Physics and chemistry of interfaces:
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
WILEY-VCH
2008
|
| Ausgabe: | 2., rev. and enl. ed., 2. reprint |
| Schriftenreihe: | Physics textbook
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XII, 386 S. Ill., graph. Darst. 240 mm x 170 mm |
| ISBN: | 3527406298 9783527406296 |
Internformat
MARC
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| 020 | |a 9783527406296 |9 978-3-527-40629-6 | ||
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| 100 | 1 | |a Butt, Hans-Jürgen |d 1961- |e Verfasser |0 (DE-588)110921550 |4 aut | |
| 245 | 1 | 0 | |a Physics and chemistry of interfaces |c Hans Jürgen Butt ; Karlheinz Graf ; Michael Kappl |
| 250 | |a 2., rev. and enl. ed., 2. reprint | ||
| 264 | 1 | |a Weinheim |b WILEY-VCH |c 2008 | |
| 300 | |a XII, 386 S. |b Ill., graph. Darst. |c 240 mm x 170 mm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Physics textbook | |
| 650 | 4 | |a Grenzflächenchemie - Lehrbuch | |
| 650 | 4 | |a Grenzflächenphysik - Lehrbuch | |
| 650 | 4 | |a Surface chemistry | |
| 650 | 4 | |a Surfaces (Physics) | |
| 650 | 0 | 7 | |a Grenzflächenphysik |0 (DE-588)4452968-5 |2 gnd |9 rswk-swf |
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| 700 | 1 | |a Graf, Karlheinz |d 1966- |e Verfasser |0 (DE-588)120729075 |4 aut | |
| 700 | 1 | |a Kappl, Michael |d 1963- |e Verfasser |0 (DE-588)128798548 |4 aut | |
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| 883 | 1 | |8 2\p |a cgwrk |d 20201028 |q DE-101 |u https://d-nb.info/provenance/plan#cgwrk | |
Datensatz im Suchindex
| _version_ | 1804139184039919616 |
|---|---|
| adam_text | Contents
Preface
XI
1
Introduction
1
2 Liquid
surfaces
5
2.1
Microscopic pictare
of the liquid
surface
.................... 5
2.2
Surface tension
................................. 6
2.3
Equation of Young and Laplace
......................... 9
2.3.1
Curved liquid surfaces
......................... 9
2.3.2
Derivation of the Young-Laplace equation
.............. 11
2.3.3
Applying the Young-Laplace equation
................. 12
2.4
Techniques to measure the surface tension
................... 13
2.5
The Kelvin equation
............................... 16
2.6
Capillary condensation
............................. 19
2.7
Nucleation theory
................................ 22
2.8
Summary
.................................... 25
2.9
Exercises
.................................... 26
3
Thermodynamics of interfaces
29
3.1
The surface excess
............................... 29
3.2
Fundamental thermodynamic relations
..................... 32
3.2.1
Internal energy and Helmholtz energy
................. 32
3.2.2
Equilibrium conditions
......................... 33
3.2.3
Location of the interface
........................ 34
3.2.4
Gibbs energy and definition of the surface tension
........... 35
3.2.5
Helmholtz surface energy,
interfacial
enthalpy, and Gibbs surface energy
36
3.3
The surface tension of pure liquids
....................... 37
3.4
Gibbs adsorption isotherm
........................... 39
3.4.1
Derivation
................................ 39
3.4.2
System of two components
....................... 40
3.4.3
Experimental aspects
.......................... 41
3.4.4
The
Marangoni
effect
.......................... 42
3.5
Summary
.................................... 43
3.6
Exercises
.................................... 44
Pkysirs and Chemistry of Interfaces. Secnnd, Revised and Enlarged Editiim. Hans-
Jürgen
Butt. Karihemz Graf. Michael KappJ
Copyright
© 2006
Wiley-VCH
Verlag
GmbH
&
Co. KOaA. Weinheim
ISBN:
3-527-40629-8
VI
Contents
The electric double layer
45
4.1
Introduction
................................... 45
4.2
Poisson-Boltzmann theory of the diffuse double layer
............. 46
4.2.1
The Poisson-Boltzmann equation
................... 46
4.2.2
Planar surfaces
............................. 47
4.2.3
