Two-dimensional optical spectroscopy:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Boca Raton, Fla. [u.a.]
CRC Press
2009
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 378 S. Ill., graph. Darst. |
| ISBN: | 9781420084290 |
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| 100 | 1 | |a Cho, Minhaeng |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Two-dimensional optical spectroscopy |c Minhaeng Cho |
| 264 | 1 | |a Boca Raton, Fla. [u.a.] |b CRC Press |c 2009 | |
| 300 | |a 378 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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Datensatz im Suchindex
| _version_ | 1804139405455130624 |
|---|---|
| adam_text | Table
of
Contents
Preface
.......................................................................................................................ix
About the Author
......................................................................................................xi
Acknowledgments
..................................................................................................xiii
Chapter
1
Introduction
........................................................................................1
References
...........................................................................................6
Chapter
2
Quantum Dynamics
............................................................................9
2.1
Time Evolution in Hubert Space
...........................................9
2.2
Time-Dependent Perturbation Theory in Hubert Space
.....12
2.3
Diagram Representation of the Time-Dependent
Perturbation Theory in Hubert Space
.................................15
2.4
Transition Amplitude and Probability in Hubert Space
......17
2.5
Time Evolution in Liouville Space
......................................20
2.6
Time-Dependent Perturbation Theory in Liouville
Space
....................................................................................22
2.7
Transition Probability in Liouville Space
and Pathways
........................................................................26
2.7.1
Second-Order Transition between Two
Populations
.............................................................26
2.7.2
Second-Order Transition between Two
Coherences
.............................................................28
2.7.3
First-Order Transition between Population
and Coherence
........................................................29
References
.........................................................................................30
Chapter
3
Linear Response Spectroscopy
.........................................................31
3.1
Linear Response Function
...................................................33
3.2
System-Bath Interaction and Line Broadening
...................36
3.3
Rotational Averaging of Tensors
..........................................45
3.4
Linear Absorption Spectroscopy
.........................................47
3.5
Raman Scattering
.................................................................50
3.6
Hyper-Raman Scattering
.....................................................54
3.7
IR-Raman Surface Vibrational Spectroscopy
......................56
3.8
Raman-IR Surface Vibrational Spectroscopy
.....................59
Appendix: Nonlinear Polarization and Generated Signal
Electric Field
........................................................................61
References
.........................................................................................62
Chapter
4
Second-Order Response Spectroscopy
.............................................63
4.1
Second-Order Response Function
.......................................64
4.2
Three-Level System and Line-Broadening Function
..........68
4.3
Sum Frequency Generation
..................................................75
4.4
Difference Frequency Generation
........................................76
4.5
IR-IR-vis Four-Wave Mixing
..............................................78
References
.........................................................................................80
Chapter
5
Third-Order Response Spectroscopy
...............................................83
5.1
Third-Order Response Function
..........................................83
5.2
Four-Level System and Line-Broadening Function
.............87
5.3
Short-Time Approximation to the Third-Order
Response Function
...............................................................93
5.4
Third-Order Response Function of a Two-Level
System
..................................................................................96
5.5
Pump-Probe Spectroscopy of a Two-Level System
..........100
5.6
Rephasing Photon Echo Spectroscopy of a Two-Level
System
................................................................................103
5.7
Nonrephasing Photon Echo Spectroscopy of a
Two-Level System
..............................................................107
5.8
Three-Pulse Photon Echo Peak Shift (PEPS)
....................108
References
.......................................................................................112
Chapter
6
Two-Dimensional Pump-Probe Spectroscopy
...............................115
6.1
Introduction to Two-Dimensional Pump-Probe
Spectroscopy
......................................................................115
6.2
Two-Dimensional Pump-Probe Spectrum of
Two-Level System
..............................................................117
6.3
Two-Dimensional Pump-Probe Spectrum of an
Anharmonic Oscillator
......................................................123
References
.......................................................................................129
Chapter
7
Two-Dimensional Photon Echo Spectroscopy
...............................131
7.1
Phase and Amplitude Detection of the Two-
Dimensional Photon Echo Signal Field
.............................132
7.2
Two-Dimensional Photon Echo Spectrum of a
Two-Level System
..............................................................135
7.3
Two-Dimensional Nonrephasing Photon Echo
Spectrum of a Two-Level System
......................................139
7.4
Two-Dimensional Photon Echo Spectrum of an
Anharmonic Oscillator
......................................................142
7.5 Simple Two-Dimensional Lorentzian
Peak Shape............
