Verfügbarkeit: Ferroelectric devices

Ferroelectric devices:

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Bibliographische Detailangaben
1. Verfasser:	Uchino, Kenji 1950- (VerfasserIn)
Format:	Buch
Sprache:	English
Veröffentlicht:	Boca Raton [u.a.] CRC Press 2010
Ausgabe:	2. ed.
Schlagworte:	Ferroelectric devices Ferroelektrikum Elektrisches Bauelement
Online-Zugang:	Inhaltsverzeichnis Klappentext
Beschreibung:	Includes bibliographical references and index
Beschreibung:	XIX, 347 S. Ill., graph. Darst.
ISBN:	9781439803752

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Datensatz im Suchindex

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adam_text	Contents Preface ...............................................................................................................................................xi Suggested Teaching Schedule ........................................................................................................xiii Prerequisite Knowledge ...................................................................................................................xv Author ............................................................................................................................................xvii List of Symbols ...............................................................................................................................xix Chapter 1 General View of Ferroelectrics ....................................................................................1 1.1 Crystal Structure and Ferroelectricity .................................................................1 1.2 Origin of Spontaneous Polarization ....................................................................4 1.3 Origin of Field-Induced Strain ............................................................................7 1.4 Electro-Optic Effect ..........................................................................................11 1.5 Example of Ferroelectrics .................................................................................17 1.5.1 Barium Titanate .....................................................................................17 1.5.2 PZT ........................................................................................................18 1.5.3 Polyvinylidene Difluoride (PVDF) ........................................................19 1.5.4 Pb-Free Piezoceramics ..........................................................................20 1.6 Applications of Ferroelectrics ...........................................................................20 References ..................................................................................................................23 Chapter 2 Mathematical Treatment of Ferroelectrics .................................................................25 2.1 Tensor Representation of Physical Properties ...................................................25 2.1.1 Fundamentals of Tensor .........................................................................25 2.1.2 Tensor Representation ............................................................................26 2.1.3 Crystal Symmetry and Tensor Form ......................................................27 2.1.4 Reduction of the Tensor (Matrix Notation) ............................................33 2.1.5 Matrix Notation of Electrostrictive Coefficients ...................................34 2.2 Phenomenology of Ferroelectricity ...................................................................42 2.2.1 Fundamentals of Phenomenology ..........................................................42 2.2.2 Landau Theory of the Phase Transition ................................................43 2.2.3 Phenomenology of Electrostriction .......................................................47 2.2.4 Converse Effects of Electrostriction ......................................................50 2.2.5 Temperature Dependence of Electrostriction ........................................50 2.3 Phenomenology of Antiferroelectricity .............................................................51 2.3.1 Antiferroelectrics ...................................................................................51 2.3.2 Phenomenology of Antiferroelectrics ....................................................52 2.4 Ferroelectric Domain Contributions .................................................................54 2.4.1 Ferroelectric Domain Reorientation ......................................................54 2.4.2 Uchida-Ikeda Model .............................................................................57 2.4.3 Crystal Structure and Coercive Field ....................................................61 2.4.4 Hysteresis Estimation Program .............................................................61 2.4.5 Domain Engineering .............................................................................64 References ..................................................................................................................73 VI Contents Chapter 3 Designing with Materials and Devices and Fabrication Processes ............................75 3.1 Material Designing ............................................................................................75 3.1.1 Composition Selection ............................................................................75 3.1.2 Dopant Effects on Ferroelectricity .........................................................77 3.1.2.1 Domain Wall Stability .............................................................78 3.1.2.2 Crystallographic Deficiencies ..................................................80 3.1.3 High-Power Characteristics ...................................................................82 3.2 Fabrication Processes of Ceramics ....................................................................85 3.2.1 Preparation of Ceramic Powders ...........................................................85 3.2.1.1 Solid-State Reaction ................................................................85 3.2.1.2 Coprecipitation ........................................................................86 3.2.1.3 Alkoxide Hydrolysis ................................................................86 3.2.2 Sintering Process ...................................................................................87 3.2.3 Single Crystal Growth ...........................................................................90 3.2.3.1 Quartz, LN, and LT .................................................................90 3.2.3.2 PZN-PT, PMN-PT, and PZT .................................................90 3.2.4 Templated Grain Growth .......................................................................90 3.3 Device Designing ..............................................................................................91 3.3.1 Single Disks ...........................................................................................91 