The full one-dimensional case
..................... 49
4.2.4
The
Grahame
equation
......................... 52
4.2.5
Capacity of the diffuse electric double layer
.............. 53
4.3
Beyond Poisson-Boltzmann theory
....................... 54
4.3.1
Limitations of the Poisson-Boltzmann theory
............. 54
4.3.2
The Stern layer
............................. 55
4.4
The Gibbs free energy of the electric double layer
............... 57
4.5
Summary
.................................... 58
4.6
Exercises
.................................... 59
Effects at charged interfaces
61
5.1
Electrocapillarity
................................ 61
5.1.1
Theory
................................. 62
5.1.2
Measurement of electrocapillarity
................... 64
5.2
Examples of charged surfaces
.......................... 65
5.2.1
Mercury
................................. 66
5.2.2
Silveriodide
.............................. 67
5.2.3
Oxides
................................. 69
5.2.4
Mica
.................................. 70
5.2.5
Semiconductors
............................. 71
5.3
Measuring surface charge densities
....................... 73
5.3.1
Potentiometric colloid titration
..................... 73
5.3.2
Capacitances
.............................. 74
5.4
Electrokinetic phenomena: The
zeta
potential
................. 76
5.4.1
The Navier-Stokes equation
...................... 77
5.4.2
Electro-osmosis and streaming potential
................ 78
5.4.3
Electrophoresis and sedimentation potential
.............. 80
5.5
Types of potentials
............................... 82
5.6
Summary
.................................... 84
5.7
Exercises
.................................... 84
і
Surface forces
85
6.1
Van
der Waals
forces between molecules
.................... 85
6.2
The van
der Waals
force between macroscopic solids
............. 89
6.2.1
Microscopic approach
......................... 89
6.2.2
Macroscopic calculation
—
Lifshitz theory
.............. 92
6.2.3
Surface energy and
Hamaker
constant
................. 96
6.3
Concepts for the description of surface forces
................. 98
6.3.1
The Derjaguin approximation
..................... 98
6.3.2
The disjoining pressure
......................... 101
6.4
Measurement of surface forces
......................... 101
Contents
VII
6.5
The electrostatic double-layer force
...................... 103
6.5.1
General equations
............................ 103
6.5.2
Electrostatic interaction between two identical surfaces
........ 106
6.5.3
The DLVO theory
............................ 108
6.6
Beyond DLVO theory
.............................. 110
6.6.1
The solvation force and confined liquids
................ 110
6.6.2
Non DĽVO
forces in an aqueous medium
............... 110
6.7
Steric and depletion interaction
......................... 113
6.7.1
Properties of polymers
......................... 113
6.7.2
Force between polymer coated surfaces
................ 114
6.7.3
Depletion forces
............................ 116
6.8
Spherical particles in contact
.......................... 117
6.9
Summary
.................................... 121
6.10
Exercises
.................................... 122
7
Contact angle phenomena and wetting
125
7.1
Young s equation
................................ 125
7.1.1
The contact angle
............................ 125
7.1.2
Derivation
................................ 126
7.1.3
The line tension
............................. 128
7.1.4
Complete wetting and wetting transitions
............... 128
7.2
Important wetting geometries
.......................... 130
7.2.1
Capillary rise
.............................. 130
7.2.2
Particles in the liquid-gas interface
.................. 131
7.2.3
Network of fibers
............................ 132
7.3
Measurement of the contact angle
....................... 133
7.3.1
Experimental methods
......................... 133
7.3.2
Hysteresis in contact angle measurements
