Colloids in agrochemicals:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Weinheim
WILEY-VCH
2009
|
| Schriftenreihe: | Colloids and interface science series
5 |
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XVI, 284 S. Ill., graph. Darst. |
| ISBN: | 9783527314652 |
Internformat
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| 245 | 1 | 0 | |a Colloids in agrochemicals |c Tharwat F. Tadros |
| 264 | 1 | |a Weinheim |b WILEY-VCH |c 2009 | |
| 300 | |a XVI, 284 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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| 490 | 1 | |a Colloids and interface science series |v 5 | |
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Datensatz im Suchindex
| _version_ | 1805092556387647488 |
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| adam_text |
VII CONTENTS PREFACE XV 1 CENERAI INTRODUCTION 3 FURTHER READING 5 2
GENERAL CLASSIFICATION OF SURFACE-ACTIVE AGENTS USED IN AGROCHEMICAL
FORMULATIONS 7 2.1 ANIONIE SURFACTANTS 7 2.1.1 CARBOXYLATES 8 2.1.2
SULFATES 8 2.1.3 SULFONATES 9 2.1.4 PHOSPHATE-CONTAINING ANIONIE
SURFACTANTS 10 2.2 CATIONIC SURFACTANTS 10 2.3 AMPHOTERIC (ZWITTERIONIC)
SURFACTANTS LI 2.4 NONIONIC SURFACTANTS 12 2A.I ALCOHOL ETHOXYLATES 12
2.4.2 ALKYLPHENOL ETHOXYLATES 13 2.4.3 FATTY ACID ETHOXYLATES 13 2.4.4
SORBITAN ESTERS AND THEIR ETHOXYLATED DERIVATIVES (SPANS AND TWEENS) 14
2.4.5 ETHOXYLATED FATS AND OILS 15 2.4.6 AMINE ETHOXYLATES 35 2.4.7
SURFACTANTS DERIVED FROM MONO- AND POLYSACCHARIDES 35 2.5 SPECIALITY
SURFACTANTS - FLUOROCARBON AND SILICONE SURFACTANTS 16 2.6 POLYMERIC
SURFACTANTS 17 2.6.1 ETHYLENE OXIDE-PROPYLENE OXIDE COPOLYMERS (EO/PO)
17 REFERENCES 18 3 PHYSICAL CHEMISTRY OF SURFACTANT SOLUTIONS 19 3.
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/988811553 DIGITALISIERT
DURCH VIII I CONTENTS 3.3.1 KINETIC ASPECTS 25 3.3.2 EQUILIBRIUM
ASPECTS: THERMODYNAMICS OF MICELLIZATION 26 3.3.3 PHASE SEPARATION MODEL
27 3.3.4 MASS ACTION MODEL 28 3.3.5 ENTHALPY AND ENTROPY OF
MICELLIZATION 30 3.3.6 DRIVING FORCE FOR MICELLE FORMATION 31 3.4
MICELLIZATION IN SURFACTANT MIXTURES (MIXED MICELLES) 33 3.4.1
SURFACTANT MIXTURES WITH NO NET INTERACTION 33 3.4.2 SURFACTANT MIXTURES
WITH A NET INTERACTION 34 3.5 SURFACTANT-POLYMER INTERACTION 35 3.5.1
FACTORS INFLUENCING THE ASSOCIATION BETWEEN SURFACTANT AND POLYMER 36
3.5.2 DRIVING FORCE FOR SURFACTANT-POLYMER INTERACTION 37 3.5.3
STRUCTURE OF SURFACTANT-POLYMER COMPLEXES 38 3.5.4
SURFACTANT-HYDROPHOBICALLY MODIFIED POLYMER INTERACTION 38 REFERENCES 39
4 INTERFACIAL ASPECTS OF AGROCHEMICAL FORMULATIONS 41 4.1 INTRODUCTION
41 4.2 EQUILIBRIUM ADSORPTION OF SURFACTANTS AT THE AIR/LIQUID AND
LIQUID/LIQUID INTERFACES 41 4.3 THE GIBBS ADSORPTION ISOTHERM 43 4.4
DYNAMIC PROCESSES OF ADSORPTION 46 CONTENTS IIX 5 INTERACTION FORCES
BETWEEN PARTICLES OR DROPLETS IN AGROCHEMICAL DISPERSIONS (SUSPENSION
CONCENTRATES OR EMULSIONS, EWS) AND THEIR ROLE IN COLLOID STABILITY 77
5.1 INTRODUCTION 77 5.2 VAN DER WAALS ATTRACTION 77 5.3 ELECTRICAL
DOUBLE LAYER REPULSION 79 5.4 TOTAL ENERGY OF INTERACTION:
DERYAGUIN-LANDAU-VERWEY-OVERBEEK (DLVO) THEORY 81 5.5 CRITERIA FOR
STABILIZATION OF DISPERSIONS WITH DOUBLE LAYER INTERACTION 83 5.5.1 THE
