Electronic structure and properties of transition metal compounds: introduction to the theory
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| 1. Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken
Wiley
2010
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| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XXXVI, 759 S. graph. Darst. |
| ISBN: | 9780470180235 |
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| 008 | 100208s2010 d||| |||| 00||| eng d | ||
| 020 | |a 9780470180235 |9 978-0-470-18023-5 | ||
| 035 | |a (OCoLC)606363239 | ||
| 035 | |a (DE-599)BVBBV036015896 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
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| 049 | |a DE-384 |a DE-11 |a DE-703 |a DE-20 | ||
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| 084 | |a VE 5300 |0 (DE-625)147116:253 |2 rvk | ||
| 084 | |a CHE 305f |2 stub | ||
| 084 | |a CHE 315f |2 stub | ||
| 084 | |a CHE 150f |2 stub | ||
| 100 | 1 | |a Bersuker, Isaak B. |e Verfasser |0 (DE-588)143414844 |4 aut | |
| 245 | 1 | 0 | |a Electronic structure and properties of transition metal compounds |b introduction to the theory |c Isaac B. Bersuker |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Hoboken |b Wiley |c 2010 | |
| 300 | |a XXXVI, 759 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Elektronenstruktur |0 (DE-588)4129531-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Übergangsmetallverbindungen |0 (DE-588)4061385-9 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Übergangsmetallverbindungen |0 (DE-588)4061385-9 |D s |
| 689 | 0 | 1 | |a Elektronenstruktur |0 (DE-588)4129531-6 |D s |
| 689 | 0 | |5 DE-604 | |
| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018908111&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-018908111 | ||
Datensatz im Suchindex
| _version_ | 1804141041082695680 |
|---|---|
| adam_text | CONTENTS
Preface
xxi
Foreword to the First Edition
xxv
Mathematical Symbols
xxvii
Abbreviations
xxxiii
1
Introduction: Subject and Methods
1
1.1
Objectives,
1
Molecular Engineering and
Intuitíve
Guesswork,
1
Main Objectives of This Book in Comparison with
Other Sources,
4
1.2
Definitions of Chemical Bonding and Transition Metal
Coordination System,
7
Chemical Bonding as an Electronic Phenomenon,
7
Definition of Coordination System,
9
13
The
Schrödinger
Equation,
12
Formulation,
12
Role of Approximations,
14
Summary Notes,
15
References,
16
viii CONTENTS
2
Atomic States
18
2.1
One-Electron
States,
18
Angular
and Radial Functions,
18
Orbital
Overlaps: Hybridized Functions,
24
Spin-Orbital Interaction,
27
Relativistic Atomic Functions,
30
2.2
Multielectron States: Energy Terms,
35
Electronic Configurations and Terms,
35
Multielectron Wavefunctions,
40
Slater-Condon and Racah Parameters,
42
The
Hartree
-Fock Method,
46
Summary Notes,
51
Questions,
51
Exercises and Problems,
52
References,
52
3
Symmetry Ideas and Group-Theoretical Description
54
3.1
Symmetry Transformations and Matrices,
54
3.2
Groups of Symmetry Transformations,
60
Example
3.1.
The Symmetry Group of an Octahedral
Oh System and Its Classes,
62
33
Representations of Groups and Matrices of Representations,
64
3.4
Classification of Molecular Terms and Vibrations,
Selection Rules, and Wigner-Eckart Theorem,
69
Example
3.2.
Energy Terms of Electronic Configuration e2,
71
3.5
Construction of Symmetrized Molecular
Orbitals
and
Normal Vibrations,
74
Example
3.3.
Construction of Eg-Symmetry-Adapted
σ
MOs
for Octahedral Oh Systems,
76
Example
3.4.
Construction of Tig -Symmetry-Adapted
π
MOs
for Octahedral Oh Systems,
79
Example
3.5.
Normal Coordinates of a Regular
Triangular Molecule X3,
80
3.6
The Notion of Double Groups,
81
Summary Notes,
82
CONTENTS ix
Exercises,
82
References,
83
4
Crystal Field Theory
84
4.1
Introduction,
84
Brief History,
84
Main Assumptions,
85
4.2
Splitting of the Energy Levels of One
d
Electron in
Ligand Fields,
86
Qualitative Aspects and Visual Interpretation,
86
Calculation of the Splitting Magnitude,
92
Example
4.1.
