Catalytic asymmetric Friedel-Crafts alkylations:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2009
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XVI, 301 S. graph. Darst. 240 mm x 170 mm |
| ISBN: | 9783527323807 |
Internformat
MARC
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| 084 | |a CHE 622f |2 stub | ||
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| 084 | |a CHE 608f |2 stub | ||
| 245 | 1 | 0 | |a Catalytic asymmetric Friedel-Crafts alkylations |c ed. by Marco Bandini ... |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2009 | |
| 300 | |a XVI, 301 S. |b graph. Darst. |c 240 mm x 170 mm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Friedel-Crafts reaction | |
| 650 | 0 | 7 | |a Katalyse |0 (DE-588)4029921-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Asymmetrische Reaktion |0 (DE-588)4143270-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Friedel-Crafts-Reaktion |0 (DE-588)4123234-3 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Friedel-Crafts-Reaktion |0 (DE-588)4123234-3 |D s |
| 689 | 0 | 1 | |a Asymmetrische Reaktion |0 (DE-588)4143270-8 |D s |
| 689 | 0 | 2 | |a Katalyse |0 (DE-588)4029921-1 |D s |
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Datensatz im Suchindex
| _version_ | 1805092412426551296 |
|---|---|
| adam_text |
VII CONTENTS FOREWORD V PREFACE XIII LIST OF CONTRIBUTORS XV 1 GENERAL
ASPECTS AND HISTORICAL BACKGROUND 1 MARCO BANDINI 1.1 INTRODUCTION 1 1.2
GENERAL ASPECTS AND HISTORICAL BACKGROUND 3 1.3 CATALYTIC
ENANTIOSELECTIVE FC REACTIONS: AN INTRODUCTION 5 1.3.1 ALKYLATING AGENTS
6 1.3.2 PRIVILEGED CATALYSTS 9 1.3.3 AROMATIC COMPOUNDS AND REACTION
CONDITIONS 13 REFERENCES 14 2 MICHAEL ADDITION 17 2.1 CHELATING
A,SS-UNSATURATED COMPOUNDS 17 JESUS M. GARCIA, MIKEL OIARBIDE AND CLAUDIO
PALOMO 2.1.1 CHELATING COMPOUNDS 18 2.1.1.1 ALKYLIDENE MALONATES 19
2.1.1.2 SS,Y-UNSATURATED A-KETOESTERS 25 2.1.1.3 A'-HYDROXY ENONES 28
2.1.1.4 A'-PHOSPHONATE ENONES 31 2.1.1.5 A,SS-UNSATURATED ACYL COMPOUNDS
32 2.1.1.5.1 CX,SS-UNSATURATED ACYL PHOSPHONATES 32 2.1.1.5.2
A,SS-UNSATURATED 2-ACYL IMIDAZOLES 34 2.1.1.6 A,SS-UNSATURATED THIOESTERS
39 2.1.1.7 NITROACRYLATES 40 2.1.1.8 EXPERIMENTAL: SELECTED PROCEDURES
42 BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/992134641
DIGITALISIERT DURCH VIII CONTENTS 2.2 SIMPLE A,SS-UNSATURATED SUBSTRATES
49 GIUSEPPE BARTOLI AND PAOLO MELCHIORRE 2.2.1 INTRODUCTION 49 2.2.1.1
A,SS-UNSATURATED ALDEHYDES 50 2.2.1.1.1 ORGANOCATALYSIS 50 2.2.1.1.2
ORGANOCATALYTIC DOMINO REACTIONS 55 2.2.1.1.3 EXPERIMENTAL: SELECTED
PROCEDURES 57 2.2.1.2 OC.SS-UNSATURATED KETONES 60 2.2.1.2.1
ORGANOMETALLIC CATALYSIS 60 2.2.1.2.2 ORGANOCATALYSIS 61 2.2.1.2.3
EXPERIMENTAL: SELECTED PROCEDURES 64 2.2.2 INTRAMOLECULAR APPROACH 65
2.3 NITROALKENES 67 LUCA BEMARDI AND ALFREDO RICCI 2.3.1 INTRODUCTION 68
