Principles of chemical sensors:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Dordrecht [u.a.]
Springer
2009
|
| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XV, 373 S. Ill., graph. Darst. |
| ISBN: | 9780387699301 |
Internformat
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV035651383 | ||
| 003 | DE-604 | ||
| 005 | 20120809 | ||
| 007 | t | ||
| 008 | 090729s2009 ad|| |||| 00||| eng d | ||
| 020 | |a 9780387699301 |c hbk. |9 978-0-387-69930-1 | ||
| 035 | |a (OCoLC)437081835 | ||
| 035 | |a (DE-599)BVBBV035651383 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-19 |a DE-11 |a DE-703 |a DE-355 |a DE-188 | ||
| 050 | 0 | |a TP159.C46 | |
| 082 | 0 | |a 681.2 |2 22 | |
| 084 | |a VG 6820 |0 (DE-625)147193:253 |2 rvk | ||
| 084 | |a VG 6830 |0 (DE-625)147194:253 |2 rvk | ||
| 084 | |a VN 7000 |0 (DE-625)147598:253 |2 rvk | ||
| 100 | 1 | |a Janata, Jiří |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Principles of chemical sensors |c Jiří Janata |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Dordrecht [u.a.] |b Springer |c 2009 | |
| 300 | |a XV, 373 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Chemical detectors | |
| 650 | 4 | |a Finite groups | |
| 650 | 4 | |a Semigroups | |
| 650 | 0 | 7 | |a Chemischer Sensor |0 (DE-588)4259288-4 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Chemischer Sensor |0 (DE-588)4259288-4 |D s |
| 689 | 0 | |5 DE-604 | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |z 978-0-387-69931-8 |
| 856 | 4 | 2 | |m HBZ Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017705971&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-017705971 | ||
Datensatz im Suchindex
| _version_ | 1804139337277767680 |
|---|---|
| adam_text | Titel: Principles of chemical sensors
Autor: Janata, Jiří
Jahr: 2009
Contents
1 Introduction to Sensors 1
1.1 Introduction 1
1.2 General Response Curve 3
1.3 Origins of Selectivity 10
Food for Thought #1 10
Irreversible Binding 10
Multiple Binding Sites 11
Symbols 11
Reference 11
2 Selectivity 13
2.1 Introduction 13
2.2 Equilibrium-Based Selectivity 13
2.2.1 Shape Recognition 14
2.2.2 Bioselectivity 17
2.2.2.1 Immunochemical Selectivity 18
2.2.2.2 Nucleotide-Based Selectivity 22
2.2.2.3 Aptamers 23
2.2.3 Imprinted Polymers 24
2.2.3.1 Solubility in Organic Materials 26
2.2.3.2 Solubility in Inorganic Materials 28
2.3 Kinetic Selectivity 30
2.3.1 Enzyme Kinetics 30
2.3.2 Zero-Flux-Boundary Sensors 40
2.4 Mass Transport Selectivity 42
2.5 Design of Selective Layers 43
2.5.1 Preparation of the Substrate 43
2.5.2 Immobilization of Specific Binding Sites 46
Food for Thought #2 47
DNA Selectivity 47
Adsorption and Absorption 48
x Contents
Gas Immunosensors 48
Linear Solubility Energy Relationship 48
Molecular Imprinting 49
Symbols 49
References 50
3 Thermal Sensors 51
3.1 Introduction 51
3.2 General 51
3.3 Push-Pull Operation 52
3.4 Thermometers 53
3.4.1 Platinum or Platinum-Indium Alloy Resistors 53
3.4.2 Thermocouples 54
3.4.3 Thermistors 54
3.5 Equivalent Circuits 55
3.6 Examples of Thermal Chemical Sensors 55
3.6.1 Glucose Thermistor 56
3.6.2 Catalytic Gas Sensors 57
3.6.3 Miniaturized Pellistor 61
Food for Thought #3 61
Enzyme Thermistor 61
Equivalent Circuit for a Thermal Sensor 61
Push-Pull Mode 62
Symbols 62
References 62
4 Mass Sensors 63
4.1 Introduction 63
4.2 Mass Sensors Based on Piezoelectric Materials 67
4.2.1 Thickness-Shear-Mode (TSM) Resonators 68
4.2.1.1 QCM in the Gas Phase 71
4.2.1.2 QCM in Aerosols and Suspensions 74
4.2.1.3 QCM in Liquids 76
Modeling with Equivalent Electrical Circuits 79
4.2.2 Surface Acoustic Wave Sensors 86
4.2.3 Plate Mode Oscillators 91
4.3 Nonpiezoelectric Mass Sensors 92
4.3.1 Resonant Cantilevers 93
Food for Thought #4 96
Electrochemical Calibration of QCM 96
Gravitational Effects 96
Enzymatic Mass Sensors 96
Determination of Hydration Numbers 96
