Carbon nanotubes and related structures: synthesis, characterization, functionalization, and applications
Gespeichert in:
| Weitere Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2010
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| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XXII, 539 S. Ill., graph. Darst. |
| ISBN: | 9783527324064 |
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CONTENTS PREFACE XV LIST OF CONTRIBUTORS XIX 1 CARBON NANOTUBES AND
RELATED STRUCTURES: PRODUCTION AND FORMATION 1 MARK H. RUEMMELI, PAOLA
AYALA, AND THOMAS PKHLER 1.1 INTRODUCTION 1 1.2 CARBON NANOTUBE
PRODUCTION 3 1.2.1 ARC DISCHARGE 3 1.2.2 LASER ABLATION 4 1.2.3 CHEMICAL
VAPOR DEPOSITION 5 1.2.4 MISCELLANEOUS SYNTHESIS METHODS 6 1.3 CATALYSTS
6 1.3.1 METALLIC CATALYSTS 7 1.3.2 CERAMIC CATALYSTS 7 1.3.3 CATALYST
FREE 8 1.4 GROWTH ENHANCEMENT 8 1.5 GROWTH MECHANISMS 9 1.5.1 FLOATING
CATALYST METHODS 10 1.5.2 SUPPORTED CATALYST ROUTES 13 1.5.3
CATALYST-FREE ROUTES 15 1.6 FUNCTIONALIZATION I6 1.7 PURIFICATION 16 1.8
FUTURE PERSPECTIVES 17 REFERENCES 17 2 THEORY OF ELECTRONIC AND OPTICAL
PROPERTIES OF DNA-SWNT HYBRIDS 23 SLAVA V. ROTKIN AND STACY E. SNYDER
2.1 INTRODUCTION 23 2.2 PHYSICAL STRUCTURE AND BONDING IN NANOTUBE-DNA
HYBRIDS: A SHORT REVIEW 24 2.3 QUANTUM MECHANICAL MODELING OF THE HYBRID
STRUCTURE: TIGH BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/996244875
DIGITALISIERT DURCH VI CONTENTS 2.4 SELF-CONSISTENT COMPUTATION SCHEME:
ACTING POTENTIAL 33 2.5 SCREENING FACTOR AND THE DIELECTRIC PERMITTIVITY
34 2.6 POLARIZATION COMPONENT OF COHESION ENERGY OF THE SWNT-SSDNA
HYBRID 35 2.7 OPTICAL ABSORPTION OF SWNT-DNA HYBRIDS 40 2.8 SUMMARY 47
REFERENCES 48 3 ELECTROCHEMISTRY 53 MATTEO LURLO, MASSIMO MARCACCIO, AND
FRANCESCO PAOLUCCI 3.1 INTRODUCTION 53 3.2 ELECTRONIC PROPERTIES OF
SWNTS 53 3.3 ELECTRODE POTENTIALS VERSUS WORK FUNCTIONS 54 3.4
ELECTROCHEMISTRY AT SWNTS VERSUS ELECTROCHEMISTRY OF SWNTS 56 3.5 CARBON
NANOTUBES FOR ELECTROCHEMICAL ENERGY STORAGE DEVICES 59 3.6 CARBON
NANOTUBES FOR ELECTROCHEMICAL SENSORS AND BIOSENSORS 59 3.7
ELECTROCHEMISTRY OF CARBON NANOTUBES 61 3.8 CYCLIC VOLTAMMETRIC
INVESTIGATIONS OF SOLUTIONS OF INDIVIDUAL SWNTS 63 3.9 VIS-NIR
SPECTROELECTROCHEMICAL INVESTIGATION OF TRUE SOLUTIONS OF
UNFUNCTIONALIZED SWNTS 66 3.10 STANDARD REDOX POTENTIALS OF INDIVIDUAL
SWNTS IN SOLUTION 67 CONTENTS VII 5.3.1 ANTHRACENE DERIVATIVES 105 5.3.2
PYRENE DERIVATIVES 107 5.3.3 OTHER POLYAROMATIC DERIVATIVES 112 5.4