............... 135
7.3.3
Surface roughness and heterogeneity
.................. 137
7.4
Theoretical aspects of contact angle phenomena
................ 139
7.5
Dynamics of wetting and dewetting
...................... 141
7.5.1
Wetting
................................. 141
7.5.2
Dewetting
................................ 145
7.6
Applications
................................... 146
7.6.1
Flotation
................................ 146
7.6.2
Detergency
............................... 147
7.6.3
Microfluidics
.............................. 148
7.6.4
Adjustable wetting
........................... 150
7.7
Summary
.................................... 151
7.8
Exercises
.................................... 152
8
Solid surfaces
153
8.1
Introduction
................................... 153
8.2
Description of crystalline surfaces
....................... 154
8.2.1
The substrate structure
......................... 154
Contents
8.2.2
Surface relaxation and reconstruction
.................155
8.2.3
Description of
adsórbate
structures
...................158
8.3
Preparation of clean surfaces
..........................158
8.4
Thermodynamics of solid surfaces
.......................161
8.4.1
Surface stress and surface tension
................... 161
8.4.2
Determination of the surface energy
.................. 164
8.4.3
Surface steps and defects
........................ 167
8.5
Solid-solid interfaces
.............................. 169
8.6
Microscopy of solid surfaces
.......................... 171
8.6.1
Optical microscopy
........................... 171
8.6.2
Electron microscopy
.......................... 172
8.6.3
Scanning probe microscopy
...................... 174
8.7
Diffraction methods
............................... 177
8.7.1
Diffraction patterns of two-dimensional periodic structures
......177
8.7.2
Diffraction with electrons, X-rays, and atoms
.............179
8.8
Spectroscopie
methods
.............................181
8.8.1
Spectroscopy using mainly inner electrons
............... 181
8.8.2
Spectroscopy with outer electrons
................... 182
8.8.3
Secondary ion mass spectrometry
................... 183
8.9
Summary
.................................... 185
8.10
Exercises
.................................... 185
Adsorption
187
9.1
Introduction
................................... 187
9.1.1
Definitions
............................... 187
9.1.2
The adsorption time
.......................... 188
9.1.3
Classification of adsorption isotherms
................. 189
9.1.4
Presentation of adsorption isotherms
.................. 191
9.2
Thermodynamics of adsorption
......................... 192
9.2.1
Heats of adsorption
........................... 192
9.2.2
Differential quantities of adsorption and experimental results
..... 193
9.3
Adsorption models
............................... 195
9.3.1
The Langmuir adsorption isotherm
................... 195
9.3.2
The Langmuir constant and the Gibbs energy of adsorption
...... 198
9.3.3
Langmuir adsorption with lateral interactions
............. 199
9.3.4
The BET adsorption isotherm
..................... 199
9.3.5
Adsorption on heterogeneous surfaces
................. 202
9.3.6
The potential theory of Polanyi
..................... 203
9.4
Experimental aspects of adsorption from the gas phase
............ 206
9.4.1
Measurement of adsorption isotherms
................. 206
9.4.2
Procedures to measure the specific surface area
............ 209
9.4.3
Adsorption on porous solids
—
hysteresis
............... 211
9.4.4
Special aspects of chemisorption
.................... 214
9.5
Adsorption from solution
............................ 215
9.6
Summary
.................................... 217
9.7
Exercises
.................................... 217
Contents
IX
10
Surface modification
219
10.1
Introduction
................................... 219
10.2
Chemical
vapor deposition...........................
