Novel concepts in catalysis and chemical reactors: improving the efficiency for the future
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2010
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XXV, 372 S. Ill., graph. Darst. |
| ISBN: | 9783527324699 |
Internformat
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Datensatz im Suchindex
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VII CONTENTS PREFACE XVII LISTOFCONTRIBUTORS XXI 1 MOLECULAR CATALYTIC
KINETICS CONCEPTS 1 RUTGER A. VAN SANTEN 1.1 KEY PRINDPLES OF
HETEROGENEOUS CATALYSIS 1 1.2 ELEMENTARY RATE CONSTANTS AND CATALYTIC
CYCLE 1 1.3 LINEAR ACTIVATION ENERGY- REACTION ENERGY RELATIONSHIPS 2
1.4 MICROKINETIC EXPRESSIONS; DERIVATION OFVOLCANO CURVE 6 1.5
COMPENSATION EFFECT 12 1.6 HYDROCARBON CONVERSION CATALYZED BY ZEOLITES
14 1.7 STRUCTURE SENSITIVE AND INSENSITIVE REACTIONS 17 1.8 THE NONMETAL
ATOM SHARING RULE OF LOW-BARRIER TRANSITION STATES 22 1.8.1 INTRODUCTION
22 1.8.2 AMMONIA OXIDATION 24 1.9 SUMMARY 29 REFERENCES 29 2
HIERARCHICAL POROUS ZEOLITES BY DEMETALLATION 31 JOKERN C. GROEN AND
JAVIER PEREZ-RAMIREZ 2.1 ZEOLITES AND CATALYST EFFECTIVENESS 31 2.2
HIERARCHICAL ZEOLITES 33 2.3 MESOPOROUS ZEOLITES BY DEMETALLATION 34 2.4
DESILICATION 36 2.4.1 INTRODUCTION 36 2.4.2 ROLE OF THE TRIVALENT CATION
37 BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/998577936
DIGITALISIERT DURCH VIII CONTENTS 2.4.3 ACCESSIBILITY AND TRANSPORT 40
2.4.3.1 CHARACTERIZATION OF HIERARCHICAL STRUCTURES: FROM ARGON
ADSORPTION TO MIP 40 2.4.3.2 VISUALIZATION BY TOMOGRAPHY 41 2.4.3.3
DIFFUSION STUDIES 41 2.4.4 DESIGN OF HIERARCHICAL ZEOLITES 42 2.4.4.1
COMBINATION OF POST-SYNTHESIS TREATMENTS 42 2.4.4.2 TUNABLE
INTRACRYSTALLINE MESOPOROSITY BY PARTIAL DETEMPLATION-DESILICATION 42
2.4.4.3 NANOCRYSTALS OF ZERO-DIMENSIONAL ZEOLITES 43 2.4.4.4 HOLLOW
ZEOLITE CRYSTALS 44 2.4.5 FUNCTIONALITY 45 2.4.5.1 CATALYST PREPARATION:
IMPROVED ION-EXCHANGE 45 2.4.5.2 CATALYSIS 45 2.5 CONCLUSIONS AND
OUTLOOK 45 REFERENCES 47 3 PREPARATION OF NANOSIZED COLD CATALYSTS AND
OXIDATION AT ROOM TEMPERATURE 51 TAKASHI TAKEI, TAMAO ISHIDA, AND
MASATAKE HARUTA 3.1 INTRODUCTION 51 3.2 PREPARATION OF NANOSIZED GOLD
CATALYSTS 52 3.2.1 DEPOSITION OF GOLD NANOPARTICLES AND CLUSTERS ONTO
METAL OXIDES 52 CONTENTS IX 4.2.1 DEFINITION, SYNTHESIS, AND PROPERTIES
OF MOFS 73 4.2.2 DISCOVERY INSTEAD OF DESIGN 76 4.3 APPLICATIONS 78
4.3.1 CATALYSIS 79 4.3.1.1 ACTIVE METAL CENTERS 79 4.3.1.2
FUNCTIONALIZED ORGANIC LIGANDS 82 4.3.1.3 CHIRAL MOF CATALYSTS 84
4.3.1.4 MOF LATTICES AS HOSTS FOR CATALYTIC FUNCTIONALITIES 85 4.3.2
SEPARATION 86 4.4 CONCLUSION 88 ACKNOWLEDGMENTS 90 ABBREVIATIONS 90
REFERENCES 90 5 ENZYMATIC CATALYSIS TODAY AND TOMORROW 95 PIOTR
KIELBASINSKI, RYSZARD OSTASZEWSKI, AND WIKTOR SZYMANSKI 5.1 INTRODUCTION
95 5.1.1 CHEMOSELECTIVITY 96 5.1.2 REGIOSELECTIVITY 96 5.1.3
