Optical properties of nanoparticle systems: Mie and beyond
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2011
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| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XIV, 488 S. Ill., graph. Darst. |
| ISBN: | 9783527410439 |
Internformat
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IMAGE 1
VIL
CONTENTS
PREFACE XIII
1 INTRODUCTION 1
2 NANOPARTICLE SYSTEMS AND EXPERIMENTAL OPTICAL OBSERVABLES 9 2.1
CLASSIFICATION OF NANOPARTICLE SYSTEMS 10 2.2 STABILITY OF NANOPARTICLE
SYSTEMS 14 2.3 EXTINCTION, OPTICAL DENSITY, AND SCATTERING 21 2.3.1 THE
ROLE OFTHE PARTIDE MATERIAL DATA 25
2.3.2 THE ROLE OF THE PARTICLE SIZE 26 2.3.3 THE ROLE OFTHE PARTICLE
SHAPE 29 23 A THE ROLE OFTHE PARTICLE CONCENTRATION 33
2.3.4.1 DILUTE SYSTEMS 33 2.3.4.2 CLOSELY PACKED SYSTEMS 34
3 INTERACTION OF LIGHT WITH MATTER - THE OPTICAL MATERIAL FUNCTION 37
3.1 CLASSICAL DESCRIPTION 37
3.1.1 THE HARMONIE OSCILLATOR MODEL 38 3.1.2 EXTENSIONS OFTHE HARMONIE
OSCILLATOR MODEL 40 3.1.3 THE DRUDE DIELECTRIC FUNCTION 41 3.2 QUANTUM
MECHANICAL CONCEPTS 42
3.2.1 THE HUBBARD DIELECTRIC FUNCTION 43 3.2.2 INTERBAND TRANSITIONS 47
3.3 TAUC-LORENTZ AND OJL MODELS 50 3.4 KRAMERS-KRONIG RELATIONS AND
PENETRATION DEPTH 52
4 FUNDAMENTALS OF LIGHT SCATTERING BY AN OBSTACLE 55 4.1 MAXWELL'S
EQUATIONS AND THE HELMHOLTZ EQUATION 56 4.2 ELECTROMAGNETIC FIELDS 59
4.3 BOUNDARY CONDITIONS 61
4.4 POYNTING'S LAW AND CROSS-SECTIONS 62 4.5 FAR-FIELD AND NEAR-FIELD 65
OPTICAL PROPERTICS OF NANOPARTICLE SYSTEMS: MIE AND BEYOND. MICHAE!
QUINTEN COPYRIGHT 2011 WILEY-VCH VERLAG GMBH & CO. KGAA, WEINHEIM
ISBN: 978-3-527-41043-9
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1005391394
DIGITALISIERT DURCH
IMAGE 2
VIII I CONTENTS
4.6 THE INCIDENT ELECTROMAGNETIC WAVE 66
4.7 RAYLEIGH'S APPROXIMATION FOR SMALL PARTICLES - THE DIPOLE
APPROXIMATION 69 4.8 RAYLEIGH-DEBYE-GANS APPROXIMATION FOR VANISHING
OPTICAL CONTRAST 71
5 MIE'S THEORY FOR SINGLE SPHERICAL PARTICLES 75 5.1 ELECTROMAGNETIC
FIELDS AND BOUNDARY CONDITIONS 76 5.2 CROSS-SECTIONS, SCATTERING
INTENSIFIES, AND RELATED QUANTIFIES 83 5.3 RESONANCES 87
5.3.1 GEOMETRIE RESONANCES 88 5.3.2 ELECTRONIC RESONANCES AND SURFACE
PLASMON POLARITONS 92 5.3.2.1 ELECTRONIC RESONANCES 92 5.3.2.2 SURFACE
PLASMON POLARITON RESONANCES 94 5.3.2.3 MULTIPLE RESONANCES 101 5.3.3
LONGITUDINAL PLASMON RESONANCES 104 5.4 OPTICAL CONTRAST 208 5.5
