The absorption spectra of solutions as studied by means of the radiomicrometer: the conductivities, dissociations, and viscosities of solutions of electrolytes in aqueous, non-aqueous, and mixed solvents
Gespeichert in:
Format: | Buch |
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Sprache: | English |
Veröffentlicht: |
Washington, D.C.
Carnegie Institution of Washington
1915
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Schriftenreihe: | Publication / Carnegie Institution <Washington, DC>
210 |
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | 202 S. 25 cm |
Internformat
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245 | 1 | 0 | |a The absorption spectra of solutions as studied by means of the radiomicrometer |b the conductivities, dissociations, and viscosities of solutions of electrolytes in aqueous, non-aqueous, and mixed solvents |c by Harry C. Jones and collaborators |
264 | 1 | |a Washington, D.C. |b Carnegie Institution of Washington |c 1915 | |
300 | |a 202 S. |c 25 cm | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
490 | 1 | |a Publication / Carnegie Institution <Washington, DC> |v 210 | |
650 | 4 | |a Absorption spectra | |
650 | 4 | |a Dissociation | |
650 | 4 | |a Electrolytes |x Conductivity | |
650 | 4 | |a Solution (Chemistry) | |
650 | 4 | |a Viscosity | |
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Datensatz im Suchindex
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adam_text | THE ABSORPTION SPECTRA OF SOLUTIONS AS STUDIED
BY MEANS OF THE RADIOMICROMETER
THE CONDUCTIVITIES, DISSOCIATIONS, AND VISCOS
ITIES OF SOLUTIONS OF ELECTROLYTES
IN AQUEOUS, NON-AQUEOUS, AND
MIXED SOLVENTS
BY
HARRY C JONES AND COLLABORATORS
WASHINGTON, D C
PUBLISHED BY THE CARNEGIE INSTITUTION OF WASHINGTON
CONTENTS
CHAPTER I
THE ABSORPTION SPECTRA OP AQUEOUS SOIYUTIONS OF HYDRATED AND NON-
HYDRATED SALTS, AS STUDIED BY MEANS OF THE RADIOMICROMETER
Page
The Radiomicrometer 9
Method of Procedure 10
The Cells 11
Earlier Results 13
Effect of Slit-Width 13
Water Absorption 16
Effect of Slit-Width on the Absorption of Light by Water 18
Absorption of Light by Water as Affected by Hydrated and by Non-hydrated Salts 19
Method of Procedure
Results
Discussion of the Results
CHAPTER II
CONDUCTIVITIES, TEMPERATURE COEFFICIENTS OF CONDUCTIVITY, DISSOCIATIONS,
AND CONSTANTS OF CERTAIN ORGANIC ACIDS IN AQUEOUS SOLUTIONS
Introduction jJJ 47
Purpose of the Investigation j U 48
Experimental i j 48
Reagents J 49
Apparatus 49
Procedure » • 51
Cell Constants 51
Values 54
Limiting Conductivities of the Acids 55
Malic acid 57
Aconitic acid 57
m-Chlorobenzoic acid 57
p-Chlorobenzoic acid 57
o-Bromobenzoic acid 57
m-Bromobenzoic acid 57
m-Acetoxybenzoic acid 57
o-Sulphobenzoic acid 58
ra-Sulphobenzoic acid 58
p-Aminobenzensulphonic acid 58
Sebasic acid 58
Dissociation Constants 59
Summary 62
CHAPTER III
A PRELIMINARY STUDY OF THE CONDUCTIVITY OF CERTAIN ORGANIC ACIDS IN ETHYL
ALCOHOL OF 15°, 25°, AND 35°
Historical 64
Experimental 67
Results 73
Malonic acid 73
o-Chlorobenzoic acid 73
p-Chlorobenzoic acid 74
p-Bromobenzoic acid • 74
o-Nitrobenzoic acid 74
p-Nitrobenzoic acid 74
1, 2, 4, Dinitrobenzoic acid 75
1, 2, 4, Dihydroxybenzoic acid 75
Tetrachlorphthalic acid: 75
Malonic, and Change in Concentration 75
o-Chlorobenzoic and Change in Concentration 76
p-Chlorobenzoic and Change in Concentration 76
p-Bromobenzoic and Change in Concentration 76
6 STUDY OF ABSORPTION SPECTRA
Results—Continued Pae°
o-Nitrobenzoic and Change in Concentration 76
p-Nitrobenzoic and Change in Concentration 76
1, 2, 4, Dinitrobenzoic and Change in Concentration 76
1, 2, 4, Dihydroxybenzoic and Change in Concentration 76
Tetrachlorphthalic acid and Change in Concentration 76
Discussion of Results ^ 77
CHAPTER IV
THE CONDUCTIVITY AND VISCOSITY OF SOLUTIONS OF POTASSIUM IODIDE AND SODIUM
IODIDE IN MIXTURES OF ETHYL ALCOHOL AND WATER
Experimental 80
Pure Anhydrous Alcohol 80
Specific-Gravity Determinations 80
Mixed Solvents 81
Dissolved Salts 82
Pipettes 82
Conductivity Cells 82
Temperature Regulators 83
Corrections for Expansion and Contraction 84
Viscosities 85
Viscosity and Fluidity of Potassium Iodide in Alcohol-Water Mixtures 86
