Frontiers of molecular spectroscopy:
Gespeichert in:
Weitere Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Amsterdam [u.a]
Elsevier
2009
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Ausgabe: | 1. ed. |
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XVII, 706 S. Ill., graph. Darst. |
ISBN: | 9780444531759 |
Internformat
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245 | 1 | 0 | |a Frontiers of molecular spectroscopy |c ed. by Jaan Laane |
250 | |a 1. ed. | ||
264 | 1 | |a Amsterdam [u.a] |b Elsevier |c 2009 | |
300 | |a XVII, 706 S. |b Ill., graph. Darst. | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
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650 | 4 | |a Molecular spectroscopy | |
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Datensatz im Suchindex
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adam_text | Contents
Preface xiii
Acknowledgments xvii
1 Old Spectroscopists Forget a Lot but They do Remember Their Lines 1
Harold Kroto
1 Introduction 1
2 Microwave Spectroscopy: A Fundamental Analysis 2
2 Frontiers of Linear and Non-Linear Raman Spectroscopy 13
Hiro-o Hamaguchi
1 Introduction 14
2 Ultrafast Chemical Exchange Dynamics of Reaction Intermediates Elucidated
by Raman Band Shape Analysis 15
2.1 Ion association dynamics in aqueous solutions of magnesium sulfate 16
2.2 Protonation/deprotonation dynamics of A/.W-dimethylacetamide in
hydrochloric acid 20
3 Time- and Space-Resolved Raman Spectroscopy of Single Living Yeast Cells 23
3.1 Time- and space-resolved Raman spectra of a dividing fission yeast
cell [19] 23
3.2 Discovery of the Raman spectroscopic signature of life in the
mitochondria of a living fission yeast cell [20,21] 25
3.3 Molecular level pursuit of a spontaneous death process of a starving
budding yeast cell by time-resolved Raman mapping [22] 26
4 Local Structures and Their Temporal Evolution in an Ethanol/Water Mixture
Probed with CARS Signal Spatial Distribution 28
5 Molecular Near-Field Effect in Resonance Hyper-Raman Scattering 31
3 Structure and Dynamics of High Rydberg States Studied by
High-Resolution Spectroscopy and Multichannel Quantum Defect Theory 35
Martin Schafer and Frederic Merkt
1 Introduction 36
2 Experimental Techniques 41
2.1 VUV lasers 41
2.2 PFI-ZEKE photoelectron spectroscopy and Rydberg-state-resolved
threshold-ionization spectroscopy 43
2.3 VUV-millimeter wave double-resonance spectroscopy 43
3 Hyperfine Structure of Rydberg States 48
3.1 Rare gas atoms: krypton and xenon 48
Contents_______________________________________^___________________________vi
3.2 MQDT calculations for rare gases 52
3.3 Ortho-hydrogen 56
4 Conclusion and Outlook 58
4 Vibrational Potential Energy Surfaces in Electronic Excited States 63
Jaan Laane
1 Introduction 64
2 Theory 67
2.1 The quartic potential energy 67
2.2 Calculation of energy levels 70
2.3 Kinetic energy functions 71
3 Experimental Methods 73
4 Electronic Ground State 77
4.1 One-dimensional potential functions 77
4.2 Two-dimensional potential energy functions 79
5 Electronic Excited States 84
5.1 Cyclic ketones 84
5.2 Stilbenes 97
