Fundamentals of materials science: the microstructure-property relationship using metals as model systems
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Heidelberg [u.a.]
Springer
2010
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XXI, 594 S. Ill., graph. Darst. |
| ISBN: | 9783642104992 |
Internformat
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| 245 | 1 | 0 | |a Fundamentals of materials science |b the microstructure-property relationship using metals as model systems |c Eric J. Mittemeijer |
| 264 | 1 | |a Heidelberg [u.a.] |b Springer |c 2010 | |
| 300 | |a XXI, 594 S. |b Ill., graph. Darst. | ||
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Datensatz im Suchindex
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|---|---|
| adam_text | Titel: Fundamentals of materials science
Autor: Mittemeijer, Eric J.
Jahr: 2010
Contents
1 Introduction............................... 1
1.1 The Notion Material....................... 1
1.2 The Notion Metal ........................ 2
1.3 Models and Experiments..................... 3
1.4 Bridging Length Scales..................... 4
1.5 Understanding of Nature, the Role of Science:
Magic, Discovery and Models.................. 5
2 Electronic Structure of the Atom; the Periodic Table ........ 9
2.1 Protons, Neutrons and Electrons................. 9
2.2 Rutherford s Model (1911) ................... 9
2.3 Bohr s Model (1913)....................... 9
2.4 The Wave or Quantum-Mechanical Model
(Heisenberg/Schrödinger, 1926); Quantum Numbers...... 12
Intermezzo: A Derivation of the Uncertainty Relation;
Dijfraction of Moving Particles at a Slit............. 14
2.4.1 The Probability Amplitude.............. 16
2.4.2 Characterizing the Possible Energy States;
the Quantum Numbers ................ 17
2.5 The Pauli Exclusion Principle and the Aufbau Prinzip .... 20
Intermezzo: The Discoverers of the Periodic System;
A First Example of a Priority Battle ............. 26
Epilogue: The Extent of the Periodic Table ............... 27
2.5.1 Atom Size and Ionization Energy........... 28
2.6 The Shape of the Probability Density Distribution
for the Electron ......................... 31
References................................ 36
3 Chemical Bonding in Solids; with Excursions to Material Properties 37
3.1 Attractive and Repulsive Forces;
Thermal Expansion and Elastic Constants............ 37
Intermezzo: The Linear Coefficient of Thermal Expansion
ofLarge and Small Crystals................... 40
3.2 Remarks on Model Types of Bonding.............. 43
3.3 Ionic Bonding; Lattice Energy and the Madelung Factor .... 44
3.4 Covalent Bonding........................ 51
3.5 Metal Bonding.......................... 57
3.5.1 The Free Electron Models............... 57
3.5.2 Zone or Band Models................. 67
3.5.3 The Crystal Structure of Metals............ 82
3.6 van der Waals Bonding ..................... 91
3.7 Hydrogen Bonding........................ 94
Epilogue: How Science Really Happens ............... 99
References................................ 100
Crystallography............................. 103
Intermezzo: Making Grain Boundaries Visible.............. 106
4.1 Geometrie Description of Crystals................ 107
4.1.1 Translation Lattice, Motif and Crystal Structure ... 107
4.1.2 The Crystal System.................. 115
Intermezzo: A Short Note on Point Groups, Crystallographic
Point Groups, Plane Groups and Space Groups;
Glide and Screw Operations................... 118
4.1.3 The Bravais Categorization of Translation Lattices . . 120
4.1.4 Description of Lattice Planes and Directions;
Miller and Miller-Bravais Indices .......... 123
4.2 Crystal Structures of Elements.................. 129
4.2.1 Crystal Structures Derived from Close
Packed Arrangements of Hard Spheres........ 130
4.2.2 The Body Centred Cubic (b.c.c.) Crystal Structure . . 141
4.2.3 Further Crystal Structures of Elements........ 145
4.2.4 The Coordination Number.............. 149
4.2.5 Polymorphism and Allotropy............. 150