Temperature Coefficients of Fluidity of Potassium Iodide 87
Viscosity and Fluidity of Sodium Iodide in Alcohol-Water Mixtures 1 87
Conductivity of Potassium Iodide in Mixtures of Ethyl Alcohol and Water 88
Conductivity of Sodium Iodide in Mixtures of Ethyl Alcohol and Water 88
Discussion of the Results 89
Viscosity and Fluidity 89
Conductivity 91
Summary • 96
Conclusions ;!1 96
CHAPTER V
CONDUCTIVITY AND VISCOSITY OF SOLUTIONS OF RUBIDIUM SALTS IN MIXTURES OF
ACETONE AND WATER
Experimental 98
Conductivity Apparatus 98
Bridge 98
Cells 99
Constant Temperature Baths 99
Temperature Regulation 99
Viscosity Apparatus 100
Solvents 101
Water 101
Acetone 101
Mixtures of Acetone and Water 101
Solutions 102
Salts 102
Procedure 102
Conductivity Measurements 102
Temperature Coefficients 103
Molecular Conductivity of Rubidium Chloride 104
Molecular Conductivity of Rubidium Bromide 104
Molecular Conductivity of Rubidium Iodide 105
Molecular Conductivity of Rubidium Nitrate 106
Viscosity and Fluidity of Rubidium Chloride and Temperature Coefficients
of Fluidity 107
Viscosity and Fluidity of Rubidium Bromide and Temperature Coefficients
of Fluidity 108
Viscosity and Fluidity of Rubidium Iodide and Temperature Coefficients
of Fluidity 109
Viscosity and Fluidity of Rubidium Nitrate and Temperature Coefficients
of Fluidity 110
Comparison of the Viscosity and Fluidity values of Rubidium Bromide in
Acetone-water Mixtures Ill
Discussion Ill
Summary 116
CONTENTS 7
CHAPTER VI
THE CONDUCTIVITY AND VISCOSITY OF CERTAIN RUBIDIUM AND AMMONIUM SALTS IN
TERNARY MIXTURES OF GLYCEROL, ACETONK, AND WATER AT 15°, 25°, AND 35°
Page
Introduction 117
Experimental 119
Apparatus 119
Thermostats 119
Conductivity Apparatus 120
Viscosity Apparatus 120
Volumetric Apparatus 120
Solvents 120
Salts 122
Solutions , 122
Procedure 122
Viscosity Data 123
Conductivity Data 127
Discussion of Results 131
Summary 140
CHAPTER VII
DISCUSSION OF EVIDENCE ON THE SOLVATE THEORY OF SOLUTION OBTAINED IN THE
LABORATORIES OF THE JOHNS HOPKINS UNIVERSITY
Earlier Work 141
Relation between Lowering of the Freezing-point of Water and Water of Crystalli
zation of the Dissolved Substance 143
Approximate Composition of the Hydrates formed by Various Substances in Solution 145
Relation between the Minima in the Freezing-] oint Curves and the Minima in the
Boiling-point Curves - 147
Relation between Water of Crystallization and Temperature of Crystallization 148
Hydrate Theory in Aqueous Solutions becomes the Solvate Theory in Solutions in
General j : 149
Temperature Coefficients of Conductivity and Hydration 151
Relation between the Hydration of ithe Ions;and Their Ionic Volumes 155
Hydration of the Ions and the Velocities with which They Move 157
Dissociation as Measured by the I Freezing-point Method and by the Conductivity
Method :|J 158
Effect of one Salt with Hydrating Power on the Hydrates formed by a Second Salt
in the Same Solution I 161
Investigations in Mixed Solvents 162
Spectroscopic Evidence Bearing on the Solvate Theory of Solution 170
Work of Jones and Uhler 170
Work of Jones and Anderson 172
Work of Jones and Strong 175
Absorption Spectra of Neodymium Salts 178
a Bands 180
Effect of Rise in Temperature 181
Spectrophotographv of Chemical Reactions 183
Work of Jones and Guy on the Absorption Spectra of Solutions 185
Work of Jones, Shaeffer, and Paulus 188
Summary of the Lines of Evidence obtained in this Laboratory bearing on the
Solvate Theory of Solution 189
How the present Solvate Theory of Solution differs from the older Hydrate Theory 190
Significance of the Solvate Theory of Solution 192
The Solvate Theory and the Theory of Electrolytic Dissociation 193
Does the Solvate Theory help to explain any of the Apparent Exceptions to the
Theory of Electrolytic Dissociation? 194
Does the Solvate Theory aid us in Explaining the Facts of Chemistry in General
and Physical Chemistry in Particular? ; 196
Why is the Nature of Solutions of such Vital Importance not only for Chemistry
but for Science in General? 197
Bibliography 199
Papers 199
Monographs 202
|
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dewey-search | 535.3 |