NONCOVALENT INTERACTIONS OF CNTS WITH HETEROCYCLIC POLYAROMATIC SYSTEMS
114 5.4.1 PORPHYRINS, PHTHALOCYANINES, AND SAPPHYRINS 114 5.4.2 METALLIC
COORDINATION 116 5.5 NONCOVALENT INTERACTIONS OF CNTS WITH SURFACTANTS
AND IONIC LIQUIDS 118 5.6 NONCOVALENT INTERACTIONS OF CNTS WITH POLYMERS
121 5.6.1 POLYMERIC AMPHIPHILES 121 5.6.2 CONJUGATED POLYMERS 123 5.6.3
BIOPOLYMERS 125 5.7 OPTICALLY ACTIVE SWCNTS 127 5.8 NONCOVALENT
INTERACTIONS OF CNTS WITH NANOPARTIDES 127 5.9 SUMMARY AND CONCLUSIONS
129 REFERENCES 229 6 COVALENT FUNCTIONALIZATION OF CARBON NANOTUBES 235
FRANK HAUKE AND ANDREAS HIRSCH 6.1 INTRODUCTION 235 6.2 CHEMICAL
FUNCTIONALIZATION OF CARBON NANOTUBES 236 6.2.1 DERIVATIZATION
STRATEGIES 236 6.2.2 TOPOLOGY AND REACTIVITY OF CARBON NANOTUBES 238 6.
VIII CONTENTS 6.4.4.1 THE ADDITION OF CARBENES AND NITRENES 157 6.4.4.2
NUDEOPHILIC CYDOPROPANATION: THE BINGLE REACTION 259 6.4.4.3 SILYLATION
OF CARBON NANOTUBES 260 6.4.5 1,3-CYCLOADDITION REACTIONS 260 6.4.5.1
CYCLOADDITION OF ZWITTERIONIC INTERMEDIATES 260 6.4.5.2 AZOMETHINE YLIDE
ADDITION 261 6.4.6 [4+2]-CYDOADDITION REACTIONS: DIELS-ALDER REACTION
264 6.4.7 ALKALI METAL-BASED REDUCTION OF CARBON NANOTUBES WITH
SUBSEQUENT SIDEWALL FUNCTIONALIZATION 266 6.4.7.1 NAPHTHALENIDES AS
ELECTRON TRANSFER REAGENTS 166 6.4.7.2 REDUCTIVE ALKYLATION OF CNTS 266
6.4.7.3 OTHER ELECTRON TRANSFER MEDIATORS 268 6.4.8 SIDEWALL
FUNCTIONALIZATION OF CARBON NANOTUBES BASED ON RADICAL CHEMISTRY 169
6.4.8.1 CARBON-CENTERED FREE RADICALS 269 6.4.8.2 SULFUR-CENTERED FREE
RADICALS 271 6.4.8.3 OXYGEN-CENTERED FREE RADICALS 272 6.4.8.4 AMINATION
OF CARBON NANOTUBE SIDEWALK 272 6.4.8.5 DIAZONIUM-BASED
FUNCTIONALIZATION SEQUENCES 272 6.4.9 SIDEWALL FUNCTIONALIZATION THROUGH
ELECTROPHILIC ADDITION 175 6.4.10 SIDEWALL FUNCTIONALIZATION THROUGH
NUCLEOPHILIC ADDITION 276 6.4.10.1 CARBON-BASED NUDEOPHILES 276 6.4.10.2
NITROGEN-BASED NUDEOPHILES 178 6.5 CONCLUSIONS 279 REFERENCES 279 7
CARBON-BASED NANOMATERIAL APPLICATIONS IN BIOMEDICINE 299 PRABHPREET
CONTENTS IX 7.3.2 BIOMEDICAL APPLICATIONS OF CARBON NANOHORNS 225
7.3.2.1 CARBON NANOHORN AS POTENT LASER THERAPEUTIC AGENT 216 7.3.2.2
CARBON NANOHORN FOR DRUG DELIVERY 226 7.3.2.3 TOXIDTY OF CARBON
NANOHORNS 229 7.4 CARBON NANODIAMONDS 229 7.4.1 INTRODUCTION 219 7.4.2
CARBON NANODIAMOND AS DELIVERY VEHICLE 221 7.4.3 CARBON NANODIAMOND AS
BIOMARKER FOR CELLULAR IMAGING 222 7.4.4 BIOCOMPATIBILITY AND TOXICITY
224 7.5 CONCLUSIONS 224 REFERENCES 225 8 GROUND AND EXCITED STATE CHARGE
TRANSFER AND ITS IMPLICATIONS 233 VITO SGOBBA AND DIRK M. GULDI 8.1
INTRODUCTION 233 8.2 GROUND AND EXCITED STATE FEATURES 235 8.3 GROUND
STATE CHARGE TRANSFER - CNT AS ELECTRON ACCEPTORS 238 8.3.1 CHEMICAL
REDUCTION 238 8.3.2 ELECTROCHEMICAL REDUCTION 239 8.3.3 REDUCTION BY
DOPING 241 8.3.4 MISCELLANEOUS 242 8.4 GROUND STATE CHARGE TRANSFER -
CNT AS ELECTRON DONORS 242 8.4.1 CHEMICAL OXIDATION 242 8.4. X CONTENTS
9 PHOTOVOLTAIC DEVICES BASED ON CARBON NANOTUBES AND RELATED STRUCTURES
292 EMMANUEL KYMAKIS 9.1 INTRODUCTION 292 9.2 PHOTOVOLTAIC CELLS BASED
ON CARBON NANOTUBES 292 9.2.1 CARBON NANOTUBES AS ELECTRON ACCEPTORS IN
ORGANIC PVS 292 9.2.2 HOLE COLLECTING ELECTRODES 297 9.3 RELATED
STRUCTURES 298 9.4 FUTURE DIRECTIONS 300 REFERENCES 302 10
LAYER-BY-LAYER ASSEMBLY OF MULTIFUNCTIONAL CARBON NANOTUBE THIN FILMS
305 BONG SUP SHIM AND NICHOLAS A. KOTOV 10.1 INTRODUCTION 305 10.2
STRUCTURE AND PROPERTIES OF CNTS 306 10.3 STRUCTURAL ORGANIZATION IN
MULTILAYERS OF CARBON NANOTUBES 307 10.4 ELECTRICAL CONDUCTOR
APPLICATIONS 309 10.5 SENSOR APPLICATIONS 312 10.6 FUEL CELL
APPLICATIONS 313 10.7 NANO-/MICROSHELL LBL COATINGS AND BIOMEDICAL
APPLICATIONS 314 10.8 CONCLUSIONS 325 REFERENCES 316 11 CARBON NANOTUBES
FOR CATALYTIC APPLICATIONS 322 EVA CASTILLEJOS AND PHILIPPE SERP 11.1
INTRODUCTION 322 11.2 MACROSCOPIC SHAPING OF CNTS 322 11.3 SPECIFIC
METAL-SUPPORT INTERACTION 323 CONTENTS XI 12 CARBON NANOTUBES AS
CONTAINERS 349 THOMAS W. CHAMBERLAIN, MARIA DEL CARMEN CIMENEZ-LOPEZ,
AND ANDREI N. KHLOBYSTOV 12.1 INTRODUCTION 349 12.2 MECHANISMS OF
NANOTUBE FILLING 350 12.3 FULLERENES AS GUEST MOLECULES 353 12.3.1
FULLERENEQO 353 12.3.2 HIGHER FULLERENES 359 12.3.3 ENDOHEDRAL
FULLERENES 361 12.3.4 FUNCTIONALIZED FULLERENES 365 12.4 OTHER TYPES OF
MOLECULES 369 12.4.1 MOLECULES WITHOUT METAL ATOMS 369 12.4.2
ORGANOMETALLIC AND COORDINATION COMPOUNDS 372 12.5 IONIC COMPOUNDS 374
12.5.1 SALTS 374 12.5.2 OXIDES AND HYDROXIDES 377 12.5.3 OTHER INORGANIC
MATERIALS 378 12.6 NANOPARTICLES IN NANOTUBES 378 12.7 CONCLUDING
REMARKS 380 REFERENCES 380 13 CARBON NANOHORN 385 MASAKO YUDASAKA AND
SUMIO LIJIMA 385 13.1 INTRODUCTION 385 13.2 PRODUCTION 385 13.3
STRUCTURE AND GROWTH MECHANISM 386 13.4 PROPERTIES 386 13.5
FUNCTIONALIZATION 389 13.5.1 MATERIAL INCORPORATION AND RELEASE 389 XII
CONTENTS 14.3.2 HELICAL PACKING OF DISCOTIC NANOGRAPHENES 416 14.3.3
COMPLEMENTARY INTERACTIONS 429 14.4 CHARGE CARRIER TRANSPORT ALONG
NANOGRAPHENE STACKS 423 14.5 SOLUTION AGGREGATION AND FIBER FORMATION
425 14.6 SOLUTION ALIGNMENT ON SURFACES 433 14.7 THERMAL PROCESSING 437
14.8 NANOGRAPHENES IN HETEROJUNCTIONS FOR SOLAR CELLS 442 14.9
PROCESSING OF NONDISCOTIC NANOGRAPHENES 443 14.10 CONDUSIONS 444
REFERENCES 445 15 ENDOHEDRALS 455 LAI FENG, TAKESHI AKASAKA, AND SHIGERU
NAGASE 15.1 INTRODUCTION 455 15.2 RECENT INVESTIGATIONS IN THE SYNTHESIS
OF ENDOHEDRAL METALLOFULLERENES 456 15.2.1 THE REACTIVE GAS ATMOSPHERE
456 15.2.2 THE SOLID ADDITIVE 457 15.3 ADVANCES IN NONCHROMATOGRAPHIC
TEDINIQUES FOR SEPARATION OF ENDOHEDRAL METALLOFULLERENES 457 15.3.1
SEPARATION BY ELECTROCHEMICAL METHOD 457 15.3.2 SEPARATION BY OTHER
CHEMICAL METHODS 458 15.4 STRUCTURES OF ENDOHEDRAL METALLOFULLERENES
DETERMINED BY X-RAY CRYSTALLOGRAPHIC METHOD 460 15.4. CONTENTS XIII 16
CARBON NA RESTRUCTURES: CALCULATIONS OF THEIR ENERGETICS,
THERMODYNAMICS, AND STABILITY 492 ZDENEK SLANINA, FILIP UHLIK, SHYI-LONG
LEE, TAKESHI AKASAKA, AND SHIGERU NAGASE 16.1 INTRODUCTION 491 16.2
ENERGETICS AND THERMODYNAMICS OF CLUSTERS 492 16.3 STABILITIES OF EMPTY
FULLERENES 495 16.4 STABILITIES OF METALLOFULLERENES 497 16.5
STABILITIES OF NONMETAL ENDOHEDRALS 505 16.6 KINETIC CONTROL 507
REFERENCES 512 INDEX 525 |
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| title | Carbon nanotubes and related structures synthesis, characterization, functionalization, and applications |
| title_auth | Carbon nanotubes and related structures synthesis, characterization, functionalization, and applications |
| title_exact_search | Carbon nanotubes and related structures synthesis, characterization, functionalization, and applications |
| title_full | Carbon nanotubes and related structures synthesis, characterization, functionalization, and applications Ed. by Dirk M. Guldi ... |
| title_fullStr | Carbon nanotubes and related structures synthesis, characterization, functionalization, and applications Ed. by Dirk M. Guldi ... |
| title_full_unstemmed | Carbon nanotubes and related structures synthesis, characterization, functionalization, and applications Ed. by Dirk M. Guldi ... |
| title_short | Carbon nanotubes and related structures |
| title_sort | carbon nanotubes and related structures synthesis characterization functionalization and applications |
| title_sub | synthesis, characterization, functionalization, and applications |
| topic | Kohlenstoff-Nanoröhre (DE-588)4581365-6 gnd |
| topic_facet | Kohlenstoff-Nanoröhre |
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