Epoxy polymers: new materials and innovations
Gespeichert in:
| Weitere Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2010
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| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XIX, 367 S. Ill., graph. Darst. |
| ISBN: | 9783527324804 |
Internformat
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CONTENTS PREFACE XV LIST OF CONTRIBUTORS XVI I 1 CENERAI CONCEPTS ABOUT
EPOXY POLYMERS 7 JEAN-PIERRE PASCAULT AND ROBERTO J.J. WILLIAMS 1.1
POLYMERIZATION CHEMISTRY OF EPOXY MONOMERS 1 1.1.1 TYPICAL EPOXY
MONOMERS AND POLYMER GROWTH MECHANISMS 1 1.1.2 STEP GROWTH
POLYMERIZATION 3 1.1.3 CHAIN HOMOPOLYMERIZATION 3 1.1.4 CHAIN
COPOLYMERIZATION 4 1.1.5 DUAL POLYMERIZATION SYSTEMS 5 1.2
TRANSFORMATIONS DURING THE FORMATION OF AN EPOXY NETWORK 6 1.2.1 GENERAL
CONSIDERATIONS 6 1.2.2 GELATION 6 1.2.3 VITRIFICATION 8 1.2.4
REACTION-INDUCED PHASE SEPARATION 8 1.2.5 TRANSFORMATION DIAGRAMS 9 1.3
GENERAL PROPERTIES OF EPOXY NETWORKS 11 REFERENCES 12 PART ONE NEW
POLYMERS/MATERIALS 73 2 THERMOPLASTIC EPOXY POLYMERS 75 JERRY E. WHITE
2.1 INTRODUCTION 15 2.2 SYNTHESIS AND CHARACTERIZATION OF EPOXY
THERMOPLASTICS 17 2.2.1 POLY(HYDROXY ETHERS) AND POLY(HYDROXY ETHER
SULFIDES) 17 2.2.2 POLY(HYDROXY ETHER SULFONAMIDES) 22 2.2.3
POLY(HYDROX)' ESTER ETHERS) 23 2.2.4 POLY(HYDROXY AMINO ETHERS) 26 2.
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/995647038 DIGITALISIERT
DURCH VI I CONTENTS 2.3.2 ADHESIVE CHARACTERISTICS 31 2.3.3 OPTICAL
PROPERTIES OF POLY(HYDROXY AMINO ETHER) 19B 32 2.3.4 GAS BARRIER
PROPERTIES OF EPOXY THERMOPLASTICS 33 2.4 CONCLUSIONS 36 ACKNOWLEDGMENTS
36 REFERENCES 37 3 EPOXY FUNCTIONAL ACRYLIC POLYMERS FOR HIGH
PERFORMANCE COATING APPLICATIONS 39 CARMEN FLOSBACH AND ROGER FUGIER 3.1
INTRODUCTION 39 3.2 EPOXY FUNCTIONAL ACRYLIC POLYMERS (EPOXY ACRYLATES)
39 3.3 SYNTHESIS OF EPOXY ACRYLATES 40 3.3.1 SEMI-BATCH PROCESS 40 3.3.2
MASS POLYMERIZATION 41 3.3.3 SUSPENSION POLYMERIZATION 41 3.3.4
POLYMERIZATION IN SUPERCRITICAL CARBON DIOXIDE 42 3.4 DESIGN OF EPOXY
ACRYLATES AS FILM-FORMING COMPONENTS IN COATINGS 42 3.4.1 GLASS
TRANSITION TEMPERATURE 42 3.4.2 MOLAR MASS 43 3.4.3 CHOICE OF
CO-MONOMERS 43 3.4.4 EPOXY ACRYLATES WITH A DUAL-CURE 45 3.4.5 STRUCTURE
OF THE POLYMER: BLOCK COPOLYMERS 45 3.4.6 STRUCTURE OF THE POLYMER:
BRANCHED EPOXY ACRYLATES 46 CONTENTS VII 4.3.1 2-FURYLOXIRANE 72 4.3.2
OTHER MONOMERS 75 4.4 CONCLUSIONS 76 REFERENCES 76 PART TWO