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spelling | The absorption spectra of solutions as studied by means of the radiomicrometer the conductivities, dissociations, and viscosities of solutions of electrolytes in aqueous, non-aqueous, and mixed solvents by Harry C. Jones and collaborators Washington, D.C. Carnegie Institution of Washington 1915 202 S. 25 cm txt rdacontent n rdamedia nc rdacarrier Publication / Carnegie Institution <Washington, DC> 210 Absorption spectra Dissociation Electrolytes Conductivity Solution (Chemistry) Viscosity Leitfähigkeit (DE-588)4120663-0 gnd rswk-swf Lösung Chemie (DE-588)4036159-7 gnd rswk-swf Absorptionsspektrum (DE-588)4141130-4 gnd rswk-swf Viskosität (DE-588)4063625-2 gnd rswk-swf Absorptionsspektrum (DE-588)4141130-4 s Lösung Chemie (DE-588)4036159-7 s DE-188 Leitfähigkeit (DE-588)4120663-0 s Viskosität (DE-588)4063625-2 s Jones, Harry Clary 1865-1916 Sonstige (DE-588)117655600 oth Carnegie Institution <Washington, DC> Publication 210 (DE-604)BV035415500 210 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017661774&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | The absorption spectra of solutions as studied by means of the radiomicrometer the conductivities, dissociations, and viscosities of solutions of electrolytes in aqueous, non-aqueous, and mixed solvents Absorption spectra Dissociation Electrolytes Conductivity Solution (Chemistry) Viscosity Leitfähigkeit (DE-588)4120663-0 gnd Lösung Chemie (DE-588)4036159-7 gnd Absorptionsspektrum (DE-588)4141130-4 gnd Viskosität (DE-588)4063625-2 gnd |
subject_GND | (DE-588)4120663-0 (DE-588)4036159-7 (DE-588)4141130-4 (DE-588)4063625-2 |
title | The absorption spectra of solutions as studied by means of the radiomicrometer the conductivities, dissociations, and viscosities of solutions of electrolytes in aqueous, non-aqueous, and mixed solvents |
title_auth | The absorption spectra of solutions as studied by means of the radiomicrometer the conductivities, dissociations, and viscosities of solutions of electrolytes in aqueous, non-aqueous, and mixed solvents |
title_exact_search | The absorption spectra of solutions as studied by means of the radiomicrometer the conductivities, dissociations, and viscosities of solutions of electrolytes in aqueous, non-aqueous, and mixed solvents |
title_full | The absorption spectra of solutions as studied by means of the radiomicrometer the conductivities, dissociations, and viscosities of solutions of electrolytes in aqueous, non-aqueous, and mixed solvents by Harry C. Jones and collaborators |
title_fullStr | The absorption spectra of solutions as studied by means of the radiomicrometer the conductivities, dissociations, and viscosities of solutions of electrolytes in aqueous, non-aqueous, and mixed solvents by Harry C. Jones and collaborators |
title_full_unstemmed | The absorption spectra of solutions as studied by means of the radiomicrometer the conductivities, dissociations, and viscosities of solutions of electrolytes in aqueous, non-aqueous, and mixed solvents by Harry C. Jones and collaborators |
title_short | The absorption spectra of solutions as studied by means of the radiomicrometer |
title_sort | the absorption spectra of solutions as studied by means of the radiomicrometer the conductivities dissociations and viscosities of solutions of electrolytes in aqueous non aqueous and mixed solvents |
title_sub | the conductivities, dissociations, and viscosities of solutions of electrolytes in aqueous, non-aqueous, and mixed solvents |
topic | Absorption spectra Dissociation Electrolytes Conductivity Solution (Chemistry) Viscosity Leitfähigkeit (DE-588)4120663-0 gnd Lösung Chemie (DE-588)4036159-7 gnd Absorptionsspektrum (DE-588)4141130-4 gnd Viskosität (DE-588)4063625-2 gnd |
topic_facet | Absorption spectra Dissociation Electrolytes Conductivity Solution (Chemistry) Viscosity Leitfähigkeit Lösung Chemie Absorptionsspektrum Viskosität |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017661774&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
volume_link | (DE-604)BV035415500 |
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