Molybdenum(VI) dioxo complexes: synthesis, characterization and catalytic application in olefin epoxidation:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
München
Verl. Dr. Hut
2010
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| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Anorganische Chemie
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 169 S. graph. Darst. 210 mm x 148 mm, 239 gr. |
| ISBN: | 9783868534030 |
Internformat
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Datensatz im Suchindex
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| adam_text | INDEX INDEX 1. INTRODUCTION 1 1. 1 INTRODUCTION 1 1.2. EPOXIDATION
REACTIONS 1 1.3. RHENIUM-CATALYZED EPOXIDATIONS 5 1. 4. INFLUENCE OF
LEWIS BASE HGANDS ON THE CATALYTIC ACTIVITY 7 1.5. MOLYBDENUM CATALYSTS
FOR OLEFIN EPOXIDATION 8 1.5. 1. STRUCTURAL ASPECTS 8 1. 5. 2.
MOLYBDENUM(VI) CIS-DIOXO COMPLEXES AND THEIR CATALYTIC APPLICATIONS 9 1.
5. 3. ORGANOMETALLIC DERIVATIVES OF DIOXOMOLYBDENUM(VI) 12 1. 5. 4.
MECHANISTIC ASPECTS OF THE EPOXIDATION WITH MO(VI) COMPLEXES 14 1. 6.
OBJECTIVES OF THE WORK 19 1. 7. REFERENCES 20 2. STUDIES ON
BIS(HALOGENO) DIOXOMOLYBDENUM(VI)-BIPYRIDINE COMPLEXES: SYNTHESIS AND
CATALYTIC ACTIVITY 27 2.1. ABSTRACT 29 2. 2. INTRODUCTION 29 2.3.
RESULTS AND DISCUSSIONS 31 2. 3. 1 SYNTHESIS AND SPECTROSCOPY 31 2. 3.
1.1. NMR SPECTROSCOPY 33 2. 3. 1. 2. FT-IR SPECTROSCOPY 36 2. 3. 1. 3.
UV-VIS SPECTROSCOPY 37 2. 3. 1. 4. THERMOGRAVIMETRY 38 BIBLIOGRAFISCHE
INFORMATIONEN HTTP://D-NB.INFO/1001928059 DIGITALISIERT DURCH 3. 5.2.
CATALYTIC REACTIONS 78 INDEX 2. 3. 1. 5. X-RAY SINGLE CRYSTAL STRUCTURE
ANALYSIS 39 2. 3. 1. 6. DFT CALCULATIONS 40 2. 3. 1.7. APPLICATION IN
EPOXIDATION CATALYSIS 45 2.4. CONCLUSION 48 2. 5. EXPERIMENTAL 49 2.5.1.
GENERAL REMARKS 49 2. 5.2. SYNTHESES OF THE COMPLEXES 50 2. 5. 3.
CATALYTIC REACTIONS 53 2. 5. 4. X-RAY STRUCTURE ANALYSIS OF COMPOUND 11
54 2. 5. 5. COMPUTATIONAL DETAILS 54 2.6. REFERENCES 55 3. BIDENTATE
LEWIS BASE ADDUCTS OF MOLYBDENUM(VI): LIGAND IMPACT ON CATALYTIC
PERFORMANCE AND STABILITY 61 3.1. ABSTRACT 63 3.2. INTRODUCTION 63 3. 3.
RESULTS AND DISCUSSION 65 3.3.1. SYNTHESIS AND SPECTROSCOPIC
CHARACTERIZATION OF COMPLEXES 1-10 66 3. 3. 2. APPLICATION IN
EPOXIDATION CATALYSIS 72 3.4. CONCLUSIONS 75 3. 5. EXPERIMENTAL SECTION
75 3. 5. 1. SYNTHESIS OF THE COMPLEXES 76 5. 5. EXPERIMENTAL SECTION 119
INDEX 3. 6. REFERENCES 78 4. DICHLORO-, DIBROMO- AND
DIMETHYL-DIOXOMOLYBDENUM(VI)- BIPYRIDINE COMPLEXES AS CATALYSTS FOR THE
EPOXIDATION OF OLEFINS 81 4. 1.ABSTRACT 83 4. 2. INTRODUCTION 83 4. 3.
RESULTS AND DISCUSSION 85 4. 3. 1. SYNTHESIS AND SPECTROSCOPIC
CHARACTERIZATION OF COMPLEXES 1-11 86 4. 3. 2. CATALYTIC EPOXIDATION OF
CIS-CYCLOOCTENE 90 4. 4. CONCLUSIONS 93 4. 5. EXPERIMENTAL SECTION 94 4.
5. 1. SYNTHESIS OF THE LIGANDS 94 4. 5. 2. SYNTHESIS OF THE COMPLEXES 96
4. 5. 3. CATALYTIC REACTIONS 100 4. 6. REFERENCES 101 5 BIDENTATE LEWIS
BASE ADDUCTS OF METHYLTRIOXORHENIUM(VH): LIGAND INFLUENCE ON CATALYTIC
PERFORMANCE AND STABILITY 105 5.1. ABSTRACT 107 5. 2. INTRODUCTION 107
5. 3. RESULTS AND DISCUSSION 108 5. 3. 1. SYNTHESIS AND SPECTROSCOPIC
CHARACTERIZATION OF COMPLEXES 1-9 109 5. 3. 2. STERIC AND ELECTRONIC
EFFECTS IN THE COORDINATION OF LEWIS BASES TO MTO 113 5. 3. 3. X-RAY
CRYSTAL STRUCTURE OF COMPLEX 7 115 5. 3. 4. APPLICATIONS AS EPOXIDATION
CATALYSTS 116 5. 4. CONCLUSIONS 119 8. APPENDIX 163 INDEX 5. 5. 1.
