Verfügbarkeit: Corrosion engineering

Corrosion engineering: principles and practice

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Bibliographische Detailangaben
1. Verfasser:	Roberge, Pierre R. (VerfasserIn)
Format:	Buch
Sprache:	English
Veröffentlicht:	New York [u.a.] McGraw-Hill 2008
Ausgabe:	[1. ed.]
Schlagworte:	Anticorrosivos Corrosão Corrosion and anti-corrosives Korrosion Korrosionsschutz
Online-Zugang:	Inhaltsverzeichnis
Beschreibung:	Includes bibliographical references and index
Beschreibung:	XIV, 754 S. Ill., graph. Darst.
ISBN:	9780071482431 0071482431

Internformat

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Datensatz im Suchindex

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adam_text	Contents Preface хш The Study of Corrosion ....................... 1 1.1 Why Study Corrosion? .................... 1 1.2 The Study of Corrosion .................... 2 1.3 Needs for Corrosion Education ............. 5 1.4 The Functions and Roles of a Corrosion Engineer ..................... 8 1.5 The Corrosion Engineer s Education ........ 11 1.6 Strategic Impact and Cost of Corrosion Damage ....................... 13 References ................................... 17 Corrosion Basics ............................. 19 2.1 Why Metals Corrode ...................... 19 2.2 Matter Building Blocks .................... 22 2.3 Acidity and Alkalinity (pH) ................ 28 2.4 Corrosion as a Chemical Reaction .......... 31 2.4.1 Corrosion in Acids ................ 31 2.4.2 Corrosion in Neutral and Alkaline Solutions ................ 32 Reference .................................... 33 Corrosion Electrochemistry .................... 35 3.1 Electrochemical Reactions ................. 35 3.2 Anodic Processes ......................... 38 3.3 Faraday s Law ........................... 39 3.4 Cathodic Processes ....................... 40 3.5 Surface Area Effect ....................... 45 Reference .................................... 47 Corrosion Thermodynamics ................... 49 4.1 Free Energy ............................. 49 4.2 Standard Electrode Potentials .............. 51 4.3 Nernst Equation .......................... 54 4.4 Thermodynamic Calculations .............. 55 4.4.1 The Aluminum-Air Power Source ... 55 4.4.2 Detailed Calculations .............. 59 4.4.3 Reference Electrodes .............. 62 ÍV Contents 4.5 Reference Half-Cells (Electrodes) ........... 62 4.5.1 Conversion between References ..... 66 4.5.2 Silver/Silver Chloride Reference Electrode ............... 66 4.5.3 Copper/Copper Sulfate Reference Electrode ............... 68 4.6 Measuring the Corrosion Potential .......... 71 4.7 Measuring pH ........................... 72 4.7.1 Glass Electrodes .................. 73 4.7.2 Antimony Electrode .............. 74 4.8 Potential-pH Diagram .................... 74 4.8.1 Е -pH Diagram of Water ............ 75 4.8.2 Е -pH Diagrams of Metals .......... 76 References ................................... 84 Corrosion Kinetics and Applications of Electrochemistry to Corrosion ............. 85 5.1 What Is Overpotential? .................... 85 5.2 Activation Polarization .................... 86 5.3 Concentration Polarization ................ 90 5.4 Ohmic Drop ............................. 94 5.4.1 Water Resistivity Measurements .... 94 5.4.2 Soil Resistivity Measurements ...... 97 5.5 Graphical Presentation of Kinetic Data (Evans Diagrams) ........................ 103 5.5.1 Activation Controlled Processes ..... 103 5.5.2 Concentration Controlled Processes ........................ 104 5.6 Examples of Applied Electrochemistry to Corrosion ............................. 107 5.6.1 Electrochemical Polarization Corrosion Testing ................. 107 5.6.2 Corrosion Monitoring ............. 121 5.6.3 Cathodic Protection ............... 134 5.6.4 Anodic Protection ................. 135 5.6.5 Aluminum Anodizing ............. 137 5.6.6 Chloride Extraction ............... 142 References ................................... 144 Recognizing the Forms of Corrosion ............ 147 6.1 Recognizing Corrosion .................... 147 6.2 General or Uniform Attack ................ 151 6.3 Localized Corrosion ...................... 155 6.3.1 Pitting Corrosion ................. 155 6.3.2 Crevice Corrosion ................. 164 Contents 6.3.3 Galvanic Corrosion ............... 175 6.3.4 Intergranular Corrosion ............ 180 6.3.5 Dealloying ....................... 181 6.3.6 Hydrogen-Induced Cracking ....... 183 6.3.7 Hydrogen Blistering ............... 184 6.4 Velocity Induced Corrosion ................ 185 6.4.1 Erosion-Corrosion ................ 188 6.4.2 Cavitation ....................... 192 6.5 Mechanically Assisted Corrosion ........... 194 6.5.1 Stress Corrosion Cracking .......... 197 6.5.2 Corrosion Fatigue ................. 201 6.5.3 Fretting Corrosion ................ 203 References ................................... 205 Corrosion Failures, Factors, and Cells ........... 207 7.1 Introduction ............................. 207 7.2 Information to Look For ................... 209 7.2.1 Temperature Effects ............... 209 7.2.2 Fluid Velocity Effects .............. 210 7.2.3 Impurities in the Environment ...... 211 7.2.4 Presence of Microbes .............. 213 7.2.5 Presence of Stray Currents ......... 213 7.3 Identifying the Corrosion Factors ........... 216 7.4 Examples of Corrosion Cells ............... 224 7.4.1 Galvanic Cells .................... 227 7.4.2 Concentration Cells ............... 231 7.4.3 Differential Aeration: Oxygen Concentration Cells ........ 233 7.4.4 Temperature Cells ................. 235 7.4.5 Stray Current Cells ................ 237 7.4.6 Stress Cells ....................... 239 7.4.7 Surface Film Cells ................. 243 7.4.8 Microbial Corrosion Cells .......... 245 7.5 Corrosion Avoidance ...................... 246 7.5.1 Pitting Mitigation ................. 247 7.5.2 Crevice Corrosion Mitigation ....... 247 7.5.3 Galvanic Corrosion Mitigation ...... 248 7.5.4 Fretting Corrosion Mitigation ....... 248 7.5.5 Mitigation of Stress Corrosion Cracking ............... 248 7.6 Visualizing Corrosion Cells ................ 250 References ................................... 254 VJ Contents Corrosion by Water ........................... 257 8.1 Importance of Water ...................... 257 8.2 Corrosion and Water Quality and Availability .......................... 257 8.2.1 Corrosion Impact ................. 258 8.2.2 Corrosion Management ............ 260 8.2.3 Condition Assessment Techniques ....................... 265 8.3 Types of Water ........................... 268 8.3.1 Natural Waters ................... 268 8.3.2 Treated Waters .................... 284 8.4 Cooling Water Systems .................... 287 8.4.1 Once-Through Systems ............ 287 8.4.2 Recirculated Systems .............. 288 8.4.3 Heat Exchangers .................. 291 8.5 Steam Generating Systems ................. 294 8.5.1 Treatment of Boiler Feedwater Makeup ................ 294 8.5.2 Fossil Fuel Steam Plants ........... 296 8.5.3 Supercritical Steam Plants .......... 297 8.5.4 Waste Heat Boilers ................ 298 8.5.5 Nuclear Boiling Water Reactors ..... 299 8.5.6 Nuclear Pressurized Water Reactors ................... 300 8.5.7 Corrosion Costs to the Power Industry ............. 302 8.6 Water Treatment .......................... 307 8.6.1 Corrosion Inhibitors ............... 309 8.6.2 Scale Control ..................... 311 8.6.3 Microorganisms .................. 311 8.7 Scaling Indices ........................... 313 8.7.1 Langelier Saturation Index ......... 314 8.7.2 Other Indices ..................... 316 8.8 Ion-Association Model .................... 318 8.8.1 Limiting Halite Deposition in a Wet High-Temperature Gas Well .... 320 8.8.2 Identifying Acceptable Operating Range for Ozonated Cooling Systems ...... 321 8.8.3 Optimizing Calcium Phosphate Scale Inhibitor Dosage in a High-TDS Cooling System .................. 326 References ................................... 327 Contents vü 9 Atmospheric Corrosion ....................... 329 9.1 Introduction ............................ 329 9.2 Types of Corrosive Atmospheres .......... 