NEAR-FIELD 112
5.5.1 SOME FURTHER DETAILS 122
6 APPLICATION OF MIE'S THEORY 123 6.1 DRUDE METAL PARTICLES (AL, NA, K)
124 6.2 NOBLE METAL PARTICLES (CU, AG, AU) 127 6.2.1 CALCULATIONS 127
6.2.2 EXPERIMENTAL EXAMPLES 129 6.2.2.1 COLLOIDAL AU AND AG SUSPENSIONS
229 6.2.2.2 GOLD AND SILVER NANOPARTICLES IN GLASS 232 6.2.2.3 COPPER
NANOPARTICLES IN GLASS AND SILICA 232 6.2.2.4 AGXAUJ-X AUOY
NANOPARTICLES IN PHOTOSENSITIVE GLASS 234 6.2.2.5 SILVER AEROSOLS 135
6.2.2.6 FURTHER EXPERIMENTS 137 6.3 CATALYST METAL PARTICLES (PT, PD,
RH) 139 6.4 MAGNETIC METAL PARTICLES (FE, NI, CO) 242 6.5 RARE EARTH
METAL PARTICLES (SE, Y, ER) 142 6.6 TRANSITION METAL PARTICLES (V, NB,
TA) 245 6.7 SUMMARY OF METAL PARTICLES 247 6.8 SEMIMETAL PARTICLES (TIN,
ZRN) 148 6.9 SEMICONDUCTOR PARTICLES (SI, SIC, CDTE, ZNSE) 252 6.9.1
CALCULATIONS 252 6.9.2 EXPERIMENTAL EXAMPLES 254 6.9.2.1 SI
NANOPARTICLES IN POLYACRYLENE 254 6.9.2.2 QUANTUM CONFINEMENT IN CDSE
NANOPARTICLES 254 6.10 CARBONACEOUS PARTICLES 156 6.11 ABSORBING OXIDE
PARTICLES (FE 2 O 3 , CR 2 O 3 , CU 2 O, CUO) 262 6.11.1 CALCULATIONS
262
IMAGE 3
CONTENTS IX
6.11.2 EXPERIMENTAL EXAMPLES 263
6.11.2.1 AEROSOLS OF FE 2 OJ 263 6.11.2.2 AEROSOLS OFCU 2 O AND CUO 265
6.11.2.3 COLLOIDAL FE 2 O 3 NANOPARTICLES 167 6.12 TRANSPARENT OXIDE
PARTICLES (SIO 2 , A1 2 O 3 , CEO 2 , TIO 2 ) 168 6.13 PARTICLES WITH
PHONON POLARITONS (MGO, NACL, CAF 2 ) 270 6.14 MISCELLANEOUS
NANOPARTICLES (ITO, LAB 6 , EUS) 272
7 EXTENSIONS OF MIE'S THEORY 277 7.1 COATED SPHERES 277
7.1.1 CALCULATIONS 177
7.1.1.1 METALLIC SHELLS ON A TRANSPARENT CORE 280 7.1.1.2 OXIDE SHELLS
ON METAL AND SEMICONDUCTING CORE PARTICLES 284 7.1.2 EXPERIMENTAL
EXAMPLES 287
7.1.2.1 AG-AU AND AU-AG CORE-SHELL PARTICLES 187 7.1.2.2 MULTISHELL
NANOPARTICLES OF AG AND AU 289 7.1.2.3 OPTICAL BISTABILITY IN
SILVER-COATED CDS NANOPARTICLES 290 7.1.2.4 AG AND AU AEROSOLS WITH SALT
SHELLS 193
7.1.2.5 FURTHER EXPERIMENTS 296 7.2 SUPPORTED NANOPARTICLES 298 7.3
CHARGED NANOPARTICLES 206
7.4 ANISOTROPIE MATERIALS 220
7.4.1 DICHROISM 220
7.4.2 FIELD-INDUCED ANISOTROPY 222 7.4.3 GRADIENT-INDEX MATERIALS 213
7.4.4 OPTICALLY ACTIVE MATERIALS 223 7.5 ABSORBING EMBEDDING MEDIA 214
7.5.1 CALCULATIONS 224
7.5.2 EXPERIMENTAL EXAMPLES 229 7.5.2.1 ABSORPTION OF SCATTERED LIGHT IN
AG AND AU COLLOIDS 229 7.5.2.2 AG AND FE NANOPARTICLES IN FULLERENE FILM
220 7.6 INHOMOGENEOUS INCIDENT WAVES 223 7.6.1 GAUSSIAN BEAM
