Enantioselective transition metal mediated dehydrogenation in the gas phase: from model systems toward real-life catalysis
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin
Logos-Verl.
2010
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | III, 180 S. graph. Darst. |
| ISBN: | 9783832526719 |
Internformat
MARC
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| 246 | 1 | |a Enantioselective transition-metal mediated dehydrogenation in the gas phase | |
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Datensatz im Suchindex
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IMAGE 1
CONTENTS
1 INTRODUCTION 1
2 MCTHODOLOGICAL OVERVIEW 9
2.1 THEORY OF GAS-PHASE REACTIONS 10
2.1.1 UNIMOLECULAR REACTIONS 10
2.1.2 THEORY OF ION-MOLECULE REACTIONS 17
2.1.3 ISOTOPIC LABELING STUDIES 21
2.2 GENERATION OF IONS IN THE GAS PHASE 23
2.2.1 ELECTROSPRAY IONIZATION 23
2.2.2 LASER VAPORIZATION 32
2.3 MASS ANALYZERS 34
2.3.1 QUADRUPOLE ANALYZERS 35
2.3.2 FT-ICR 39
3 GASEOUS CHIRAL METAL COMPLEXES 45
3.1 REACTIONS OF TRANSITION METALS WITH A MIXTURE OF ENAN- TIOMERIC
ALCOHOLS 46
3.2 REACTIONS OF TRANSITION METALS WITH A MIXTURE OF ENAN- TIOMERIC
METHYL LACTATES 49
3.3 SUMMARY 51
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1007903406
DIGITALISIERT DURCH
IMAGE 2
CONTENTS
4 [(BINOLATO)M]+ AND [(BINOLATO)M(ROH)]+ COMPLEXES 53
4.1 BINOL: A VERSATILE CHIRAL LIGAND 55
4.2 STRUCTURE AND ENERGETICS OF [(BINOL)FE] + COMPLEXES . . 58
4.3 [(BINOLATO)FE(ROH)]+ COMPLEXES 66
4.4 SUMMARY OF THE RESULTS FOR THE [(BINOLATO)FE] + SYSTEM . . 66
4.5 BINOLATO COMPLEXES OF OTHER TRANSITION METALS 68
4.6 SUMMARY 73
5 ENANTIOSELECTIVE BOND ACTIVATION BY [(BINOLATO)NI] + IONS 75
5.1 ANAYLSIS OF THE ESI SOURCE SPECTRA 76
5.2 THE REACTION MECHANISM 79
5.2.1 LABELING EXPERIMENTS 82
5.2.2 KINETIC ISOTOPE EFFECTS 84
5.3 PES OF [(BINOLATO)NI(ROH)]+ COMPLEXES 84
5.3.1 EXPERIMENTAL FINDINGS 85
5.3.2 DFT CALCULATIONS 89
5.4 THE STEREOCHEMICAL EFFECT 94
5.5 DECONVOLUTION OF THE CHIRAL EFFECT 100
5.6 SUMMARY 105
6 VARIATIONS ON A THEME 107
6.1 CHANGING THE CHIRAL SUBSTRATES 108
6.1.1 CID OF [(BINOLATO)NI(ETHYL LACTATE)]+COMPLEXES . 108
6.1.2 CIDOF[(BINOLATO)NI(ETHYL-3-HYDROXYBUTYRATE)] +
COMPLEXES 112
6.1.3 CID OF [(BINOLATO)NI(SEC-BUTYLAMINE)]+ COMPLEXES 119
6.2 CHANGING THE CHIRAL LIGAND 119
6.2.1 COMPLEXES WITH ETHYL LACTATE 120
IMAGE 3
CONTENTS
6.2.2 COMPLEXES WITH ETHYL-3-HYDROXYBUTYRATE 121
6.2.3 COMPLEXES WITH CHIRAL SECONDARY ALCOHOLS 125
6.3 SUMMARY 128
7 LIGAND-INDUCED REACTION PATHWAYS 131
7.1 THE 2,2'-BISPHENOL SYSTEM 132
7.2 THE HYDROBENZOIN SYSTEM 134
7.3 THE L,2-DICYCLOHEXYL-L,2-ETHANEDIOL SYSTEM 140
7.4 SUMMARY 140
8 FROM GAS-PHASE MODELS TOWARDS REAL-LIFE CATALYSTS 143
8.1 GENERATION OF [(BINAP)RU]+ CATIONS IN THE GAS PHASE . . 144
8.2 GENERATION OF GASEOUS [(BINAP)RUCL(DIAMINE)] + COMPLEXESL49
8.3 SUMMARY 153
9 CONCLUSIONS AND OUTLOOK 155
10 BIBLIOGRAPHY 161
LIST OF PUBLICATIONS 181
CURRICULUM VITAE 182 |
| any_adam_object | 1 |
| author | Novara, Francesca Rita 1979- |
| author_GND | (DE-588)142726516 |
| author_facet | Novara, Francesca Rita 1979- |
| author_role | aut |
| author_sort | Novara, Francesca Rita 1979- |
| author_variant | f r n fr frn |
| building | Verbundindex |
| bvnumber | BV036758552 |
| ctrlnum | (OCoLC)694880706 (DE-599)DNB1007903406 |
| dewey-full | 547.215 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.215 |
| dewey-search | 547.215 |
