Carbon-centered free radicals and radical cations: strucutre, reactivity, and dynamics
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, N.J.
Wiley
2010
|
| Schriftenreihe: | Wiley series on reactive intermediates in chemistry and biology
3 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Includes index. |
| Beschreibung: | XXII, 370 S. Ill., graph. Darst. |
| ISBN: | 9780470390092 |
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| 245 | 1 | 0 | |a Carbon-centered free radicals and radical cations |b strucutre, reactivity, and dynamics |c ed. by Malcolm D. E. Forbes |
| 264 | 1 | |a Hoboken, N.J. |b Wiley |c 2010 | |
| 300 | |a XXII, 370 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Wiley series on reactive intermediates in chemistry and biology |v 3 | |
| 500 | |a Includes index. | ||
| 650 | 4 | |a Free radicals (Chemistry) | |
| 650 | 4 | |a Carbon, Activated | |
| 650 | 4 | |a Reactivity (Chemistry) | |
| 650 | 4 | |a Cations | |
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Datensatz im Suchindex
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| adam_text | IMAGE 1
CONTENTS
ABOUT THE VOLUME EDITOR XIII
PREFACE TO SERIES XV
INTRODUCTION XVII
CONTRIBUTORS XXI
1. ABRIEF HISTORY OF CARBON RADICALS 1
MA/CO/RN D. E. FORBES
2. INTERMOLECULAR RADICAL ADDITIONS TO ALKYNES: CASCADE-TYPE RADICAL
CYCLIZATIONS 9
UTA WILLE
2.1 INTRODUCTION 9
2.2 CASCADE REACTIONS INVOLVING RADICALS OF SECOND ROW ELEMENTS 11 2.2.1
CASCADE REACTIONS INITIATED BY ADDITION OF C-CENTERED RADICALS TO
ALKYNES 11
2.2.2 CASCADE REACTIONS INITIATED BY ADDITION OF O-CENTERED RADICALS TO
ALKYNES (SELF-TERMINATING RADICAL OXYGENATIONS) 16 2.2.3 CASCADE
REACTIONS INITIATED BY ADDITION OF N-CENTERED RADICALS TO ALKYNES 24
2.3 CASCADE REACTIONS INITIATED BY ADDITION OF HIGHER MAIN GROUP
(VI)-CENTERED RADICALS TO ALKYNES 27
2.3.1 CASCADE REACTIONS INITIATED BY ADDITION OF SN-CENTERED RADICALS TO
ALKYNES 27
V
IMAGE 2
VI CONTENTS
2.4CASCADEREACTIONSINITIATEDBYADDITIONOFHIGHERMAIN
GROUP(VI)-CENTEREDRADICALS
TO ALKYNES30
2.4.1CASCADEREACTIONSINITIATEDBYADDITION
OF S-CENTERED
RADICALS
TO ALKYNES30
2.4.2CASCADEREACTIONSINITIATEDBYADDITION
OF SE-CENTERED
RADICALS
TO ALKYNES36
2.5 CASCADEREACTIONSINITIATED BY ADDITIONOFHIGHERMAIN
GROUP(V)-CENTEREDRADICALS
TO ALKYNES37
2.5.1CASCADEREACTIONSINITIATEDBYADDITIONOFP-CENTERED RADICALSTOALKYNES37
3.RADICALCATIONFRAGMENTATIONREACTIONSINORGANICSYNTHESIS 43 ALEXANDER J.
