Cellulose science and technology:
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Lausanne
EPFL Press
2010
|
| Ausgabe: | 1. ed. |
| Schriftenreihe: | Fundamental sciences chemistry
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 364 S. Ill., graph. Darst. |
| ISBN: | 9782940222414 9781420066883 |
Internformat
MARC
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| 020 | |a 9781420066883 |9 978-1-420-06688-3 | ||
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| 100 | 1 | |a Wertz, Jean-Luc |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Cellulose science and technology |c Jean-Luc Wertz, Olivier Bédué and Jean P. Mercier |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a Lausanne |b EPFL Press |c 2010 | |
| 300 | |a 364 S. |b Ill., graph. Darst. | ||
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| 700 | 1 | |a Mercier, Jean P. |e Verfasser |4 aut | |
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Datensatz im Suchindex
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| adam_text | IMAGE 1
OS
TABLE OF CONTENTS
FI RST FOREWORD................................................... 5
SECOND FOREWORD 7
PREFACE.................................................................
1 9
CHAPTER 1
INTROD UCTION .... 21
1.1 THE CELLULOSE MOLECULE 21
1.1.1 MOLECULAR STRUCTURE 21
1.1.2 GLUCOSE
CHEMISTRY.................................................. 23
1.1.3 RELATED DI- AND POLYSACCHARIDES 25
DISACCHARIDES 25
POLYSACCHARIDES.. 26
IMAGE 2
CELLULOSE SCIENCE AND TECHNOLOGY
1.2 STRUCTURE OF THE BOOK......... 30
1.3
REFERENCES........................................................................
31
CHAPTER 2
BIOSYNTHESIS OF CELLULOSE 33
2.1; LNTRODUCTION 33
2.2 SELECTIVE PRINCIPLES OF BOTANY 34
2.2.1 CLASSIFICATION OF GREEN PLANTS 34
2,.2.2 PLANT CELLS ......................... 36
10
2.3 CELLULOSE-RELATED BIOLOGY , .
2.3.1 FROM GENES TO PROTEINS ..
2.3.2 DNA CLONING AND PER ..
2.4 TERMINAL COMPLEXES , , , .
2.5 GLUCOSE POLYRNERIZATION BY CELLULOSE SYNTHASES .
2.5.1 CELLULOSE SYNTHASE SUBSTRATE .
2.5.2 CELLULOSE SYNTHASES .
PROCESSIVE J3-GLYCOSYLTRANSFERASES ..
CONSERVED MOTIFS .
CELLULOSE SYNTHESE FAMILY ..
2.5.3 POLYMERIZATION MODELS ..
2.5.4 POLYMERIZATION OF CELLULOSE IN ACETOBACTERXYLINUM .
BIOSYNTHETIC PATHWAY OF CELLULOSE .
UNIPROT DESCRIPTION , ..
OTHER BAETERIA . , ..
2.5.5 POLYMERIZATION OF CELLULOSE IN PLANTS ..
GENES ENCODING CEIIULOSE SYNTHASES ..
KORRIGAN ..
SITOSTEROL-J3-GLUCOSIDE PRIMER ..
OTHER NON-EATALYTIC MOLECULES ..
2.6 CHAIN ASSEMBLY INTO RNICROFIBRILS .
2.6.1 CHAIN ASSEMBLY IN ACETOBACTERXYLINUM .
38
38
41
41
46
46
47 47 48 49
51
54 S4 57 57
58 58 64 66 67
68
69
IMAGE 3
TABLE OF CONTENTS
2.6 .. 2 CHAIN ASSEMBLY IN
PLANTS......................................... 70
2.7 STATUS OF NON-IN-VIVO CELLULOSE SYNTHESIS 75
2.7.1
INVITROSYNTHESIS..................................................... 75
SYNTHESIS BY BACTERIAL SYNTHASES 75
SYNTHESIS BY PLANT SYNTHASES 75
ENZYMATIC POLYMERIZATION 76
2.7.2 CHEMICAL
SYNTHESIS.................................................. 79
2.8 REFERENCES...... 80
3.1 TNTRODUCTION .
3.2 SUPRAMOLECULAR STRUCTURE ..
3.2.1 CRYSTALLINITY OF CELLULOSE MATERIALS .
3.2.2 CRYSTAL POLYMORPHS .
3.2.3 COORDINATE SYSTEM .
3.2.4 CELLULOSE I ..
3.2.5 CELLULOSE 11 .
3.2.6 CELLULOSE 111 AND IV .
3.2.7 SODA CELLULOSES .
3.2.8 SUMMARY OF CRYSTAL STRUCTURES .
3.3 MORPHOLOGICAL STRUCTURE .
3.3.1 INTRODUCTION .
3 .. 3.2 MICROFIBRILS .