STEREOSELECTIVITY 96 5.2 ENZYMATIC CATALYSIS TODAY 98 5.2.1 RECENT
DEVELOPMENTS IN HETEROGENEOUS BIOCATALYSIS 98 5.2.2 DERACEMIZATION
PROCESSES 101 5.2.2.1 DYNAMIC PROCESSES (COMBINATION OF ENZYMES AND
CHEMICAL CATALYSTS X| CONTENTS 6.2.1 CALCINATION IN OXIDATIVE
ATMOSPHERES 121 6.2.2 AEROSOL FLAME TECHNOLOGIES 122 6.2.3 SOLUTION
COMBUSTION SYNTHESIS 123 B.2.4 SULFONIC ACID FUNCTIONALIZATION OF
ORDERED MESOPOROUS MATERIALS AND PERIODIC ORGANOSILICAS 123 6.2.5
SURFACE OXIDATION OF CARBON NANOFIBERS PRIOR TO FUNCTIONALIZATION 125
6.2.6 PURIFICATION, OPENING, AND SIZE REDUCTION OF CARBON NANOTUBES BY
OXIDATIVE TREATMENTS 125 6.2.7 METAL-FREE CATALYSIS BY OXYGEN-CONTAINING
CARBON NANOTUBES 127 6.3 A CATALYTIC OXIDATION TOOL. FENTON CHEMISTRY IN
SOLID CATALYST SYNTHESIS 127 6.3.1 WHAT IS THE FENTON REACTION? 127
6.3.2 CAN WE USE FENTON CHEMISTRY IN SOLID CATALYST SYNTHESIS? 128 6.3.3
KINETICS OF FENTON CHEMISTRY 129 6.4 FIRST CONCEPT IN CATALYST DESIGN.
SHIFTING COMPLEXATION EQUILIBRIA FOR ION-EXCHANGE BY OXIDATION OF THE
ORGANIC CHELATES 130 6.5 SECOND CONCEPT IN CATALYST DESIGN. ONE-POT
SYNTHESIS OF FE ZEOLITE CATALYSTS 131 6.6 THIRD CONCEPT IN CATALYST
DESIGN. FENTON DETEMPLATION. MILD ORGANIC TEMPLATE REMOVAL IN MICRO- AND
MESOPOROUS MOLECULAR SIEVES 132 CONTENTS XI 7.6.4 PHOTOCATALYSIS 151
7.6.5 CATALYTIC OXIDATION - A WAY TO TREAT VOLATILE ORGANIC EMISSIONS
152 7.6.5.1 CASE - UTILIZATION OF REVERSE FLOW REACTOR (RFR) IN
INDUSTRIAL CL-VOC OXIDATION 152 7.7 THE URBAN CHALLENGE 353 7.7.1
CHALLENGES IN CONTROL OF EMISSION FROM AUTOMOTIVE EXHAUST 154 7.7.1.1
CASE - AUTOMOTIVE EXHAUST GAS CATALYST RESEARCH 154 7.8 FUTURE ADVANCES
IN CATALYSIS FOR SUSTAINABILITY 155 7.9 CONCLUSIONS 157 REFERENCES 158 8
CATALYTIC ENGINEERING IN THE PROCESSING OFBIOMASS INTO CHEMICALS 163
TAPIO SALMI, DMITRY MURZIN, PAEIVI MAEKI-ARVELA, JOHAN WARNA, KARI ERAENEN,
NARENDRA KUMAR, AND JYRI-PEKKA MIKKOLA 8.1 INTRODUCTION 163 8.2
CHEMICALS AND FUELS FROM BIOMASS 164 8.3 CHEMICAL REACTION ENGINEERING
IN BIOMASS TRANSFORMATION 269 8.3.1 REACTION AND MASS TRANSFER IN POROUS
CATALYST STRUCTURES 170 8.3.2 RATE EQUATIONS 171 8.3.3 REACTOR MODELS
172 8.3.4 MODEL SIMULATION AND PARAMETER ESTIMATION TECHNIQUES 172 8.3.5
HYDROLYSIS OF POLYSACCHARIDES - FROM ARABINOGALACTAN TO MONOMER XII |
CONTENTS 9.3 OTHER STRUCTURED CATALYSTS 197 9.3.1 ARRAYSOF STRUCTURAL
ELEMENTS 198 9.3.2 FIBROUS STRUCTURED CATALYSTS 201 9.4 FOAMS 202 9.5
WHY ARE INDUSTRIAL APPLICATIONS OF STRUCTURED REACTORS SO SCARCE? 203
9.6 CONCLUDING REMARKS 205 REFERENCES 205 10 ZEOLITE MEMBRANES IN
CATALYSIS: WHAT IS NEW AND HOW BRIGHT IS THE FUTURE? 211 JOHAN VAN DEN
BERGH, NORIKAZU NISHIYAMA, AND FREEK KAPTEIJN 10.1 INTRODUCTION 211 10.2
ZEOLITES: A VERSATILE, WELL-DEFINED CLASS OF MATERIALS 212 10.2.1