PONIATOWSKI AND PAUL E. FLOREANCIG
3.1 INTRODUCTION 3.1.1OXIDATIVECARBON-CARBONBONDCLEAVAGE
3.1.2THERMODYNAMICANDKINETICCONSIDERATIONS
3.1.3REACTIVEINTERMEDIATELIFETIME
3.2ELECTRONTRANSFER-INITIATEDCYCLIZATIONREACTIONS
3.2.1RATEENHANCEMENTANDMECHANISTICSTUDIES 3.2.2DEVELOPMENT
OF ACATALYTICAEROBICPROTOCOL
3.2.3OXIDATIVECASCADEREACTIONS 3.3OXIDATIVEACYLIMINIUMIONFORMATION
3.4CARBON-CARBONBONDFORMATION 3.4.1CHEMOSELECTIVITYANDREACTIVITY
3.4.2REACTIONSCOPE 3.5SUMMARYANDOUTLOOK 43 44 46 49 49
50 50
52 52 54 54
55 58
61 4. SELECTIVITYINRADICALCATIONCYCLOADDITIONS
CHRISTO S. SEVOV AND DIA!WIEST
4.1 INTRODUCTION 61 4.2MECHANISMANDTHEORIGIN OF THERATEACCELERATION 62
4.3SELECTIVITYINRADICALCATIONCYCLOADDITIONS 63 4.4CHEMOSELECTIVITY 64
4.4.1EFFECT OF DIENOPHILESUBSTITUENTSONCHEMOSELECTIVITY 64 4.4.2EFFECT
OF SENSITIZERSANDSOLVENTSONCHEMOSELECTIVITY66 4.4.3EFFECT
OF CONCENTRATIONSONCHEMOSELECTIVITY 67 4.4.4EFFECT OF
ELECTRON-RICHDIENOPHILES ON CHEMOSELECTIVITY 67
4.5REGIOSELECTIVITY 68 4.6PERISELECTIVITY 69
4.6.1EFFECTS OF SOLVENTANDCONCENTRATIONONPERISELECTIVITY70 4.6.2EFFECT
OF DIENE/DIENOPHILEREDOXPOTENTIALS ON PERISELECTIVITY 71
4.6.3SUBSTITUENTANDSTERICEFFECTS ON PERISELECTIVITY 72
4.6.4QUANTIFYINGPERISELECTIVITYTHROUGHIONPAIRASSOCIATION74
IMAGE 3
CONTENTS
4.7 ENDO/EXO SELECTIVITY 4.7.1 EFFECTS OF SECONDARY ORBITALINTERACTION
AND SOLVENTS ON ENDO/EXO SELECTIVITY 4.7.2 EFFECT OF SENSITIZER ON
ENDO/EXO SELECTIVITY 4.7.3 ION PAIRS AND ENDO/EXO SELECTIVITIES 4.8
CONCLUSIONS
VII
75
75 76 77
79
S. THE STABILITY OF CARBON-CENTERED RADICALS 83
MICHELLE L. COOLE, CHING YEH UN, AND HENDRIK ZIPSE
5.1 INTRODUCTION 83
5.LL THE CONSEQUENCES OF DIFFERENT STABILITY DEFINITIONS: HOW STABLE ARE
ETHYL AND FLUOROMETHYL RADICALS? 85 5.2 THEORETICAL METHODS 86
5.2.1 TESTING THE PERFORMANCE OF DIFFERENT THEORETICAL APPROACHES: HOW
STABLE ARE ALLYL AND BENZYL RADICALS? 87 5.2.2 THE APPLICATION OF IMOMO
SCHEMES: HOW STABLE ARE BENZYL AND DIPHENYLMETHYL RADICALS? 89
5.3 RSE VALUES FOR CARBON-CENTERED RADICALS 91
5.4 USE OF RSE VALUES IN PRACTICAL APPLICATIONS 91
5.4.1 SUSCEPTIBILITY TO HYDROGEN ATOM ABSTRACTION 91
5.4.2 ASSESSMENT OF RADICAL STABILITY IN OTHER TYPES OF REACTIONS 100
5.5 CONCLUSIONS 102
6. INTERPLAY OF STEREOELECTRONIC VIBRATIONAL AND ENVIRONMENTAL ETTECTS
IN TUNING PHYSICOCHEMICAL PROPERTIES OF CARBON-CENTERED RADICALS 105
VINCENZO BARONE, MALGORZALA BICZYSKO, AND PAOLA CIMINO
6.1 INTRODUCTION 105
6.2 EPR SPECTROSCOPY 107
6.2.1 THEORETICAL BACKGROUND 107
6.2.2 ENVIRONMENTAL EFFECTS 108