SYNTHESES OF COMPLEXES 120 5. 5. 2. SINGLE CRYSTAL X-RAY STRUCTURE
DETERMINATION OF COMPLEX 7 123 5. 5. 3. CATALYTIC REACTIONS 123 5. 6.
REFERENCES 123 6 ADDUCT FORMATION OF DICHLORODIOXOMOLYBDENUMCVI) AND
METHYLTRIOXORHENIUM(VII) WITH A SERIES OF BIDENTATE NITROGEN DONOR
LIGANDS 127 6.1. ABSTRACT 129 6. 2. INTRODUCTION 129 6. 3. RESULTS AND
DISCUSSION 131 6. 3. 1. DETERMINATION OF FORMATION CONSTANTS 132 6. 3.2.
THE SOLVENT EFFECT 137 6. 3.3. THE ELECTRONIC EFFECT 138
6.3.4.THESTERICEFFECT 140 6. 3. 5. ENTHALPY AND ENTROPY OF LIGAND
FORMATION 141 6. 3. 6. MTO VERSUS MOO 2 CB ADDUCTS 143 6.4. CONCLUSIONS
144 6. 5. EXPERIMENTAL SECTION 144 6. 5.1. MATERIAL AND METHODS 144 6.
5. 2. FORMATION CONSTANT MEASUREMENTS 145 6. 6. REFERENCES 146 7.
SUMMARY 153
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| any_adam_object | 1 |
| author | Günyar, Alev 1978- |
| author_GND | (DE-588)141328037 |
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| author_variant | a g ag |
| building | Verbundindex |
| bvnumber | BV036461656 |
| classification_tum | CHE 374d CHE 167d CHE 658d CHE 334d |
| ctrlnum | (OCoLC)643722508 (DE-599)DNB1001928059 |
| dewey-full | 546.53425 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546.53425 |
| dewey-search | 546.53425 |
| dewey-sort | 3546.53425 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| edition | 1. Aufl. |
| format | Thesis Book |
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| indexdate | 2024-07-09T22:39:57Z |
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| isbn | 9783868534030 |
| language | English |
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| physical | 169 S. graph. Darst. 210 mm x 148 mm, 239 gr. |
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| spelling | Günyar, Alev 1978- Verfasser (DE-588)141328037 aut Molybdenum(VI) dioxo complexes: synthesis, characterization and catalytic application in olefin epoxidation Alev Günyar 1. Aufl. München Verl. Dr. Hut 2010 169 S. graph. Darst. 210 mm x 148 mm, 239 gr. txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Techn. Univ., Diss., 2010 Alkene (DE-588)4001207-4 gnd rswk-swf Molybdänkomplexe (DE-588)4223139-5 gnd rswk-swf Katalysator (DE-588)4029919-3 gnd rswk-swf Epoxidation (DE-588)4152560-7 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Molybdänkomplexe (DE-588)4223139-5 s Katalysator (DE-588)4029919-3 s Epoxidation (DE-588)4152560-7 s Alkene (DE-588)4001207-4 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020333535&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Günyar, Alev 1978- Molybdenum(VI) dioxo complexes: synthesis, characterization and catalytic application in olefin epoxidation Alkene (DE-588)4001207-4 gnd Molybdänkomplexe (DE-588)4223139-5 gnd Katalysator (DE-588)4029919-3 gnd Epoxidation (DE-588)4152560-7 gnd |
| subject_GND | (DE-588)4001207-4 (DE-588)4223139-5 (DE-588)4029919-3 (DE-588)4152560-7 (DE-588)4113937-9 |
| title | Molybdenum(VI) dioxo complexes: synthesis, characterization and catalytic application in olefin epoxidation |
| title_auth | Molybdenum(VI) dioxo complexes: synthesis, characterization and catalytic application in olefin epoxidation |
| title_exact_search | Molybdenum(VI) dioxo complexes: synthesis, characterization and catalytic application in olefin epoxidation |
| title_full | Molybdenum(VI) dioxo complexes: synthesis, characterization and catalytic application in olefin epoxidation Alev Günyar |
| title_fullStr | Molybdenum(VI) dioxo complexes: synthesis, characterization and catalytic application in olefin epoxidation Alev Günyar |
| title_full_unstemmed | Molybdenum(VI) dioxo complexes: synthesis, characterization and catalytic application in olefin epoxidation Alev Günyar |
| title_short | Molybdenum(VI) dioxo complexes: synthesis, characterization and catalytic application in olefin epoxidation |
| title_sort | molybdenum vi dioxo complexes synthesis characterization and catalytic application in olefin epoxidation |
| topic | Alkene (DE-588)4001207-4 gnd Molybdänkomplexe (DE-588)4223139-5 gnd Katalysator (DE-588)4029919-3 gnd Epoxidation (DE-588)4152560-7 gnd |
| topic_facet | Alkene Molybdänkomplexe Katalysator Epoxidation Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020333535&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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