Splitting of a ¿/-Electron Term in
Octahedral Crystal Fields,
94
Group-Theoretical Analysis,
97
4.3
Several
d
Electrons,
99
Case of a Weak Field,
99
Strong Crystal Fields and Low- and High-Spin Complexes,
105
Example
4.2.
High- and Low-Spin Octahedral
Complexes of Iron,
110
Energy Terms of Strong-Field Configurations,
110
Arbitrary Ligand Fields and Tanabe-
Sugano
Diagrams,
112
4.4
/-Electron Term Splitting,
115
4.5
Crystal Field Parameters and Extrastabilization Energy,
121
4.6
Limits of Applicability of Crystal Field Theory,
126
Summary Notes,
128
Questions,
129
Exercises and Problems,
129
References,
130
5
Method of Molecular
Orbitals
and Related
Approaches
132
5.1
Basic Ideas of the MO LCAO Method,
133
Main Assumptions,
133
Secular Equation,
134
Classification by Symmetry,
135
CONTENTS
Symmetrized
Orbitals, 138
Simplification of the Secular Equation,
141
5.2
Charge Distribution and Bonding in the MO LCAO
Method and the Case of Weak Covalency,
142
Atomic Charges and Bond Orders,
142
Example
5.1.
Shortcomings of Mulliken s Definition of
Atomic Charges in Molecules,
145
Bonding,
Nonbonding,
and Antibonding
Orbitals, 147
Case of Weak Covalency,
149
Angular Overlap Model,
151
5.3
Methods of Calculation of MO Energies and LCAO
Coefficients,
154
SCF MO LCAO Approximation,
154
The Role of Basis Sets,
157
Electron Correlation Effects,
161
Example
5.2.
Exercise:
Ab Initio
Calculation of CuF2
Using Hartree-Fock and MP2 Methods,
166
5.4 Semiquantitative
Approaches,
168
Pseudopotentials or Effective Core Potentials (ECPs),
170
Density-Functional Approaches,
171
Example
5.3.
Exercise: Calculation of ZnCb by the
DFT Method,
178
Example
5.4.
Exercise:
Ab
Initio Calculation of the
Electronic Structure of MnO4~ Square-Planar,
Tetrahedral, and Square-Based Pyramidal
Configuration,
180
Relativistic Approaches,
184
5.5
Semiempirical Methods,
187
Zero-Differential Overlap (ZDO),
188
Extended Hiickel (Hoffmann) Method,
192
Iterative Extended Hiickel Method,
193
Example
5.5.
Aig-Type
MOs
of Octahedral
TiFö3
Calculated Using the Extended Hiickel
(Wolfsberg-Helmholz) Approximation,
196
Quasirelativistic Parameterization,
198
Example
5.6.
Quasirelativistic Evaluation of Energies
of Ionization of Several Valence States (EIVS) of
5,
p, and
d
Electrons of the Pt Atom,
201
CONTENTS xi
5.6
Fragmentary Calculations, Molecular Mechanics, and
Combined Quantum/Classical (QM/MM) Modeling,
201
Fragmentary Calculations,
202
Molecular Mechanics,
206
Example
5.7.
Application of Molecular Modeling to
Transition Metal Complexes with
Macrocycles,
208
Combined Quantum/Classical (QM/MM) Methods,
211
Example
5.8.
Oxidative Addition of W2 to Pt(/-Bu)3)2
Treated by ONIOM Version of QM/MM Methods,
215
Example
5.9.
Iron Picket-Fence
Porphyrin
Treated by
the QM/MM Method with Charge Transfer
(QM/MM/CT),
221
5.7
General Comparison of Methods,
224
Summary Notes,
229
Exercises and Problems,
230
References,
231
6
Electronic Structure and Chemical Bonding
238
6.1
Classification of Chemical Bonds by Electronic Structure
and Role of
d
and
ƒ
Electrons in Coordination Bonding,
238
Criticism of the Genealogical Classification,
239
Classification by Electronic Structure and Properties,
241
Features of Coordination Bonds,
243
Coordination Bonding by
Pre-
and
Posttransition
Elements,
245
6.2
Qualitative Aspects and Electronic
Configurations,
246
Most Probable MO Schemes,
246
Electronic Configurations in Low- and High-Spin Complexes,
247
Covalence Electrons and Ionization Potentials,
251
6.3
Ligand Bonding,
254
General Considerations:
Multiorbital
Bonds,
254
Monoorbital
Bonds: Coordination of NH3 and H2O,
259
Example
6.1. Ab Initio
Numerical SCF-CI Calculations
of the Electronic Structure of
Monoorbital
Bonds:
Ni(H2O)„
and
Ni(PH3)„, n
= 1, 2, 261
Diorbitai
Bonds: Coordination of the
N2
Molecule,
261
Example
6.2.