4.3 The Notions Alloy, Solid Solution,
Ordered Solid Solution and Compound............. 152
4.4 Crystalline Solid Solutions and Compounds .......... 153
4.4.1 Substitutional Solid Solutions............. 153
4.4.2 Interstitial Solid Solutions .............. 159
Intermezzo: Thermochemical Surface Engineering;
Nitriding and Carburizing of Iran and Steels.......... 168
4.4.3 Crystal Structures of Further Materials........ 170
4.5 Determination of the Crystal Structure;
X-Ray Diffraction Analysis................... 171
Intermezzo: The von Laue Theory.................... 173
4.6 The Stereographic Projection.................. 178
4.7 The Texture of a Polycrystal;
the Pole Figure, the Inverse Pole Figure
and the Orientation Distribution Function............ 180
4.8 Aperiodic Crystals........................ 189
4.8.1 Incommensurately Modulated Atomic Structures . . 189
4.8.2 Quasicrystals..................... 193
Intermezzo: A Revolution in Crystallography; Young Versus Old . 193
Epilogue: The Notion Crystal Revisited................. 197
Appendix: How to Deal with Atoms at Unit-Cell Boundaries...... 198
References................................ 200
5 The Crystal Imperfection; Lattice Defects .............. 201
5.1 Point Defects (Zero-Dimensional):
Thermal and Constitutional Vacancies;
Interstitial, Substitutional and Antistructure Atoms;
Schottky and Frenkel Defects.................. 202
5.2 Line Defects (One-Dimensional):
Edge and Screw Dislocations.................. 206
5.2.1 The Edge Dislocation................. 207
5.2.2 The Screw Dislocation................ 208
5.2.3 Dislocation Line and Burgers Vector;
Dislocation Density.................. 209
Intermezzo: A Historical Note About the Burgers Vector........ 211
5.2.4 Strain Energy of a Dislocation............ 213
5.2.5 Glide of Dislocations; Slip Systems ......... 215
Intermezzo: The Peierls Stress...................... 217
5.2.6 Dislocation Production: Frank-Read Source,
Cross-Slip and Vacancy Condensation........ 219
5.2.7 Climbof Dislocations................. 223
5.2.8 Partial and Sessile Dislocations............ 224
5.3 Planar Defects (Two-Dimensional):
Grain Boundaries, Twin Boundaries,
Stacking Faults and Antiphase Boundaries;
Coherent and Incoherent Interfaces............... 228
Intermezzo: Coherent and Incoherent Interfaces Versus
Coherent and Incoherent Dijfraction.............. 240
5.4 Volume Defects (Three-Dimensional): Second-Phase
Particles and Pores........................ 241
References................................ 243
6 Analysis of the Microstructure;
Analysis of Lattice Imperfections:
Light and Electron Microscopical and X-Ray Diffraction Methods . 245
6.1 TheLens............................. 246
6.1.1 The Paraxial Approximation............. 246
6.1.2 The Compound Lens................. 249
6.2 Image Formation......................... 249
6.3 The (Reflected) Light Optical Microscope ........... 253
6.3.1 The Magnifier ( Loupe )............... 253
6.3.2 The Compound Microscope.............. 255
6.4 Köhler Illumination....................... 257
6.5 Resolving Power......................... 259
6.5.1 Minimal Image Construction............. 259
6.5.2 Maximal Magnification................ 260
6.6 Bright and Dark Field and Other Imaging Techniques
by Light Microscopy....................... 261
6.7 Transmission Electron Microscopy............... 267
6.7.1 Basic Constitution and Action of the TEM:
Imaging and Diffraction Modes............ 269
6.7.2 The Diffraction Pattern; the Zone Law........ 271
6.7.3 Diffraction Contrast Images: Bright Field
and Dark Field Imaging ............... 272
6.7.4 Examples of Bright and Dark Field TEM
Images......................... 274
6.7.5 Convergent Beam Electron Diffraction (CBED);
Microdiffraction;
Scanning Transmission Electron Microscopy (STEM) 276
6.7.6 High-Resolution Transmission Electron
Microscopy (HRTEM) ................ 280
6.7.7 Analytical Electron Microscopy (AEM);
Chemical Composition Maps;
Electron Probe Micro-Analysis (EPMA)
