Emulsion science and technology:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH-Verl.
2009
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XVIII, 326 S. Ill., graph. Darst. 25 cm |
| ISBN: | 9783527325252 |
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Datensatz im Suchindex
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CONTENTS PREFACE XIII LIST OF CONTRIBUTORS XV 1 EMULSION SCIENCE AND
TECHNOLOGY: A GENERAL INTRODUCTION 1 THARWAT F. TADROS 1.1 INTRODUCTION
1 1.2 INDUSTRIAL APPLICATIONS OF EMULSIONS 3 1.3 THE PHYSICAL CHEMISTRY
OF EMULSION SYSTEMS 4 1.3.1 THE INTERFACE (GIBBS DIVIDING LINE) 4 1.4
THE THERMODYNAMICS OF EMULSION FORMATION AND BREAKDOWN 5 1.5 INTERACTION
ENERGIES (FORCES) BETWEEN EMULSION DROPLETS AND THEIR COMBINATIONS 7
1.5.1 VAN DER WAALS ATTRACTION 7 1.5.2 ELECTROSTATIC REPULSION 9 1.5.3
STERIC REPULSION 11 1.6 ADSORPTION OF SURFACTANTS AT THE LIQUID/LIQUID
INTERFACE 12 1.6.1 THE GIBBS ADSORPTION ISOTHERM 13 1.6.2 MECHANISM OF
EMULSIFICATION 16 1.6.3 METHODS OF EMULSIFICATION 18 1.6.4 ROLE OF
SURFACTANTS IN EMULSION FORMATION 19 1.6.5 ROLE OF SURFACTANTS IN
DROPLET DEFORMATION 21 1.7 SELECTION OF EMULSIFIERS 25 1.7.1 THE
HYDROPHILIC-IIPOPHILIC BALANCE (HLB) CONCEPT 25 1.7.2 THE PHASE
INVERSION TEMPERATURE (PIT) CONCEPT 27 1.7.3 THE COHESIVE ENERGY RATIO
(CER) CONCEPT 29 BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/991677595 DIGITALISIERT DURCH VI CONTENTS 1.9.1.1
FLOCCULATION OF ELECTROSTATICALLY STABILIZED EMULSIONS 38 1.9.1.2
FLOCCULATION OF STERICALLY STABILIZED EMULSIONS 40 1.9.2 GENERAL RULES
FOR REDUCING (ELIMINATING) FLOCCULATION 41 1.10 OSTWALD RIPENING 41 1.11
EMULSION COALESCENCE 43 1.11.1 RATE OF COALESCENCE 44 1.11.2 PHASE
INVERSION 45 1.12 RHEOLOGY OF EMULSIONS 46 1.12.1 INTERFACIAL RHEOLOGY
46 1.12.2 MEASUREMENT OF INTERFACIAL VISCOSITY 47 1.12.3 INTERFACIAL
DILATIONAL ELASTICITY 47 1.12.4 INTERFACIAL DILATIONAL VISCOSITY 48
1.12.5 NON-NEWTONIAN EFFECTS 49 1.12.6 CORRELATION OF INTERFACIAL
RHEOLOGY WITH EMULSION STABILITY 49 1.12.6.1 MIXED SURFACTANT FILMS 49
1.12.6.2 PROTEIN FILMS 49 1.12.7 BULK RHEOLOGY OF EMULSIONS 50 1.12.8
RHEOLOGY OF CONCENTRATED EMULSIONS 53 1.12.9 INFLUENCE OF DROPLET
DEFORMABILITY ON EMULSION RHEOLOGY 53 1.12.10 VISCOELASTIC PROPERTIES OF
CONCENTRATED EMULSIONS 53 REFERENCES 55 2 STABILIZATION OF EMULSIONS,
NANOEMULSIONS AND MULTIPLE EMULSIONS USIN CONTENTS VII 3.2 MATERIALS AND
METHODS 68 3.3 RESULTS AND DISCUSSION 69 3.4 CONCLUSIONS 73 REFERENCES
73 4 ENHANCEMENT OF STABILIZATION AND PERFORMANCE OF PERSONAL CARE