Electronic Structure and Bonding in FeN2,
264
Coordination of Carbon Monoxide,
264
CONTENTS
Example
6.3.
Bonding and Charge Transfer in the
Pt—CO Complex,
265
Example
6.4.
Bonding in
M
—
CO with
M
=
Cr,
Fe,
Co,
Ni,
267
Example
6.5.
Bonding in Sc
—
CO,
Ni
—
CO, and
Ni(CO)2,
268
σ + π
Bonding,
269
Example
6.6.
Electronic Structure of Transition Metal
Hexacarbonils M(CO)6,
271
CO Bonding on Surfaces,
273
Bonding of NO,
275
Example
6.7.
Coordination of NO on the Ni(l
11)
Surface,
276
Coordination of C2H4,
277
Example
6.8.
Ethylene
Bonding to Transition Metal
Centers,
278
Example
6.9.
Ethylene
Bonding in PtCl3(C2H4) and
PdCl3(C2H4r,
279
Metal-Metal Bonds and Bridging Ligands,
282
Example
6.10.
Multiple Metal-Metal Bonds in
2 and
[МогСУ4-,
284
6.4
Energies, Geometries, and Charge Distributions,
291
Ionization Energies,
291
Example
6.11. Ab Initio
Calculations of Ni(C3H5)2,
293
Total and Bonding Energies, Geometries, and Other
Properties,
295
6.5
Relativistic Effects,
303
Orbital Contraction and Valence Activity,
304
Example
6.12.
Relativistic Effects in Catalytic Activity
of Pt and Pd Complexes,
306
Bond Lengths, Bond Energies, and Vibrational Frequencies,
307
Example
6.13.
Relativistic Effects in Metal
Hydrids, 307
Correlation Between Spin-Orbital Splitting and Bonding,
310
Example
6.14.
Relativistic Semiempirical Calculation of
PtClô2-,
312
Other Relativistic Effects,
315
Summary Notes,
315
CONTENTS xiii
Exercises and Problems,
316
References,
318
7
Electronic Control of Molecular Shapes and
Transformations via Vibronic Coupling
324
7.1
Molecular Vibrations,
325
Adiabatic Approximation,
325
Normal Coordinates and Harmonic Vibrations,
328
Special Features of Vibrations of Coordination Systems,
336
7.2
Vibronic Coupling,
337
Vibronic Constants,
337
Orbital Vibronic Constants,
339
Example
7.1.
Vibronic MO Description of Electronic
Structure of N2 and CO,
342
7.3
The Jahn-Teller Effect,
344
The Jahn-Teller Theorem,
344
The Jahn-Teller Effect in a Twofold-Degenerate Electronic
State,
351
Threefold-Degenerate Electronic States,
364
7.4
Pseudo-Jahn-Teller Effect and the Two-Level Paradigm,
369
Pseudo-Jahn-Teller (PJT) Instability,
369
Uniquiness of the Vibronic Mechanism of Configuration
Instability: The Two-Level Paradigm,
377
Example
7.2.
Numerical Confirmation of PJT Origin of
Instability of High-Symmetry Configurations,
379
Example
7.3.
Numerical Calculations Confirming the
PJT Origin of Configuration Instability of
Coordination Systems,
380
Further Insight into the
Pseudo-
JTE and Hidden JTE,
381
Example
7.4.
Comparison of Covalence versus
Polarization Contributions to PJT Instability,
384
Example
7.5.
Why Some ML2 Molecules
(M
=
Ca, Sr,
Ba; L
=
H, F, Cl, Br)
are Bent
While Others Are Linear,
385
Example
7.6.
Hidden JTE in
СиРз:
Ab Initio
Calculations,
387
Summary Notes,
388
Exercises and Problems,
389
References,
390
xiv CONTENTS
8 Electronic
Structure
Investigated by Physical
Methods
392
8.1
Band Shapes of Electronic Spectra,
393
Qualitative Interpretation of Vibrational Broadening,
393
Example
8.1.
