Surface enhanced raman spectroscopy: Analytical, biophysical and life science applications
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2011
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| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XXII, 331 S. Ill, graph. Darst. |
| ISBN: | 9783527325672 |
Internformat
MARC
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| 245 | 1 | 0 | |a Surface enhanced raman spectroscopy |b Analytical, biophysical and life science applications |c ed. by Sebastian Schlücker |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2011 | |
| 300 | |a XXII, 331 S. |b Ill, graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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| 700 | 1 | |a Schlücker, Sebastian |d 1973- |0 (DE-588)123722713 |4 edt | |
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Datensatz im Suchindex
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IMAGE 1
VIL
CONTENTS
PREFACE XV LIST OF CONTRIBUTORS XVII
1 BASIC ELECTROMAGNETIC THEORY OF SERS 1 PABLO G. ETCHEGOIN AND ERIC C.
LE RU 1.1 INTRODUCTION 1
1.2 PLASMON RESONANCES AND FIELD ENHANCEMENTS 2 1.2.1 OPTICAL PROPERTIES
OF SIMPLE METALS 2 1.2.2 PLANAR SURFACES 4
1.2.3 THE METALLIC CYLINDER (2D) AND SPHERE (3D) 7 1.2.3.1 THE
ELECTROSTATIC APPROXIMATION 7 1.2.3.2 LOCALIZED SURFACE PLASMON
RESONANCES OF THE CYLINDER 9 1.2.3.3 LOCALIZED SURFACE PLASMON
RESONANCES OF THE SPHERE 10 1.2.3.4 LOCAL FIELD ENHANCEMENTS 11 1.2.4
SIZE EFFECTS 12
1.2.5 SHAPE EFFECTS 12
1.2.6 INTERACTING OBJECTS AND GAPS 15 1.2.6.1 COUPLED PLASMON RESONANCES
15 1.2.6.2 TIP-ENHANCED RAMAN SCATTERING (TERS) 17 1.2.7 CHOICE OF METAL
18
1.2.7.1 GOLD VERSUS SILVER 18 1.2.7.2 OTHER COINAGE AND TRANSITION
METALS 19 1.3 FIELD ENHANCEMENT DISTRIBUTION AND LOCALIZATION 20 1.3.1
ELECTROMAGNETIC HOT SPOTS 20 1.3.2 LONG-TAIL DISTRIBUTION OF
ENHANCEMENTS 21 1.4 ELECTROMAGNETIC MODEL FOR THE SERS AND FLUORESCENCE
ENHANCEMENT FACTORS 23 1.4.1 ENHANCED ABSORPTION 23 1.4.2 COMPARISON OF
RAMAN AND FLUORESCENCE PROCESSES 24 1.4.3 THE || 4 APPROXIMATION TO
SERS ENHANCEMENT FACTORS 27 1.4.4 FLUORESCENCE QUENCHING AND ENHANCEMENT
28
1.4.5 COMPARISON OF SERS AND FLUORESCENCE ENHANCEMENTS 29 1.4.6 OTHER
FORMS OF ENHANCEMENTS 31
SURFACE ENHANCED RAMAN SPECTROSCOPY: ANALYTICAL, BIOPHYSICAL AND LIFE
SCIENCE APPLICATIONS. EDITED BY SEBASTIAN SCHLUCKER COPYRIGHT 2011
WILEY-VCH VERLAG GMBH & CO. KGAA, WEINHEIM ISBN: 978-3-527-32567-2
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1002408245
DIGITALISIERT DURCH
IMAGE 2
VIII I CONTENTS
1.5 THE MAGNITUDE OF THE SERS ENHANCEMENT FACTOR IN TYPICAL CASES 32
1.6 CONCLUSIONS 33
REFERENCES 34
2 NANOPARTICLE SERS SUBSTRATES 39 YULING WANG AND ERKANG WANG 2.1
INTRODUCTION 39
2.2 PREPARATION AND STABILITY OF METAL NANOPARTICLE COLLOIDAL SERS