TYPES OF MICROFIBRILS .
CRYSTALLINE FEATURES .
CHAIN POLARITY AND BIOSYNTHESIS .
AMORPHOUS DOMEINS .
3.3.3 PLANT CELL WALLS .
EXTRACELLULAR MATRIX .
PRIMARY CELL WALL .
MICROTUBULES .
CHAPTER 3
STRU U RTI UUL 87
11
87
- 8888899090101105107108109109110110 1,11 L 17117118118119121
IMAGE 4
CELLULOSE SCIENCE AND TECHNOLOGY
WALL PROTEINS .. 122
PORES................ 123
SIOSYNTHESIS . ......................... 123
REPRESENTATIVE EXAMPLES 124
3.3.4 BACTERIAL
CELLULOSE.................................................. 127
3.4 PROPERTIES .... 130
3.4.1 MECHANICAL PROPERTIES 130
TNEORETICEL VALUES 130
EXPERIMENTAL VAFUES 130
3.4.2 PHYSICAL PROPERTIES AND LIQUID CRYSTALS 132
THERMAL, ELECTRICAL AND APIKAL PROPERTIES. 132
LIQUID CRYSTALS .. 134
12 3.4.3 ENVIRONMENTAL PROPERTIES 137
3.4.4 NANOCOMPOSITES 138
3.5,
REFERENCES..........................................................................
140
153 155
156
156 158
158
159
147
148
148
149 151
147
R: EI
ON .
4.3.1 ALKALI METAL HYDROXIDES ..
4.2.1 WATER .
WATERSORPTION ISOTHERMS .
SOUND WATER ..
WATER RETENTION VALUE, FIBER SATURATION POINT AND SALUTE EXC/USION .
CELLULOSE PLASTICIZATION WITH WATER .
4.2.2 ORGANIC LIQUIDS ..
INTERACTION OF CELLULOSE WITH ORGANIE LIQUIDS . TNCLUSION COMPOUNDS .
4.1
4.2
4.3
CHAPTER 4
MERCERIZATION ... 159
ALKALI CEL/ULOSES 159
IMAGE 5
TABLE OF CONTENTS
4.4
4.5
4.3.2
4.3.3
4.3.4
4.3.5
4.4.1
4.4.2
CHANGES IN IIBER DIMENSIONS ON SWELLING ..
SUPRAMOLECULAR AND MORPHOLOGICAL STRUCTURE .
MECHANISM OF SWELLING BY ALKALIS .
INORGANIC ACIDS AND SALTS .
AMINES .
SWEL/ING OI CELLULOSE BYAMINES , .
EFFECT OF AMINES ON CELLULOSE PROPERTIES ..
AMMONIA ..
SWEL/ING OF CELLULOSE BY LIQUID AMMONIA .
EFFECT OF LIQUID AMMONIA ON CELIULOSE PROPERTIES .
HYDRAZINE .
NON-DERIVATIZING SOLVENTS .
AQUEOUS SOLUTIONS OF TRANSITION METAL COMPLEXES ..
NON-AQUEOUS UCI/DMA SYSTEM .
ORGANIC AMINE OXIDES ..
AQUEOUS SODIUM HYDROXIDE ..
LONIC LIQUIDS ..
DERIVATIZING SOLVENTS ..
VISCOSE PROCESS .
N204/DMF SYSTEM ..
DMSO/PARAFORMALDEHYDE SYSTEM ..
NC2S .
161 162 164
167
170 170 172
173 173 174
1175
175
176 13
-- 176177178188192194196200201201 CHAPTER 5 ENZYMATIC HYDROLYSIS OF
CELLULOSE 209 5.1 LNTRODUCTION 209 5.2
CEUULASES...........................................................................
210 5.2.1 ORGANISM SOURCE 2105.2.2 ENDO- AND EXO-ACTION 2105.2.3 MODULAR
STRUCTURE 211 CATALYTIC MODULE.. 211 CARBOHYDRATE-BINDING
MODULE..................................... 213
IMAGE 6
CELLULOSE SCIENCE AND TECHNOLOGY
5.2.4 MECHANISM 217
5.2.5 NOMENCLATURE 218
5.3 NONCOMPLEXED CELLULASE SYSTEMS................................ 219
5.3.1 SOLUBILIZATION OF NATIVE CELLULOSE 219
5.3.2 TRICHODERMA TEESEI (HYPOCREA JECORINA) 220
CEL7A 221
CEI6A.........................................................................