3.3.2 Multilayers .............................................................................................92 3.3.3 Unimorphs/Bimorphs ............................................................................94 3.3.4 Flextension/Hinge-Lever Amplification Mechanisms ..........................98 3.3.5 Flexible Composites ...............................................................................99 3.3.6 Thin/Thick Films ...................................................................................99 3.3.6.1 Film Manufacturing Techniques .............................................99 3.3.6.2 MEMS Applications ..............................................................101 3.3.6.3 Constraints in Thin/Thick Films ..........................................102 3.4 Size Effect on Ferroelectricity .........................................................................102 3.4.1 Grain Size Effect on Ferroelectricity ...................................................103 3.4.2 3-D Particle Size Effect on Ferroelectricity ........................................105 References ................................................................................................................112 Chapter 4 High-Permittivity Dielectrics ...................................................................................115 4.1 Ceramic Capacitors .........................................................................................115 4.2 Chip Capacitors ...............................................................................................116 4.2.1 Thin Multilayer Capacitor ...................................................................116 4.2.2 Base-Metal Internal Electrode ............................................................117 4.2.2.1 Barium Titanate-Based Chip ................................................117 4.2.2.2 PbTiCyBased Chip ...............................................................117 4.3 Hybrid Substrates ............................................................................................119 4.4 Relaxor Ferroelectrics .....................................................................................121 4.4.1 High Permittivity .................................................................................121 4.4.2 Diffuse Phase Transition .....................................................................122 4.4.3 Dielectric Relaxation ...........................................................................124 References ................................................................................................................130 Chapter 5 Ferroelectric Memory Devices .................................................................................131 5.1 DRAM .............................................................................................................131 5.1.1 Principle of DRAM ..............................................................................131 5.1.2 Ferroelectric DRAM ............................................................................135 Contents 5.2 Nonvolatile Ferroelectric Memory ..................................................................136 5.2.1 FeRAM (Inversion Current Type) .......................................................136 5.2.2 MFSFET ..............................................................................................139 References ................................................................................................................142 Chapter 6 Pyroelectric Devices ................................................................................................145 6.1 Pyroelectric Materials .....................................................................................145 6.1.1 Pyroelectric Effect ...............................................................................145 6.1.2 Responsivity .........................................................................................148 6.1.3 Figures of Merit ...................................................................................150 6.2 Temperature/Infrared Sensors .........................................................................152 6.3 Infrared Image Sensors ...................................................................................152 6.4 Electrocaloric Devices .....................................................................................154 6.4.1 Electrocaloric Effect ............................................................................154 6.4.1.1 Phenomenological Formula ...................................................154 6.4.1.2 Electrocaloric Materials ........................................................157 References ................................................................................................................160 Chapter 7 Piezoelectric Devices ...............................................................................................161 7.1 Piezoelectric Materials and Properties ............................................................161 7.1.1 Piezoelectric Figures of Merit ..............................................................161 7.1.2 Piezoelectric Materials .........................................................................167 7.1.2.1 Single Crystals .......................................................................168 7.1.2.2 Polycrystalline Materials .......................................................168 7.1.2.3 Relaxor Ferroelectrics ............................................................172 7.1.2.4 Polymers ................................................................................172 7.1.2.5 Composites ............................................................................173 7.1.2.6 Thin Films .............................................................................173 7.2 Pressure Sensors/Accelerometers/Gyroscopes ................................................174 7.3 Piezoelectric Vibrators/Ultrasonic Transducers ..............................................177 7.3.1 Piezoelectric Resonance .......................................................................177 7.3.1.1 Piezoelectric Equations ..........................................................177 7.3.1.2 Electromechanical Coupling Factor ......................................177 7.3.1.3 Longitudinal Vibration Mode ................................................180 7.3.2 Equivalent Circuits of Piezoelectric Vibrators .....................................184 7.3.3 Piezoelectric Vibrators .........................................................................186 7.3.4 Ultrasonic Transducers ........................................................................187 7.3.4.1 Ultrasonic Imaging ................................................................187 7.3.4.2 Sonochemistry .......................................................................188 7.3.5 Resonators/Filters ................................................................................189 7.4 Surface