5.3 Bicyclic aromatics 104
5.4 Cavity ringdown spectroscopy of enones 124
6 Summary and Conclusions 129
5 Raman Spectroscopy in Art and Archaeology: A New Light on Historical
Mysteries 133
Howell G.M. Edwards
1 Introduction 134
2 Raman Spectroscopy 139
3 Case Studies 145
3.1 Biodeteriorated wall paintings 145
3.2 Roman wall paintings 149
3-3 Egyptian mummies 149
3.4 Tissues and resins 151
3.5 Textiles 159
3.6 Ivories 165
4 Conclusions 169
6 Real-Time Vibrational Spectroscopy and Ultrafast Structural Relaxation 175
Takayoshi Kobayashi
1 Ultrashort Pulse Laser 176
1.1 Introduction 176
1.2 Group-velocity matching by noncollinear geometry 177
1.3 Pulse-front matching 178
1.4 Generation of sub-5 fs 181
1.5 Generation of sub-4-fs pulse 184
vii Contents
2 Ultrafast Spectroscopy 189
2.1 Introduction 189
2.2 Ultrafast dynamics in PDA 192
2.3 Experimental 194
2.4 Results and discussion 195
7 Applications of Coherent Raman Spectroscopy 219
Dmitry Pestov, Alexei V. Sokolov, and Marian 0. Scully
1 Introduction 219
2 FAST CARS 221
3 Hybrid Technique for CARS 230
4 Coherent versus Incoherent Raman Scattering 236
5 Summary 238
8 High-Resolution Laboratory Terahertz Spectroscopy and Applications
to Astrophysics 241
Stephan Schlemmer, Thomas Giesen, Frank Lewen, and Gisbert Winnewisser
1 Introduction 242
2 High-Resolution Terahertz Spectrometers 244
2.1 BWOs, powerful radiation sources for terahertz spectroscopy 247
2.2 Schottky multipliers and their applications 248
2.3 Superlattice multipliers and their applications 250
2.4 Cologne sideband spectrometer for THz applications 252
3 Future Trends in Terahertz Spectroscopy 254
3.1 Supersonic jet-spectroscopy 254
3.2 Spectroscopy in ion traps 256
4 Conclusions 258
9 Selective Detection of Proteins and Nucleic Acids with Biofunctionalized
SERS Labels 267
S. Schlucker and W. Kiefer
1 Introduction 268
2 Protein Detection with SERS Labels 269
2.1 Immunosandwich assay for protein detection employing silver films 271
2.2 Enzyme immunosandwich assay for protein detection utilizing silver
nanoparticles 271
2.3 Immunosandwich assay for protein detection with Raman-
immunogold conjugates 273
2.4 Protein detection with nanostructures prepared by seeded growth
of silver on gold 274
3 Nucleic Acid Detection with SERS Labels 276
3.1 Gene probe for DNA detection employing solid SERS substrates 276
3.2 DNA detection by SERRS employing aggregated silver colloids 277
3.3 DNA/RNA detection with nanostructures prepared by seeded growth
of silver on gold 279
Contents
4 Encapsulation of SERS Labels 280
4.1 Silica encapsulation of SERS labels 280
4.2 Protein encapsulation of SERS labels 283
4.3 Polymer encapsulation of SERS labels 283
5 Microscopic Applications of SERS Labels 284
5.1 Introduction to Raman microscopy with SERS labels 284
5.2 SERS microscopy for protein localization 285
10 Surface-Enhanced Raman Scattering Spectroscopy 289
Tamitake Itoh, Athiyanathil Sujith, and Yukihiro Ozaki
1 Introduction 290
2 Part I: Examination of Electromagnetic Mechanism of Surface-Enhanced
Raman Scattering 290
2.1 Experiments 291
2.2 Results and Discussion 294