| dewey-sort | 3547.215 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| spelling | Novara, Francesca Rita 1979- Verfasser (DE-588)142726516 aut Enantioselective transition metal mediated dehydrogenation in the gas phase from model systems toward real-life catalysis vorgelegt von Francesca Rita Novara Enantioselective transition-metal mediated dehydrogenation in the gas phase Berlin Logos-Verl. 2010 III, 180 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Zugl.: Berlin, Techn. Univ., Diss., 2010 Asymmetrische Reaktion (DE-588)4143270-8 gnd rswk-swf Katalytische Dehydrierung (DE-588)4163421-4 gnd rswk-swf Reaktionsmechanismus (DE-588)4177123-0 gnd rswk-swf Massenspektrometrie (DE-588)4037882-2 gnd rswk-swf Chirale Verbindungen (DE-588)4348527-3 gnd rswk-swf Gasphasenreaktion (DE-588)4156043-7 gnd rswk-swf Isotopenmarkierung (DE-588)4176811-5 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Katalytische Dehydrierung (DE-588)4163421-4 s Gasphasenreaktion (DE-588)4156043-7 s Übergangsmetallkomplexe (DE-588)4131837-7 s Chirale Verbindungen (DE-588)4348527-3 s Asymmetrische Reaktion (DE-588)4143270-8 s Reaktionsmechanismus (DE-588)4177123-0 s Massenspektrometrie (DE-588)4037882-2 s Isotopenmarkierung (DE-588)4176811-5 s DE-604 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3553707&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020675648&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Novara, Francesca Rita 1979- Enantioselective transition metal mediated dehydrogenation in the gas phase from model systems toward real-life catalysis Asymmetrische Reaktion (DE-588)4143270-8 gnd Katalytische Dehydrierung (DE-588)4163421-4 gnd Reaktionsmechanismus (DE-588)4177123-0 gnd Massenspektrometrie (DE-588)4037882-2 gnd Chirale Verbindungen (DE-588)4348527-3 gnd Gasphasenreaktion (DE-588)4156043-7 gnd Isotopenmarkierung (DE-588)4176811-5 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| subject_GND | (DE-588)4143270-8 (DE-588)4163421-4 (DE-588)4177123-0 (DE-588)4037882-2 (DE-588)4348527-3 (DE-588)4156043-7 (DE-588)4176811-5 (DE-588)4131837-7 (DE-588)4113937-9 |
| title | Enantioselective transition metal mediated dehydrogenation in the gas phase from model systems toward real-life catalysis |
| title_alt | Enantioselective transition-metal mediated dehydrogenation in the gas phase |
| title_auth | Enantioselective transition metal mediated dehydrogenation in the gas phase from model systems toward real-life catalysis |
| title_exact_search | Enantioselective transition metal mediated dehydrogenation in the gas phase from model systems toward real-life catalysis |
| title_full | Enantioselective transition metal mediated dehydrogenation in the gas phase from model systems toward real-life catalysis vorgelegt von Francesca Rita Novara |
| title_fullStr | Enantioselective transition metal mediated dehydrogenation in the gas phase from model systems toward real-life catalysis vorgelegt von Francesca Rita Novara |
| title_full_unstemmed | Enantioselective transition metal mediated dehydrogenation in the gas phase from model systems toward real-life catalysis vorgelegt von Francesca Rita Novara |
| title_short | Enantioselective transition metal mediated dehydrogenation in the gas phase |
| title_sort | enantioselective transition metal mediated dehydrogenation in the gas phase from model systems toward real life catalysis |
| title_sub | from model systems toward real-life catalysis |
| topic | Asymmetrische Reaktion (DE-588)4143270-8 gnd Katalytische Dehydrierung (DE-588)4163421-4 gnd Reaktionsmechanismus (DE-588)4177123-0 gnd Massenspektrometrie (DE-588)4037882-2 gnd Chirale Verbindungen (DE-588)4348527-3 gnd Gasphasenreaktion (DE-588)4156043-7 gnd Isotopenmarkierung (DE-588)4176811-5 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| topic_facet | Asymmetrische Reaktion Katalytische Dehydrierung Reaktionsmechanismus Massenspektrometrie Chirale Verbindungen Gasphasenreaktion Isotopenmarkierung Übergangsmetallkomplexe Hochschulschrift |
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