Impedance Matching 96
Symbols 97
References 98
Contents xj
5 Electrochemical Sensors 99
5.1 Introduction 99
5.2 General Rules of Electrochemistry 100
5.2.1 Thought Experiment I (Curve A) 101
5.2.2 Thought Experiment II (Curve B) 103
5.3 Nature of Interfaces 104
5.4 Nature of the Current-Voltage Curve 107
5.4.1 Throught Experiment III 108
5.4.2 Charge-Transfer Region 109
5.4.3 Mass Transport Region Ill
5.5 Determination of Cell Parameters: Experimental Methods 112
5.5.1 Tafel Plots 112
5.5.2 The Equivalent Electrical Circuit Approach 113
Food for Thought #5 116
Electrochemical Divider 116
Electrochemical Immunosensors 116
Interfaces 116
Mixed Potential 117
Nyquist Plots 117
Voltage and Potential 117
Symbols 117
References 118
6 Potentiometric Sensors 119
6.1 Introduction 119
6.2 Ion Sensors 119
6.2.1 Interfaces in Ion Sensors 119
6.2.1.1 Ion-Selective Interface 120
6.2.1.2 Semipermeable Interface 123
6.2.1.3 Nonselective Interface with Low Rc{ 124
6.2.1.4 Nonselective Interface with High /?cl 129
6.2.2 Components of Potentiometric Cells 131
6.2.2.1 Reference Electrodes 131
First Kind 132
Second Kind 132
Redox Reference Electrode 135
Miniaturization of Reference Electrodes 136
6.2.2.2 Ion-Selective Electrodes 138
6.2.2.2.1 Solid Membrane Electrodes 139
Glass Electrode 139
Fluoride Electrode 143
Other Solid-State Ion-Selective
Electrodes 144
6.2.2.2.2 Liquid Membrane Electrodes 146
xii Contents
6.2.3 Assembled Electrochemical Cell 149
6.2.3.1 Symmetrical Ion-Selective Electrodes 151
6.2.3.2 Asymmetric Membrane Ion Sensors 151
6.2.3.2.1 Coated Wire Electrodes 153
6.2.3.2.2 Field-Effect Transistors 156
pHISFET 162
ISFETs for Other Ions 165
Multiple Ion ISFETs 166
6.3 Potentiometric Sensors for Neutral Species 168
6.3.1 Potentiometric Enzyme Sensors 168
6.3.2 Severinghaus Electrodes 171
6.3.3 Work Function Sensors 173
6.3.3.1 Kelvin Probe 174
6.3.3.2 Suspended Gate Field-Effect Transistor 175
6.3.3.3 Field-Effect Transistors with Semiconductor Gate . 176
6.3.3.3.1 Physics of WF Modulation 177
6.3.3.3.2 Chemical Modulation of WF 181
6.3.3.4 High-Temperature Ionic Sensors 189
Food for Thought #6 194
Adsorption FET 194
Contact Potential 194
Liquid Junction Potential 195
Electrochemical Cell 195
Designed Nonselectivity 195
Hydrogel ISFET 195
Kelvin Probe 196
Perfect Liquid Junction 196
Nonequilibrium Ion-Selective Electrodes 196
Reference Electrode 196
Single-Electrode Measurement 197
Symbols 197
References 198
7 Amperometric Sensors 201
7.1 General Considerations 201
7.2 Microelectrodes 206
7.3 Oxygen Electrodes 208
7.4 Clark Electrode 210
7.5 Amperometric Selectivity 214
7.5.1 Modified Electrodes 216
7.5.2 Potentiodynamic Sensors 220
7.5.3 Amperometric Biosensors 221
7.5.3.1 Oxygen-Based Enzyme Electrodes 223
7.5.3.2 Oxidation of Hydrogen Peroxide 225
7.5.3.3 Direct Oxidation of Glucose Oxidase 227
Contents xln
7.6 Amperometric Fuel Cells 230
7.7 High Temperature Limiting Current Sensors 232
Food for Thought #7 237
Electrode Placement in Potentiometric and Amperometric
Measurement 237
Constant Current 238
Fuel Cell Amperometric Sensors 238
Symbols 238
References 239
8 Conductometric Sensors 241
8.1 Introduction 241
8.1.1 The Origin of Sensor Response 242
8.1.1.1 Contact Resistance 244
8.1.1.1.1 Partially Blocked Contacts 245
8.1.1.1.2 Schottky Contacts 245
8.1.1.2 Bulk Resistance 247
8.1.1.3 Surface Resistance 247
8.2 Chemiresistors 248
8.2.1 Thin Metal Film Sensors 248
8.2.2 Semiconductor Film Sensors 249
8.2.2.1 Inorganic Semiconductor Chemiresistors 250
8.2.2.2 Organic Semiconductor Chemiresistors 255
Organic Field-Effect Transistors (OFETs) 258
8.3 AC Conductometric Sensors 259
8.3.1 Gas Membrane Sensors 259
8.3.2 Dielectrometric Sensors 260
8.3.3 Interfacial Charge Sensors 261
Food for Thought #8 263
Bubbles 263
Closed Circuit 263
Capacitive pH Sensors 263
Channel Conductivity Sensors 263