2.3.2 ORGANOCATALYTIC ENANTIOSELECTIVE REACTIONS 68 2.3.2.1
FRIEDEL-CRAFTS ALKYLATION OFLNDOLES 68 2.3.2.1.1 THIOUREA CATALYSTS 69
2.3.2.1.2 BISSULFONAMIDE CATALYSTS 72 2.3.2.1.3 PHOSPHORIC ACID
CATALYSTS 73 2.3.2.1.4 SYNTHETIC APPLICATIONS 74 2.3.3 FRIEDEL-CRAFTS
REACTIONS OFNAPHTHOLS 75 2.3.3.1 THIOUREA CATALYSTS 75 2.3.4 ADDITION OF
1,2,3-TRIAZOLES 76 2.3.4. CONTENTS IX 3.1.2.1.2 CHURAL
BISOXAZOLINE-CU(II) CATALYSIS 108 3.1.2.2 EXPERIMENTS: SELECTED
REPRESENTATIVE PROCEDURES 114 3.1.3 ORGANOCATALYSIS 116 3.1.3.1
FUNDAMENTAL EXAMPLES AND MECHANISM 116 3.1.3.2 EXPERIMENTS: SELECTED
REPRESENTATIVE PROCEDURES 118 3.1.4 HETEROGENEOUS CATALYSIS 118 3.2
IMINES 119 SHU-LI YOU 3.2.1 CATALYTIC ASYMMETRIE FRIEDEL-CRAFTS REACTION
OF IMINES 120 3.2.1.1 INTERMOLECULAR APPROACH 120 3.2.1.1.1
ORGANOMETALLIC CATALYSIS 120 3.2.1.1.2 ORGANOCATALYSIS 123 3.2.1.2
PICTET-SPENGLER REACTION 132 3.2.2 SELECTED PROCEDURES 138 REFERENCES
240 4 NUCLEOPHILIC ALLYLIC ALKYLATION AND HYDROARYLATION OF ALLENES 245
MARCO BANDINI AND ACHILLE UMANI-RONCHI 4.1 INTRODUCTION 145 4.2 ALLYLIC
ALKYLATIONS 247 4.2.1 INTERMOLECULAR APPROACH 147 4.2.1.1 BENZENE-LIKE
COMPOUNDS 147 4.2.1.2 INDOLES 150 4.2.1.3 ASYMMETRIE ALLYLATIONS 252
4.2.1. X CONTENTS 5.1.3 ASYMMETRIE RING-OPENING OF RACEMIC AND MESO
EPOXIDES 179 5.1.3.1 INTRODUCTION 179 5.1.3.2 SALEN-CHROMIUM-CATALYZED
KINETIC RESOLUTION OF EPOXIDES WITH INDOLES 179 5.1.3.3 EXPERIMENTS:
SELECTED PROCEDURES 280 5.2 DIRECT ACTIVATION OF ALCOHOLS 281 5.2.1
INTRODUCTION 182 5.2.2 DIASTEREOSELECTIVE REACTIONS 282 5.2.2.1 BF 3
-MEDIATED REACTIONS 183 5.2.2.2 GOLD(III) CATALYSIS 284 5.2.3
ENANTIOSELECTIVE REACTIONS 287 5.2.3.1 RUTHENIUM CATALYSIS 287 5.2.3.2
BRONSTED ACID CATALYSIS 192 5.2.3.3 EXPERIMENTS: SELECTED PROCEDURES 192
5.2.3.4 FC REACTIONS WITH CHIRAL FERROCENYL COMPOUNDS 293 5.2.3.4.1
INDIUM-PROMOTED NUDEOPHILIC SUBSTITUTION WITH FERROCENE 193 5.2.3.4.2
"ON WATER" FC REACTIONS 294 5.2.3.4.3 EXPERIMENTS: SELECTED PROCEDURES
296 REFERENCES 198 6 UNACTIVATED ALKENES 203 ROSSA. WIDENHOEFER 6.1
INTRODUCTION 203 6.2 EARLY STUDIES 204 6.2.1 ENANTIOSELECTIVE
HYDROARYLATION OF NORBORNENE 204 6.2.2 ATROPSELECTIVE ALKYLATION OF
BIARYLS 206 6.3 RH(I)-CATALYZED ENANTIOSELECTIVE HYDROARYLATION OF
IMINOARENES 207 6.3.1 CATALYST CONTROL 207 6.3.1.1 ALKYLATION OF
AROMATIC KETIMINES 207 CONTENTS XI 7.2.3 SYNTHESIS OFPOLYCYDIC INDOLES
228 7.2.4 SYNTHESIS OF 2-AMINOMETHYL INDOLES 229 7.2.5 EXPERIMENTS:
SELECTED PROCEDURES 232 7.3 TOTAL SYNTHESIS OF PYRROLE-CONTAINING
COMPOUNDS 240 7.3.1 SYNTHESIS OF (+)-HELIOTRIDANE 240 7.3.2 SYNTHESIS OF
THE INDOLIZIDINE ALKALOIDS TASHIROMINE, EPI-TASHIROMINE, RAZHINAL,
RHAZINILAM, LEUCONOLAM AND EPI-LEUCONALAM 241 7.3.3 SYNTHESIS OF
PYRROLO[L,2-A]PYRAZINES 242 7.3.4 EXPERIMENTS: SELECTED PROCEDURES 244
7.4 FRIEDEL-CRAFTS ALKYLATION OFFURAN DERIVATIVES IN TOTAL SYNTHESIS 247