6.2.3 VIBRATION A1 EFFECTS 108
6.2.4 DYNAMICAL EFFECTS 109
6.3 CALCULATION OF EPR PARAMETERS 110
6.3.1 GEOMETRIE PARAMETERS 112
6.3.2 EPR PARAMETERS 113
6.3.3 CASE STUDIES: GLYCINE AND GLYCYL RADICALS 117
6.3.3.1 GLYCINE RADICAL 117
6.3.3.2 GLYCYL RADICAL 119
6.3.4 CASE STUDIES: VIBRATIONALLY AVERAGED PROPERTIES OF VINYL AND
METHYL RADICALS 120
6.4 VIBRATIONAL PROPERTIES BEYOND THE HARMONIE APPROXIMATION 122
IMAGE 4
VIII CONTENTS
6.4.1CASESTUDIES:ANHARMONICFREQUENCIES OF PHENYL
ANDNAPHTHYLCATIONRADICALS
122
6.4.2CASESTUDIES:GASANDMATRIXISOLATEDIRSPECTRA OF THE
VINYLRADICAL
125
6.5ELECTRONICPROPERTIES:VERTICALEXCITATIONENERGIES,STRUCTURE,
ANDFREQUENCIES
IN EXCITEDELECTRONICSTATES 126 6.5.1THEORETICALBACKGROUND 126
6.5.2CASESTUDIES:VERTICALEXCITATIONENERGIES OF THE
VINYLRADICAL
126
6.5.3CASESTUDIES:STRUCTURESANDFREQUENCIES OF THEVINYL
RADICAL
IN FIRSTTHREEDOUBLETEXCITEDELECTRONICSTATES 129 6.6VIBRONICSPECTRA 129
6.6.1THEORETICALBACKGROUND 132 6.6.2COMPUTATIONALSTRATEGY 134
6.6.3CASESTUDIES:ELECTRONICABSORPTIONSPECTRUM OFPHENYLRADICAL
134
6.7CONCLUDINGREMARKS 137
7. UNUSUAL STRUCTURES OFRADICALIONSIN CARBON SKELETONS:
NONSTANDARDCHEMICAL BONDINGBYRESTRICTINGGEOMETRIES
141
GEORGGESCHEIDT
7.1 INTRODUCTION 141 7.2THETOOLS 142
7.2.1CYCLOVOLTAMMETRY 143 7.2.2EPRPARAMETERS:EXPERIMENTALANDCALCULATED
143
7.3PAGODANEANDITSDERIVATIVES 144 7.4DIFFERENTSTAGES OF
CYCLOADDITION/CYCLOREVERSIONREACTIONS WITHINCONFINEDENVIRONMENTS
151
7.5EXTENDINGTHE CAGECONCEPT 152 7.6SUMMARY 154
8.MAGNETICFIELDETTECTSONRADICALPAIRSINHOMOGENEOUSSOLUTION157 JONATHAN.
R. WOODWARD
8.1 INTRODUCTION 8.2THESPIN-CORRELATEDRADICALPAIR
8.2.1 RADICALPAIRINTERACTIONS 8.2.2INTRARADICALINTERACTIONS
8.2.3INTERRADICALINTERACTIONS 8.3APPLICATION
OF AMAGNETICFIELD
8.3.1THEZEEMANEFFECT 8.4SPIN-STATEMIXING 8.4.1COHERENTSPIN-STATEMIXING
8.4.2THELIFECYCLE
OF ARADICALPAIR
8.4.3INCOHERENTSPIN-STATEMIXING
157 158
159 159
160 162 162
163 163
165 167
IMAGE 5
CONTENTS
8.5 THE MAGNETIE FIELD DEPENDENEE OF RADICAL PAIR REAETIONS 8.5.1
NORMAL MAGNETIE FIELDS 8.5.2 WEAK MAGNETIE FIELDS
8.5.3 STRONG MAGNETIE FIELDS 8.6 THEORETIEAL APPROAEHES 8.6.1 GENERAL
APPROAEHES 8.6.2 MODELING DIFFUSION
8.6.3 THE SEMICLASSIEAL APPROACH 8.6.4 THE STOEHASTIE LIOUVILLE EQUATION
8.6.5 MONTE CARLO APPROAEHES 8.7 EXPERIMENTAL APPROAEHES
8.7.1 FLUORESEENEE DETEETION 8.7.2 OPTIEAL ABSORPTION DETEETION 8.7.3
RAPID FIELD SWITEHING 8.8 THE LIFE CYCLE OF RADICA1 PAIRS IN HOMOGENEOUS
SOLUTION
8.8.1 DIFFERENTIATING G-PAIRS AND F-PAIRS 8.9 SUMMARY