3 Part II: Biomedical Applications 300
3.1 Cellular Probing 300
3.2 Biological Imaging 305
3.3 Pathogen detection 311
3.4 Conclusion 316
11 Spectroscopy and Broken Symmetry 321
P.R. Bunker and Per Jensen
1 Introduction 322
2 The Symmetrization Postulate 323
3 The Molecular Symmetry Group 325
3.1 Nuclear spin and ortho-para interactions 326
3.2 Missing levels 331
3.3 Parity and chiral molecules 332
4 Time Reversal Symmetry 336
5 The Breakdown of the Symmetrization Postulate 338
5.1 The breakdown of the Pauli exclusion principle 338
5.2 The appearance of missing levels 339
6 The Breakdown of Inversion Symmetry 340
7 The Breakdown of Time Reversal Symmetry 341
12 Broadband Modulation of Light by Coherent Molecular Oscillations 347
A.M. Burzo and A.V. Sokolov
1 Introduction 347
2 Molecular Modulation: Basic Principles 350
3 Broadband Generation: Experimental Results 350
4 Amplitude and Frequency Modulation at 90 THz 352
5 Raman Generation in Gases with Several Input Fields 353
6 Molecular Modulation in Waveguides 359
7 Summary 363
ix Contents
13 Generalized Two-Dimensional Correlation Spectroscopy 367
Isao Noda
1 Introduction 368
2 Generealized 2D Correlation Analysis 369
2.1 Perturbation-induced dynamic spectra 369
2.2 2D Correlation analysis of dynamic spectra 370
3 Properties of 2D Correlation Spectra 372
3.1 Synchronous spectra 372
3.2 Asynchronous spectra 374
4 Application Example 375
5 Conclusions 380
14 Microwave Spectroscopy 383
Jens-Uwe Grabow and Walther Caminati
1 Introduction 384
2 Frequency-Domain (Frequency Scan/Continuous Wave) Techniques 385
2.1 Continuous radiation microwave excitation on stationary gases 386
2.2 Continuous radiation microwave excitation on supersonic expansions 394
3 Time-Domain (Stationary Frequency/Impulse) Techniques 400
3.1 Pulsed radiation microwave excitation of stationary gases 402
3.2 MW-MW and MW-RF double resonance 407
3.3 Pulsed radiation microwave excitation of supersonic jets 414
3.4 External fields 425
4 Time-Domain (Frequency Ramp/Chirp) Techniques 436
4.1 Chirped radiation microwave excitation of supersonic jets 437
4.2 Fast passage FT-MW apparatus 438
4.3 MW-(MW, mm, sub-mm) and MW-(MW, mm, sub-mm)/(IR, VIS, UV)
multiple resonance 447
15 Microwave Spectroscopy 455
Walther Caminati and Jens-Uwe Grabow
1
2
Introduction 456
General Aspects 457
2.1 Conformational equilibria 459
2.2 Tautomeric equilibria 460
2.3 Large amplitude motions 461
2.4 Chemical bond and nuclear quadrupole coupling: examples of
severe interaction 468
Isolated Molecules 470
3-i Chemistry and MW spectroscopy: new molecular species and
in situ preparation 470
3.2 Transition metal complexes 491
3-3 Biomolecules 494
3-4 Nonpolar Molecules 498
Contents
3.5 Polcyclic aromatic hydrocarbons and heterocycles 500
3.6 Molecules of Astrophysical Interests 501
4 Molecular Adducts 502
4.1 Van der Waals Complexes 503
4.2 Hydrogen-bonded Complexes 512
4.3 Charge Transfer Complexes 522
4.4 Molecular Recognition 525
4.5 Molecular Aggregation 526
4.6 Quantum solvation 531
16 Raman Spectroscopy of Viruses and Viral Proteins 553
Daniel Nemecek and George J. Thomas, Jr.
