensors |