Carbocations and electrophilic reactions:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim [u.a.]
Verlag Chemie [u.a.]
1974
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Dt. Ausg. u. d. T.: Olah, George A.: Carbokationen und elektrophile Reaktionen. - Literaturverz. S. 135 - 148 |
| Beschreibung: | 148 S. Ill., graph. Darst. |
| ISBN: | 3527255613 0471653144 |
Internformat
MARC
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| 003 | DE-604 | ||
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| 020 | |a 0471653144 |c (Wiley) kart. |9 0-471-65314-4 | ||
| 035 | |a (OCoLC)831088208 | ||
| 035 | |a (DE-599)DNB740120573 | ||
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| 100 | 1 | |a Olah, George A. |d 1927-2017 |e Verfasser |0 (DE-588)123159172 |4 aut | |
| 245 | 1 | 0 | |a Carbocations and electrophilic reactions |c George A. Olah |
| 264 | 1 | |a Weinheim [u.a.] |b Verlag Chemie [u.a.] |c 1974 | |
| 300 | |a 148 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Dt. Ausg. u. d. T.: Olah, George A.: Carbokationen und elektrophile Reaktionen. - Literaturverz. S. 135 - 148 | ||
| 650 | 0 | 7 | |a Carbokation |0 (DE-588)4147294-9 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Elektrophile Reaktion |0 (DE-588)4151948-6 |2 gnd |9 rswk-swf |
| 653 | 0 | |a Carbokation | |
| 653 | 0 | |a Reaktion, Elektrophile | |
| 653 | 0 | |a Karbokation | |
| 653 | 0 | |a Chemische Reaktion | |
| 689 | 0 | 0 | |a Elektrophile Reaktion |0 (DE-588)4151948-6 |D s |
| 689 | 0 | |8 1\p |5 DE-604 | |
| 689 | 1 | 0 | |a Carbokation |0 (DE-588)4147294-9 |D s |
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Datensatz im Suchindex
| _version_ | 1808047029635514368 |
|---|---|
| adam_text |
CONTENTS
INTRODUCTION
1.
GENERAL
CONCEPT
.
9
1.1.
DEFINITION
AND
DIFFERENTIATION
OF
CARBENIUM
AND
CARBONIUM
IONS
.
9
1.2.
DEVELOPMENT
OF
MODEM
THEORY:
KINETIC
AND
STEREOCHEMICAL
STUDIES
.
13
1.3.
OBSERVATION
OF
STABLE,
LONG-LIVED
IONS
.
.
14
2.
PREPARATION
AND
STRUCTURE
OF
STABLE
TRIVALENT
CARBENIUM
IONS
.
15
2.1.
ALKYLCARBENIUM
IONS
(ALKYL
CATIONS)
.
.
15
2.2.
CYCLOPROPYLCARBENIUM
IONS
.
33
2.3.
ALKENYL
CATIONS
.
36
2.4.
ALKADIENYL
AND
POLYENYL
CATIONS
.
38
2.5.
ARENIUMLONS
.
38
2.6.
CYCLOALKYL
CATIONS
.
42
2.7.
BRIDGEHEAD
CARBENIUM
IONS
.
44
2.8.
ARYL
AND
ALKYLARYLCARBENIUM
IONS
.
46
2.9.
DICARBENIUM
IONS
.
51
2.10.
AROMATICALLY
STABILIZED
CARBENIUM
IONS
.
54
2.11.
HETEROATOM-STABILIZED
CARBENIUM
IONS
.
.
55
2.12.
HALOGEN
AS
HETEROATOM
.
55
2.13.
OXYGEN
AS
HETEROATOM
.
59
2.14.
SULFUR
AS
HETEROATOM
.
70
2.15.
NITROGEN
AS
HETEROATOM
.
70
3.
EQUILIBRATING
CARBENIUM
IONS
OR
STATIC
CARBONIUM
IONS?
THE
CLASSICAL-NONCLASSICAL
ION
CONTROVERSY
72
3.1.
EQUILIBRATING
ALKYLCARBENIUM
IONS
.
73
3.2.
THE
EQUILIBRATING
CYCLOPENTYL
CATION
.
.
78
3.3.
THE
NORBOMYL
CATION
.
80
3.4.
CYCLOPROPYLMETHYL
AND
CYCLOBUTYL
CATIONS
89
3.5.