7.4.1 SYNTHESIS OF AMINOBUTENOLIDES 248 7.4.2 EXPERIMENTS: SELECTED
PROCEDURES 248 7.5 FRIEDEL-CRAFTS ALKYLATION OF ARENES IN TOTAL
SYNTHESIS 249 7.5.1 SYNTHESIS OF OPTICALLY ACTIVE MANDELIC ACID
DERIVATIVES AND AROMATIC A-AMINO ACIDS 250 7.5.2 SYNTHESIS OF OPTICALLY
ACTIVE CHROMANES 250 7.5.3 EXPERIMENTS: SELECTED PROCEDURES 252 7.6
ASYMMETRIE SYNTHESIS OF NATURAL PRODUCTS BASED ON DIASTEREOSELECTIVE
FRIEDEL-CRAFTS REACTIONS 253 7.6.1 SYNTHESIS OF HAPALINDOLE ALKALOIDS
253 XII CONTENTS 8.4.8 PECHMANN SYNTHESES 284 8.4.9 USE OF EPOXIDES AS
ALKYLATING AGENTS 284 8.5 CONDUSIONS AND PERSPECTIVES 286 REFERENCES 286
INDEX 289 |
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| isbn | 9783527323807 |
| language | English |
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| spelling | Catalytic asymmetric Friedel-Crafts alkylations ed. by Marco Bandini ... Weinheim Wiley-VCH 2009 XVI, 301 S. graph. Darst. 240 mm x 170 mm txt rdacontent n rdamedia nc rdacarrier Friedel-Crafts reaction Katalyse (DE-588)4029921-1 gnd rswk-swf Asymmetrische Reaktion (DE-588)4143270-8 gnd rswk-swf Friedel-Crafts-Reaktion (DE-588)4123234-3 gnd rswk-swf Friedel-Crafts-Reaktion (DE-588)4123234-3 s Asymmetrische Reaktion (DE-588)4143270-8 s Katalyse (DE-588)4029921-1 s DE-604 Bandini, Marco 1973- Sonstige (DE-588)138575347 oth text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3227438&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017557478&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Catalytic asymmetric Friedel-Crafts alkylations Friedel-Crafts reaction Katalyse (DE-588)4029921-1 gnd Asymmetrische Reaktion (DE-588)4143270-8 gnd Friedel-Crafts-Reaktion (DE-588)4123234-3 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4143270-8 (DE-588)4123234-3 |
| title | Catalytic asymmetric Friedel-Crafts alkylations |
| title_auth | Catalytic asymmetric Friedel-Crafts alkylations |
| title_exact_search | Catalytic asymmetric Friedel-Crafts alkylations |
| title_full | Catalytic asymmetric Friedel-Crafts alkylations ed. by Marco Bandini ... |
| title_fullStr | Catalytic asymmetric Friedel-Crafts alkylations ed. by Marco Bandini ... |
| title_full_unstemmed | Catalytic asymmetric Friedel-Crafts alkylations ed. by Marco Bandini ... |
| title_short | Catalytic asymmetric Friedel-Crafts alkylations |
| title_sort | catalytic asymmetric friedel crafts alkylations |
| topic | Friedel-Crafts reaction Katalyse (DE-588)4029921-1 gnd Asymmetrische Reaktion (DE-588)4143270-8 gnd Friedel-Crafts-Reaktion (DE-588)4123234-3 gnd |
| topic_facet | Friedel-Crafts reaction Katalyse Asymmetrische Reaktion Friedel-Crafts-Reaktion |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3227438&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017557478&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT bandinimarco catalyticasymmetricfriedelcraftsalkylations |