Rhenium and molybdenum Lewis base and Schiff base complexes:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
München
Verl. Dr. Hut
2010
|
| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Anorganische Chemie
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 199 S. graph. Darst. 210 mm x 148 mm, 283 gr. |
| ISBN: | 9783868534542 |
Internformat
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| 100 | 1 | |a Zhou, Mingdong |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Rhenium and molybdenum Lewis base and Schiff base complexes |c Mingdong Zhou |
| 250 | |a 1. Aufl. | ||
| 264 | 1 | |a München |b Verl. Dr. Hut |c 2010 | |
| 300 | |a 199 S. |b graph. Darst. |c 210 mm x 148 mm, 283 gr. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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| 490 | 0 | |a Anorganische Chemie | |
| 502 | |a Zugl.: München, Techn. Univ., Diss., 2010 | ||
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Datensatz im Suchindex
| _version_ | 1804142981470486529 |
|---|---|
| adam_text | INDEX INDEX 1. INTRODUCTION 1 1.1 EPOXIDATION REACTIONS 1 1.1.1
INDUSTRIAL EPOXIDATION PROCESSES 2 1.1.2 ASYMMETRIC EPOXIDATION 5 1.2
METHYLTRIOXORHENIUM (VII) AND ITS COMPLEXES IN OLEFIN EPOXIDATION 6
1.2.1 BACKGROUND 8 1.2.2 MECHANISM OF THE EPOXIDATION REACTIONS WITH
METHYLTRIOXORHENIUM (VII) 10 1.2.3 AN OVERVIEW ON THE LITERATURE WORK 15
1.3 MOO 2 X 2 (VI) COMPLEXES IN OLEFIN EPOXIDATION 16 1.4 OBJECTIVES 17
1.5 REFERENCES 17 2. MTO SCHIFF BASE COMPLEXES: SYNTHESIS, STRUCTURES
AND CATALYTIC APPLICATION IN OLEFIN EPOXIDATION 23 2.1 ABSTRACT 23 2.2
INTRODUCTION 23 2.3 RESULTS AND DISCUSSION 25 2.3.1 SYNTHESIS AND
SPECTROSCOPIC EXAMINATIONS 25 2.3.2 X-RAY CRYSTAL STRUCTURE OF COMPLEXES
1-5 29 2.3.3 I7 O NMR SPECTROSCOPY 34 2.3.4 APPLICATION IN EPOXIDATION
CATALYSIS 36 2.4 CONCLUSIONS 39 2.5 EXPERIMENTAL SECTION 40 2.5.1
SYNTHESIS AND CHARACTERIZATION 40 2.5.2 SINGLE CRYSTAL X-RAY STRUCTURE
DETERMINATION OF COMPLEXES 1-5 42 2.5.3 CATALYTIC REACTIONS 44 2.6
REFERENCES 45 BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1002581028
DIGITALISIERT DURCH INDEX 3. (N-SALICYLIDENE)ANILINE DERIVED SCHIFF BASE
COMPLEXES OF METHYL- TRIOXORHENIUM(VII) - LIGAND INFLUENCE AND CATALYTIC
PERFORMANCE 49 3.1 ABSTRACT 49 3.2 INTRODUCTION 49 3.3 RESULTS AND
DISCUSSION 51 3.3.1 SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION 52
3.3.2 X-RAY CRYSTAL STRUCTURE OF COMPLEXES 5-9 56 3.3.3 APPLICATION AS
EPOXIDATION CATALYSTS 61 3.4 CONCLUSIONS 63 3.5 EXPERIMENTAL SECTION 64
3.5.1 SYNTHETIC METHODS AND CHARACTERIZATION DATA 64 3.5.2 X-RAY CRYSTAL
DETERMINATION 66 3.5.3 CATALYTIC REACTIONS 67 3.6 REFERENCES 68 4. A
(SALICYLIDENE)ANILINE DERIVED SCHIFF BASE ADDUCT OF METHYLTRI-
OXORHENIUM(VII) - CIS- AND TRANS-COORDINATION OF THE LIGAND 72 4.1
ABSTRACT 72 4.2 INTRODUCTION 72 4.3 RESULTS AND DISCUSSION 74 4.3.1
SPECTROSCOPY AND CATALYSIS 74 4.3.2 STRUCUTRUAL IMPLICATIONS 76 4.4
CONCLUSIONS 80 4.5 EXPERIMENTAL SECTION 80 4.5.1 SYNTHESIS AND
CHARACTERISATION 80 4.5.2 SINGLE CRYSTAL X-RAY STRUCTURE DETERMINATION
81 4.5.3 CATALYTIC CYCLOOCTENE EPOXIDATION 82 4.6 REFERENCES 83 5.
