Synthesis and coordination chemistry of polydentate imidazolin-2-imine ligands:
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| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
München
Verl. Dr. Hut
2009
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| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Anorganische Chemie
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 161 S. graph. Darst. 210 mm x 148 mm, 238 gr. |
| ISBN: | 9783868533064 |
Internformat
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| 264 | 1 | |a München |b Verl. Dr. Hut |c 2009 | |
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Datensatz im Suchindex
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| adam_text | SYNTHESIS AND COORDINATION CHEMISTRY OF POLYDENTATE IMIDAZOLIN-2-IMINE
LIGANDS VON DER FAKULTAT FUR LEBENSWISSENSCHAFTEN DER TECHNISCHEN
UNIVERSITAT CAROLO-WILHELMINA ZU BRAUNSCHWEIG ZUR ERLANGUNG DES GRADES
EINER DOKTORIN DER NATURWISSENSCHAFTEN (DR. RER. NAT.) GENEHMIGTE
DISSERTATION VON SABINA-ALEXANDRA FILIMON AUS TTRGU SECUIESC, RUMANIEN
TABLE OF CONTENTS 1 INTRODUCTION AND OBJECTIVES 1 1.1 N-HETEROCYCLIC
CARBENES 1 1.2 IMIDAZOLIN-2-IMINATO LIGANDS 6 2 RESULTS AND DISCUSSION
14 2. 1 TRIAZENES FORMATION VIA REACTION OF IMIDAZOLIN-2-YLIDENES WITH
AZIDES .... 14 2.1.1 INTRODUCTION 14 2.1.2 SYNTHESIS OF
L-(L,3,4,5-TETRAMETHYLIMIDAZOLIN-2-YLIDENE)-3-NAPHTHYLTRIAZENE 15 2.1.3
SYNTHESIS OF
L-(L,3,4,5-TETRAMETHYLIMIDAZOLIN-2-YLIDENE)-3-BENZYLTRIAZENE 18 2.1.4
SYNTHESIS OF TRIS[L-(L,3,4,5-TETRAMETHYLIMIDAZOLIN-2-YLIDENE)-3-
ETHYLTRIAZENO]AMINE 19 2.1.5 DECOMPOSITION OF TRIAZENES TO IMINE LIGANDS
22 2.2 IMIDAZOLIDIN-2-IMINE BASED LIGANDS 24 2.2.1 CONCEPT OF
IMIDAZOLIDIN-2-IMINE BASED LIGANDS 24 2.2.2 SYNTHESIS OF
L-(L,3-DIMETHYLIMIDAZOLIDIN-2-IMINO)NAPHTHALENE 25 2.2.3 SYNTHESIS OF
L,8-BIS(L,3-DIMETHYLIMIDAZOLIDIN-2-IMINO)ANTHRACENE 26 2.2.4 SYNTHESIS
OF (LS,25,45,5/F)-2-(L,3-DIMETHYL-IMIDAZOLIDIN-2-IMINOMETHYL)-5-VINYL-
L-AZABICYCLO[2.2.2]OCTANE AND
(15,2I?,4S,5/?)-2-(L,3-DIMETHYL-IMIDAZOLIDIN-2-
IMINOMETHYL)-5-VINYL-L-AZABICYCLO[2.2.2]OCTANE 28 2.2.5 RUTHENIUM(II)
COMPLEXES WITH DMIQCI AND DMIQCD LIGANDS 31 2.2.5.1 RUTHENIUM(II)
COMPLEXES IN LITERATURE 31 2.2.5.2 SYNTHESES OF RU(II) COMPLEXES 32
2.2.5.3 TRANSFER HYDROGENATION CATALYZED BY RU(II) COMPLEXES 35 2.2.6
NICKEL(II) AND PALLADIUM(II) COMPLEXES WITH DMIQCI AND DMIQCD
LIGANDS.... 38 2.2.6.1 INTRODUCTION 38 2.2.6.2 SYNTHESES OF PD(II)
COMPLEXES 40 2.2.6.3 SYNTHESES OF NI(II) COMPLEXES 42 2.3 BENZENE BASED
PINCER LIGAND 45 2.3.1 CONCEPT OF ECE-PINCER LIGANDS 45 2.3.2 SYNTHESES
OF 2,6-BIS[(IMIDAZOLIN-2-IMINO)METHYL]-L-BROM-BENZENE LIGANDS 47 2.3.3
SYNTHESIS OF PD(II) COMPLEX WITH NCN BU LIGAND 49 2.3.4 SUZUKI COUPLING
OF 4-BROMBENZENE WITH PHENYLBORONIC ACID CATALYZED BY PD(II) COMPLEX
(18) 50 2.4 PYRIDINE BASED PINCER LIGAND 53 2.4.1 SYNTHESIS OF 2,6-BIS[(
1 ) 3-DI-K/T-BUTYLIMIDAZOLIN-2-IMINO)METHYL]PYRIDINE LIGAND... 53 2.4.2
IRON AND COBALT CHEMISTRY OF THE TL BU LIGAND 56 2.4.2.1 SYNTHESES OF
IRON COMPLEXES WITH TL BU LIGAND 58 2.4.2.2 SYNTHESIS OF COBALT COMPLEX
WITH TL BU LIGAND 66 2.4.3 MANGANESE CHEMISTRY OF THE TL BU LIGAND 68
2.4.3.1 SYNTHESES OF MANGANESE COMPLEXES WITH TL BU LIGAND 69 2.4.3.2
EPOXIDATION OF 1-OCTENE CATALYZED BY MN(II) COMPLEXES 76 2.4.4 NICKEL