FORMULATIONS USING POLYMERIC SURFACTANTS 75 THARWAT F. TADROS, MARTINE
LEMMENS, BART LEVECKE, AND KARL BOOTEN 4.1 INTRODUCTION 75 4.2
EXPERIMENTAL 76 4.3 RESULTS AND DISCUSSION 76 4.3.1 MASSAGE LOTION 76
4.3.2 HYDRATING SHOWER GEL 79 4.3.3 SOFT CONDITIONER 80 4.3.4 SUN SPRAY
SPF19 81 4.4 CONCLUSIONS 82 REFERENCES 81 5 EFFECT OF AN EXTERNAL FORCE
FIELD ON SELF-ORDERING OF THREE-PHASE CELLULAR FLUIDS IN TWO DIMENSIONS
83 WALDEMAR NOWICKI AND GRAZYNA NOWICKA 5.1 INTRODUCTION 83 5.2 THE
MODEL 84 5.3 RESULTS AND DISCUSSION 85 5.3.1 ENERGIES OF CLUSTER
INSERTION AND TRANSFORMATION 85 5.3.2 EVOLUTION OF THE SYSTEM IN A
GRAVITATIONAL FIELD 90 5.4 CONCLUSIONS 93 REFERENCES 94 6 THE PHYSICAL
CHEMISTRY AND SENSORY PROPERTIES OF COSMETIC EMULSIONS: APPLICATIO VIII
CONTENTS 7 NANOPARTICLE PREPARATION BY MINIEMULSION POLYMERIZATION 107
MAN WU, ELISE ROTUREAU, EMMANUELLE MARIE, EDITH DELLACHERIE, AND ALAIN
DURAND 7.1 INTRODUCTION 107 7.2 EXPERIMENTAL 108 7.2.1 MATERIALS 108
7.2.2 EMULSION PREPARATION 108 7.2.3 POLYMERIZATION 108 7.2.4 SIZE
MEASUREMENT OF THE EMULSION DROPLETS 108 7.2.5 PARTICLE CHARACTERIZATION
109 7.3 RESULTS AND DISCUSSION 109 7.3.1 SYNTHESIS OF HYDROPHOBICALLY
MODIFIED DEXTRANS 109 7.3.2 PREPARATION OF O/W MINIEMULSIONS 111 7.3.2.1
CONTROL OF INITIAL DROPLET SIZE BY PROCESS VARIABLES 111 7.3.2.2
INFLUENCE OF POLYMER STRUCTURE ON INITIAL DROPLET SIZE 112 7.3.3
STABILITY OF MINIEMULSIONS WITHIN POLYMERIZATION DURATION 114 7.3.3.1
MECHANISM AND KINETICS OF MINIEMULSION POLYMERIZATION 114 7.3.3.2
MECHANISM AND RATE OF EMULSION AGING 116 7.3.3.3 VARIATION OF THE RATE
OF EMULSION AGING WITH POLYMERIZATION CONDITIONS 118 7.3.4 PREPARATION
OF DEFINED NANOPARTIDES WITH VARIOUS MONOMERS 123 CONTENTS IX 8.7
EMULSIFICATION USING AN ASYMMETRIC STRAIGHT-THROUGH MC ARRAY 250 8.8
CONDUSIONS AND OUTLOOK 252 REFERENCES 254 9 ISOTROPIC AND ANISOTROPIC
METAL NANOPARTIDES PREPARED BY INVERSE MICROEMULSION 257 IGNDC CAPEK 9.1
INTRODUCTION 157 9.1.1 PROPERTIES OF NANOSCALE PARTIDES 257 9.1.2
PRODUCTION OF NANOPARTIDES AND MICROEMULSIONS 158 9.2 GENERAL ASPECTS OF
MICROEMULSIONS 259 9.2.1 DROPLET DIMENSIONS 160 9.2.2 THE USE OF W/O
MICROEMULSIONS 262 9.2.3 NANOPARTIDE PREPARATION 262 9.2.4
SURFACTANT-BASED METHODS 164 9.2.5 COPREDPITATION 266 9.3 ISOTROPIC
NANOPARTIDES 266 9.4 ANISOTROPIC NANOPARTIDES 267 9.5 CONDUSIONS AND
OUTLOOK 179 REFERENCES 185 10 PREPARATION OF NANOEMULSIONS BY
SPONTANEOUS EMULSIFICATION AND STABILIZATION WITH
POLY(CAPROLACTONE)-6-POLY(ETHYLENE OXIDE) BLOCK COPOLYMERS 292 EMMANUEL
LANDREAU, YOUSSEFAGUNI, THIERRY HAMAIDE, AND YVES CHEVALIER 10.1