144
7.6 Simple Two-Dimensional
Gaussian Peak Shape
...............146
References
.......................................................................................¡48
Chapter
8
Coupled Multi-Chromophore System
.............................................151
8.1
Frenkel Hamiltonian in Site Representation
......................152
8.2
Delocalized Exciton Representation
..................................154
8.3
Delocalized State Energy and Transition
Dipole
Matrix Element
..................................................................155
8.4
Transition Frequency-Frequency Correlation
Functions
............................................................................157
8.5
Exchange-Narrowing Effect on Absorption Spectrum
......158
8.6
Measurements of Auto-and
Cross-Frequency-Frequency Correlation Functions
.........160
8.7
Exciton Population Transfer
...............................................163
References
.......................................................................................166
Chapter
9
Two-Dimensional Spectroscopy of Coupled Dimers
.....................169
9.1
Model Hamiltonian of a Coupled Two-Level System
Dimer
.................................................................................169
9.2
Delocalized Excited-State Energy Fluctuations
and Time Correlation Functions
........................................172
9.3
Coupled Two-Level System Dimer: Quantum Beats
at Short Time
.....................................................................174
9.4
Coupled Two-Level System Dimer: Intermediate
Time Region
.......................................................................179
9.5
Coupled Two-Level System Dimer: Population
Transfer Effects
..................................................................181
9.6
Coupled Anharmonic Oscillators: Model Hamiltonian
.... 188
9.7
Coupled Anharmonic Oscillators: Two-Dimensional
Photon Echo Spectrum at Short Time
...............................191
9.8
Coupled Anharmonic Oscillators: Degenerate Case
.........195
9.9
Coupled Anharmonic Oscillators: Population
Transfer Effects
..................................................................204
References
.......................................................................................207
Chapter
10
Chemical Exchange and Two-Dimensional Spectroscopy
.............209
10.1
Model System
.....................................................................210
10.2
Chemical Exchange Diagrams: Two-Level System
...........212
10.3
Chemical Exchange Diagrams: Anharmonic
Oscillator
............................................................................216
References
.......................................................................................221
Chapter
11
Polarization-Controlled Two-Dimensional Spectroscopy
..............223
11.1
Parallel Polarization ZZZZ-Echo: Two-Level System
.......223
11.2
Perpendicular Polarization ZYYZ-Echo: Two-Level
System
................................................................................228
11.3
Difference Two-Dimensional Photon Echo Spectrum:
Coupled Two-Level System Dimer
....................................230
11.4
Parallel Polarization ZZZZ-Echo: Anharmonic
Oscillators
..........................................................................231
11.5
Perpendicular Polarization ZYYZ-Echo: Anharmonic
Oscillators
..........................................................................233
11.6
Difference Two-Dimensional Echo Spectrum:
Coupled Anharmonic Oscillators
......................................235
11.7
Generalized Polarization-Controlled
Two-Dimensional Spectroscopy
........................................237
11.8
Determination of the Angle between Any Two
Transition
Dipole
Vectors
..................................................240
References
.......................................................................................243
Chapter
12
Applications of Two-Dimensional Vibrational Spectroscopy
........245
12.1
Single Anharmonic Oscillator Systems
.............................246
12.2
Coupled Two-Oscillator Systems
.......................................253
12.3
Polypeptide Secondary Structures
.....................................258
12.4
Globular Proteins and Membrane-Bound Proteins
............265
12.5
Nucleic Acids
.....................................................................266
12.6
Hydrogen-Bonding Dynamics and Chemical
Exchange
............................................................................267
12.7
Solute-Solvent Complexation and Micro-Solvation
..........270
12.8
Internal Rotation
................................................................272
12.9
Transient Two-Dimensional
IR
Spectroscopy:
Protein Folding and Unfolding
..........................................272
References
.......................................................................................274
Chapter
13
Applications of Two-Dimensional Electronic Spectroscopy
..........283
13.1
Application to Fenna-Matthews-Olson
Light-Harvesting Complex
.................................................283