330 9.2.1 Industrial ....................... 330 9.2.2 Marine ......................... 331 9.2.3 Rural ........................... 331 9.2.4 Indoor .......................... 333 9.3 Factors Affecting Atmospheric Corrosion ... 334 9.3.1 Relative Humidity and Dew Point .................. 338 9.3.2 Pollutants ....................... 339 9.3.3 Deposition of Aerosol Particles ___ 340 9.3.4 Deicing Salts .................... 341 9.4 Measurement of Atmospheric Corrosivity Factors ...................... 349 9.4.1 Time of Wetness ................. 349 9.4.2 Sulfur Dioxide ................... 350 9.4.3 Airborne Chlorides ............... 350 9.4.4 Atmospheric Corrosivity .......... 353 9.5 Atmospheric Corrosivity Classification Schemes ................... 358 9.5.1 Environmental Severity Index ..... 358 9.5.2 ISO Classification of Corrosivity of Atmospheres .................. 362 9.5.3 Maps of Atmospheric Corrosivity ... 362 9.6 Atmospheric Corrosion Tests .............. 366 9.7 Corrosion Behavior and Resistance ........ 370 9.7.1 Iron, Steel, and Stainless Steel ...... 370 9.7.2 Copper and Copper Alloys ........ 375 9.7.3 Nickel and Nickel Alloys .......... 376 9.7.4 Aluminum and Aluminum Alloys ... 377 9.7.5 Zinc and Zinc Alloys ............. 379 9.7.6 Polymeric Materials .............. 381 References ................................... 383 10 Corrosion in Soils and Microbiologically Influenced Corrosion ....................... 385 10.1 Introduction ............................ 385 10.2 Corrosion in Soils ....................... 385 10.2.1 Soil Classification ................ 387 10.2.2 Soil Parameters Affecting Corrosivity ............. 389 10.2.3 Soil Corrosivity Classifications ..... 391 10.2.4 Auxiliary Effects of Corrosion Cells ................ 394 Viii Contents 10.2.5 Examples of Buried Systems ....... 398 10.2.6 Corrosion of Materials Other Than Steel ................. 403 10.3 Microbiologically Influenced Corrosion ---- 407 10.3.1 Planktonic or Sessile .............. 409 10.3.2 Microbes Classification ........... 411 10.3.3 Monitoring Microbiologically Influenced Corrosion ............. 416 References ................................... 428 11 Materials Selection, Testing, and Design Considerations .................. 431 11.1 Materials Selection ....................... 431 11.2 Complexity of Corrosion Conscious Materials Selection ...................... 433 11.2.1 Multiple Forms of Corrosion ...... 433 11.2.2 Multiple Material/ Environment Combinations ....... 434 11.2.3 Precision of Corrosion Data ....... 437 11.2.4 Complexity of Materials / Performance Interactions ......... 438 11.3 Selection Compromises ................... 440 11.3.1 Life-Cycle Costing ............... 441 11.3.2 Condition Assessment ............ 443 11.3.3 Prioritization .................... 445 11.4 Materials Selection Road Map ............. 445 11.4.1 Identify Initial Slate of Candidate Materials ........... 446 11.4.2 Screen Materials Based on Past Experience ............... 447 11.4.3 Conduct Environmental Assessment ..................... 447 11.4.4 Evaluate Materials Based on Potential Corrosion Failure Modes .......... 450 11.4.5 Select Corrosion Prevention and Control Methods ............. 451 11.5 Design Considerations ................... 451 11.5.1 Designing Adequate Drainage ..... 454 11.5.2 Adequate Joining and Attachments ................. 459 11.6 Testing Considerations ................... 463 11.6.1 Test Objectives ................... 463 11.6.2 Test Standards ................... 464 11.6.3 Cabinet Testing ...... ............ 471 References ................................... 474 Contents ¡χ 12 Corrosion as a Risk ........................... 477 12.1 Risk Assessment ........................ 477 12.2 Risk Analysis ........................... 478 12.3 Risk and Corrosion Control ............... 481 12.4 Key Performance Indicators .............. 484 12.4.1 Cost of Corrosion Key Performance Indicator ....... 485 12.4.2 Corrosion Inhibition Level Key Performance Indicator ........... 486 12.4.3 Completed Maintenance Key Performance Indicator ....... 