9. CHEMICAL TRANSFORMATIONS WITHIN THE PARAMAGNETIC WORLD INVESTIGATED
BY PHOTO-CIDNP MARTIN GOEZ
9.1 INTRODUCTION 9.2 CIDNP THEORY 9.3 EXPERIMENTAL METHODS 9.4
RADIEAL-RADIEAL TRANSFORMATIONS DURING DIFFUSIVE
EXEURSIONS 9.5 RADIEAL-RADIEAL TRANSFORMATIONS AT REENEOUNTERS 9.6
INTEREONVERSIONS OF BIRADIEALS 9.7 CONCLUSIONS
IX
167 167 169 171
172 172 173
173 174 174 174
175 176 176 176
177 180
185
185 186 190
191 196 199 203
10. SPIN RELAXATION IN RU-CHROMOPHORE-LINKED AZINELDIQUAT RADICAL PAIRS
205
MATTHEW T. RAWLS, ILYA KUPROV, C. MICHAEL ELLIOTT, AND ULRICH E. STEINER
10.1 INTRODUCTION 205
10.2 EPR FOR THE ISOLATED IONS 209
10.3 CALEULATION METHODS FOR EPR OF THE ISO1ATED IONS 211
10.3.1 CALCU1ATION OF G TENSOR COMPONENTS 212
10.3.2 CALCULATION OF HYPERFINE COUPLING CONSTANTS 213
10.3.2.1 AB INITIO HYPERFINE COUPLING CONSTANTS: GENERAL NOTES 213
10.3.2.2 THEORETIEAL VALUES OF ISOTROPIE AND ANISOTROPIE HYPERFINE
COUPLING CONSTANTS 214
10.4 IMP1IEATIONS FOR SPIN-RELAXATION IN LINKED RADICA1 PAIRS 216
IMAGE 6
X CONTENTS
11.REACTIONDYNAMICSOFCARBON-CENTEREDRADICALSINEXTREME
ENVIRONMENTSSTUDIEDBYTHECROSSEDMOLECULARBEAMTECHNIQUE
221
RALF I. KAISER
11.1 INTRODUCTION 221 11.2THECROSSEDMOLECULARBEAMMETHOD 223
11.3EXPERIMENTALSETUP224
11.3.1THECROSSEDBEAMMACHINE224
11.3.2SUPERSONICBEAMSOURCES
227
11.3.2.1ABLATIONSOURCE227
11.3.2.2PYROLYTICSOURCE
228
11.3.2.3PHOTOLYTICSOURCE 228 11.4CROSSEDBEAMSTUDIES229
11.4.1REACTIONS
OF PHENYLRADICALS229
11.4.2REACTIONS
OF CNANDC 2 HRADICALS236
11.4.3REACTIONSOFCARBONATOMS,DICARBONMOLECULES,AND TRICARBONMOLEEULES
237
11.5CONCLUSIONS240
12.LASERFLASHPHOTOLYSISOFPHOTOINITIATORS:ESR,OPTICAL,AND IR
SPECTROSCOPYDETECTIONOFTRANSIENTS 249
[GOR V. KHUDYAKOVANDNICHOLAS J. TURRO
12.1 INTRODUCTION 249 12.2PHOTODISSOCIATION OF INITIATORS250
12.2.1QUANTUMYIELDS
OF FREERADICALS IN NONVISCOUSSOLUTIONS250
12.2.2CAGEEFFECTUNDERPHOTODISSOCIATION252
12.2.3THEMAGNETICFIELDEFFECT
ON PHOTODISSOCIATION 253
12.3TRESRDETECTION OF TRANSIENTS254 12.3.1CIDEPUNDERPHOTODISSOCIATION
OF INITIATORS254
12.3.2ADDITION
OF FREERADICALS TO THEDOUBLEBONDS OF MONOMERS260
12.3.3ELECTRONSPIN POLARIZATIONTRANSFERFROMRADICALS
OF
PHOTOINITIATORS TO STABLENITROXYLPOLYRADICALS 268 12.4OPTICALDETECTION
OF TRANSIENTS270 12.4.1UV-VISSPECTRA
OF REPRESENTATIVERADICALS270
12.4.2REPRESENTATIVEKINETICDATAONREACTIONS
OF PHOTOINITIATOR
FREERADICALS270
12.5IRDETECTION
OF FREERADICALSANDMONITORINGTHEIRREACTIONS274 12.6CONCLUDINGREMARKS274
13.DYNAMICS OF RADICAL PAIR PROCESSESIN BULK POLYMERS 281 CARLOS A.