13.2
Application to Semiconductors
..........................................289
References
.......................................................................................291
Chapter
14
Two-Dimensional Second-Order Response Spectroscopy
.............293
14.1
Two-Dimensional Sum Frequency Generation
..................294
14.2
Two-Dimensional Sum Frequency Generation
of Solution Sample
.............................................................296
14.3
Two-Dimensional Sum Frequency Generation
of Coupled Two-Level System Dimer
................................298
14.4
Two-Dimensional Sum Frequency Generation
of Coupled Anharmonic Oscillators
..................................301
14.5
Two-Dimensional Difference Frequency Generation
........305
14.6
IR-IR-vis Sum Frequency Generation and Difference
Frequency Generation
........................................................306
14.7
Other IR-IR-vis Four-Wave-Mixings
................................313
14.8
Fifth-Order Raman Scattering
...........................................316
References
.......................................................................................320
Chapter
15
Linear Optical Activity Spectroscopy
............................................323
15.1
Radiation-Matter Interaction Hamiltonian and
Polarization
........................................................................324
15.2
Circular Dichroism and Optical Rotatory Dispersion
.......326
15.3
Raman Optical Activity
.....................................................334
15.4
IR-Raman Optical Activity Spectroscopy
.........................341
15.5
Raman-IR Optical Activity Spectroscopy
.........................346
References
.......................................................................................350
Chapter
16
Nonlinear Optical Activity Spectroscopy
.......................................351
16.1
Nonlinear Optical Activity Measurement Methods
..........351
16.2
Rotational Averaging of Higher-Rank Tensors
..................353
16.3
Two-Dimensional Optical Activity Pump-Probe:
Two-Level System
..............................................................358
16.4
Two-Dimensional Optical Activity Photon Echo:
Two-Level System
..............................................................367
16.5
Two-Dimensional Optical Activity Photon Echo
of Coupled Two-Level System Dimer
................................369
References
.......................................................................................373
Index
......................................................................................................................375
|
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| id | DE-604.BV035693082 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:43:34Z |
| institution | BVB |
| isbn | 9781420084290 |
| language | English |
| lccn | 2009015407 |
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| oclc_num | 212843967 |
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| owner_facet | DE-703 DE-20 DE-11 |
| physical | 378 S. Ill., graph. Darst. |
| publishDate | 2009 |
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| publishDateSort | 2009 |
| publisher | CRC Press |
| record_format | marc |
| spelling | Cho, Minhaeng Verfasser aut Two-dimensional optical spectroscopy Minhaeng Cho Boca Raton, Fla. [u.a.] CRC Press 2009 378 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Optical spectroscopy Quantum optics Quantenoptik (DE-588)4047990-0 gnd rswk-swf Optische Spektroskopie (DE-588)4043680-9 gnd rswk-swf Laserspektroskopie (DE-588)4034620-1 gnd rswk-swf Optische Spektroskopie (DE-588)4043680-9 s Quantenoptik (DE-588)4047990-0 s DE-604 Laserspektroskopie (DE-588)4034620-1 s Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017747129&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Cho, Minhaeng Two-dimensional optical spectroscopy Optical spectroscopy Quantum optics Quantenoptik (DE-588)4047990-0 gnd Optische Spektroskopie (DE-588)4043680-9 gnd Laserspektroskopie (DE-588)4034620-1 gnd |
| subject_GND | (DE-588)4047990-0 (DE-588)4043680-9 (DE-588)4034620-1 |
| title | Two-dimensional optical spectroscopy |
| title_auth | Two-dimensional optical spectroscopy |
| title_exact_search | Two-dimensional optical spectroscopy |
| title_full | Two-dimensional optical spectroscopy Minhaeng Cho |
| title_fullStr | Two-dimensional optical spectroscopy Minhaeng Cho |
| title_full_unstemmed | Two-dimensional optical spectroscopy Minhaeng Cho |
| title_short | Two-dimensional optical spectroscopy |
| title_sort | two dimensional optical spectroscopy |
| topic | Optical spectroscopy Quantum optics Quantenoptik (DE-588)4047990-0 gnd Optische Spektroskopie (DE-588)4043680-9 gnd Laserspektroskopie (DE-588)4034620-1 gnd |
| topic_facet | Optical spectroscopy Quantum optics Quantenoptik Optische Spektroskopie Laserspektroskopie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017747129&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT chominhaeng twodimensionalopticalspectroscopy |