Solvents and solvent effects in organic chemistry:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2011
|
| Ausgabe: | 4., updated and enl. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XXVI, 692 S. Ill., graph. Darst. 25 cm |
| ISBN: | 9783527324736 |
Internformat
MARC
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| 245 | 1 | 0 | |a Solvents and solvent effects in organic chemistry |c Christian Reichardt ; Thomas Welton |
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| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2011 | |
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Datensatz im Suchindex
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| adam_text |
CONTENTS 1 INTRODUCTION 1 2 SOLUTE-SOLVENT INTERACTIONS 7 2.1 SOLUTIONS
7 2.2 INTERMOLECULAR FORCES 12 2.2.1 ION-DIPOLE FORCES 13 2.2.2
DIPOLE-DIPOLE FORCES 14 2.2.3 DIPOLE-INDUCED DIPOLE FORCES 15 2.2.4
INSTANTANEOUS DIPOLE-INDUCED DIPOLE FORCES 16 2.2.5 HYDROGEN BONDING 17
2.2.6 ELECTRON-PAIR DONOR/ELECTRON-PAIR ACCEPTOR INTERACTIONS (EPD/EPA
INTERACTIONS) 23 2.2.7 SOLVOPHOBIC INTERACTIONS 31 2.3 SOLVATION 34 2.4
PREFERENTIAL SOLVATION 43 2.5 MICELLAR SOLVATION (SOLUBILIZATION) 48 2.6
IONIZATION AND DISSOCIATION 52 3 CLASSIFICATION OF SOLVENTS 65 3.1
CLASSIFICATION OF SOLVENTS ACCORDING TO CHEMICAL CONSTITUTION 65 3.2
CLASSIFICATION OF SOLVENTS USING PHYSICAL CONSTANTS 75 3.3
CLASSIFICATION OF SOLVENTS IN TERMS OF ACID-BASE BEHAVIOUR 88 3.3.1
BRONSTED-LOWRY THEORY OF ACIDS AND BASES 88 3.3.2 LEWIS THEORY OF ACIDS
AND BASES 93 3.4 CLASSIFICATION OF SOLVENTS IN TERMS OF SPECIFIC
SOLUTE/SOLVENT INTERACTIONS 96 3.5 CLASSIFICATION OF SOLVENTS USING
MULTIVARIATE STATISTICAL METHODS 99 4 SOLVENT EFFECTS ON THE POSITION OF
HOMOGENEOUS CHEMICAL EQUILIBRIA 107 4.1 GENERAL REMARKS 107 4.2 SOLVENT
EFFECTS ON ACID/BASE EQUILIBRIA 109 4.2.1 BRANSTED ACIDS AND BASES IN
SOLUTION 109 4.2.2 GAS-PHASE ACIDITIES AND BASICITIES 114 4.3 SOLVENT
EFFECTS ON TAUTOMERIE EQUILIBRIA 121 4.3. BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/1002408202 DIGITALISIERT DURCH XVI CONTENTS 5 SOLVENT
EFFECTS ON THE RATES OF HOMOGENEOUS CHEMICAL REACTIONS 165 5.1 GENERAL
REMARKS 165 5.2 GAS-PHASE REACTIVITIES 173 5.3 QUALITATIVE THEORY OF
SOLVENT EFFECTS ON REACTION RATES 180 5.3.1 THE HUGHES-INGOLD RULES 181
5.3.2 SOLVENT EFFECTS ON DIPOLAR TRANSITION STATE REACTIONS 192 5.3.3
SOLVENT EFFECTS ON ISOPOLAR TRANSITION STATE REACTIONS 206 5.3.4 SOLVENT
EFFECTS ON FREE-RADICAL TRANSITION STATE REACTIONS 220 5.3.5 LIMITATIONS
OF THE HUGHES-INGOLD RULES 235 5.4 QUANTITATIVE THEORIES OF SOLVENT
EFFECTS ON REACTION RATES 239 5.4.1 GENERAL REMARKS 239 5.4.2 REACTIONS
BETWEEN NEUTRAL, APOLAR MOLECULES 240 5.4.3 REACTIONS BETWEEN NEUTRAL,
DIPOLAR MOLECULES 246 5.4.4 REACTIONS BETWEEN NEUTRAL MOLECULES AND IONS
254 5.4.5 REACTIONS BETWEEN IONS 255 5.5 SPECIFIC SOLVATION EFFECTS ON
REACTION RATES 259 5.5.1 INFLUENCE OF SPECIFIC ANION SOLVATION ON THE
RATES OF SN AND OTHER REACTIONS 259 5.5.2 PROTIC AND DIPOLAR APROTIC
SOLVENT EFFECTS ON THE RATES OF SN REACTIONS 265 5.5.3 QUANTITATIVE
SEPARATION OF PROTIC AND DIPOLAR APROTIC SOLVENT EFFECTS FOR REACTION
RATES BY MEANS OF SOLVENT-TRANSFER ACTIVITY COEFFICIENTS 277 5.5.4
ACCELERATION OF BASE-CATALYSED REACTIONS IN DIPOLAR APROTIC SOLVENTS 282
5.5.5 INFLUENCE OF SPECIFIC CATION SOLVATION ON THE RATES OF SN
REACTIONS. 285 5.5.6 SOLVENT INFLUENCE ON THE REACTIVITY OF AMBIDENT
ANIONS 292 5.5.7 SOLVENT EFFECTS ON MECHANISMS AND STEREOCHEMISTRY OF
ORGANIC REACTION CONTENTS XVII 6.5.1 NONSPECIFIC SOLVENT EFFECTS ON NMR
CHEMICAL SHIFTS 410 6.5.2 SPECIFIC SOLVENT EFFECTS ON NMR CHEMICAL
SHIFTS 417 6.5.3 SOLVENT EFFECTS ON SPIN-SPIN COUPLING CONSTANTS 422 7
EMPIRICAL PARAMETERS OF SOLVENT POLARITY 425 7.1 LINEAR GIBBS ENERGY
RELATIONSHIPS 425 7.2 EMPIRICAL PARAMETERS OF SOLVENT POLARITY FROM
EQUILIBRIUM MEASUREMENTS 432 7.3 EMPIRICAL PARAMETERS OF SOLVENT
POLARITY FROM KINETIC MEASUREMENTS . 438 7.4 EMPIRICAL PARAMETERS OF
SOLVENT POLARITY FROM SPECTROSCOPIE MEASUREMENTS 448 7.5 EMPIRICAL