Immunocapacitor 264
Ion Channel Sensors 264
Polyelectrolyte Sensors 264
Missing Warburg 264
Symbols 265
References 266
9 Optical Sensors 267
9.1 Introduction 267
9.2 Corpuscular Properties of Light 268
9.2.1 The Lambert-Beer Law 270
9.2.2 Luminescence 272
xiv Contents
9.3 Wavelike Properties of Light 276
9.3.1 Guiding of Light 278
9.3.2 Coupling of Light 281
9.3.3 Guided Modes 282
9.3.4 Reflectance 284
9.3.4.1 Diffuse Reflectance 284
9.3.4.2 Plasmon Resonance 286
9.3.5 Photoluminescent Schottky Diodes 288
9.4 Selectivity 291
9.4.1 Design of Optical Sensors 292
9.4.2 Optical Arrays 297
9.4.3 Optical Ion Sensors 299
9.4.4 Fluorescence Gas Sensors 303
9.4.5 Optical Biosensors 305
Food for Thought #9 308
Activities 308
Evanescent Field 308
Optrodes in Dilute Solutions 309
Symbols 309
References 310
10 Multivariate Sensing 313
10.1 Introduction 313
10.2 Higher-Order Sensors 314
10.3 Sensing Arrays 317
10.4 Multivariate Analysis 318
10.4.1 Preprocessing of Input Data 318
10.4.2 Data Display 319
10.4.3 Data Processing 319
10.4.3.1 Principal Component Analysis 321
10.4.3.2 Principal Component Regression 322
10.4.3.3 Partial Least Squares 323
10.4.3.4 Self-organizing Maps 324
10.4.3.5 Neural Networks 325
10.4.3.6 Cluster Analysis 327
10.4.3.7 Visual-Empirical Region-of-Influence 328
10.4.3.8 Hybrid Approaches 329
10.4.4 Evaluation Dynamic Data 330
10.4.4.1 Time as a Parameter 330
10.4.4.2 Spatial Information Obtained with Sensing Arrays 332
Food forThought#10 338
Beauty Contest 338
Artificial Neural Networks 339
Symbols 339
References 339
Contents xv
A Survey of Thermodynamics 341
A. 1 Introduction 341
A.2 The First Law 341
A.3 The Second Law 342
A.3.1 The Equilibrium 343
A.3.2 Chemical Potential 344
A.3.3 Ideal: Real Solutions 345
A.3.4 Absorption 345
A.3.5 Adsorption 346
A.3.6 Phase Equilibria 347
B Survey of Kinetics 349
B.I Equilibrium and Rate Equations 349
B.2 Activation Energy 350
B.3 Diffusion 351
C Survey of Solid-State Physics 353
C. 1 Introduction 353
C.2 The Semiconductor Field Effect 359
C.3 Current-Voltage Relationships for the IGFET 360
Reference 365
D Conversions of Equivalent Electrical Circuits 367
Index 369
|
| any_adam_object | 1 |
| author | Janata, Jiří |
| author_facet | Janata, Jiří |
| author_role | aut |
| author_sort | Janata, Jiří |
| author_variant | j j jj |
| building | Verbundindex |
| bvnumber | BV035651383 |
| callnumber-first | T - Technology |
| callnumber-label | TP159 |
| callnumber-raw | TP159.C46 |
| callnumber-search | TP159.C46 |
| callnumber-sort | TP 3159 C46 |
| callnumber-subject | TP - Chemical Technology |
| classification_rvk | VG 6820 VG 6830 VN 7000 |
| ctrlnum | (OCoLC)437081835 (DE-599)BVBBV035651383 |
| dewey-full | 681.2 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 681 - Precision instruments and other devices |
| dewey-raw | 681.2 |
| dewey-search | 681.2 |
| dewey-sort | 3681.2 |
| dewey-tens | 680 - Manufacture of products for specific uses |
| discipline | Chemie / Pharmazie Handwerk und Gewerbe / Verschiedene Technologien |
| edition | 2. ed. |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01527nam a2200421 c 4500</leader><controlfield tag="001">BV035651383</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20120809 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">090729s2009 ad|| |||| 00||| eng d</controlfield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">9780387699301</subfield><subfield code="c">hbk.