SUBSTRATES 40 2.2.1 COLLOIDAL SPHERICAL METAL NANOPARTICLES 41 2.2.1.1
CHEMICAL REACTION FOR METAL NANOPARTICLE PREPARATION 41 2.2.1.2 LASER
ABLATION AND PHOTOREDUCTION FOR METAL NANOPARTICLE
PREPARATION 44
2.2.1.3 SIZE EFFECT OF SERS SIGNAL ON METAL NANOPARTICLES 45 2.2.1.4
NEAR-INFRARED (NIR) EXCITATION FOR SERS ON METAL NANOPARTICLES 46
2.2.1.5 STABILITY OF THE METAL NANOPARTICLE COLLOIDS 47
2.2.2 AGGREGATION OF METAL NANOPARTICLES 47 2.23 BIMETALLIC NANOPARTICLE
SERS SUBSTRATE 50 2.2.4 NANOPARTICLES WITH VARIOUS SHAPES 52 2.3
CHARACTERIZATION OF NANOPARTIDE-BASED SERS SUBSTRATES 57
2.4 NANOPARTICLES ON THE UNFUNCTIONALIZED SOLID SURFACE AS SERS
SUBSTRATES 58 2.5 CONCLUSION AND OUTLOOK 60
REFERENCES 60
3 QUANTITATIVE SERS METHODS 71 STEVEN E.J. BELL AND ALAN STEWART 3.1
INTRODUCTION 71
3.2 SERS MEDIA 71
3.3 STABILITY AND SHELF UFE 73
3.4 REPRODUCIBILITY AND INTERNAL STANDARDS 74 3.5 SELECTIVITY 78
3.6 CONCLUSION 82
REFERENCES 83
4 SINGLE-MOLECULE- AND TRACE DETECTION BY SERS 87 NICHOLAS P.W.
PIECZONKA, GOLAM MOULA, ADAM R. SKARBEK, AND RICARDO F. AROCA
4.1 INTRODUCTION 87
4.1.1 SERS 87
4.1.2 THE TWO REGIMES: ENSEMBLE AND TRACE/SM 88 4.1.3 REQUIREMENTS FOR
SM-SERS 89 4.2 EXPERIMENTS AND RESULTS 90
4.2.1 THE LANGMUIR-BLODGETT METHOD FOR SM-SERRS 90
IMAGE 3
CONTENTS IX
4.2.2 LB SM-SERRS TO BIOLOGICALLY RELEVANT SYSTEMS 91
4.2.3 EXPERIMENTAL DETAILS 93 4.2.4 SINGLE-MOLECULE EXAMPLES 94 4.2.4.1
TAGGED PHOSPHOLIPID 94 4.2.4.2 R18, OCTADECYL RHODAMINE B 97 4.3
CONCLUSIONS 99
REFERENCES 99
5 DETECTION OF PERSISTENT ORGANIC POLLUTANTS BY USING SERS SENSORS BASED
ON ORGANICALLY FUNCTIONALIZED AG NANOPARTICLES 103 LUCA GUENINI,
PATRICIO LEYTON, MARCELO CAMPOS-VALLETTE, CONCEPCION DOMINGO, JOSE V.
GARCIA-RAMOS, AND
SANTIAGO SANCHEZ-CORTES 5.1 INTRODUCTION 103
5.2 INCLUSION HOSTS 106
5.2.1 CALIXARENES 106
5.2.2 A, Y-ALIPHATIC DIAMINES 112 5.3 CONTACT HOSTS 115
5.3.1 VIOLOGENS 115
5.3.2 CARBON NANOTUBES 118 5.4 OCCLUSION HOSTS 120
5.4.1 HUMIC SUBSTANCES 120 5.5 CONCLUSIONS 122
ACKNOWLEDGEMENTS 124 REFERENCES 124
6 SERS AND PHARMACEUTICALS 129
SIMONA CINTAE PINZARU AND IOANA E. PAVEL 6.1 INTRODUCTION 129
6.2 SERS OF ANTIPYRETICS AND ANALGESICS 130 6.3 SERS OF ANTIMALARIALS
139
6.4 SERS OF ANTICARCINOGENICS AND ANTIMUTAGENICS 142 6.4.1
5-FLUOROURACIL 142 6.4.2 ^-CAROTENE 150
6.5 CONCLUDING REMARKS 152
REFERENCES 152
7 SERS AND SEPARATION SCIENCE 155
ALISON J. HOBRO AND BERNHARD LENDL 7.1 INTRODUCTION 155
7.2 SERS AND CAPILLARY ELECTROPHORESIS (CE) 157 7.3 SERS AND LIQUID
CHROMATOGRAPHY (LC) 161 7.4 SERS AND GAS CHROMATOGRAPHY (GC) 164 7.5
SERS AND THIN LAYER CHROMATOGRAPHY (TLC) 165
7.6 OTHER SEPARATION METHODS 166
IMAGE 4
X I CONTENTS
7.7 CONCLUSIONS 169
REFERENCES 169
8 SERS AND MICROFLUIDICS 173
THOMAS HENKEL, ANNE MAERZ, AND JUERGEN POPP 8.1 INTRODUCTION 173
8.2 LAB-ON-A-CHIP TECHNOLOGY 174 8.3 MICROFLUIDIC PLATFORMS AND