Broad and Narrow Bands in Light
Absorption and Emission by Transition Metal
Complexes,
396
Theory of Absorption Band Shapes,
396
Band Shapes of Electronic Transitions between
Nondegenerate
States; Zero-Phonon Lines,
399
Types of Electronic Transitions on Intensity,
402
Example
8.2.
Selection Rules for Polarized Light
Absorption by the PtCU2 Complex,
403
8.2
d-d, Charge Transfer, Infrared, and Raman Spectra,
405
Origin and Special Features of d-d Transitions,
406
Example
8.3.
d-d Transitions in the Absorption
Spectrum of
Мп(Н2О)б2+,
407
Example
8.4.
Temperature-Dependent Absorption
Spectra of K^NaCrFe and Emerald,
410
Spectrochemical and Nephelauxetic Series,
411
Charge Transfer Spectra,
415
Example
8.5.
Some Ligand
-»
Metal or
Metal
-»
Ligand Charge Transfer Spectra,
416
Infrared Absorption and Raman Scattering,
417
Example
8.6.
Resonance Raman Spectrum of Red
K2[Ni(dto)2] in Solid State,
421
Transitions Involving Orbitally Degenerate States,
422
83
Х
-Ray and Ultraviolet Photoelectron Spectra; EXAFS,
426
General Ideas,
426
Example
8.7.
Photoelectron Spectra of Specific
Coordination Systems and Their Interpretation,
429
Electron Relaxation; Shakeup and
CI
Satellites,
431
Example
8.8.
Configuration Interaction Satellite to the
K+
Зі
Emission Line in the UPS Spectrum of KF,
434
Chemical Shift,
436
Example
8.9.
The Is Line of Nitrogen in the XPS of
Different Coordination Systems Reflecting the
Variety of Its Bonding in Different Groups,
439
CONTENTS xv
EXAFS and Related Methods,
440
Example
8.
JO. Applications of EXAFS Spectroscopy to
a Variety of Problems,
442
8.4
Magnetic Properties,
443
Magnetic Moment and Quenching of Orbital Contribution,
443
Paramagnetic Susceptibility,
447
Electron Spin Resonance (ESR),
449
Magnetic Exchange Coupling,
457
Example
8.11.
Magnetic Exchange Coupling in
Binuclear Copper Acetate Hydrate,
461
Example
8.12.
The Nature of Metal-Metal Bonding in
Binuclear Copper Acetate Hydrate,
462
Spin Crossover,
465
Magnetic Circular Dichroism (MCD),
468
8.5
Gamma-Resonance Spectroscopy,
472
The Mossbauer Effect,
472
y-Resonance Spectra,
473
Isomer
Shift and Quadrupole Splitting in GRS,
474
Hyperfine Splitting,
478
Example
8.13.
Magnetic Hyperfine Structure in GRS of
Coordination Compounds with a 57Fe Nucleus,
479
Example
8.14.
Observation of Spin Crossover in the
y-Resonance Spectrum of [Fe(phen)2(NCS)2],
482
8.6
Electron Charge and Spin Density Distribution in
Diffraction Methods,
483
The Method of Deformation Density,
483
Example
8.15.
Deformation Density in Sodium
Nitroprusside (Direct Inspection),
485
Example
8.16.
Metal-Metal Bonding in Mn2(CO)10;
Fragment Deformation Density,
488
Example
8.17.
Density Modeling for
Fe(II)-Phthalocyanine and
CotHbTetraphenyl-porphyrin,
491
Spin Densities from Neutron Scattering,
493
Example
8.18.
Spin Distributions in Some Coordination
Systems Obtained from Neutron Scattering,
494
Summary Notes,
495
Exercises and Problems,
497
References,
500
xvi CONTENTS
9
Stereochemistry and Crystal Chemistry
506
9.1
Definitions. Semiclassical Approaches,
506
The Notion of Molecular Shape,
506
Directed Valences, Localized Electron Pairs, and Valence
Shell Electron Pair Repulsion (VSEPR),
508
Nonbonding
Orbitals
and Nodal Properties,
512
Example
9.1.
Influence of
Nonbonding
MOs
on
Coordination Geometry,
513
Complementary Spherical Electron Density Model,
514
Example
9.2.