(NANO)STRUCTURED EPOXY NETWORKS 79 5 NANOSTRUCTURED EPOXIES BY THE USE
OF BLOCK COPOLYMERS 81 SIXUN ZHENG 5.1 INTRODUCTION 81 5.2 FORMATION
MECHANISMS OF NANOSTRUCTURES IN THERMOSETS 83 5.2.1 SELF-ASSEMBLY
APPROACH 84 5.2.2 REACTION-INDUCED MICROPHASE SEPARATION 84 5.3
MORPHOLOGIES OF EPOXY THERMOSETS MODIFIED WITH BLOCK COPOLYMERS 87 5.3.1
SELECTION OF BLOCK COPOLYMERS 87 5.3.2 NANOPHASE BEHAVIOR OF EPOXIES
CONTAINING BLOCK COPOLYMERS 89 5.3.3 DEMIXING BEHAVIOR OF EPOXY-MISCIBLE
BLOCKS INDUCED BY CURING REACTION 100 5.4 THERMOMECHANICAL PROPERTIES OF
NANOSTRUCTURED THERMOSETS 102 5.4.1 GLASS TRANSITION TEMPERATURES 102
5.4.2 FRACTURE TOUGHNESS OF NANOSTRUCTURED THERMOSETS 103 5.5
CONCLUSIONS 104 REFERENCES 205 6 SELF-ASSEMBLY OF EPOXY-BASED POLYMERS
709 CRISTINA E. HOPPE AND ROBERTO JJ. WILLIAMS 6. VILI CONTENTS 7.2
POLYMER DISPERSED LIQUID CRYSTAL PREPARED BY PIPS 123 7.3 BLOCK
COPOLYMERS USED AS A POLYMER DISPERSING AGENT FOR LIQUID CRYSTAL 129 7.4
EPOXY POLYMERS BASED ON AZO-BENZENE ORGANIC MOLECULES 133 7.5
CONCLUSIONS AND PERSPECTIVES 235 REFERENCES 136 8 POSS AND OTHER HYBRID
EPOXY POLYMERS 737 LIBAR MATEJKA 8.1 INTRODUCTION 137 8.2 EPOXY-SILICA
HYBRIDS 239 8.2.1 STRUCTURE AND MORPHOLOGY OF THE HYBRIDS 139 8.2.2
THERMOMECHANICAL PROPERTIES OF THE HYBRIDS 140 8.2.3 RUBBERY HYBRID
FORMATION, STRUCTURE AND THERMOMECHANICAL PROPERTIES 141 8.2.4
APPLICATION OF THE HYBRIDS 143 8.3 EPOXY-POSS HYBRIDS 144 8.3.1 TYPES OF
POSS HYBRIDS 144 8.3.2 STRUCTURE AND MORPHOLOGY OF THE POSS HYBRID
NETWORK 145 8.3.3 REACTIVITY OF THE EPOXY-FUNCTIONAL POSS 145 8.3.4
HYBRIDS WITH PENDANT POSS 246 8.3.5 HYBRIDS WITH POSS AS NETWORK
JUNCTIONS 147 8.3.6 HYBRIDS WITH UNBOUND POSS 149 8.3.7 PROPERTIES OF
POSS HYBRIDS 149 8.3. CONTENTS IX 9.5.2.3 VISCOSITY OF SUSPENSIONS 169
9.5.2.4 THIXOTROPY 169 9.6 STRUCTURATION OF LAMELLAR SILICATES IN A
REACTIVE MEDIUM 169 9.6.1 STRUCTURATION DURING REACTION 169 9.6.2
CATALYTIC EFFECT OF OLS ON EPOXY REACTIONS AND GEL TIME 171 9.6.3
STRUCTURATION AT THE END OF REACTION 272 9.7 MECHANICAL PROPERTIES OF
LAMELLAR SILICATES-MODIFIED EPOXIES 2 73 9.7.1 MODELING THE MODULUS OF
NANOCOMPOSITES 174 9.7.2 STIFFNESS AND TOUGHNESS OF GLASSY EPOXY
NANOCOMPOSITES 174 9.7.3 STIFFNESS AND TOUGHNESS OF RUBBERY EPOXY
NANOCOMPOSITES 177 9.8 TERNARY BLENDS BASED ON EPOXY/LAYERED SILICATES
178 9.9 BARRIER PROPERTIES OF NANOCLAY-MODIFIED EPOXIES 279 9.10
CONCLUSIONS 180 REFERENCES 181 10 EPOXY /CARBON NANOTUBE NANOCOMPOSITES
185 LUYI SUN AND HUNG-JUE SUE 10.1 INTRODUCTION 185 10.2 PREPARATION OF