ZETA POTENTIAL 83 5.6 STERIC STABILIZATION OF DISPERSIONS 85 5.7
INTERACTION BETWEEN PARTICLES OR DROPLETS CONTAINING ADSORBED POLYMERIC
SURFACTANT LAYERS 85 5.7.1 MIXING INTERACTION, G MIX 86 5.7.2 ELASTIC
INTERACTION, G D 87 5.7.3 CRITERIA FOR EFFECTIVE STERIC STABILIZATION 89
5.8 FLOCCULATION OF STERICALLY STABILIZED DISPERSIONS 90 REFERENCES 91 6
EMULSION CONCENTRATES (EWS) 93 6.1 INTRODUCTION 93 6.2 FORMATION OF
EMULSIONS 94 6.3 MECHANISM OF EMULSIFICATION 95 6.4 METHODS OF
EMULSIFICATION 96 X I CONTENTS 6.8 FLOCCULATION OF EMULSIONS 114 6.8.1
GENERAL RULES FOR REDUCING (ELIMINATING) FLOCCULATION 115 6.8.1.1
CHARGE-STABILIZED EMULSIONS, E.G. USING IONIC SURFACTANTS 335 6.8.1.2
STERICALLY STABILIZED EMULSIONS 115 6.9 OSTWALD RIPENING 115 6.10
COALESCENCE OF EMULSIONS 337 6.10.1 RATE OF COALESCENCE 119 6.11 PHASE
INVERSION 339 6.12 EXPERIMENTAL METHODS FOR ASSESSMENT OF EMULSION
STABILITY 320 6.12.1 ASSESSMENT OF CREAMING OR SEDIMENTATION 323 6.12.2
ASSESSMENT OF EMULSION FLOCCULATION 122 6.12.3 ASSESSMENT OF OSTWALD
RIPENING 323 6.12.4 ASSESSMENT OF COALESCENCE 323 6.12.5 ASSESSMENT OF
PHASE INVERSION 323 REFERENCES 123 7 SUSPENSION CONCENTRATES (SCS) 125
7.1 INTRODUCTION 125 7.2 PREPARATION OF SUSPENSION CONCENTRATES AND THE
ROLE OF SURFACTANTS/DISPERSING AGENTS 326 7.3 WETTING OF THE
AGROCHEMICAL POWDER 126 7.3.1 MEASUREMENT OF CONTACT ANGLES OF LIQUIDS
AND SURFACTANT SOLUTIONS ON POWDERS 329 7.3.2 DISPERSION AND MILLING 129
7.3.3 EFFECT OF SURFACTANT ADSORPTION 130 7.4 CONTROL OF THE PHYSICAL
STABILITY OF SUSPENSION CONCENTRATES 132 CONTENTS I XI 7.5.2.3
MEASUREMENT OF CRYSTAL GROWTH (OSTWALD RIPENING) 350 7.6 BULK PROPERTIES
OF SUSPENSION CONCENTRATES 151 7.6.1 EQUILIBRIUM SEDIMENT VOLUME (OR
HEIGHT) AND REDISPERSION 353 7.6.2 RHEOLOGICAL MEASUREMENTS 151 7.6.2.1
ASSESSMENT OF SEDIMENTATION 352 7.6.2.2 ASSESSMENT OF FLOCCULATION 355
7.6.3 TIME EFFECTS DURING FLOW - THIXOTROPY 357 7.6.4 CONSTANT STRESS
(CREEP) EXPERIMENTS 358 7.6.5 DYNAMIC (OSCILLATORY) MEASUREMENTS 159
REFERENCES 164 8 OIL-BASED SUSPENSION CONCENTRATES 365 8.1 INTRODUCTION
365 8.2 STABILITY OF SUSPENSIONS IN POLAR MEDIA 366 8.3 STABILITY OF
SUSPENSIONS IN NONPOLAR MEDIA 368 8.3.1 CHARACTERIZATION OF THE ADSORBED
POLYMER LAYER 369 8.4 THEORY OF STERIC STABILIZATION 369 8.4.1 CRITERIA
FOR EFFECTIVE STERIC STABILIZATION 172 8.5 SETTLING OF SUSPENSIONS 372
8.5.1 PREVENTION OF FORMATION OF DILATANT SEDIMENTS 172 8.5.2 EXAMPLES
OF SUSPENDING AGENTS THAT CAN BE APPLIED FOR PREVENTION OF SETTLING IN
NON-AQUEOUS SUSPENSIONS 374 8.6 EMULSIFICATION OF OIL-BASED SUSPENSIONS
376 8.6.1 MECHANISM OF SPONTANEOUS EMULSIFICATION AND THE ROLE OF MIXED
SURFACTANT FILM 176 8.6.2 POLYMERIC SURFACTANTS FOR OIL-BASED
SUSPENSIONS AND THE CHOICE OFEMULSIFIER XLI I CONTENTS 9.4.7 PREVENTION
OF CRYSTALLIZATION 190 9.4.8 MODEL SUSPOEMULSION OF POLYSTYRENE LATEX
AND ISOPARAFFINIC OIL STABILIZED WITH SYNPERONIC PE(PEO-PPO-PEO A-B-A
BLOCK COPOLYMER) 191 9.4.9 MODEL SYSTEMS OF POLYSTYRENE LATEX WITH
GRAFTED PEO CHAINS AND HEXADECANE EMULSIONS 192 9.5 CONCLUSIONS 195
REFERENCES 196 10 MICROEMULSIONS 397 10.1 INTRODUCTION 197 10.2
THERMODYNAMIC DEFINITION OF MICROEMULSIONS 398 10.3 APPLICATION IN