ETHYLENEARENIUM
IONS
.
94
4.
THE
ROLE
OF
CARBOCATIONS
IN
ELECTROPHILIC
REACTIONS
.
95
4.1.
GENERAL
CONSIDERATIONS
.
95
4.2.
FORMATION
OF
METHONIUM
ION
(THE
SIMPLEST
CARBONIUM
ION)
FROM
METHANE
.
96
4.3.
BORON
ANALOGS
OF
CARBOCATIONS
.
98
4.4.
STERIC
EFFECTS
IN
THE
FORMATION
OF
CARBONIUM
IONS
.
99
4.5.
ELECTROPHILIC
REACTIONS
AT
SINGLE
BONDS:
O-DONOR
SYSTEMS
.
100
4.6.
PROTOLYSIS
AND
HYDROGEN-DEUTERIUM
EXCHANGE
.
102
4.7.
ALKYLATION
.
108
4.8.
NITRATION
.
112
4.9.
CHLORINATION
.
113
4.10.
REARRANGEMENTS
AND
RELATED
TRANSFORMATIONS
.
116
4.11.
THE
QUESTION
OF
HYPERCONJUGATION
.
122
4.12.
CONCERNING
THE
MECHANISM
OF
ELECTROPHILIC
REACTIONS
OF
JT-DONOR
SYSTEMS
.
123
5.
OUTLOOK
.
131
REFERENCES
.
135 |
| any_adam_object | 1 |
| author | Olah, George A. 1927-2017 |
| author_GND | (DE-588)123159172 |
| author_facet | Olah, George A. 1927-2017 |
| author_role | aut |
| author_sort | Olah, George A. 1927-2017 |
| author_variant | g a o ga gao |
| building | Verbundindex |
| bvnumber | BV036772961 |
| ctrlnum | (OCoLC)831088208 (DE-599)DNB740120573 |
| dewey-full | 547.4 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.4 |
| dewey-search | 547.4 |
| dewey-sort | 3547.4 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV036772961 |
| illustrated | Illustrated |
| indexdate | 2024-08-22T00:53:34Z |
| institution | BVB |
| isbn | 3527255613 0471653144 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-020689781 |
| oclc_num | 831088208 |
| open_access_boolean | |
| owner | DE-11 DE-210 |
| owner_facet | DE-11 DE-210 |
| physical | 148 S. Ill., graph. Darst. |
| psigel | HUB-ZB011201011 |
| publishDate | 1974 |
| publishDateSearch | 1974 |
| publishDateSort | 1974 |
| publisher | Verlag Chemie [u.a.] |
| record_format | marc |
| spelling | Olah, George A. 1927-2017 Verfasser (DE-588)123159172 aut Carbocations and electrophilic reactions George A. Olah Weinheim [u.a.] Verlag Chemie [u.a.] 1974 148 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Dt. Ausg. u. d. T.: Olah, George A.: Carbokationen und elektrophile Reaktionen. - Literaturverz. S. 135 - 148 Carbokation (DE-588)4147294-9 gnd rswk-swf Elektrophile Reaktion (DE-588)4151948-6 gnd rswk-swf Carbokation Reaktion, Elektrophile Karbokation Chemische Reaktion Elektrophile Reaktion (DE-588)4151948-6 s 1\p DE-604 Carbokation (DE-588)4147294-9 s 2\p DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020689781&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Olah, George A. 1927-2017 Carbocations and electrophilic reactions Carbokation (DE-588)4147294-9 gnd Elektrophile Reaktion (DE-588)4151948-6 gnd |
| subject_GND | (DE-588)4147294-9 (DE-588)4151948-6 |
| title | Carbocations and electrophilic reactions |
| title_auth | Carbocations and electrophilic reactions |
| title_exact_search | Carbocations and electrophilic reactions |
| title_full | Carbocations and electrophilic reactions George A. Olah |
| title_fullStr | Carbocations and electrophilic reactions George A. Olah |
| title_full_unstemmed | Carbocations and electrophilic reactions George A. Olah |
| title_short | Carbocations and electrophilic reactions |
| title_sort | carbocations and electrophilic reactions |
| topic | Carbokation (DE-588)4147294-9 gnd Elektrophile Reaktion (DE-588)4151948-6 gnd |
| topic_facet | Carbokation Elektrophile Reaktion |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020689781&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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