CHESTAANDRICHARD G. WEISS
13.1 INTRODUCTION 281 13 .1.1 GENERALCONSIDERATIONS 281
IMAGE 7
CONTENTS XI
13.1.2 ESCAPE PROBABILITY OF AN ISOLATED, INTIMATE RADICAL PAIR IN
LIQUIDS AND BULK POLYMERS 283
13.2 SINGLET-STATE RADICAL PAIRS FROM IRRADIATION OF ARYL ESTERS AND
ALKYL ARYL ETHERS 286
13.2.1 GENERAL MECHANISTIC CONSIDERATIONS FROM SOLUTION AND GAS-PHASE
STUDIES 286
13.2.1.1 PHOTO-FRIES REACTIONS OF ARYL ESTERS 287
13.2.1.2 PHOTO-CLAISEN REACTIONS OF ALKYL ARYL ETHERS 289 13.3
PHOTO-REACTIONS OF ARYL ESTERS IN POLYMER MATRICES. KINETIC INFORMATION
FROM CONSTANT INTENSITY IRRADIATIONS 289
13.3.1 RELATIVE RATE INFORMATION FROM IRRADIATION OF ARYL ESTERS IN
WHICH ACYL RADICALS DO NOT DECARBONYLATE RAPIDLY 290 13.3.2 ABSOLUTE AND
RELATIVE RATE INFORMATION FROM CONSTANT INTENSITY IRRADIATION OF ARYL
ESTERS IN WHICH ACYL
RADICALS DO DECARBONYLATE RAPIDLY 293
13.4 RATE INFORMATION FROM CONSTANT INTENSITY IRRADIATION OF ALKYL ARYL
ETHERS 297
13.4.1 RATE INFORMATION FROM AN OPTICALLY ACTIVE ETHER 299 13.4.1.1
RESULTS FROM IRRADIATION IN N-ALKANE SOLUTIONS 299 13.4.1.2 RESULTS FROM
IRRADIATION IN POLYETHYLENE FILMS 304 13.5 COMPARISON OF CALCULATED
RATES TO OTHER METHODS FOR
POLYETHYLENE FILMS 306
13.6 TRIPLET-STATE RADICAL PAIRS 308
13.6.1 TRIPLET-STATE RADICAL PAIRS FROM THE PHOTOREDUCTION OF
BENZOPHENONE BY HYDROGEN DONORS 308
13.6.2 TRIPLET-STATE RADICAL PAIRS FROM NORRISH TYPE I PROCESSES 311
13.7 CONDUDING REMARKS 318
14. ACRYLIC POLYMER RADICALS: STRUCTURAL CHARACTERIZATION AND DYNAMICS
325 MALEOLM D. E. FORBES AND NATALIA V. LEBEDEVA
14.1 INTRODUCTION 325
14.2 THE PHOTODEGRADATION MECHANISM 326
14.3 POLYMER STRUCTURES 327
14.4 THE TIME-RESOLVED EPR EXPERIMENT 329
14.5 TACTICITY AND TEMPERATURE DEPENDENCE OF ACRYLATE RADICALS 332 14.6
STRUCTURAL DEPENDENCE 334
14.6.1 DRPOLY(METHYL METHACRYLATE), DRPMMA 335
14.6.2 POLY(ETHYL METHACRYLATE), PEMA 337
14.6.3 POLY(ETHYL CYANOACRYLATE), PECA 337
14.6.4 POLY(ETHYL ACRYLATE), PEA 337
14.6.5 POLY(FLUOROOCTYL METHACRYLATE), PFOMA 338
14.6.6 POLYACRYLIC ACID, PAA 339
14.6.7 POLYMETHACRYLIC ACID, PMAA 340
14.7 OXO-ACYL RADICALS 340
IMAGE 8
XII
14.8SPINPOLARIZATIONMECHANISMS 14.9SOLVENTEFFECTS
14.9.1PHEFFECTSONPOLY(ACID)RADICALS
14.9.2GENERALFEATURESFORPOLYACRYLATES 14.10DYNAMICEFFECTS
14.10.1THETWO-SITE
LUMP MODEL
14.10.2SIMULATIONSANDACTIVATIONPARAMETERS
14.11 CONCLUSIONS
INDEX
CONTENTS
343 344 344
345 347
348 350
352
359
|
| any_adam_object | 1 |
| author2 | Forbes, Malcolm D. E. 1960- |
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| id | DE-604.BV036428528 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:39:11Z |
| institution | BVB |
| isbn | 9780470390092 |
| language | English |
| lccn | 2009031417 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-020301159 |
| oclc_num | 711800692 |
| open_access_boolean | |
| owner | DE-11 DE-19 DE-BY-UBM |
| owner_facet | DE-11 DE-19 DE-BY-UBM |
| physical | XXII, 370 S. Ill., graph. Darst. |
| publishDate | 2010 |
| publishDateSearch | 2010 |
| publishDateSort | 2010 |
| publisher | Wiley |
| record_format | marc |