and Electron Energy Loss Spectroscopy (EELS) . . . 283
6.8 Scanning Electron Microscopy................. 285
6.8.1 Secondary Electron Images.............. 287
6.8.2 Back-Scattered Electron Images........... 288
6.8.3 Chemical Composition Maps;
Electron Probe Micro-Analysis (EPMA)....... 288
6.9 X-ray Diffraction Analysis of the Imperfect Microstructure . . 290
6.9.1 Determination of Crystallite Size and Microstrain . . 291
6.9.2 Determination of (Residual) Macrostress....... 296
Intermezzo: Grain Interaction...................... 299
Intermezzo: Surface Anisotropy and Thin Films............. 300
References................................ 301
7 Phase Equilibria............................. 303
7.1 The Notion Phase........................ 304
7.2 The Notion Component..................... 304
7.3 The Notions Equilibrium and Stationary State:
Internal Energy, Entropy, (Helmholtz) Free Energy
and Gibbs Energy........................ 305
7.4 Degrees of Freedom; the Phase Rule.............. 310
7.5 Phase Diagrams......................... 311
7.5.1 One-Component Systems............... 311
Intermezzo: Entropy of Fusion and the Structure of Liquids....... 313
7.5.2 Binary Systems.................... 314
7.5.3 Ternary Systems.................... 330
7.6 Microstructure Development with Reference
to the Phase Diagram ...................... 334
References................................ 337
8 Diffusion................................. 339
8.1 The Continuum Approach to Diffusion;
Fick s First and Second Laws.................. 339
8.2 The Atomistic Approach to Diffusion.............. 342
Intermezzo: Brownian motion...................... 343
8.3 Solutions of Fick s Laws..................... 345
8.4 Diffusion Mechanisms in Crystalline Systems......... 347
8.4.1 Exchange Mechanisms................ 347
8.4.2 The Vacancy Mechanism; Substitutional Diffusion . . 348
8.4.3 Interstitial Diffusion.................. 348
8.5 The Jump Frequency and the Activation Energy of Diffusion . 349
8.5.1 The Determination of A//vac............. 354
8.5.2 The Determination of A//mjg............. 356
8.6 Microstructure and Diffusion.................. 357
8.6.1 Diffusion Along the Low-Angle Symmetrical
TiltBoundary..................... 359
8.6.2 Diffusion Along a Moving Grain Boundary..... 360
Intermezzo: Priority and Scientific Decency............... 362
Appendix: Diffusion in Thin Film Systems;
Concentration-Depth Profiles.................. 365
References................................ 368
9 Phase Transformations......................... 371
9.1 Thermodynamics and Kinetics of Phase
Transformations;
Thermal Activation and the Activation Energy......... 372
9.2 Energetics of Nucleation;
Homogeneous and Heterogeneous Transformations;
Homogeneous and Heterogeneous Nucleation......... 374
Intermezzo: Nucleation ofAlN in Fe-Al Alloy.............. 377
9.3 Diffusional and Diffusionless Transformations......... 378
9.4 Diffusional Transformations; Examples............. 380
9.4.1 Age-Hardening Alloys; Clusters ,
Transition and Equilibrium Precipitates ....... 380
9.4.2 Eutectoid Transformation............... 385
Intermezzo: The Fe-C System; Steels and Cast Irons.......... 386
9.4.3 Discontinuous Transformation............ 391
9.4.4 The Widmanstätten Morphology........... 394
9.4.5 Grain-Boundary Wetting............... 395
9.5 Diffusionless Transformations; Examples............ 399
9.5.1 The Massive Transformation............. 400
9.5.2 The Martensitic Transformation ........... 404
Intermezzo: Shape Memory Alloys.................... 418
Intermezzo: The Hardness oflron-Based Interstitial Martensitic
Specimens............................ 420
Intermezzo: Tempering oflron-Based Interstitial Martensitic
Specimens............................ 421
9.6 The Analysis of the Kinetics of Phase Transformations..... 424
9.6.1 Time-Temperature-Transformation (TTT) Diagrams and
Continuous Cooling Transformation (CCT) Diagrams 426
9.6.2 Thermal History and the Stage of Transformation . . 429
9.6.3 The Transformation Rate; the Additivity Rule .... 432