APPLICATION FOR SERS 176 8.3.1 CAPILLARY-DRIVEN TEST STRIPES 176 8.3.2
MICROFLUIDIC LARGE-SCALE INTEGRATION AND PDMS MICROCHANNELS 178 8.3.3
CENTRIFUGAL MICROFLUIDICS 180 8.3.4 ELECTROKINETIC PLATFORM 181
8.3.5 DROPLET-BASED MICROFLUIDICS 183 8.3.5.1 STRAIGHT PLUG-FLOW CONCEPT
184 8.3.5.2 SURFACTANT-STABILIZED SAMPLE DROPLETS 184 8.3.5.3 PROCESSING
AS FOAMS IN MICROCHANNEL SYSTEMS 185 8.3.5.4 CONCLUSION 185 8.4 SUMMARY
187
REFERENCES 188
9 ELECTROCHEMICAL SERS AND ITS APPLICATION IN ANALYTICAL, BIOPHYSICAL
AND LIFE SCIENCE 191 BIN REN, YAN CUI, DE-YIN WU, AND ZHONG-QUN TIAN
9.1 ELECTROCHEMICAL SURFACE-ENHANCED RAMAN SPECTROSCOPY 191 9.2 FEATURES
OF ELECTROCHEMICAL SURFACE-ENHANCED RAMAN SPECTROSCOPY 192
9.2.1 ELECTROCHEMICAL DOUBLE LAYER OF EC-SERS SYSTEMS 193 9.2.2
POTENTIAL-DEPENDENT SERS SPECTRAL CHARACTERS 194 9.2.3 ELECTRODE
MATERIALS AND EXCITATION ENERGY DEPENDENCE 194 9.2 A ELECTROLYTE
SOLUTIONS AND SOLVENT DEPENDENCE 195 9.2.5 THE ELECTROCHEMICALLY
INFLUENCED SERS ENHANCEMENT 195 9.3 EXPERIMENTAL TECHNIQUES OF EC-SERS
197 9.3.1 EXPERIMENTAL SETUP 197 9.3.2 EC-SERS CELL DESIGN 298 9.3.3
IMPROVING THE DETECTION SENSITIVITY 199 9.3.4 PREPARATION OF SERS-ACTIVE
ELECTRODE SURFACES 299 9.3.4.1 ELECTROCHEMICAL OXIDATION AND REDUCTION
CYCLES (ORCS) 299 9.3.4.2 PREPARATION OF SERS SUBSTRATES USING METAL
NANOPARTICLES 200 9.3.5 SERS SUBSTRATE CLEANING 201 9.3.6 AN APPROACH TO
RELIABLE SERS MEASUREMENT ON BIO-RELATED SYSTEMS
BY THE DEFOCUSSING METHOD 203 9.4 APPLICATIONS OF EC-SERS 204 9.4.1
MODEL SYSTEM - BENZENE ADSORPTION AND REACTION ON TRANSITION METAL
SURFACES 204
9.4.2 SERS FOR STUDYING BIOLOGICAL MOLECULES 206
IMAGE 5
CONTENTS | XI
9.4.2.1 SERS STUDY OF THE ADSORPTION BEHAVIOUR OF NADH 207
9.4.2.2 SERS STUDY OF SINGLE-STRANDED AND DOUBLE-STRANDED DNA ON GOLD
SURFACES 208 9.4.2.3 EC-SERS STUDY OF CYTOCHROME C ON A DNA-MODIFIED
GOLD SURFACE 208 9.4.3 EC-SERS AS A METHOD TO IMPROVE THE DETECTION
SENSITIVITY OF
DOPAMINE 222
9.4.4 DISCRIMINATION OF MUTATIONS IN DNA SEQUENCES BY ELECTROCHEMICAL
MELTING USING SERS AS PROBING SIGNAL 222 9.5 PERSPECTIVES 213
9.5.1 ORDERED NANOSTRUCTURED ELECTRODE SURFACES 214 9.5.2 EC-SERS STUDY
OF CELL UNDER CULTURING CONDITION 215 9.5.3 INTEGRATION OF EC-SERS WITH
MICROFLUIDIC DEVICES 226 9.5.4 APPLICATIONS OF EC-SERS IN BIOSCIENCES
AND BIOSENSORS 216
ACKNOWLEDGEMENTS 226 REFERENCES 227
10 ELECTRON TRANSFER OF PROTEINS AT MEMBRANE MODELS 22 9 PETER
HILDEBRANDT, JIU-JU FENG, ANJA KRANICH, KHOA H. LY, DIEGO F. MARTIN,
MARCELO MARTI, DANIEL H. MURGIDA, DAMIAN A. POGGI, NATTAWADEE
WISITRUANGSAKUL, MURAT SEZER, INEZ M. WEIDINGER, AND INGO ZEBGER 10.1
INTRODUCTION 229
10.2 MODEL MEMBRANES AND MEMBRANE MODELS 222 10.3 METHODS FOR PROBING
ELECTION TRANSFER PROCESSES OF CYTOCHROME C AT COATED ELECTRODES 225