ILLUMINATION 223 7.6.2 EVANESCENT WAVES FROM TOTAL INTERNAI REFLECTION
226
8 LIMITATIONS OF MIE'S THEORY-SIZE AND QUANTUM SIZE EFFECTS IN VERY
SMALL NANOPARTICLES 233 8.1 BOUNDARY CONDITIONS-THE SPILL-OUT EFFECT 233
8.2 FREE PATH EFFECT IN NANOPARTICLES 234 8.3 CHEMICAL INTERFACE
DAMPING-DYNAMIC CHARGE TRANSFER 240
9 BEYOND MIE'S THEORY I-NONSPHERICAL PARTICLES 245 9.1 SPHEROIDS AND
ELLIPSOIDS 247
9.1.1 SPHEROIDS (ELLIPSOIDS OF REVOLUTION) 247 9.1.1.1 ELECTROMAGNETIC
FIELDS 248
IMAGE 4
X CONTENTS
9.1.1.2 SCATTERING COEFFICIENTS 252 9.1.1.3 CROSS-SECTIONS 252 9.1.1.4
RESONANCES 252 9.1.1.5 NUMERICAL EXAMPLES 254 9.1.1.6 EXTENSIONS 254
9.1.2 ELLIPSOIDS (RAYLEIGH APPROXIMATION) 255 9.1.3 NUMERICAL EXAMPLES
FOR ELLIPSOIDS 259 9.1.3.1 METAL PARTICLES 259 9.1.3.2 SEMIMETAL AND
SEMICONDUCTOR PARTICLES 265 9.1.3.3 CARBONACEOUS PARTICLES 266 9.1.3.4
PARTICLES WITH PHONON POLARITONS 267 9.1.3.5 MISCELLANEOUS PARTICLES 267
9.1.4 EXPERIMENTAL RESULTS 268
9.1.4.1 PROLATE SPHEROIDAL SILVER PARTICLES IN FOURCAULT GLASS 268
9.1.4.2 PLASMA POLYMER FILMS WITH NONSPHERICAL SILVER PARTICLES 269
9.1.4.3 FURTHER EXPERIMENTS 272 9.2 CYLINDERS 273
9.2.1 ELECTROMAGNETIC FIELDS AND SCATTERING COEFFICIENTS 273 9.2.2
EFIICIENRIES AND SCATTERING INTENSITIES 277 9.2.3 RESONANCES 279 9.2.4
EXTENSIONS 282
9.2.5 NUMERICAL EXAMPLES 282 9.2.5.1 METAL PARTICLES 283 9.2.5.2
SEMIMETAL AND SEMICONDUCTOR PARTICLES 288 9.2.5.3 CARBONACEOUS PARTICLES
291 9.2.5.4 OXIDE PARTICLES 292 9.2.5.5 PARTICLES WITH PHONON POLARITONS
293 9.2.5.6 MISCELLANEOUS PARTICLES 294 9.3 CUBIC PARTICLES 296 9.3.1
THEORETICAL CONSIDERATIONS 296 9.3.2 NUMERICAL EXAMPLES 298 9.3.2.1
METAL PARTICLES 299
9.3.2.2 SEMIMETAL AND SEMICONDUCTOR PARTICLES 299 9.3.2.3 PARTICLES WITH
PHONON POLARITONS 300 9.3.2.4 MISCELLANEOUS PARTICLES 301 9.4 NUMERICAL
METHODS 302 9.4.1 DISCRETE DIPOLE APPROXIMATION 302 9.4.2 T-MATRIX
METHOD OR EXTENDED BOUNDARY CONDITION METHOD 305 9.4.3 OTHER NUMERICAL
METHODS 307
9.4.3.1 POINT MATCHING METHOD 307 9.4.3.2 DISCRETIZED MIE FORMALISM 307
9.4.3.3 GENERALIZED MULTIPOLE TECHNIQUE 307 9.4.3.4 FINITE DIFFERENCE
TIME DOMAIN TECHNIQUE 307 9.5 APPLICATION OF NUMERICAL METHODS TO
NONSPHERICAL
NANOPARTICLES 308
IMAGE 5
CONTENTS XI
9.5.1 NONMETALLIC NANOPARTICLES 308
9.5.2 METALLIC NANOPARTICLES 310
10 BEYOND MIE'S THEORY IL-THE GENERALIZED MIE THEORY 327 10.1 DERIVATION