1 Introduction 554
2 Pathways of Virus Assembly 555
3 Advantages of Raman Spectroscopy 557
4 Experimental Raman Methods 558
5 Analysis of Spectral Data 561
5.1 General considerations 561
5.2 The single-value decomposition approach 563
6 General Characteristics of Viral Protein and Nucleic Acid Raman Spectra 565
6.1 The protein Raman spectrum 567
6.2 The nucleic acid Raman spectrum 570
7 Applications in Structural Studies of Viruses 572
7.1 Assembly and maturation of the bacteriophage P22 capsid 572
7.2 The scaffolding protein of bacteriophage P22 576
7.3 The portal of bacteriophage P22 576
7.4 The terminase of bacteriophage P22 579
7.5 The tailspike of bacteriophage P22 581
7.6 Accessory proteins of the bacteriophage P22 portal/tail vertex 583
7.7 Filamentous bacteriophages 583
7.8 Assembly and maturation of the bacteriophage HK97 head 586
8 Overview and Conclusions 590
17 Vibrational Spectroscopy via Inelastic Neutron Scattering 597
Bruce S. Hudson
1 Introduction 598
2 Basic Scattering Theory 598
3 Experimental Neutron Scattering 603
3.1 Neutron sources 603
3.2 Types of neutron scattering 603
3.3 Vibrational inelastic scattering 605
4 Advantages of INS for Vibrational Spectroscopy 607
5 Examples of INS Spectra and Their Utility 608
5.1 Hydrocarbons 608
5.2 Short, strong, symmetric hydrogen bonds 613
xi Contents
18 Optimal Signal Processing in Cavity Ring-Down Spectroscopy 623
Kevin K. Lehmann and Haifeng Huang
1 Introduction 624
2 The Model 625
3 Generalized Least Squares Fit with Correlated Data 628
4 Weight Matrix for Model of Cavity Ring-Down Data 630
5 Detector Noise Limited Cavity Ring-Down Data 633
5.1 To average and then fit, or fit each decay and average the fit results? 638
6 Linearization of the Fit in Cavity Ring-Down Spectroscopy 638
7 Determination of Ring-Down Rate by Fourier Transform Method 641
8 The Successive Integration Method for Exponential Fitting 643
9 Analog-Detected Cavity Ring-Down 646
9.1 Phase shift method 646
9.2 Gated integrator method 649
9.3 Logarithm-differentiator method 650
10 Shot Noise Limited Cavity Ring-Down Data 651
11 Effect of Residual Mode Beating in the Ring-Down Decay 655
12 Conclusions 657
19 Spectroscopy and Dynamics of Neutrals and Ions by High-Resolution
Infrared-Vacuum Ultraviolet Photoionization and Photoelectron
Methods 659
Cheuk-Yiu Ng
1 Introduction 660
2 IR-VUV Laser Photoion-Photoelectron Apparatus 663
3 Experimental Measurements 665
3.1 VUV-PIE and VUV-PFI-PE measurements 665
3.2 IR-VUV-PI measurements 665
3.3 IR-VUV-PFI-PE measurements 673
3.4 IR-VUV-PIE and IR-VUV-PIE depletion measurements 680
3.5 IR-VUV-PFI-PE depletion measurements 682
3.6 VUV-IR-PIRI measurements 686
4 Summary and Future Prospects 689
Index 693
|
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genre_facet | Aufsatzsammlung |
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illustrated | Illustrated |
indexdate | 2024-07-09T22:09:02Z |
institution | BVB |
isbn | 9780444531759 |
language | English |
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spelling | Frontiers of molecular spectroscopy ed. by Jaan Laane 1. ed. Amsterdam [u.a] Elsevier 2009 XVII, 706 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Molecular spectroscopy Molekülspektroskopie (DE-588)4128850-6 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Molekülspektroskopie (DE-588)4128850-6 s DE-604 Laane, Jaan 1942- (DE-588)12045467X edt HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018879224&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Frontiers of molecular spectroscopy Molecular spectroscopy Molekülspektroskopie (DE-588)4128850-6 gnd |
subject_GND | (DE-588)4128850-6 (DE-588)4143413-4 |
title | Frontiers of molecular spectroscopy |
title_auth | Frontiers of molecular spectroscopy |
title_exact_search | Frontiers of molecular spectroscopy |
title_full | Frontiers of molecular spectroscopy ed. by Jaan Laane |
title_fullStr | Frontiers of molecular spectroscopy ed. by Jaan Laane |
title_full_unstemmed | Frontiers of molecular spectroscopy ed. by Jaan Laane |
title_short | Frontiers of molecular spectroscopy |
title_sort | frontiers of molecular spectroscopy |
topic | Molecular spectroscopy Molekülspektroskopie (DE-588)4128850-6 gnd |
topic_facet | Molecular spectroscopy Molekülspektroskopie Aufsatzsammlung |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018879224&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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