((2-HYDROXYNAPTHALEN-1-YL)METHYLENE)ANILINE DERIVED SCHIFF BASE ADDUCTS
OF MTO: SYNTHESIS AND CATALYTIC APPLICATION 86 INDEX 5.1 ABSTRACT 86 5.2
INTRODUCTION 86 5.3 RESULTS AND DISCUSSION 88 5.3.1 SYNTHESIS AND
SPECTROSCOPIC CHARACTERIZATION 88 5.3.2 APPLICATION IN EPOXIDATION
CATALYSIS 93 5.4 CONCLUSIONS 94 5.5 EXPERIMENTAL SECTION 95 5.5.1
SYNTHESIS AND CHARACTERIZATION 95 5.5.2 CATALYTIC REACTIONS 96 5.6
REFERENCES 97 6. MONO- AND BIS- METHYLTRIOXORHENIUM(VII) COMPLEXES WITH
SALEN LIGANDS: SYNTHESIS, PROPERTIES, APPLICATIONS 99 6.1 ABSTRACT 99
6.2 INTRODUCTION 100 6.3 EXPERIMENTAL SECTION 101 6.3.1 SYNTHETIC
METHODS AND CHARACTERIZATION DATA 101 6.3.2 PREPARATION OF COMPLEXES 1-4
102 6.3.3 PREPARATION OF COMPLEXES 5-7 103 6.3.4 X-RAY SINGLE CRYSTAL
STRUCTURE DETERMINATION OF COMPLEXES 1,6,7 104 6.3.5 CATALYTIC REACTIONS
106 6.3.6 COMPUTATIONAL DETAILS 107 6.4 RESULTS AND DISCUSSION 107 6.4.1
SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION 107 6.4.2 X-RAY CRYSTAL
STRUCTURES OF COMPLEXES 1,6, 7 113 6.4.3 DFT-COMPUTED GEOMETRIES FOR
COMPLEXES 1-7 AND COMPUTATIONAL CONSIDER- ATIONS ON THE ADDUCT FORMATION
117 6.4.4 APPLICATIONS AS EPOXIDATION CATALYSTS 123 6.5 CONCLUSIONS 126
6.6 REFERENCES 126 8.4 CONCLUSIONS 165 INDEX 7. BIDENTATE LEWIS BASE
ADDUCTS OF METHYLTRIOXORHENIUM(VII): LIGAND INFLUENCE ON CATALYTIC
PERFORMANCE AND STABILITY 131 7.1 ABSTRACT 131 7.2 INTRODUCTION 131 7.3
RESULTS AND DISCUSSION 132 7.3.1 SYNTHESIS AND SPECTROSCOPIC
CHARACTERIZATION OF COMPLEXES 1-9 133 7.3.2 STERIC AND ELECTRONIC
EFFECTS IN THE COORDINATION OF LEWIS BASES TO MTO 138 7.3.3 X-RAY
CRYSTAL STRUCTURE OF COMPLEX 7 140 7.3.4 APPLICATIONS AS EPOXIDATION
CATALYSTS 140 7.4 CONCLUSIONS 143 7.5 EXPERIMENTAL SECTION 144 7.5.1
SYNTHESIS OF THE COMPLEXES 144 7.5.2 SINGLE CRYSTAL X-RAY STRUCTURE
DETERMINATION OF COMPLEX 7 146 7.5.3 CATALYTIC REACTIONS 147 7.6
REFERENCES 147 8. STUDIES ON BIS(HALOGENO)
DIOXOMOLYBDENUM(VI)-BIPYRIDINE COMPLEXES: SYNTHESIS AND CATALYTIC
ACTIVITY 150 8.1 ABSTRACT 150 8.2 INTRODUCTION 150 8.3 RESULTS AND
DISCUSSION 152 8.3.1 SYNTHESIS AND SPECTROSCOPY 152 8.3.2 NMR
SPECTROSCOPY 155 8.3.3 IR SPECTROSCOPY 157 8.3.4 UV/VIS SPECTROSCOPY 157
8.3.5 THERMOGRAVIMETRY 158 8.3.6 X-RAY CRYSTAL STRUCTURE ANALYSIS 159
8.3.7 DFT CALCULATIONS 160 8.3.8 APPLICATION IN EPOXIDATION CATALYSIS
164 195 INDEX 8.5 EXPERIMENTAL SECTION 8.5.1 GENERAL REMARKS 8.5.2
SYNTHESIS OF THE COMPLEXES 8.5.3 CATALYTIC REACTIONS 8.5.4 X-RAY
STRUCTURE DETERMINATION OF COMPLEX 11 8.5.5 COMPUTATIONAL DETAILS 8.6
REFERENCES 9. ADDUCT FORMATION OF DICHLORODIOXOMOLYBDENUM(VI) AND
METHYLTRI- OXORHENIUM(VII) WITH A SERIES OF BIDENTATE NITROGEN DONOR
LIGANDS 9.1 ABSTRACT 9.2 INTRODUCTION 9.3 RESULTS AND DISCUSSION 9.3.1
DETERMINATION OF FORMATION CONSTANTS 9.3.2 THE SOLVENT EFFECT 9.3.3 THE
ELECTRONIC EFFECT 9.3.4 THE STERIC EFFECT 9.3.5 ENTHALPY AND ENTROPY OF
LIGAND FORMATION 9.3.6 MTO VERSUS MOO 2 CL 2 ADDUCTS 9.4 CONCLUSIONS 9.5
EXPERIMENTAL SECTION 9.5.1 MATERIAL AND METHODS 9.5.2 FORMATION CONSTANT