Acoustic Wave Devices ......................................................................191 7.5 Micromass Sensors ..........................................................................................193 7.5.1 Biosensor ..............................................................................................193 7.5.2 Viscosity Sensor ...................................................................................194 7.6 Piezoelectric Transformers ..............................................................................194 7.7 Piezoelectric Actuators ....................................................................................198 7.7.1 Ceramic Actuator Materials .................................................................198 7.7.2 Actuator Designs ..................................................................................200 7.7.3 Drive/Control Techniques ....................................................................201 νϋί Contents 7.7.4 Device Applications.............................................................................207 7.7.4.1 Servo Displacement Transducers ...........................................207 7.7.4.2 Pulse-Drive Motors ................................................................208 7.8 Ultrasonic Motors ............................................................................................212 7.8.1 Ultrasonic Motors (USM) ....................................................................212 7.8.2 Classification and Principles of Ultrasonic Motors .............................214 7.8.2.1 Standing-Wave Type ..............................................................214 7.8.2.2 Propagating-Wave Type .........................................................215 7.8.3 Standing Wave-Type Motors ...............................................................216 7.8.3.1 Rotary Motors ........................................................................216 7.8.3.2 Linear Motors ........................................................................218 7.8.4 Propagating Wave-Type Motors ..........................................................219 7.8.4.1 Linear Motors ........................................................................219 7.8.4.2 Rotary Motors .......................................................................220 7.8.4.3 Comparison of the Various Ultrasonic Motors .....................223 7.8.5 Smooth Impact Drive Mechanism (SIDM) .........................................224 7.9 Piezoelectric Energy Harvesting .....................................................................224 7.9.1 Piezoelectric Passive Damping to Energy Harvesting .........................224 7.9.2 High-Energy Harvesting (~W) .............................................................225 7.9.3 Low-Energy Harvesting (~mW) ...........................................................227 References ................................................................................................................232 Chapter 8 Electro-Optic Devices ..............................................................................................235 8.1 Electro-Optic Effect—Review ........................................................................235 8.2 Transparent Electro-Optic Ceramics ..............................................................235 8.2.1 (Pb,La)(Zr,Ti)O3 ...................................................................................236 8.2.2 PMN-PT ..............................................................................................239 8.2.3 Pb(Zn1/3Nb2/3)O3 ..................................................................................241 8.3 Bulk Electro-Optic Devices ............................................................................242 8.3.1 Ferpic ...................................................................................................242 8.3.2 Eye Protection Application ..................................................................243 8.3.3 Stereo TV Application .........................................................................243 8.3.4 Two-Dimensional Displays ..................................................................244 8.3.4.1 Fabrication Process of the 2-D Display .................................244 8.3.4.2 Characteristics of the Light Valve Array ..............................246 8.3.4.3 Construction of the Image Projector .....................................247 8.3.5 KTN Single Crystal Optical Switch ....................................................251 8.3.6 Laser Beam Scanner ............................................................................252 8.4 Waveguide Modulators ....................................................................................252 8.4.1 LiNbO3 Waveguide ..............................................................................252 8.4.2 PZT Thin Film Waveguide ..................................................................254 References ................................................................................................................259 Chapter 9 PTC Materials ..........................................................................................................261 9.1 Mechanism of PTC Phenomenon ....................................................................261 9.1.1 PTC Phenomenon .................................................................................261 Contents ix 9.1.2 Mechanism of the PTC Phenomenon ...................................................261 9.1.2.1 Semiconducting Properties ....................................................261 9.1.2.2 Schottky Barrier Effect .........................................................263 9.1.2.3 Experimental Verification .....................................................265 9.2 PTC Thermistors .............................................................................................266 9.3 Grain Boundary Layer Capacitors ...................................................................269 References ................................................................................................................272 Chapter 10 Composite Materials ................................................................................................273 10.1 Connectivity ...................................................................................................273 10.2 Composite Effects ..........................................................................................274 10.2.1 Sum Effects ......................................................................................274 12.2.2 Combination Effects ........................................................................275 10.2.3 Product Effects .................................................................................276 10.3 PZT:Polymer Composites ..............................................................................277 10.3.1 Piezoelectric Composite Materials ...................................................277 