10.4 THE UNUSUAL DISTANCE DEPENDENCE OF THE INTERFACIAL ELECTRON
TRANSFER
PROCESS 228
10.5 ELECTION TRANSFER AND PROTEIN ORIENTATIONAL DYNAMICS 232 10.6
ELECTRIC FIELD EFFECTS ON THE ELECTRON TRANSFER DYNAMICS 232 10.7
ELECTRON TRANSFER AND PROTEIN STRUCTURAL CHANGES 234 10.8 OVERALL
DESCRIPTION OF THE MECHANISM AND DYNAMICS OF THE
INTERFACIAL PROCESSES 235 10.9 INTERFACIAL ELECTRIC FIELDS AND THE
BIOLOGICAL FUNCTIONS OF CYTOCHROME C 237 REFERENCES 239
11 QUANTITATIVE DNA ANALYSIS USING SURFACE-ENHANCED RESONANCE RAMAN
SCATTERING 241 ROSS STEVENSON, KAREN FAULDS, AND DUNCAN GRAHAM 11.1
INTRODUCTION 241
11.2 SERRS SURFACES 242
11.3 RAMAN REPORTERS 245
11.4 SERRS DNA PROBES 248 11.5 SENSITIVITY 252
IMAGE 6
XII CONTENTS
11.6
11.7 11.8
MULTIPLEXING ASSAYS 256 CONCLUSION REFERENCES
253
259 259
12 SERS MICROSCOPY: NANOPARTICLE PROBES AND BIOMEDICAL APPLICATIONS 263
SEBASTIAN SCHLUCKER
12.1 INTRODUCTION 263
12.2 SERS NANOPARTICLE PROBES 264 12.2.1 COMPONENTS OF A SERS LABEL 264
12.2.2 CHOICE OF METAL COLLOID 265 12.2.3 CHOICE OF RAMAN REPORTER 267
12.2.4 PROTECTION AND STABILIZATION 269 12.3 BIOMEDICAL APPLICATIONS OF
SERS MICROSCOPY 272 12.3.1 IMMUNOHISTOCHEMISTRY 273 12.3.2 METHODOLOGIES
IN RAMAN MICROSPECTROSCOPY 274
12.3.3 IMMUNO-SERS MICROSCOPY FOR IN VITRO TISSUE DIAGNOSTICS 275 12.3.4
APPLICATIONS IN VIVO 278 12.4 SUMMARY AND OUTLOOK 279
ACKNOWLEDGEMENT 280 REFERENCES 281
13 1-P AND 2-P EXCITED SERS AS INTRACELLULAR PROBE 285 JANINA KNEIPP
13.1 FROM TAGS TO PROBES: CHALLENGES IN INTRACELLULAR PROBING 285 13.1.1
LOCALIZATION AND TARGETING 286 13.1.2 INFLUENCE OF SURROUNDINGS ON
NANOPROBE AGGREGATION
AND STABILITY 287
13.1.3 PROBE IDENTIFICATION 290 13.2 PROBING OF INTRACELLULAR PARAMETERS
292 13.3 SURFACE-ENHANCED HYPER RAMAN SCATTERING AND ITS POTENTIAL IN
STUDIES OF CELLS 297
ACKNOWLEDGEMENTS 301 REFERENCES 301
14 SURFACE- AND TIP-ENHANCED CARS 305 TARO ICHIMURA AND SATOSHI KAWATA
14.1 INTRODUCTION 305
14.2 CARS : COHERENT ANTI-STOKES RAMAN SCATTERING 305 14.3 LOCAL
ENHANCEMENT OF CARS BY METALLIC NANOSTRUCTURES 307 14.4 SURFACE-ENHANCED
CARS 309 14.4.1 EXPERIMENTAL SYSTEM FOR SECARS MEASUREMENTS 309
14.4.2 SECARS OF ADENINE NANOCRYSTALS 320 14.4.3 SECARS OF SINGLE-WALLED
CARBON NANOTUBES 314
IMAGE 7
CONTENTS XIII
14.5 TIP-ENHANCED CARS 315
14.5.1 EXPERIMENTAL SYSTEM FOR TECARS MICROSCOPY 315 14.5.2 TECARS
IMAGING OF DNA MOLECULES 326 14.5.3 TECARS IMAGING OF CNTS 318
REFERENCES 329
INDEX 323 |
| any_adam_object | 1 |
| author2 | Schlücker, Sebastian 1973- |
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| dewey-full | 543.57 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 543 - Analytical chemistry |
| dewey-raw | 543.57 |
| dewey-search | 543.57 |
| dewey-sort | 3543.57 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| format | Book |