MEASUREMENTS 9.6 REFERENCES 10. SUMMARY 166 166 167 170 170 171 172 176
176 177 178 179 184 185 186 188 189 190 190 190 191 192
|
| any_adam_object | 1 |
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| author_facet | Zhou, Mingdong |
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| ctrlnum | (OCoLC)705565235 (DE-599)DNB1002581028 |
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| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
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| dewey-search | 546.54525 546.53425 |
| dewey-sort | 3546.54525 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| edition | 1. Aufl. |
| format | Thesis Book |
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| indexdate | 2024-07-09T22:40:24Z |
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| isbn | 9783868534542 |
| language | English |
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| physical | 199 S. graph. Darst. 210 mm x 148 mm, 283 gr. |
| publishDate | 2010 |
| publishDateSearch | 2010 |
| publishDateSort | 2010 |
| publisher | Verl. Dr. Hut |
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| series2 | Anorganische Chemie |
| spelling | Zhou, Mingdong Verfasser aut Rhenium and molybdenum Lewis base and Schiff base complexes Mingdong Zhou 1. Aufl. München Verl. Dr. Hut 2010 199 S. graph. Darst. 210 mm x 148 mm, 283 gr. txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Techn. Univ., Diss., 2010 Rheniumkomplexe (DE-588)4223129-2 gnd rswk-swf Molybdänkomplexe (DE-588)4223139-5 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Rheniumkomplexe (DE-588)4223129-2 s Molybdänkomplexe (DE-588)4223139-5 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020352531&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Zhou, Mingdong Rhenium and molybdenum Lewis base and Schiff base complexes Rheniumkomplexe (DE-588)4223129-2 gnd Molybdänkomplexe (DE-588)4223139-5 gnd |
| subject_GND | (DE-588)4223129-2 (DE-588)4223139-5 (DE-588)4113937-9 |
| title | Rhenium and molybdenum Lewis base and Schiff base complexes |
| title_auth | Rhenium and molybdenum Lewis base and Schiff base complexes |
| title_exact_search | Rhenium and molybdenum Lewis base and Schiff base complexes |
| title_full | Rhenium and molybdenum Lewis base and Schiff base complexes Mingdong Zhou |
| title_fullStr | Rhenium and molybdenum Lewis base and Schiff base complexes Mingdong Zhou |
| title_full_unstemmed | Rhenium and molybdenum Lewis base and Schiff base complexes Mingdong Zhou |
| title_short | Rhenium and molybdenum Lewis base and Schiff base complexes |
| title_sort | rhenium and molybdenum lewis base and schiff base complexes |
| topic | Rheniumkomplexe (DE-588)4223129-2 gnd Molybdänkomplexe (DE-588)4223139-5 gnd |
| topic_facet | Rheniumkomplexe Molybdänkomplexe Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020352531&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT zhoumingdong rheniumandmolybdenumlewisbaseandschiffbasecomplexes |