EPOXY/CNT NANOCOMPOSITES 187 10.2.1 PROCESSING TECHNIQUES 187 10.2.2
NON-COVALENT FUNCTIONALIZATION 188 10.2.3 COVALENT FUNCTIONALIZATION 190
10.2. X CONTENTS 11.2.2 TEMPERATURE 217 11.2.3 MECHANICAL REQUIREMENTS
219 11.2.4 ENVIRONMENTAL AGING 220 11.2.5 TOXICOLOGY 221 11.3 CRITERIA
FOR SELECTING ADHESIVE FORMULATIONS 222 11.3.1 SELECTION OF COMPONENTS
222 11.3.1.1 EPOXY PREPOLYMERS 222 11.3.1.2 CURING AGENTS 222 11.3.1.3
ADDITIVES 223 11.3.2 AMBIENT-CURE FORMULATION (STEEL/CONCRETE ADHESIVE)
223 11.3.3 MEDIUM TO HIGH-TEMPERATURE CURE FORMULATION (STEEL/STEEL
ADHESIVE) 224 11.3.3.1 MECHANICAL AND THERMAL PROPERTIES OF DIFFERENT
FORMULATIONS 227 11.3.3.2 AGING IN WATER AT 60C 232 11.4 CONCLUSIONS
AND PERSPECTIVES 232 ACKNOWLEDGMENTS 233 REFERENCES 233 12 UV-CURED
NANOSTRUCTURED EPOXY COATINGS 235 MARCO SANGERMANO 12.1 INTRODUCTION 235
12.2 ORGANIC-ORGANIC NANOCOMPOSITE EPOXY COATINGS 236 12.2.1 BLOCK
COPOLYMERS AS ORGANIC NANOBUILDING BLOCKS 237 12.2.2 HYPERBRANCHED
POLYMERS 239 CONTENTS XI 13.2.3 TOUGHNESS MODIFICATION 262 13.2.4
INTERFACIAL PROPERTIES BETWEEN FIBERS AND MATRIX 263 13.3 MANUFACTURING
PROCESS 264 13.4 PERSPECTIVES 265 13.4.1 COST ANALYSIS 265 13.4.2
THERMAL CURING VERSUS ELECTRON BEAM CURING 266 13.4.3 POTENTIAL
APPLICATIONS 266 REFERENCES 267 14 COMPOSITE PROCESSING: STATE OF THE
ART AND FUTURE TRENDS 277 STEPHAN COSTANTINO AND URS WALDVOGEL 14.1
INTRODUCTION 271 14.2 INFUSION 271 14.2.1 PROCESS 271 14.2.2 SCRIMP
PROCESS 272 14.2.3 VACUUM ASSISTED PROCESS 273 14.2.4 CONTROLLED
ATMOSPHERIC PRESSURE RESIN INFUSION 274 14.3 RESIN TRANSFER MOLDING 275
14.4 PREPREG 276 14.4.1 PROCESS AND APPLICATIONS 276 14.4.2 OUT OF
AUTOCLAVE PREPREGS 277 14.5 ALTERNATIVE MOLD HEATING METHODS 278 14.5.1
ROCTOOL: THE CAGE SYSTEM TO MAKE FAST RTM 278 14.5.2 QUICKSTEP: ANOTHER
WAY TO CURE 278 14.6 SHEET MOLDING COMPOUND (SMC)/BULK MOLDING COMPOUND
(BMC XII CONTENTS 15.1.2 BCPS AS ADDITIVES FOR CONTROLLING PROPERTIES
290 15.1.3 BCPS AS ADDITIVES FOR CONTROLLING PROCESSING 292 15.1.4 OUR
AIM 291 15.2 TYPICAL PREPARATION OF THERMOPLASTIC CURABLE FORMULATIONS
291 15.2.1 MATERIALS 292 15.2.2 SAMPLE PREPARATION 292 15.3 RHEOLOGICAL
BEHAVIOR OF BLENDS OF BLOCK COPOLYMER AND THERMOSET PRECURSORS 293 15.4
CHOICE OF THE HARDENER 296 15.5 PROCESSING AND PROPERTIES 298 15.5.1
THERMOPLASTIC PROCESSING 298 15.5.2 PROPERTIES 298 15.6 CONCLUSIONS 302
ACKNOWLEDGMENTS 301 REFERENCES 301 16 STRUCTURAL EPOXY FOAMS 303 LISA A.