9.6.4 Heterogeneous Phase Transformations
as a Composite Phenomenon:
Nucleation, Growth and Impingement........ 432
9.6.5 Modes of Nucleation................. 433
9.6.6 Modes of Growth................... 436
9.6.7 The Activation Energies for Nucleation and Growth . 438
9.6.8 Extended Volume and Extended Transformed
Fraction........................ 439
9.6.9 Modes of Impingement................ 442
9.6.10 The Transformed Fraction .............. 444
9.6.11 The Classical and Generalized
Johnson-Mehl-Avrami Equation;
the Additivity Rule Revisited............ 445
9.6.12 The Effective Activation Energy........... 447
9.6.13 Experimental Determination of the Degree
of Transformation; Dilatometry and Calorimetry . . . 448
9.6.14 Fitting of Kinetic Models............... 451
9.6.15 Direct Determination of the Effective
Activation Energy and the Growth Exponent..... 453
9.7 The Coupling of Thermodynamics to Kinetics......... 459
References................................ 460
10 Recovery, Recrystallization and Grain Growth............ 463
10.1 Recovery............................. 463
10.1.1 Dislocation Annihilation and Rearrangement..... 465
10.1.2 Kinetics of Recovery................. 469
10.2 Recrystallization......................... 470
10.2.1 Nucleation of Recrystallization........... 471
Intermezzo: The History ofan Idea;
the Subgrain as Origin of Recrystallization........... 475
10.2.2 Kinetics of Recrystallization............. 476
10.3 Grain Growth .......................... 477
10.3.1 The Grain-Boundary Network;
on Grain-Boundary/Interfacial Energy
and Tension...................... 478
Intermezzo: Interface Stabilized Microstructures............ 483
10.3.2 Grain-Boundary Curvature-Driven Growth...... 484
10.3.3 Kinetics of Grain Growth;
Inhibition of Grain Growth.............. 487
10.3.4 Abnormal Grain Growth............... 491
10.3.5 Particle Coarsening; Ostwald Ripening........ 493
References................................ 495
11 Mechanical Strength of Materials................... 497
11.1 Elastic Versus Plastic Deformation;
Ductile and Brittle Materials................... 498
11.2 Basic Modes of Uniaxial Deformation; Concepts
of Stress and Strain; Uniaxial Elastic Deformation Laws .... 499
Intermezzo: Short History of the Poisson Constant........... 502
Intermezzo: Negative Poisson Constant................. 503
11.3 Elastically Isotropie and Anisotropie Materials......... 504
11.4 Elastic Deformation Upon Three-Axial and Biaxial Loading . . 507
11.5 Elastic Strain Energy....................... 512
11.6 Rubber Elasticity; Elastomeric Behaviour............ 514
11.7 Viscoelasticity/Anelasticity; Mechanical Hysteresis...... 516
11.8 Plastic Deformation Characteristics............... 519
11.9 The Tensile Stress-Strain Curve; True Stress and True Strain . 521
11.9.1 Strain and Strain Rate Due to Dislocation
Movement....................... 525
11.9.2 The Yield Drop Phenomenon;
Cottrell-Bilby Atmospheres.............. 526
11.9.3 Shear Yielding and Craze Yielding.......... 531
11.10 Yielding Criteria in Cases of Two-and Three-Axial Loading . . 532
Intermezzo: Application of the von Mises Criterion to Predict
the Location ofFailure in Ball Bearings............. 533
11.11 Critical Resolved Shear Stress;
the Plastic Deformation of Single Crystals........... 536
11.12 Plastic Deformation of Polycrystals............... 539
11.13 Hardness Parameters; Macroscopic, Microscopic
and Nanoscopic......................... 540
Intermezzo: The Hardest Materials ................... 542
Intermezzo: Combined Nanoindentation and Scanning Probe
Microscopy............................ 544
Intermezzo: Hardness-Depth Profiling on Nanoscale.......... 548
11.14 Strengthening, Hardening Mechanisms
(of Metals in Particular)..................... 550
11.14.1 Strain Hardening (Work Hardening)......... 550
11.14.2 Grain Size; the Hall-Petch Relation ......... 551
11.14.3 Solid Solution Hardening............... 554
11.14.4 Precipitation/Dispersion Strengthening........ 555