ZEOLITE CATALYSIS 213 10.2.2 ZEOLITE MEMBRANES 213 10.3 APPLICATION
OPTIONS 214 10.3.1 REACTOR LEVEL 215 10.3.1.1 MEMBRANE REACTORS:
NOMENCLATURE 215 10.3.1.2 PACKED-BED MEMBRANE REACTOR 216 10.3.1.3
CATALYTIC MEMBRANE REACTOR 217 10.3.1.4 NONSELECTIVE MEMBRANE REACTORS
217 10.3.2 PARTICLE LEVEL 218 10.3.2.1 BASIC CONCEPTS 218 CONTENTS XIII
11 MICROSTRUCTURES ON MACROSEALE: MICROCHANNEL REACTORS FOR MEDIUM- AND
LARGE-SIZE PROCESSES 239 ANNA LEE Y. TONKOVICH AND JAN J. LEROU 11.1
INTRODUCTION 239 11.2 BACKGROUND ON MEDIUM- TO LARGE-SCALE PROCESSES IN
MICROCHANNELS 239 11.3 FUNDAMENTAL CHALLENGES OF MICROCHANNEL SCALE-UP
240 11.4 OVERCOMING THE SCALE-UP CHALLENGES 242 11.4.1 PRESSURE-DROP
DESIGN 243 11.4.2 HEAT-TRANSFER DESIGN 245 11.4.3 REACTOR DESIGN 250
11.4.4 MECHANICAL AND MANUFACTURING DESIGNS 252 11.5 EXAMPLE OF SCALE-UP
THROUGH CONCURRENT MODELING 254 11.6 CONCLUSIONS 258 REFERENCES 259 12
INTENSIFICATION OF HEAT TRANSFER IN CHEMICAL REACTORS: HEAT EXCHANGER
REACTORS 261 MICHAEL CABASSUD AND CHRISTOPHE GOURDON 12.1 INTRODUCTION
263 12.1.1 CHEMICAL REACTION INTENSIFICATION 261 12.1.2 HEAT EXCHANGER
REACTOR (HEX REACTOR) 262 12.1.2.1 THERMAL INTENSIFICATION 262 12.1.2.2
FLOW INTENSIFICATION 263 12.1.2.3 REACTOR DYNAMICS 263 XIV CONTENTS
ACKNOWLEDGEMENT 284 LIST OF SYMBOLS 284 GREEK SYMBOLS 285 SUBSCRIPTS 285
SUPERSCRIPTS 285 REFERENCES 285 13 REACTORS USING ALTERNATIVE ENERGY
FORMS FOR GREEN SYNTHETIC ROUTES AND NEW FUNCTIONAL PRODUCTS 289 GUIDO
MUL, TOM VAN GERVEN, AND ANDRZEJ STANKIEWICZ 13.1 INTRODUCTION 289 13.2
ENERGY OF ELECTROMAGNETIC FIELD 290 13.2.1 MICROWAVE REACTORS 290 13.2.2
PHOTOCHEMICAL REACTORS 292 13.3 ENERGY OF ELECTRIC FIELD 294 13.3.1
ELECTROCHEMICAL REACTORS 294 13.3.2 PLASMA REACTORS 295 13.4 ENERGY
OFMAGNETIC FIELD 296 13.5 ENERGY OFACOUSTIC FIELD 297 13.6 ENERGY OFFLOW
298 13.6.1 HYDRODYNAMIC CAVITATION REACTORS 298 13.6.2 SUPERSONIC
SHOCKWAVE-BASED REACTORS 299 13.7 ENERGY OF CENTRIFUGAL
FIELDS-HIGH-GRAVITY SYSTEMS 300 13.7.1 ROTATING PACKED BED REACTORS 300
CONTENTS XV 14.7 KEY CONSIDERATIONS FOR B2C VIABILITY 322 14.7.1 PROCESS
COMPLEXITY 322 14.7.2 REACTION CLASSIFKATION 321 14.7.3 PROCESS
INTENSIFICATION - REDUCTION OF REACTION VOLUMES 323 14.7.4 REACTION
SELECTIVITY 324 14.7.5 OPERATING SCALE 324 14.7.6 PROCESS ANALYTICS AND
CONTROL 325 14.7.7 PROCESS ECONOMICS 326 14.7.8 INNOVATION AND RISK
MANAGEMENT 327 14.8 CONCLUSIONS 328 REFERENCES 328 15 PROGRESS IN
METHODS FOR IDENTIFICATION OF MICRO- AND MACROSEALE PHYSICAL PHENOMENA
IN CHEMICAL REACTORS: IMPROVEMENTS IN SCALE-UP OF CHEMICAL REACTORS 333
BENGT ANDERSSON AND DEREK CREASER 15.1 INTRODUCTION 332 15.2
EXPERIMENTAL METHODS 332 15.2.1 FLOW CHARACTERIZATION 332 15.2.2 BUBBLE
AND DROP SIZE MEASUREMENT 334 15.2.3 CONCENTRATION MEASUREMENTS 334
15.2.4 CHARACTERIZATION OFOPAQUE MULTIPHASE FLOWS 336 15.2.4.1 X-RAY-