OF THE GENERALIZED MIE THEORY 318 10.2 RESONANCES 322
10.3 COMMON RESULTS 325
10.3.1 INFLUENCE OF SHAPE 325 10.3.2 INFLUENCE OF LENGTH 327 10.3.3
INFLUENCE OF INTERPARTICLE DISTANCE 327 10.3.4 ENHANCEMENT OF SCATTERING
AND EXTINCTION 329
10.3.5 THE PROBLEM OF CONVERGENCE 332 10.4 EXTENSIONS OFTHE GENERALIZED
MIE THEORY 335 10.4.1 INCIDENT BEAM 335
10.4.2 NONSPHERICAL PARTICLES 336
11 THE GENERALIZED MIE THEORY APPLIED TO DIFFERENT SYSTEMS 341 11.1
METAL PARTICLES 342
11.1.1 CALCULATIONS 342 11.1.2 EXPERIMENTAL RESULTS 346 11.1.2.1
EXTINCTION OF LIGHT IN COLLOIDAL GOLD AND SILVER SYSTEMS 346 11.1.2.2
TOTAL SCATTERING OF LIGHT BY AGGREGATES 353 11.1.2.3 ANGLE-RESOLVED
LIGHT SCATTERING BY NANOPARTICLE AGGREGATES 355 11.1.2.4 PTOBD ON
AGGREGATED GOLD AND SILVER NANOCOMPOSITES 358 11.1.2.5 LIGHT-INDUCED VAN
DER WAALS ATTRACTION 360 11.1.2.6 COALESCENCE OF NANOPARTICLES 362
11.1.2.7 FURTHER EXPERIMENTS WITH GOLD AND SILVER NANOPARTICLES 363 11.2
SEMIMETAL AND SEMICONDUCTOR PARTICLES 364 11.3 NONABSORBING DIELECTRICS
367 11.4 CARBONACEOUS PARTICLES 369 11.5 PARTICLES WITH PHONON
POLARITONS 372 11.6 MISCELLANEOUS PARTICLES 375 11.7 AGGREGATES OF
NANOPARTICLES OF DIFFERENT MATERIALS 376 11.8 OPTICAL PARTICLE SIZING
379 11.9 STOCHASTICALLY DISTRIBUTED SPHERES 382 11.10 AGGREGATES OF
SPHERES AND NUMERICAL METHODS 387 11.10.1 APPLICATIONS OFTHE DISCRETE
DIPOLE APPROXIMATION 387 11.10.2 APPLICATIONS OFTHE T-MATRIX APPROACH
389 11.10.3 OTHER METHODS 389
12 DENSELY PACKED SYSTEMS 393 12.1 THE TWO-FLUX THEORY OF KUBELKA AND
MUNK 394 12.2 APPLICATIONS OFTHE KUBELKA-M UNK THEORY 397 12.2.1 DENSE
SYSTEMS OF COLOR PIGMENTS: CR 2 O 3 , FE 2 O 3 , AND CU 2 O 398
12.2.2 DENSE SYSTEMS OFWHITE PIGMENTS: SIO 2 AND TIO 2 399
IMAGE 6
X I II CONTENTS
12.2.3 DENSE SYSTEMS OF ZRN AND TIN NANOPARTICLES 400
12.2.4 DENSE SYSTEMS OF SILICON NANOPARTICLES 401 12.2.5 DENSE SYSTEMS
OF IR ABSORBERS: ITO AND LAB 6 403 12.2.6 DENSE SYSTEMS OF NOBLE METALS:
AG AND AU 404 12.2.7 THE LYCURGUS CUP 406 12.3 IMPROVEMENTS OF THE
KUBELKA-MUNK THEORY 407
13 NEAR-FIELD AND SERS 422
13.1 WAVEGUIDING ALONG PARTICLE CHAINS 412 13.2 SCANNING NEAR-FIELD
OPTICAL MICROSCOPY 416 13.3 SERS WITH AGGREGATES 420
14 EFFECTIVE MEDIUM THEORIES 427
14.1 THEORETICAL RESULTS FOR DIELECTRIC NANOPARTICLE COMPOSITES 432 14.2
THEORETICAL RESULTS FOR METAL NANOPARTICLE COMPOSITES 433 14.3
EXPERIMENTAL EXAMPLES 437
REFERENCES 442 COLOR PLATES 479 INDEX 485 |