..... 222
ENDOGLUCANASES 226
CBMS ........................................ 226
5.3.3 HUTNICOLE INSOIENS 228
CEL7A
.....................................................................
228
CEI6A..........................................................................
.... 229
14 ENDOGLUCANASES 229
CELLULOSE DIGESTION 231
5.3.4 KINETICS AND ACTIVITY 232
5.3.5 SYNERGISM 233
5.4 MULTIENZYME COMPLEXES 234
5.4.1 THE CELLULOSOME CONCEPT 234
5.4.2 TYPES OF CELLULOSOME 234
5.4.3 SCAFFOLDIN CARBOHYDRATE-BINDING MODULES 235
5.4.4 COHESIN-DOCKERIN INTERACTION 236
5.4.5 REPRESENTATIVE EXAMPLES OF CELLULOSOME............. 240
CLOSTRIDIUM CELLULOLYTICUM 240
CLOSTRIDIUM THERMOCELLUM ............... 241
ACETIVIBRIO CELLUJOLYTICUS 245
RUMINOCOCCUS FLAVEFACIENS 246
BACTEROIDES CELLULOSOLVENS 247
5.4.6 DESIGNER CELLULOSOMES...........................................
247
5.5
REFERENCES........................................................................
248
CHAPTER 6
NON-BIOLOGICAL DEGRADATION OF CELLULOSE .. 257
6.1 INTRODUCTION 257
IMAGE 7
TABLE OF CONTENTS
6.2 ACID HYDROLYSIS .
6.2.1 MECHANISM AND KINETICS ..
6.3 ALKALINE DEGRADATION .
6.3.1 ACTION OF ALKALIS ON MONOSACCHARIDES ..
6.3.2 ACTION OF ALKALIS ON CELLULOSE ..
ENDWISE DEGRADATION (PEELING) ..
ALKALINE HYDROLYSIS .
6.4 OXIDATIVE DEGRADATION ..
6.4.1 OXIDATION BY SODIUM HYPOCHLORITE ..
6.4.2 OXIDATION BY ATMOSPHERIC OXYGEN AND BY HYDROGEN PEROXIDE ..
6.5 THERMAL DEGRADATION ..
6.6 MECHANICAL AND RADIATION DEGRADATION .
6.6.1 MECHANICAL DEGRADATION .
6.6.2 RADIATION DEGRADATION ..
IR, VISIBLE AND UV RADIATION .
HIGH-ENERGY RADIATION .
6.1 REFERENCES .
258
258
260
260
261 261 262
263
264
265
266 15
268
268
270 270 271
272
CHAPTER 7
CELLULOSE DERIVATIVES 275
7.1 INTRODUCTION 275
1.2
ESTERIFICATION....................................................................
277
7.2.1 INORGANIC CELLULOSE ESTERS......................................
277
CELLULOSE NITRATE 277
CELLULOSE NITRITE 278
CELLULOSE SULFATE 279
PHOSPHORUS-CONTAINING CELLULOSE DERIVATIVES............... 279 CELLULOSE
BORATES 280
DEOXYCELLULOSES 280
ESTERS OF CARBONIC ACID DERIVATIVES.. 281
7.2.2 ORGANIC CELLULOSE ESTERS 282
IMAGE 8
16
CELLULOSE SCIENCE AND TECHNOLOGY
CELLULOSE FORMATE 282
CELLULOSE ACETATE 282
ESTERS OF HIGHER ALIPHATIC ACIDS.. 284
CELLULOSE CARBAMATES 286
CELLULOSE SULFONATES........... 286
7.2.3 SUMMARY ....................................... 287
7 .3 ETHERIFICATION 287
7.3.1 ALKYL ETHERS OF CELLULOSE 288
7.3.2 CARBOXYMETHYLCELLULOSE 289
1.3.3 HYDROXYALKYL ETHERS OF CEILLULOSE........................... 290
7.3.4 CYANOETHYLCELLULOSE 293
1.3.5 OTHER ETHERS OF CELLULOSE 293
7.3.6 SUMMARY.. 294
7.4 CROSSLINKING OF CELLULOSE 295
7.4.1 CHEMICAL FINISHING OF TEXTILES AND PAPER 295
1.4.2 CROSSLINKING AGENTS 296
7.5 GRAFTING OF CELLULOSE 298
7.6
REFERENCES... ....................................................................