INTRODUCTION 191 10.1.1 BLOCK COPOLYMERS 192 10.1.1.1 SPONTANEOUS
EMULSIFICATION 193 10.1.1.2 BIODEGRADABILITY AND BIOCOMPATIBILITY 194
10.1.2 BLOCK COPOLYMER MICELLES 194 10.1. X CONTENTS 11 ROUTES TOWARDS
THE SYNTHESIS OF WATERBORNE ACRYLIC/CLAY NANOCOMPOSITES 209 GABRIELA
DIACONU, MARIA PAULIS, AND JOSE R. LEIZA 11.1 INTRODUCTION 209 11.2
EXPERIMENTAL 212 11.2.1 MATERIALS 212 11.2.2 SYNTHESIS OF WATERBORNE
(MMA-BA)/MMT NANOCOMPOSITES BY EMULSION POLYMERIZATION 213 11.2.3
SYNTHESIS OF WATERBORNE (MMA-BA)/MMT NANOCOMPOSITES BY MINIEMULSION
POLYMERIZATION 224 11.2.4 CHARACTERIZATION AND MEASUREMENTS 225 11.3
RESULTS AND DISCUSSION 217 11.3.1 WATERBORNE NANOCOMPOSITES BY EMULSION
POLYMERIZATION 227 11.3.2 WATERBORNE NANOCOMPOSITES BY MINIEMULSION
POLYMERIZATION 229 11.4 CONDUSIONS 226 REFERENCES 226 12 PREPARATION
CHARACTERISTICS OF GIANT VESICLES WITH CONTROLLED SIZE AND HIGH
ENTRAPMENT EFFICIENCY USING MONODISPERSE WATER-IN-OIL EMULSIONS 229
TAKASHI KUROIWA, MITSUTOSHI NAKAJIMA, KUNIHIKO UEMURA, SEIGO SATO,
SUKEKUNI MUKATAKA, AND SOSAKU ICHIKAWA 12.1 INTRODUCTION 229 12.2
MATERIALS AND METHODS 230 12.2.1 MATERIALS 230 12.2.2 PREPARATION OF W/O
EMULSIONS USING MC EMULSIFICATION 230 12.2.3 FORMATION OF GVS 231
CONTENTS XI 13.4.1 KINETIC AND MOLECULAR WEIGHT PARAMETERS 281 13.4.2
X-RAY DIFFRACTION STUDIES 284 13.4.2.1 HOMOPOLYMERS 284 13.4.2.2
COPOLYMERS 288 13.4.3 THERMAL AND MECHANICAL PROPERTIES 290 13.4.3.1
POLYSTYRENE AND POLY(METHYL METHACRYLATE) NANOCOMPOSITES 290 13.4.3.2
POLYFETHYLENE OXIDE) NANOCOMPOSITES 293 13.5 POLYMER-INORGANIC
NANOCOMPOSITES 296 13.6 GENERA] 301 13.7 CONDUSIONS AND OUTLOOK 302
REFERENCES 310 INDEX 317 |
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| indexdate | 2024-07-20T10:12:16Z |
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| isbn | 9783527325252 |
| language | English |
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| subject_GND | (DE-588)4014626-1 |
| title | Emulsion science and technology |
| title_auth | Emulsion science and technology |
| title_exact_search | Emulsion science and technology |
| title_full | Emulsion science and technology ed. by Tharwat F. Tadros |
| title_fullStr | Emulsion science and technology ed. by Tharwat F. Tadros |
| title_full_unstemmed | Emulsion science and technology ed. by Tharwat F. Tadros |
| title_short | Emulsion science and technology |
| title_sort | emulsion science and technology |
| topic | Emulsions Emulsion (DE-588)4014626-1 gnd |
| topic_facet | Emulsions Emulsion |
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