| series | Wiley series on reactive intermediates in chemistry and biology |
| series2 | Wiley series on reactive intermediates in chemistry and biology |
| spelling | Carbon-centered free radicals and radical cations strucutre, reactivity, and dynamics ed. by Malcolm D. E. Forbes Hoboken, N.J. Wiley 2010 XXII, 370 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wiley series on reactive intermediates in chemistry and biology 3 Includes index. Free radicals (Chemistry) Carbon, Activated Reactivity (Chemistry) Cations Polymere (DE-588)4046699-1 gnd rswk-swf Radikal Chemie (DE-588)4076475-8 gnd rswk-swf Kation (DE-588)4163478-0 gnd rswk-swf Kohlenstoffradikal (DE-588)4502398-0 gnd rswk-swf Kohlenstoffradikal (DE-588)4502398-0 s DE-604 Radikal Chemie (DE-588)4076475-8 s Polymere (DE-588)4046699-1 s Kation (DE-588)4163478-0 s Forbes, Malcolm D. E. 1960- (DE-588)140801278 edt Wiley series on reactive intermediates in chemistry and biology 3 (DE-604)BV025587684 3 OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020301159&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Carbon-centered free radicals and radical cations strucutre, reactivity, and dynamics Wiley series on reactive intermediates in chemistry and biology Free radicals (Chemistry) Carbon, Activated Reactivity (Chemistry) Cations Polymere (DE-588)4046699-1 gnd Radikal Chemie (DE-588)4076475-8 gnd Kation (DE-588)4163478-0 gnd Kohlenstoffradikal (DE-588)4502398-0 gnd |
| subject_GND | (DE-588)4046699-1 (DE-588)4076475-8 (DE-588)4163478-0 (DE-588)4502398-0 |
| title | Carbon-centered free radicals and radical cations strucutre, reactivity, and dynamics |
| title_auth | Carbon-centered free radicals and radical cations strucutre, reactivity, and dynamics |
| title_exact_search | Carbon-centered free radicals and radical cations strucutre, reactivity, and dynamics |
| title_full | Carbon-centered free radicals and radical cations strucutre, reactivity, and dynamics ed. by Malcolm D. E. Forbes |
| title_fullStr | Carbon-centered free radicals and radical cations strucutre, reactivity, and dynamics ed. by Malcolm D. E. Forbes |
| title_full_unstemmed | Carbon-centered free radicals and radical cations strucutre, reactivity, and dynamics ed. by Malcolm D. E. Forbes |
| title_short | Carbon-centered free radicals and radical cations |
| title_sort | carbon centered free radicals and radical cations strucutre reactivity and dynamics |
| title_sub | strucutre, reactivity, and dynamics |
| topic | Free radicals (Chemistry) Carbon, Activated Reactivity (Chemistry) Cations Polymere (DE-588)4046699-1 gnd Radikal Chemie (DE-588)4076475-8 gnd Kation (DE-588)4163478-0 gnd Kohlenstoffradikal (DE-588)4502398-0 gnd |
| topic_facet | Free radicals (Chemistry) Carbon, Activated Reactivity (Chemistry) Cations Polymere Radikal Chemie Kation Kohlenstoffradikal |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020301159&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV025587684 |
| work_keys_str_mv | AT forbesmalcolmde carboncenteredfreeradicalsandradicalcationsstrucutrereactivityanddynamics |