AGROCHEMICALS 199 10.4 BASIC PRINCIPLES OF MICROEMULSION FORMATION AND
THERMODYNAMIC STABILITY 200 10.4.1 MIXED FILM THEORIES 200 10.4.2
SOLUBILIZATION THEORIES 202 10.4.3 THERMODYNAMIC THEORY OF MICROEMULSION
FORMATION AND STABILITY 204 10.4.4 REASON FOR COMBINING TWO SURFACTANTS
205 10.4.5 FACTORS DETERMINING W/O VERSUS O/W MICROEMULSIONS 206 10.5
CHARACTERIZATION OF MICROEMULSIONS USING SCATTERING TECHNIQUES 207
10.5.1 TIME-AVERAGED (STATIC) LIGHT SCATTERING 208 10.5.1.1 CALCULATION
OF DROPLET SIZE FROM INTERFACIAL AREA 210 CONTENTS XIII 12
CONTROLLED-RELEASE FORMULATIONS 235 12.1 INTRODUCTION 235 12.2
MICROENCAPSULATION 235 12.3 MECHANISM OF RELEASE OF ACTIVE INGREDIENT
FROM MICROCAPSULES 237 12.4 ENCAPSULATION BY PHASE SEPARATION FROM
AQUEOUS SOLUTION 237 12.5 MICROENCAPSULATION OF SOLID PARTICLES 238 12.6
CONTROLLED RELEASE OF AGROCHEMICALS FROM MATRIX-BASED MICROPARTICLES 239
12.7 MECHANISM OF CONTROLLED RELEASE FROM MICROPARTICLES 240 12.8
CONTROLLED RELEASE FROM GRANULES 242 REFERENCES 245 13 BASIC PRINCIPLES
OF SELECTION OF ADJUVANTS IN AGROCHEMICAL FORMULATIONS 247 13.1
INTRODUCTION 247 13.2 INTERACTIONS AT THE AIR/SOLUTION INTERFACE AND
THEIR EFFECT ON DROPLET FORMATION 253 13.3 SPRAY IMPACTION AND ADHESION
255 13.4 DROPLET SLIDING AND SPRAY RETENTION 258 13.5 WETTING AND
SPREADING 262 13.6 EVAPORATION OF SPRAY DROPS AND DEPOSIT FORMATION 266
13.7 SOLUBILIZATION AND ITS EFFECT ON TRANSPORT 268 13.8 INTERACTION
BETWEEN SURFACTANT, AGROCHEMICAL AND TARGET SPECIES 271 REFERENCES 272
SUBJECT INDEX 273 |
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| spelling | Colloids in agrochemicals Tharwat F. Tadros Weinheim WILEY-VCH 2009 XVI, 284 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Colloids and interface science series 5 Agricultural chemicals Colloids Industrial applications Agrochemikalie (DE-588)4238318-3 gnd rswk-swf Kolloidchemie (DE-588)4134420-0 gnd rswk-swf Kolloidchemie (DE-588)4134420-0 s Agrochemikalie (DE-588)4238318-3 s DE-604 Tadros, Tharwat F. 1937-2018 Sonstige (DE-588)129740837 oth Colloids and interface science series 5 (DE-604)BV023312660 5 text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3112896&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017637387&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Colloids in agrochemicals Colloids and interface science series Agricultural chemicals Colloids Industrial applications Agrochemikalie (DE-588)4238318-3 gnd Kolloidchemie (DE-588)4134420-0 gnd |
| subject_GND | (DE-588)4238318-3 (DE-588)4134420-0 |
| title | Colloids in agrochemicals |
| title_auth | Colloids in agrochemicals |
| title_exact_search | Colloids in agrochemicals |
| title_full | Colloids in agrochemicals Tharwat F. Tadros |
| title_fullStr | Colloids in agrochemicals Tharwat F. Tadros |
| title_full_unstemmed | Colloids in agrochemicals Tharwat F. Tadros |
| title_short | Colloids in agrochemicals |
| title_sort | colloids in agrochemicals |
| topic | Agricultural chemicals Colloids Industrial applications Agrochemikalie (DE-588)4238318-3 gnd Kolloidchemie (DE-588)4134420-0 gnd |
| topic_facet | Agricultural chemicals Colloids Industrial applications Agrochemikalie Kolloidchemie |
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