488 12.4.4 Selecting Key Performance Indicators ....................... 488 12.5 Risk Assessment Methods ................ 491 12.5.1 Hazard and Operability ........... 491 12.5.2 Failure Modes, Effects, and Criticality Analysis ........... 493 12.5.3 Risk Matrix Methods ............. 495 12.5.4 Fault Tree Analysis .............. 496 12.5.5 Event Tree Analysis .............. 500 12.6 Risk-Based Inspection .................... 503 12.6.1 Probability of Failure Assessment ..................... 504 12.6.2 Consequence of Failure Assessment ..................... 504 12.6.3 Application of Risk-Based Inspection ...................... 505 12.7 Industrial Example: Transmission Pipelines ................... 507 12.7.1 External Corrosion Damage Assessment ............. 512 12.7.2 Internal Corrosion Damage Assessment ............. 515 12.7.3 Hydrostatic Testing .............. 518 12.7.4 In-Line Inspection ................ 518 References ................................... 522 13 Cathodic Protection ........................... 525 13.1 Cathodic ProtectionHistoricalNotes ....... 525 13.2 How Cathodic Protection Works in Water ... 526 13.2.1 Sacrificial Cathodic Protection ..... 527 13.2.2 Impressed Current Cathodic Protection .............. 529 Contents 13.3 How Cathodic Protection Works in Soils ... 532 13.3.1 Sacrificial Cathodic Protection ----- 536 13.3.2 Impressed Current Cathodic Protection ............. 536 13.3.3 Anode Beds .................... 538 13.3.4 Anode Backfill .................. 540 13.4 How Cathodic Protection Works in Concrete ...................... 544 13.4.1 Impressed Current Cathodic Protection ............. 545 13.4.2 Sacrificial Cathodic Protection ---- 548 13.5 Cathodic Protection Components ......... 550 13.5.1 Reference Electrodes ............ 550 13.5.2 Anodes ........................ 553 13.5.3 Rectified Current Sources ........ 561 13.5.4 Other Current Sources ........... 563 13.5.5 Wires and Cables ............... 564 13.6 Potential to Environment ................ 565 13.7 Current Requirement Tests .............. 566 13.7.1 Tests for a Coated System ........ 567 13.7.2 Tests for a Bare Structure ......... 569 13.8 Stray Current Effects .................... 569 13.9 Monitoring Pipeline Cathodic Protection Systems ..................... 571 13.9.1 Close Interval Potential Surveys ... 571 13.9.2 Pearson Survey ................. 573 13.9.3 Direct and Alternating Current Voltage Gradient Surveys ........ 576 13.9.4 Corrosion Coupons ............. 577 13.10 Simulation and Optimization of Cathodic Protection Designs ........... 578 13.10.1 Modeling Ship Impressed Current Cathodic Protection ...... 579 13.10.2 Modeling Cathodic Protection in the Presence of Interference .... 582 References ................................... 585 14 Protective Coatings ........................... 587 14.1 Types of Coatings ...................... 587 14.2 Why Coatings Fail ...................... 588 14.3 Soluble Salts and Coating Failures ........ 592 14.4 Economic Aspects of Coatings Selection and Maintenance .............. 598 14.5 Organic Coatings ....................... 603 14.5.1 Coating Functionality ........... 603 14.5.2 Basic Components .............. 610 Contents xi 14.6 Temporary Preservatives ................ 615 14.6.1 Jointing Compounds and Sealants .................... 615 14.6.2 Corrosion Prevention Compounds ................... 615 14.6.3 Volatile Corrosion Inhibitors ...... 620 14.7 Inorganic (Nonmetallic) Coatings ......... 623 14.7.1 Hydraulic Cement .............. 623 14.7.2 Ceramics and Glass ............. 624 14.7.3 Anodizing ..................... 625 17.7.4 Phosphatizing .................. 625 14.7.5 Chromáte Filming .............. 626 14.7.6 Nitriding ...................... 626 14.7.7 Passive Films ................... 626 14.7.8 Pack Cementation ............... 627 14.8 Metallic Coatings ....................... 627 14.8.1 Electroplating .................. 627 14.8.2 Electroless Plating ............... 629 14.8.3 Hot-Dip Galvanizing ............ 630 14.8.4 Cladding ...................... 