220
10.3
Soft matter deposition
.............................. 222
10.3.1
Self-assembled monolayers
...................... 222
10.3.2
Physisorption of Polymers
....................... 226
10.3.3
Polymerization on surfaces
....................... 228
10.3.4
Plasma polymerization
......................... 230
10.4
Etching techniques
............................... 232
10.5
Lithography
................................... 235
10.6
Summary
.................................... 237
10.7
Exercises
.................................... 238
11
Friction, lubrication, and wear
241
11.1
Friction
..................................... 241
11.1.1
Introduction
............................... 241
11.1.2
Amontons and Coulomb s Law
.................... 242
11.1.3
Static, kinetic, and stick-slip friction
.................. 244
11.1.4
Rolling friction
............................. 245
11.1.5
Friction and adhesion
.......................... 247
11.1.6
Experimental Aspects
......................... 247
11.1.7
Techniques to measure friction
..................... 247
11.1.8
Macroscopic friction
.......................... 249
11.1.9
Microscopic friction
.......................... 250
11.2
Lubrication
................................... 253
11.2.1
Hydrodynamic lubrication
....................... 254
11.2.2
Boundary lubrication
.......................... 256
11.2.3
Thin film lubrication
.......................... 257
11.2.4
Lubricants
............................... 258
11.3
Wear
....................................... 259
11.4
Summary
.................................... 261
11.5
Exercises
.................................... 262
12
Surfactants, micelles, emulsions, and foams
265
12.1
Surfactants
................................... 265
12.2
Spherical micelles, cylinders, and bilayers
................... 269
12.2.1
The critical micelle concentration
................... 269
12.2.2
Influence of temperature
........................ 271
12.2.3
Thermodynamics of micellization
................... 272
12.2.4
Structure of surfactant aggregates
................... 274
12.2.5
Biological membranes
......................... 277
12.3
Macroemulsions
................................. 278
12.3.1
General properties
........................... 278
12.3.2
Formation
................................ 280
12.3.3
Stabilization
.............................. 282
χ
Contents
12.3.4 Evolution
and aging
.......................... 285
12.3.5
Coalescence and demulsification
.................... 287
12.4
Microemulsions
................................. 287
12.4.1
Size of droplets
............................. 288
12.4.2
Elastic properties of surfactant films
.................. 289
12.4.3
Factors influencing the structure of microemulsions
.......... 290
12.5
Foams
...................................... 292
12.5.1
Classification, application and formation
............... 292
12.5.2
Structure of foams
........................... 293
12.5.3
Soap films
............................... 294
12.5.4
Evolution of foams
........................... 297
12.6
Summary
.................................... 298
12.7
Exercises
.................................... 298
13
Thin films on surfaces of liquids
301
13.1
Introduction
................................... 301
13.2
Phases of monomolecular films
......................... 304
13.3
Experimental techniques to study monolay
ers
................. 307
13.3.1
Optical methods
............................ 307
13.3.2
X-ray reflection and diffraction
..................... 308
13.3.3
The surface potential
.......................... 311
13.3.4
Surface elasticity and viscosity
..................... 313
13.4
Langmuir-Blodgett transfer
........................... 314
13.5
Thick films
-
spreading of one liquid on another
................ 316
13.6
Summary
.................................... 318
13.7
Exercises
.................................... 319
14
Solutions to exercises
321
Appendix
A Analysis of diffraction patterns
343
A.
1
Diffraction at three dimensional crystals
.................... 343
A.I.I Bragg condition
............................. 343
A.
1.2 Laue
condition
............................. 344
A.
1.3
The reciprocal lattice
.......................... 345
A.
1.4 Ewald
construction
........................... 347
A.2 Diffraction at Surfaces
............................. 347
A.3 Intensity of diffraction peaks
.......................... 349
В
Symbols and abbreviations
353
Bibliography
357
Index
379
|
| any_adam_object | 1 |