AND Y-RAY-COMPUTED TOMOGRAPHY 336 15.2.4.2 ELECTRICAL IMPEDANCE
TOMOGRAPHY (EIT) 336 15.2.4. XVI CONTENTS 15.6 THE FUTURE 353 LIST OF
SYMBOLS 354 SUBSCRIPT 354 REFERENCES 354 INDEX 357 |
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| indexdate | 2024-07-20T10:43:10Z |
| institution | BVB |
| isbn | 9783527324699 |
| language | English |
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| spelling | Novel concepts in catalysis and chemical reactors improving the efficiency for the future ed. by Andrzej Cybulski ... Weinheim Wiley-VCH 2010 XXV, 372 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chemischer Reaktor (DE-588)4121085-2 gnd rswk-swf Katalyse (DE-588)4029921-1 gnd rswk-swf Chemische Verfahrenstechnik (DE-588)4069941-9 gnd rswk-swf Chemische Verfahrenstechnik (DE-588)4069941-9 s Katalyse (DE-588)4029921-1 s Chemischer Reaktor (DE-588)4121085-2 s DE-604 Cybulski, Andrzej Sonstige oth text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3385136&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020510620&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Novel concepts in catalysis and chemical reactors improving the efficiency for the future Chemischer Reaktor (DE-588)4121085-2 gnd Katalyse (DE-588)4029921-1 gnd Chemische Verfahrenstechnik (DE-588)4069941-9 gnd |
| subject_GND | (DE-588)4121085-2 (DE-588)4029921-1 (DE-588)4069941-9 |
| title | Novel concepts in catalysis and chemical reactors improving the efficiency for the future |
| title_auth | Novel concepts in catalysis and chemical reactors improving the efficiency for the future |
| title_exact_search | Novel concepts in catalysis and chemical reactors improving the efficiency for the future |
| title_full | Novel concepts in catalysis and chemical reactors improving the efficiency for the future ed. by Andrzej Cybulski ... |
| title_fullStr | Novel concepts in catalysis and chemical reactors improving the efficiency for the future ed. by Andrzej Cybulski ... |
| title_full_unstemmed | Novel concepts in catalysis and chemical reactors improving the efficiency for the future ed. by Andrzej Cybulski ... |
| title_short | Novel concepts in catalysis and chemical reactors |
| title_sort | novel concepts in catalysis and chemical reactors improving the efficiency for the future |
| title_sub | improving the efficiency for the future |
| topic | Chemischer Reaktor (DE-588)4121085-2 gnd Katalyse (DE-588)4029921-1 gnd Chemische Verfahrenstechnik (DE-588)4069941-9 gnd |
| topic_facet | Chemischer Reaktor Katalyse Chemische Verfahrenstechnik |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3385136&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020510620&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT cybulskiandrzej novelconceptsincatalysisandchemicalreactorsimprovingtheefficiencyforthefuture |