The Inert-Gas Rule in Stereochemistry of
Some Coordination Compounds,
517
9.2
Vibronic Effects in Stereochemistry,
519
Nuclear Motion Effects: Relativity to the Means of
Observation and Vibronic Amplification of Distortions,
519
Qualitative Stereochemical Effects of Jahn-Teller and
Pseudo-Jahn-Teller Distortions,
522
Example
9.3.
Stereochemistry of
MX„
Systems
Controlled by Electronic Structure and Vibronic
Coupling,
524
Example
9.4.
Pseudo-
JT Origin of Distortions in
CuCls3- versus ZnCls3 ,
525
Off-Center Position of the Central Atom,
528
Geometry of Ligand Coordination,
530
Stereochemically Active and Inert Lone Pairs,
535
Pseudorotations
in Coordination Systems,
539
9.3
Mutual Influence of Ligands,
544
The Model: trans and
cis
Influences in Stereochemistry,
544
Electronic Factors,
546
Vibronic Theory of Ligand Mutual Influence,
549
9.4
Crystal Stereochemistry,
554
The Plasticity Effect,
554
Distortion Isomers,
559
Example
9.5.
Origin of Distortion Isomers in
Cu(NH3)2X2, X
=
Cl, Br,
559
Temperature-Dependent Solid-State Conformers,
562
Cooperative Effects: Order-Disorder and Displacive
Phase Transitions and
Helicoidal
Structures,
566
Summary Notes,
572
Exercises and Problems,
573
References,
575
CONTENTS xvii
10 Electron Transfer,
Redox
Properties, and
Electron-Conformational
Effects
579
10.1 Electron Transfer and Charge Transfer
by Coordination,
579
Intramolecular
Charge Transfer and Intermolecular
Electron Transfer, 579
Redox
Capacitance,
584
Example
10.1. Charge Transfer
by Coordination of
Peroxide to Iron
Porphyrin, 587
Hard and Soft Acids and Bases,
587
10.2
Electron Transfer in Mixed-Valence Compounds,
591
Mixed-Valence Compounds as Electronic Systems;
a Two-Level Dimer,
591
Example
10.2.
The Creutz-Taube (CT) Ion as a
Mixed-Valence System,
594
Magnetic Properties,
597
Mixed-Valence Trimers: Coexistence of Localized and
Delocalized States,
601
Example
10.3.
Tricenter
Ferredoxin,
606
10.3
Electron-Conformational Effects in Biological Systems,
609
Distortions Produced by Excess Electronic Charge;
Special Features of Metalloenzymes,
609
Trigger Mechanism of Hemoglobin
Oxygénation:
Comparison with Peroxidase,
612
Summary Notes,
618
Exercises and Problems,
619
References,
620
11
Reactivity and Catalytic Action
623
11.1
Electronic Factors in Reactivity,
623
Chemical Reactivity and Activated Complexes,
623
Frontier
Orbitals
and Perturbation Theory,
627
Orbital Symmetry Rules in Reaction Mechanisms,
630
Example
11.1.
Orbital Symmetry Rules and Vibronic
Coupling in Formation of
Cyclobutane
from
Ethylene
with Catalyst Participation,
633
11.2
Electronic Control of Chemical Activation via Vibronic
Coupling,
635
xviii CONTENTS
Chemical Activation by Electron Rearrangement,
635
Activation of Small Molecules by Coordination:
Semiempirical Approach,
640
Example
11.2.
Activation of Carbon Monoxide,
642
Example
11.3.
Numerical Estimate of CO Activation by
Coordination to a NiO Surface,
646
Example
11.4.
Activation of Dinitrogen,
646
Example
11.5.
Activation of Nitrogen Monoxide,
648
Example
11.6.
Activation of Hydrogen,
649
Example
11.7.
Activation of Oxygen by
Hemoproteins,
650
Jahn-Teller-
and
Pseudo-Jahn-Teller-Induced
Chemical
Activation,
652
Example
11.8.
Jahn-Teller-Induced Substitution
Reactions in Octahedral Complexes with an
E
Term,
655
11.3
Direct Computation of Energy Barriers of Chemical
Reactions,
656
Substitution Reactions: The trans Effect,
656
Ligand Coupling and Cleavage Processes,
662
CO Reductive
Hydrogénation
and Carbonyl Insertion
Reactions,
666
Olefin
Insertion Reactions,
674
Example
11.9.