MONDY, REKHA R. RAO, HARRY MOFFAT, DOUG ADOLF, AND MATHEW CELINA 16.1
BACKGROUND 303 16.2 CONTINUUM-LEVEL MODEL FOR FOAMING MATERIALS 305 16.3
MATERIAL MODELS AND EXPERIMENTS TO POPULATE NUMERICAL MODEL 306 16.3.1
VARIABLE DENSITY AND GAS PRODUCTION MODELS 306 16.3.2 EPOXY
POLYMERIZATION MODEL 307 16.3.3 VISCOSITY AND SLIP MODELS 307 16.3.4
THERMAL PROPERTIES MODELS 311 357 CONTENTS XIII 17.2.1
MICROCAPSULE-BASED SELF-HEALING 326 17.2.2 ALTERNATIVE HEALING
CHEMISTRIES 337 17.2.3 HOLLOW-FIBER-BASED HEALING 338 17.2.4
MICROVASCULAR HEALING SYSTEMS 339 17.3 INTRINSICALLY HEALING MATERIALS
340 17.3.1 REMENDABLE POLYMERS 340 17.3.2 SUPRAMOLECULAR ASSEMBLY 341
17.4 POTENTIAL APPLICATIONS OF SELF-HEALING MATERIALS IN A BIO-
ENGINEERING SETTING 341 17.5 OUTLOOK FOR SELF-HEALING MATERIALS 343
REFERENCES 343 PART FOUR CONCLUSIONS AND PERSPECTIVES 345 18 CONCLUSIONS
AND PERSPECTIVES 347 JEAN-PIERRE PASCAULT AND ROBERTO JJ. WILLIAMS 18.1
DEFINITIONS OF EPOXY POLYMERS 347 18.2 NEW MONOMERS AND FORMULATIONS 348
18.3 NANOSTRUCTURED EPOXIES 349 18.4 ENGINEERING PROPERTIES 352 18.5
FUNCTIONAL PROPERTIES 353 18.6 HEALTH-RELATED ISSUES 354 18.7 LIFE-CYCLE
ASSESSMENT 354 REFERENCES 355 INDEX |
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| language | English |
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| spelling | Epoxy polymers new materials and innovations ed. by Jean-Pierre Pascault ... Weinheim Wiley-VCH 2010 XIX, 367 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Epoxy resins Polymers Epoxidharz (DE-588)4070891-3 gnd rswk-swf Epoxidharz (DE-588)4070891-3 s DE-604 Pascault, Jean-Pierre edt text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3339677&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018924014&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Epoxy polymers new materials and innovations Epoxy resins Polymers Epoxidharz (DE-588)4070891-3 gnd |
| subject_GND | (DE-588)4070891-3 |
| title | Epoxy polymers new materials and innovations |
| title_auth | Epoxy polymers new materials and innovations |
| title_exact_search | Epoxy polymers new materials and innovations |
| title_full | Epoxy polymers new materials and innovations ed. by Jean-Pierre Pascault ... |
| title_fullStr | Epoxy polymers new materials and innovations ed. by Jean-Pierre Pascault ... |
| title_full_unstemmed | Epoxy polymers new materials and innovations ed. by Jean-Pierre Pascault ... |
| title_short | Epoxy polymers |
| title_sort | epoxy polymers new materials and innovations |
| title_sub | new materials and innovations |
| topic | Epoxy resins Polymers Epoxidharz (DE-588)4070891-3 gnd |
| topic_facet | Epoxy resins Polymers Epoxidharz |
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