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| id | DE-604.BV036573064 |
| illustrated | Illustrated |
| indexdate | 2024-12-06T11:01:32Z |
| institution | BVB |
| isbn | 9783527325672 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-020494137 |
| oclc_num | 697821789 |
| open_access_boolean | |
| owner | DE-20 DE-355 DE-BY-UBR DE-92 |
| owner_facet | DE-20 DE-355 DE-BY-UBR DE-92 |
| physical | XXII, 331 S. Ill, graph. Darst. |
| publishDate | 2011 |
| publishDateSearch | 2011 |
| publishDateSort | 2011 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Surface enhanced raman spectroscopy Analytical, biophysical and life science applications ed. by Sebastian Schlücker Weinheim Wiley-VCH 2011 XXII, 331 S. Ill, graph. Darst. txt rdacontent n rdamedia nc rdacarrier Raman-Spektroskopie (DE-588)4176916-8 gnd rswk-swf Oberflächenspektroskopie (DE-588)4172259-0 gnd rswk-swf Raman-Spektroskopie (DE-588)4176916-8 s Oberflächenspektroskopie (DE-588)4172259-0 s DE-604 Schlücker, Sebastian 1973- (DE-588)123722713 edt text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3474336&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020494137&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Surface enhanced raman spectroscopy Analytical, biophysical and life science applications Raman-Spektroskopie (DE-588)4176916-8 gnd Oberflächenspektroskopie (DE-588)4172259-0 gnd |
| subject_GND | (DE-588)4176916-8 (DE-588)4172259-0 |
| title | Surface enhanced raman spectroscopy Analytical, biophysical and life science applications |
| title_auth | Surface enhanced raman spectroscopy Analytical, biophysical and life science applications |
| title_exact_search | Surface enhanced raman spectroscopy Analytical, biophysical and life science applications |
| title_full | Surface enhanced raman spectroscopy Analytical, biophysical and life science applications ed. by Sebastian Schlücker |
| title_fullStr | Surface enhanced raman spectroscopy Analytical, biophysical and life science applications ed. by Sebastian Schlücker |
| title_full_unstemmed | Surface enhanced raman spectroscopy Analytical, biophysical and life science applications ed. by Sebastian Schlücker |
| title_short | Surface enhanced raman spectroscopy |
| title_sort | surface enhanced raman spectroscopy analytical biophysical and life science applications |
| title_sub | Analytical, biophysical and life science applications |
| topic | Raman-Spektroskopie (DE-588)4176916-8 gnd Oberflächenspektroskopie (DE-588)4172259-0 gnd |
| topic_facet | Raman-Spektroskopie Oberflächenspektroskopie |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3474336&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020494137&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT schluckersebastian surfaceenhancedramanspectroscopyanalyticalbiophysicalandlifescienceapplications |