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| id | DE-604.BV036806854 |
| illustrated | Illustrated |
| indexdate | 2024-07-20T10:53:10Z |
| institution | BVB |
| isbn | 9783527410439 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-020722924 |
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| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Quinten, Michael Verfasser (DE-588)111740789 aut Optical properties of nanoparticle systems Mie and beyond Michael Quinten Weinheim Wiley-VCH 2011 XIV, 488 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Nanopartikel (DE-588)4333369-2 gnd rswk-swf Lichtstreuung (DE-588)4167602-6 gnd rswk-swf Optische Eigenschaft (DE-588)4123887-4 gnd rswk-swf Nanopartikel (DE-588)4333369-2 s Optische Eigenschaft (DE-588)4123887-4 s Lichtstreuung (DE-588)4167602-6 s DE-604 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3520449&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020722924&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Quinten, Michael Optical properties of nanoparticle systems Mie and beyond Nanopartikel (DE-588)4333369-2 gnd Lichtstreuung (DE-588)4167602-6 gnd Optische Eigenschaft (DE-588)4123887-4 gnd |
| subject_GND | (DE-588)4333369-2 (DE-588)4167602-6 (DE-588)4123887-4 |
| title | Optical properties of nanoparticle systems Mie and beyond |
| title_auth | Optical properties of nanoparticle systems Mie and beyond |
| title_exact_search | Optical properties of nanoparticle systems Mie and beyond |
| title_full | Optical properties of nanoparticle systems Mie and beyond Michael Quinten |
| title_fullStr | Optical properties of nanoparticle systems Mie and beyond Michael Quinten |
| title_full_unstemmed | Optical properties of nanoparticle systems Mie and beyond Michael Quinten |
| title_short | Optical properties of nanoparticle systems |
| title_sort | optical properties of nanoparticle systems mie and beyond |
| title_sub | Mie and beyond |
| topic | Nanopartikel (DE-588)4333369-2 gnd Lichtstreuung (DE-588)4167602-6 gnd Optische Eigenschaft (DE-588)4123887-4 gnd |
| topic_facet | Nanopartikel Lichtstreuung Optische Eigenschaft |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3520449&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020722924&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT quintenmichael opticalpropertiesofnanoparticlesystemsmieandbeyond |