10.3.2 Principle of PZT:Polymer Composites .............................................278 10.3.3 Theoretical Models for 0-3 Composites ...........................................281 10.3.4 Advanced PZT:Polymer Composites ................................................283 10.4 Composite Dampers and Energy Harvesters .................................................284 10.4.1 Piezoelectric Composite Dampers ....................................................284 10.4.2 Piezoelectric Composite Energy Harvesting ....................................288 10.5 Magnetoelectric Sensors ................................................................................290 References ................................................................................................................296 Chapter 11 Future of Ferroelectric Devices ................................................................................297 11.1 Market Share ..................................................................................................297 11.1.1 Market Share of Ferroelectric Devices .............................................297 11.1.2 Market Share of Piezoelectric Actuators ..........................................298 11.2 Reliability Issues ............................................................................................300 11.2.1 Materials Improvements ...................................................................300 11.2.2 Reliability of Devices .......................................................................301 11.2.3 Drive/Control Techniques ................................................................303 11.2.4 Safety Systems ..................................................................................303 11.3 Development of Bestselling Devices .............................................................304 11.3.1 Three Creativities .............................................................................304 11.3.2 Technological Creativity ...................................................................304 11.3.2.1 Discovery of a New Function or Material ........................304 11.3.2.2 Performance Improvement ...............................................308 11.3.3 Product Planning Creativity .............................................................314 11.3.3.1 Seeds and Needs ...............................................................314 11.3.3.2 Innovation Obstacle in Technology Management ............316 11.3.3.3 Development Pace .............................................................316 11.3.3.4 Specifications ....................................................................316 11.3.3.5 Product Design Philosophy ...............................................318 11.3.3.6 Smart Systems ...................................................................318 χ Contents 11.3.4 Marketing Creativity ........................................................................319 11.3.4.1 Choose Your Customers ....................................................320 11.3.4.2 Narrow Your Focus ...........................................................322 11.3.4.3 Dominate Your Market .....................................................326 11.3.5 Business Strategy ..............................................................................327 11.3.5.1 Analysis Tools ...................................................................328 11.3.5.2 Internal Environmental Analysis ......................................329 11.3.5.3 External Environmental Analysis .....................................331 References ................................................................................................................337 Index ..............................................................................................................................................339 INDUSTRIAL ELECTRONICS Ferroelectric Devices Second Edition Discover a Strategy to Develop Bestselling Ferroelectric Devices Updating its bestselling predecessor, Ferroelectric Devices, Second Edition assesses the last decade of developments—and setbacks—in the commercialization of ferroelectricity. Field pioneer and esteemed author Uchino provides insight into why this relatively nascent and interdisciplinary process has failed so far because it lacks a systematic accumulation of fundamental knowledge regarding materials and device development. Filling the informational void, this collection of information reviews state-of-the-art research and development trends reflecting nano and optical technologies, environmental regulation, and alternative energy sources. Like the first edition, which became a standard in the field, this volume provides a general introduction to ferroelectrics along with theoretical background. It then addresses practical design and device manufacturing, including recently developed processes and applications. Updating old data with a forecast of future developments, the text analyzes improvements to original ferroelectric devices to aid the design process of new ones. The second edition includes new sections on • Pb-free piezoelectrics • Size effect on ferroelectricity • Electrocaloric devices • Micro-mass sensors • Piezoelectric energy harvesting • Light valves and scanners • Multi-ferroic devices, including magneto-electric sensors Uchino provides a general introduction to the theoretical background of ferroelectric devices, practical materials, device designs, drive/control techniques, and typical applications. He presents frequently asked questions from students, lab demonstrations for practical understanding, and check point quizzes and model solutions to monitor understanding. After a thorough exploration of ferroelectric devices and their past, this book looks to the industry s future, assessing market size and remaining reliability/lifetime issues. The author also unveils his strategy for developing best-selling ferroelectric devices. CRC Press Taylor &. Francis Group :■ informa business KIDEOI ISSN: 178-1-4310-0375-2 ЧОООГЈ 6000 Broken Sound Parkway, NW Suite 300, Boca Raton, FL 33487 270 Madison Avenue New York, NY 100 і 6 2 Park Square, Milton Park Abmgdon, Oxon OX14 4RN, UK WWW com
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title	Ferroelectric devices
title_auth	Ferroelectric devices
title_exact_search	Ferroelectric devices
title_full	Ferroelectric devices Kenji Uchino
title_fullStr	Ferroelectric devices Kenji Uchino
title_full_unstemmed	Ferroelectric devices Kenji Uchino
title_short	Ferroelectric devices
title_sort	ferroelectric devices
topic	Ferroelectric devices Ferroelektrikum (DE-588)4154121-2 gnd Elektrisches Bauelement (DE-588)4070746-5 gnd
topic_facet	Ferroelectric devices Ferroelektrikum Elektrisches Bauelement
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018963558&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018963558&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT uchinokenji ferroelectricdevices

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