PARAMETERS OF SOLVENT POLARITY FROM OTHER MEASUREMENTS . 481 7.6
INTERRELATION AND APPLICATION OF SOLVENT POLARITY PARAMETERS 483 7.7
MULTIPARAMETER APPROACHES 490 8 SOLVENTS AND GREEN CHEMISTRY 509 8.1
GREEN CHEMISTRY 509 8.2 REDUCTION OF SOLVENT USE 511 8.3 GREEN SOLVENT
SELECTION 513 8.4 NON-TRADITIONAL SOLVENTS 514 8.4.1 WATER 514 8.4.2
SUPERCRITICAL CARBON DIOXIDE (SC-CO 2 ) 529 8.4.3 IONIC LIQUIDS 534
8.4.4 POLYETHYLENE GLYCOLS (PEGS) 543 8.4.5 BIOMASS-DERIVED SOLVENTS 544
8.5 OUTLOOK 548 APPENDIX 549 A. PROPERTIES, PURIFICATION, AND USE OF
ORGANIC SOLVENTS 549 A. 1 PHYSICAL PROPERTIES 549 A.2 PURIFICATION OF
ORGANIC SOLVENTS 556 A.3 SPECTROSCOPIE SOLVENTS 557 A.4 SOLVENTS AS
REACTION MEDIA 562 A. |
| any_adam_object | 1 |
| author | Reichardt, Christian Welton, Thomas |
| author_GND | (DE-588)142722804 |
| author_facet | Reichardt, Christian Welton, Thomas |
| author_role | aut aut |
| author_sort | Reichardt, Christian |
| author_variant | c r cr t w tw |
| building | Verbundindex |
| bvnumber | BV036680480 |
| classification_rvk | VE 7600 VK 5700 |
| classification_tum | CHE 168f |
| ctrlnum | (OCoLC)682106001 (DE-599)DNB1002408202 |
| dewey-full | 541.3482 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.3482 |
| dewey-search | 541.3482 |
| dewey-sort | 3541.3482 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| edition | 4., updated and enl. ed. |
| format | Book |
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| indexdate | 2024-07-20T10:47:00Z |
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| language | English |
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| spelling | Reichardt, Christian Verfasser aut Solvents and solvent effects in organic chemistry Christian Reichardt ; Thomas Welton 4., updated and enl. ed. Weinheim Wiley-VCH 2011 XXVI, 692 S. Ill., graph. Darst. 25 cm txt rdacontent n rdamedia nc rdacarrier Reaktionskinetik (DE-588)4048655-2 gnd rswk-swf Lösungsmitteleffekt (DE-588)4168032-7 gnd rswk-swf Metallorganische Verbindungen (DE-588)4038906-6 gnd rswk-swf Lösungsmittel (DE-588)4036160-3 gnd rswk-swf Organische Chemie (DE-588)4043793-0 gnd rswk-swf Organische Chemie (DE-588)4043793-0 s Lösungsmittel (DE-588)4036160-3 s DE-604 Lösungsmitteleffekt (DE-588)4168032-7 s Reaktionskinetik (DE-588)4048655-2 s 1\p DE-604 Metallorganische Verbindungen (DE-588)4038906-6 s 2\p DE-604 Welton, Thomas Verfasser (DE-588)142722804 aut X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3474329&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020599354&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Reichardt, Christian Welton, Thomas Solvents and solvent effects in organic chemistry Reaktionskinetik (DE-588)4048655-2 gnd Lösungsmitteleffekt (DE-588)4168032-7 gnd Metallorganische Verbindungen (DE-588)4038906-6 gnd Lösungsmittel (DE-588)4036160-3 gnd Organische Chemie (DE-588)4043793-0 gnd |
| subject_GND | (DE-588)4048655-2 (DE-588)4168032-7 (DE-588)4038906-6 (DE-588)4036160-3 (DE-588)4043793-0 |
| title | Solvents and solvent effects in organic chemistry |
| title_auth | Solvents and solvent effects in organic chemistry |
| title_exact_search | Solvents and solvent effects in organic chemistry |
| title_full | Solvents and solvent effects in organic chemistry Christian Reichardt ; Thomas Welton |
| title_fullStr | Solvents and solvent effects in organic chemistry Christian Reichardt ; Thomas Welton |
| title_full_unstemmed | Solvents and solvent effects in organic chemistry Christian Reichardt ; Thomas Welton |
| title_short | Solvents and solvent effects in organic chemistry |
| title_sort | solvents and solvent effects in organic chemistry |
| topic | Reaktionskinetik (DE-588)4048655-2 gnd Lösungsmitteleffekt (DE-588)4168032-7 gnd Metallorganische Verbindungen (DE-588)4038906-6 gnd Lösungsmittel (DE-588)4036160-3 gnd Organische Chemie (DE-588)4043793-0 gnd |
| topic_facet | Reaktionskinetik Lösungsmitteleffekt Metallorganische Verbindungen Lösungsmittel Organische Chemie |
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