299
CHAPTER 8
FUELS AND CHEMIEALS FROM BIOMASS 303
8.1 CEUULOSIC BIERNASS FOR RENEWABLE ENERQY AND PRODUCTS
,............................................................. 303
8.1.1 BIOMASS 303
8.1.2 BIOREFINERY AND GLOBAL WARMING 304
8.1.3 BIOETHANOL AND BIODIESEL...................................... 305
8.1.4 CONVERSION PATHWAYS 306
8.2 BIOCHEMICAL CONVERSION OF CELLULOSIC BIOMASS 307 8.2.1 ENZYMATIC
HYDROLYSIS 308
8.2.2 ACID HYDROLYSIS 312
DILUTE ACID HYDROLYSIS 312
IMAGE 9
TABLE OF CONTENTS
CONCENTRATED ACID HYDROLYSIS .
8.3 THERMOCHEMICAL CONVERSION OF CELLULOSIC BIOMASS ..
8.3.1 PRIMARY ROUTES FOR THERMOCHEMICAL CONVERSION ..
8.3.2 GASIFICATION .
GASIFICATION FOLLOWED BY FISCH ER-TROPSCH SYNTHESIS .
GASIFICATION FOLLOWED BY FERMENTATION .
8.3.3 FAST PYROLYSIS .
8.3.4 HYDROTHERMAL UPGRADING .
8.4 INTEGRATED BIOREFINERIES .
8.5 REFERENCES .
CHAPTER 9
PERSPECTIVES .
9.1 CELLULOSIC BIOMASS: THE PETROLEUM OF THE FUTURE? ....
9.1.1 PLANNED REDUCTIONS IN GREENHOUSE GAS (GHG) EMISSIONS .
EUROPEAN UNION .
UNITED STATES OF AMERICA .
9.1.2 GLOBAL BIOFUEL PRODUCTION .
9.1.3 BIOETHANOL COSTS AND YIELDS .
9.1.4 CELLULOSIC BIOMASS CONVERSION TECHNOLOGIES .
9.2 BIOSYNTHESIS OF CELLULOSE ..
9.3 CELLULOSE NANOFIBERS .
9.4 LONIC LIQUIDS AS NEW CELLULOSE SOLVENTS .
9.5 WORL!DWIDER&D PROJECTS ..
9.6 REFEREN,CES .
313
315
315
316 316 319
321
322
323
324
17
327
327
327 328
328
329
330
331
333
334
335
336
337
GLOSSARY 339
KEYWORD INDEX........... 359
|
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| id | DE-604.BV036648054 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:44:52Z |
| institution | BVB |
| isbn | 9782940222414 9781420066883 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-020567625 |
| oclc_num | 699571044 |
| open_access_boolean | |
| owner | DE-11 |
| owner_facet | DE-11 |
| physical | 364 S. Ill., graph. Darst. |
| publishDate | 2010 |
| publishDateSearch | 2010 |
| publishDateSort | 2010 |
| publisher | EPFL Press |
| record_format | marc |
| series2 | Fundamental sciences chemistry |
| spelling | Wertz, Jean-Luc Verfasser aut Cellulose science and technology Jean-Luc Wertz, Olivier Bédué and Jean P. Mercier 1. ed. Lausanne EPFL Press 2010 364 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Fundamental sciences chemistry Cellulose (DE-588)4147454-5 gnd rswk-swf Cellulose (DE-588)4147454-5 s DE-604 Bédué, Olivier Verfasser aut Mercier, Jean P. Verfasser aut OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020567625&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Wertz, Jean-Luc Bédué, Olivier Mercier, Jean P. Cellulose science and technology Cellulose (DE-588)4147454-5 gnd |
| subject_GND | (DE-588)4147454-5 |
| title | Cellulose science and technology |
| title_auth | Cellulose science and technology |
| title_exact_search | Cellulose science and technology |
| title_full | Cellulose science and technology Jean-Luc Wertz, Olivier Bédué and Jean P. Mercier |
| title_fullStr | Cellulose science and technology Jean-Luc Wertz, Olivier Bédué and Jean P. Mercier |
| title_full_unstemmed | Cellulose science and technology Jean-Luc Wertz, Olivier Bédué and Jean P. Mercier |
| title_short | Cellulose science and technology |
| title_sort | cellulose science and technology |
| topic | Cellulose (DE-588)4147454-5 gnd |
| topic_facet | Cellulose |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020567625&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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