630 14.8.5 Metallizing (Thermal Spray) ...... 631 14.9 Coating Inspection and Testing ........... 638 14.9.1 Condition of the Substrate ....... 639 14.9.2 Condition of the Existing Coating System ................. 641 14.9.3 Coating Inspection .............. 641 14.9.4 Laboratory Testing .............. 647 14.9.5 Holiday Detection .............. 652 14.10 Surface Preparation ..................... 654 14.10.1 Principles of Coating Adhesion ... 654 14.10.2 Abrasive Cleaning .............. 655 14.10.3 Water Jetting ................... 658 14.10.4 Wet Abrasive Blasting ........... 659 14.10.5 Other Surface Preparation Methods ............ 659 References .................................. 661 15 High-Temperature Corrosion ................. 663 15.1 Introduction ........................... 663 15.2 Thermodynamic Principles .............. 666 15.2.1 Standard Free Energy of Formation ................... 666 15.2.2 Vapor Species Diagrams ......... 669 15.2.3 2D Isothermal Stability Diagrams .............. 673 XU Contents 15.3 Kinetic Principles ........................ 675 15.3.1 Scale as a Diffusion Barrier ........ 676 15.3.2 Basic Kinetic Models ............. 678 15.3.3 Pilling-Bedworth Ratio ........... 680 15.4 Practical High-Temperature Corrosion Problems ...................... 683 15.4.1 Oxidation ....................... 684 15.4.2 Sulfidation ...................... 690 15.4.3 Carburization ................... 700 15.4.4 Metal Dusting ................... 704 15.4.5 Nitridation ...................... 705 15.4.6 Gaseous Halogen Corrosion ....... 706 15.4.7 Fuel Ash and Salt Deposits ........ 706 15.4.8 Corrosion by Molten Salts ......... 708 15.4.9 Corrosion in Liquid Metals ........ 709 References ................................... 710 A Historical Perspective ......................... 711 References ................................... 714 В Periodic Table ................................ 715 С SI Units Conversion Table ..................... 717 A.I How to Read This Table .................. 717 A.2 Using the Table .......................... 723 Index ....................................... 725
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publisher	McGraw-Hill
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spelling	Roberge, Pierre R. Verfasser aut Corrosion engineering principles and practice Pierre R. Roberge [1. ed.] New York [u.a.] McGraw-Hill 2008 XIV, 754 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Anticorrosivos larpcal Corrosão larpcal Corrosion and anti-corrosives Korrosion (DE-588)4032518-0 gnd rswk-swf Korrosionsschutz (DE-588)4032522-2 gnd rswk-swf Korrosion (DE-588)4032518-0 s DE-604 Korrosionsschutz (DE-588)4032522-2 s Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018605817&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Roberge, Pierre R. Corrosion engineering principles and practice Anticorrosivos larpcal Corrosão larpcal Corrosion and anti-corrosives Korrosion (DE-588)4032518-0 gnd Korrosionsschutz (DE-588)4032522-2 gnd
subject_GND	(DE-588)4032518-0 (DE-588)4032522-2
title	Corrosion engineering principles and practice
title_auth	Corrosion engineering principles and practice
title_exact_search	Corrosion engineering principles and practice
title_full	Corrosion engineering principles and practice Pierre R. Roberge
title_fullStr	Corrosion engineering principles and practice Pierre R. Roberge
title_full_unstemmed	Corrosion engineering principles and practice Pierre R. Roberge
title_short	Corrosion engineering
title_sort	corrosion engineering principles and practice
title_sub	principles and practice
topic	Anticorrosivos larpcal Corrosão larpcal Corrosion and anti-corrosives Korrosion (DE-588)4032518-0 gnd Korrosionsschutz (DE-588)4032522-2 gnd
topic_facet	Anticorrosivos Corrosão Corrosion and anti-corrosives Korrosion Korrosionsschutz
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018605817&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT robergepierrer corrosionengineeringprinciplesandpractice

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