11.15 Failure by Fracture; Crack Propagation............. 557
11.16 Failure by Creep......................... 562
11.16.1 Superplasticity..................... 566
11.17 Failure by Fatigue........................ 567
11.18 Residual, Internal Stresses.................... 573
Epilogue: The Essence of Materials Science;
Optimizing the Fatigue Strength ofFerritic Steels by Nitriding . 576
References................................ 580
Index...................................... 583
|
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| author | Mittemeijer, Eric J. 1950- |
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| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 620 - Engineering and allied operations |
| dewey-raw | 620.11 |
| dewey-search | 620.11 |
| dewey-sort | 3620.11 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Physik Werkstoffwissenschaften / Fertigungstechnik |
| format | Book |
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| id | DE-604.BV036032548 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:09:48Z |
| institution | BVB |
| isbn | 9783642104992 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-018924596 |
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| physical | XXI, 594 S. Ill., graph. Darst. |
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| publisher | Springer |
| record_format | marc |
| spelling | Mittemeijer, Eric J. 1950- Verfasser (DE-588)144008998 aut Fundamentals of materials science the microstructure-property relationship using metals as model systems Eric J. Mittemeijer Heidelberg [u.a.] Springer 2010 XXI, 594 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Materials science Stoffeigenschaft (DE-588)4192147-1 gnd rswk-swf Mikrostruktur (DE-588)4131028-7 gnd rswk-swf Metallischer Werkstoff (DE-588)4136513-6 gnd rswk-swf Metallischer Werkstoff (DE-588)4136513-6 s Mikrostruktur (DE-588)4131028-7 s Stoffeigenschaft (DE-588)4192147-1 s DE-604 Erscheint auch als Online-Ausgabe 978-3-642-10500-5 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018924596&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Mittemeijer, Eric J. 1950- Fundamentals of materials science the microstructure-property relationship using metals as model systems Materials science Stoffeigenschaft (DE-588)4192147-1 gnd Mikrostruktur (DE-588)4131028-7 gnd Metallischer Werkstoff (DE-588)4136513-6 gnd |
| subject_GND | (DE-588)4192147-1 (DE-588)4131028-7 (DE-588)4136513-6 |
| title | Fundamentals of materials science the microstructure-property relationship using metals as model systems |
| title_auth | Fundamentals of materials science the microstructure-property relationship using metals as model systems |
| title_exact_search | Fundamentals of materials science the microstructure-property relationship using metals as model systems |
| title_full | Fundamentals of materials science the microstructure-property relationship using metals as model systems Eric J. Mittemeijer |
| title_fullStr | Fundamentals of materials science the microstructure-property relationship using metals as model systems Eric J. Mittemeijer |
| title_full_unstemmed | Fundamentals of materials science the microstructure-property relationship using metals as model systems Eric J. Mittemeijer |
| title_short | Fundamentals of materials science |
| title_sort | fundamentals of materials science the microstructure property relationship using metals as model systems |
| title_sub | the microstructure-property relationship using metals as model systems |
| topic | Materials science Stoffeigenschaft (DE-588)4192147-1 gnd Mikrostruktur (DE-588)4131028-7 gnd Metallischer Werkstoff (DE-588)4136513-6 gnd |
| topic_facet | Materials science Stoffeigenschaft Mikrostruktur Metallischer Werkstoff |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018924596&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT mittemeijerericj fundamentalsofmaterialssciencethemicrostructurepropertyrelationshipusingmetalsasmodelsystems |