Polymerization with Ziegler-Natta
Catalysts,
677
Photochemical Reactions of Organometallics,
682
Summary Notes,
686
Questions and Problems,
687
References,
689
Appendixes
Appendix
1.
Tables of Characters of Irreducible Representations of
Most Usable Symmetry Point Groups and Direct Products
of Some Representations,
692
Appendix
2.
General Expressions for the Matrix Element Vmm of
Perturbation of the States of One
d
Electron in Crystal
Fields of Arbitrary Symmetry,
697
Appendix
3.
Calculation of the Destabilization and Splitting of the
States of One
d
Electron in Crystal Fields of Different
Symmetries,
700
CONTENTS xix
Appendix 4. Matrix Elements
of Crystal Field Perturbation of a
Two-Electron Term F(nd)2,
Vý
,
і, у
= 1, 2,.... 7
Expressed by One-Electron Matrix Elements Vmm
Given in Appendix
2, 703
Appendix
5.
Matrix Elements of Crystal Field Perturbation of
ƒ
Electron States,
705
Answers and Solutions
707
Subject Index
745
Formula Index
753
|
| any_adam_object | 1 |
| author | Bersuker, Isaak B. |
| author_GND | (DE-588)143414844 |
| author_facet | Bersuker, Isaak B. |
| author_role | aut |
| author_sort | Bersuker, Isaak B. |
| author_variant | i b b ib ibb |
| building | Verbundindex |
| bvnumber | BV036015896 |
| classification_rvk | UP 3400 VE 5300 |
| classification_tum | CHE 305f CHE 315f CHE 150f |
| ctrlnum | (OCoLC)606363239 (DE-599)BVBBV036015896 |
| dewey-full | 546/.6 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546/.6 |
| dewey-search | 546/.6 |
| dewey-sort | 3546 16 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| edition | 2. ed. |
| format | Book |
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| id | DE-604.BV036015896 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:09:34Z |
| institution | BVB |
| isbn | 9780470180235 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-018908111 |
| oclc_num | 606363239 |
| open_access_boolean | |
| owner | DE-384 DE-11 DE-703 DE-20 |
| owner_facet | DE-384 DE-11 DE-703 DE-20 |
| physical | XXXVI, 759 S. graph. Darst. |
| publishDate | 2010 |
| publishDateSearch | 2010 |
| publishDateSort | 2010 |
| publisher | Wiley |
| record_format | marc |
| spelling | Bersuker, Isaak B. Verfasser (DE-588)143414844 aut Electronic structure and properties of transition metal compounds introduction to the theory Isaac B. Bersuker 2. ed. Hoboken Wiley 2010 XXXVI, 759 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Elektronenstruktur (DE-588)4129531-6 gnd rswk-swf Übergangsmetallverbindungen (DE-588)4061385-9 gnd rswk-swf Übergangsmetallverbindungen (DE-588)4061385-9 s Elektronenstruktur (DE-588)4129531-6 s DE-604 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018908111&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Bersuker, Isaak B. Electronic structure and properties of transition metal compounds introduction to the theory Elektronenstruktur (DE-588)4129531-6 gnd Übergangsmetallverbindungen (DE-588)4061385-9 gnd |
| subject_GND | (DE-588)4129531-6 (DE-588)4061385-9 |
| title | Electronic structure and properties of transition metal compounds introduction to the theory |
| title_auth | Electronic structure and properties of transition metal compounds introduction to the theory |
| title_exact_search | Electronic structure and properties of transition metal compounds introduction to the theory |
| title_full | Electronic structure and properties of transition metal compounds introduction to the theory Isaac B. Bersuker |
| title_fullStr | Electronic structure and properties of transition metal compounds introduction to the theory Isaac B. Bersuker |
| title_full_unstemmed | Electronic structure and properties of transition metal compounds introduction to the theory Isaac B. Bersuker |
| title_short | Electronic structure and properties of transition metal compounds |
| title_sort | electronic structure and properties of transition metal compounds introduction to the theory |
| title_sub | introduction to the theory |
| topic | Elektronenstruktur (DE-588)4129531-6 gnd Übergangsmetallverbindungen (DE-588)4061385-9 gnd |
| topic_facet | Elektronenstruktur Übergangsmetallverbindungen |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018908111&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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