CHEMISTRY OF THE TL BU LIGAND 78 2.4.4.1 SYNTHESES OF NI(II) COMPLEXES
WITH TL BU LIGAND 79 2.4.5 COPPER CHEMISTRY OF THE TL B LIGAND 83
2.4.5.1 REACTION OF TL BU CU(I) COMPLEX WITH ORGANIC AZIDES 84 2.4.5.2
REACTION OF TL BU CU(I) COMPLEX WITH S 8 86 2.4.5.3 REACTION OF TL BU
CU(I) COMPLEX WITH O2 AND PHIO 89 2.4.6 ZINC CHEMISTRY OF THE TL BU
LIGAND 90 2.4.6.1 SYNTHESIS OF ZN(II) COMPLEXES WITH TL LBU LIGAND 91
2.4.6.2 LACTIDE POLYMERIZATION CATALYZED BY ZN(II) COMPLEXES 94 2.4.7
LANTHANIDE CHEMISTRY OF THE TL BU LIGAND 95 2.4.7.1 SYNTHESIS OF
GD(III) COMPLEX WITH TL^ LIGAND 96 3 SUMMARY 99 4 EXPERIMENTAL SECTION
109 5 CRYSTALLOGRAPHIC DATA 136 6 REFERENCES 143
|
| any_adam_object | 1 |
| author | Filimon, Sabina-Alexandra 1981- |
| author_GND | (DE-588)140368035 |
| author_facet | Filimon, Sabina-Alexandra 1981- |
| author_role | aut |
| author_sort | Filimon, Sabina-Alexandra 1981- |
| author_variant | s a f saf |
| building | Verbundindex |
| bvnumber | BV035986567 |
| ctrlnum | (OCoLC)643941551 (DE-599)DNB999630946 |
| discipline | Chemie / Pharmazie |
| edition | 1. Aufl. |
| format | Thesis Book |
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| illustrated | Illustrated |
| indexdate | 2024-07-09T22:09:02Z |
| institution | BVB |
| isbn | 9783868533064 |
| language | English |
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| physical | 161 S. graph. Darst. 210 mm x 148 mm, 238 gr. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | Verl. Dr. Hut |
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| series2 | Anorganische Chemie |
| spelling | Filimon, Sabina-Alexandra 1981- Verfasser (DE-588)140368035 aut Synthesis and coordination chemistry of polydentate imidazolin-2-imine ligands von Sabina-Alexandra Filimon 1. Aufl. München Verl. Dr. Hut 2009 161 S. graph. Darst. 210 mm x 148 mm, 238 gr. txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: Braunschweig, Techn. Univ., Diss., 2009 (DE-588)4113937-9 Hochschulschrift gnd-content GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018879368&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Filimon, Sabina-Alexandra 1981- Synthesis and coordination chemistry of polydentate imidazolin-2-imine ligands |
| subject_GND | (DE-588)4113937-9 |
| title | Synthesis and coordination chemistry of polydentate imidazolin-2-imine ligands |
| title_auth | Synthesis and coordination chemistry of polydentate imidazolin-2-imine ligands |
| title_exact_search | Synthesis and coordination chemistry of polydentate imidazolin-2-imine ligands |
| title_full | Synthesis and coordination chemistry of polydentate imidazolin-2-imine ligands von Sabina-Alexandra Filimon |
| title_fullStr | Synthesis and coordination chemistry of polydentate imidazolin-2-imine ligands von Sabina-Alexandra Filimon |
| title_full_unstemmed | Synthesis and coordination chemistry of polydentate imidazolin-2-imine ligands von Sabina-Alexandra Filimon |
| title_short | Synthesis and coordination chemistry of polydentate imidazolin-2-imine ligands |
| title_sort | synthesis and coordination chemistry of polydentate imidazolin 2 imine ligands |
| topic_facet | Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018879368&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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