</subfield><subfield code="9">978-0-387-69930-1</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)437081835</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV035651383</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakddb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-19</subfield><subfield code="a">DE-11</subfield><subfield code="a">DE-703</subfield><subfield code="a">DE-355</subfield><subfield code="a">DE-188</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">TP159.C46</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">681.2</subfield><subfield code="2">22</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VG 6820</subfield><subfield code="0">(DE-625)147193:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VG 6830</subfield><subfield code="0">(DE-625)147194:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VN 7000</subfield><subfield code="0">(DE-625)147598:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Janata, Jiří</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Principles of chemical sensors</subfield><subfield code="c">Jiří Janata</subfield></datafield><datafield tag="250" ind1=" " ind2=" "><subfield code="a">2. ed.</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Dordrecht [u.a.]</subfield><subfield code="b">Springer</subfield><subfield code="c">2009</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">XV, 373 S.</subfield><subfield code="b">Ill., graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chemical detectors</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Finite groups</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Semigroups</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Chemischer Sensor</subfield><subfield code="0">(DE-588)4259288-4</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Chemischer Sensor</subfield><subfield code="0">(DE-588)4259288-4</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="776" ind1="0" ind2="8"><subfield code="i">Erscheint auch als</subfield><subfield code="n">Online-Ausgabe</subfield><subfield code="z">978-0-387-69931-8</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">HBZ Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017705971&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-017705971</subfield></datafield></record></collection> |
| id | DE-604.BV035651383 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:42:29Z |
| institution | BVB |
| isbn | 9780387699301 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017705971 |
| oclc_num | 437081835 |
| open_access_boolean | |
| owner | DE-19 DE-BY-UBM DE-11 DE-703 DE-355 DE-BY-UBR DE-188 |
| owner_facet | DE-19 DE-BY-UBM DE-11 DE-703 DE-355 DE-BY-UBR DE-188 |
| physical | XV, 373 S. Ill., graph. Darst. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | Springer |
| record_format | marc |
| spelling | Janata, Jiří Verfasser aut Principles of chemical sensors Jiří Janata 2. ed. Dordrecht [u.a.] Springer 2009 XV, 373 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chemical detectors Finite groups Semigroups Chemischer Sensor (DE-588)4259288-4 gnd rswk-swf Chemischer Sensor (DE-588)4259288-4 s DE-604 Erscheint auch als Online-Ausgabe 978-0-387-69931-8 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017705971&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Janata, Jiří Principles of chemical sensors Chemical detectors Finite groups Semigroups Chemischer Sensor (DE-588)4259288-4 gnd |
| subject_GND | (DE-588)4259288-4 |
| title | Principles of chemical sensors |
| title_auth | Principles of chemical sensors |
| title_exact_search | Principles of chemical sensors |
| title_full | Principles of chemical sensors Jiří Janata |
| title_fullStr | Principles of chemical sensors Jiří Janata |
| title_full_unstemmed | Principles of chemical sensors Jiří Janata |
| title_short | Principles of chemical sensors |
| title_sort | principles of chemical sensors |
| topic | Chemical detectors Finite groups Semigroups Chemischer Sensor (DE-588)4259288-4 gnd |
| topic_facet | Chemical detectors Finite groups Semigroups Chemischer Sensor |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017705971&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT janatajiri principlesofchemicalsensors |