| author | Butt, Hans-Jürgen 1961- Graf, Karlheinz 1966- Kappl, Michael 1963- |
| author_GND | (DE-588)110921550 (DE-588)120729075 (DE-588)128798548 |
| author_facet | Butt, Hans-Jürgen 1961- Graf, Karlheinz 1966- Kappl, Michael 1963- |
| author_role | aut aut aut |
| author_sort | Butt, Hans-Jürgen 1961- |
| author_variant | h j b hjb k g kg m k mk |
| building | Verbundindex |
| bvnumber | BV035542977 |
| classification_rvk | UP 7500 VE 7000 |
| classification_tum | CHE 180f PHY 629f PHY 650f |
| ctrlnum | (OCoLC)316247956 (DE-599)BVBBV035542977 |
| dewey-full | 530 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 530 - Physics |
| dewey-raw | 530 |
| dewey-search | 530 |
| dewey-sort | 3530 |
| dewey-tens | 530 - Physics |
| discipline | Chemie / Pharmazie Physik Chemie |
| edition | 2., rev. and enl. ed., 2. reprint |
| format | Book |
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| genre | (DE-588)4123623-3 Lehrbuch gnd-content |
| genre_facet | Lehrbuch |
| id | DE-604.BV035542977 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:40:03Z |
| institution | BVB |
| isbn | 3527406298 9783527406296 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017599006 |
| oclc_num | 316247956 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-M347 |
| owner_facet | DE-355 DE-BY-UBR DE-M347 |
| physical | XII, 386 S. Ill., graph. Darst. 240 mm x 170 mm |
| publishDate | 2008 |
| publishDateSearch | 2008 |
| publishDateSort | 2008 |
| publisher | WILEY-VCH |
| record_format | marc |
| series2 | Physics textbook |
| spelling | Butt, Hans-Jürgen 1961- Verfasser (DE-588)110921550 aut Physics and chemistry of interfaces Hans Jürgen Butt ; Karlheinz Graf ; Michael Kappl 2., rev. and enl. ed., 2. reprint Weinheim WILEY-VCH 2008 XII, 386 S. Ill., graph. Darst. 240 mm x 170 mm txt rdacontent n rdamedia nc rdacarrier Physics textbook Grenzflächenchemie - Lehrbuch Grenzflächenphysik - Lehrbuch Surface chemistry Surfaces (Physics) Grenzflächenphysik (DE-588)4452968-5 gnd rswk-swf Oberflächenphysik (DE-588)4134881-3 gnd rswk-swf Grenzflächenchemie (DE-588)4246080-3 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Oberflächenphysik (DE-588)4134881-3 s Oberflächenchemie (DE-588)4126166-5 s 1\p DE-604 Grenzflächenphysik (DE-588)4452968-5 s Grenzflächenchemie (DE-588)4246080-3 s 2\p DE-604 Graf, Karlheinz 1966- Verfasser (DE-588)120729075 aut Kappl, Michael 1963- Verfasser (DE-588)128798548 aut text/html http://deposit.dnb.de/cgi-bin/dokserv?id=2686609&prov=M&dok_var=1&dok_ext=htm Inhaltstext Digitalisierung UB Regensburg application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017599006&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Butt, Hans-Jürgen 1961- Graf, Karlheinz 1966- Kappl, Michael 1963- Physics and chemistry of interfaces Grenzflächenchemie - Lehrbuch Grenzflächenphysik - Lehrbuch Surface chemistry Surfaces (Physics) Grenzflächenphysik (DE-588)4452968-5 gnd Oberflächenphysik (DE-588)4134881-3 gnd Grenzflächenchemie (DE-588)4246080-3 gnd Oberflächenchemie (DE-588)4126166-5 gnd |
| subject_GND | (DE-588)4452968-5 (DE-588)4134881-3 (DE-588)4246080-3 (DE-588)4126166-5 (DE-588)4123623-3 |
| title | Physics and chemistry of interfaces |
| title_auth | Physics and chemistry of interfaces |
| title_exact_search | Physics and chemistry of interfaces |
| title_full | Physics and chemistry of interfaces Hans Jürgen Butt ; Karlheinz Graf ; Michael Kappl |
| title_fullStr | Physics and chemistry of interfaces Hans Jürgen Butt ; Karlheinz Graf ; Michael Kappl |
| title_full_unstemmed | Physics and chemistry of interfaces Hans Jürgen Butt ; Karlheinz Graf ; Michael Kappl |
| title_short | Physics and chemistry of interfaces |
| title_sort | physics and chemistry of interfaces |
| topic | Grenzflächenchemie - Lehrbuch Grenzflächenphysik - Lehrbuch Surface chemistry Surfaces (Physics) Grenzflächenphysik (DE-588)4452968-5 gnd Oberflächenphysik (DE-588)4134881-3 gnd Grenzflächenchemie (DE-588)4246080-3 gnd Oberflächenchemie (DE-588)4126166-5 gnd |
| topic_facet | Grenzflächenchemie - Lehrbuch Grenzflächenphysik - Lehrbuch Surface chemistry Surfaces (Physics) Grenzflächenphysik Oberflächenphysik Grenzflächenchemie Oberflächenchemie Lehrbuch |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=2686609&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017599006&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT butthansjurgen physicsandchemistryofinterfaces AT grafkarlheinz physicsandchemistryofinterfaces AT kapplmichael physicsandchemistryofinterfaces |