Nano- and micro-mechanics of polymer blends and composites:
"The aim of this book is to give a state-of-art overview on aspects of micro- and nanomechanics of polymers, polymeric blends and composites"--Provided by publisher.
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| Format: | Book |
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| Language: | English |
| Published: |
Munich [u.a.]
Hanser
2009
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Summary: | "The aim of this book is to give a state-of-art overview on aspects of micro- and nanomechanics of polymers, polymeric blends and composites"--Provided by publisher. |
| Item Description: | Literaturangaben |
| Physical Description: | XX, 604 S. Ill., graph. Darst. 25 cm |
| ISBN: | 9783446413238 9781569904350 |
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| 245 | 1 | 0 | |a Nano- and micro-mechanics of polymer blends and composites |c József Karger-Kocsis ; Stoyko Fakirov |
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| adam_text | Titel: Nano- and micro-mechanics of polymer blends and composites
Autor: Karger-Kocsis, József
Jahr: 2009
Content
PART I POLYMERS
Chapter 1 Nano- and Micromechanics
of Crystalline Polymers
A. Galeski, G. Regnier
1.1. Introduction 3
1.2. Tensile deformation of crystalline polymers 4
1.3. Cavitation in tensile deformation 4
1.4. Tensile deformation of polyethylene and polypropylene 8
1.5. Deformation micromechanisms in crystalline polymers 13
1.6. Molecular mechanisms at a nanometer scale 16
1.7. Dislocations in crystal plasticity 23
1.8. Generation of dislocations 25
1.9. Competition between crystal plasticity and cavitation 34
1.10. Micromechanics modeling in semicrystalline polymers 35
1.10.1. Microstructure and mechanical properties 35
1.10.2. The micromechanical models 36
1.10.3. Idealizing the microstructure of semicrystalline polymers 38
1.10.4. Elastic behavior prediction 40
1.11. Large deformations and bottlenecks 45
1.12. Phenomenological models of polymer deformation
under tensile and compressive stresses 45
1.13. Conclusions 47
References 48
viii Content
Chapter 2 Modeling Mechanical Properties
of Segmented Polyurethanes
V. V. Ginzburg , J. Bicerano, C. P. Christenson,
A. K. Schrock, A. Z. Patashinski
2.1. Introduction 59
2.2. Predicting Young s modulus of segmented polyurethanes 63
2.2.1. Relationship between Young s modulus
and formulation - experimental observations 63
2.2.2. Theory 64
2.2.3. Young s modulus: comparing theory with experiments 72
2.3. Modeling tensile stress-strain behavior 76
2.4. Linear viscoelasticity 82
2.5. Non-equilibrium factors and their influence on mechanical properties 84
2.6. Conclusions and Outlook 84
Acknowledgment 85
References 85
PART II NANOCOMPOSITES:
INFLUENCE OF PREPARATION
Chapter 3 Nanoparticles/Polymer Composites:
Fabrication and Mechanical Properties
M. Q. Zhang, M. Z. Rong, W. H. Ruan
3.1. Introduction 93
3.2. Dispersion-oriented manufacturing of nanocomposites 95
3.2.1. Conventional two-step manufacturing 95
3.2.2. Specific two-step manufacturing 107
3.2.3. One-step manufacturing 118
3.3. Dispersion and filler/matrix interaction-oriented
manufacturing of nanocomposites 120
3.3.1. Two-step manufacturing in terms of in situ reactive
compatibilization 120
3.3.2. One-step manufacturing in terms of in situ graft
and crosslinking 124
3.4. Dispersion, filler/filler interaction and filler/matrix
interaction-oriented manufacturing of nanocomposites 129
3.5. Conclusions 135
Acknowledgements 136
References 136
Content ix
Chapter 4 Rubber Nanocomposites:
New Developments, New Opportunities
L. Bokobza
4.1. Introduction 141
4.2. General considerations on elastomeric composites 142
4.3. Spherical in situ generated reinforcing particles 144
4.4. Carbon nanotube-filled rubber composites 153
4.5. Conclusions 161
References 162
Chapter 5 Organoclay, Particulate and Nanofibril
Reinforced Polymer-Polymer
Composites: Manufacturing,
Modeling and Applications
D. Bhattacharyya, S. Pakirov
5.1. Introduction 167
5.2. Polypropylene/organoclay nanocomposites: experimental
characterisation and modeling 169
5.2.1. Peculiarities of polymer /clay nanocomposites 169
5.2.2. Parametric study and associated properties
of PP/organoclay nanocomposites 171
5.2.3. Evaluation of the experimental data by means
of Taguchi and Pareto ANOVA methods 174
5.2.4. Materials, manufacturing and characterisation
of nanocomposites 178
5.2.5. Analytical models for composites 179
5.2.6. Comparisons of experimental results with the calculated values 182
5.3. The dispersion problem in the case of polymer-polymer
nanocomposites 185
5.3.1. Manufacturing of nanofibrillar polymer-polymer composites 187
5.3.2. Nanofibrillar vs. microfibrillar polymer-polymer
composites and their peculiarities 188
5.4. Directional, thermal and mechanical characterisation
of polymer-polymer nanofibrillar composites 190
5.4.1. Directional state of NFC as revealed by wide-angle
X-ray scattering 190
5.4.2. Thermal characterization of NFC 192
5.4.3. Mechanical properties of NFC 193
5.5. Potentials for application of nanofibrillar composites
and the materials developed from neat nanofibrils 196
x Content
5.6. Conclusions and outlook 199
Acknowledgments 200
References 201
PART III NANO- AND MICROCOMPOSITES:
INTERPHASE
Chapter 6 Viscoelasticity of Amorphous
Polymer Nanocomposites
with Individual Nanoparticles
J. Kalfus
6.1. Introduction 209
6.2. Brief physics of amorphous polymer matrices 210
6.2.1. Equilibrium structure of amorphous chains 210
6.2.2. Microscopic relaxation modes and segmental mobility 212
6.2.3. Entropy vs. energy driven mechanical response 214
6.3. Basic aspects of amorphous polymer nanocomposites 216
6.3.1. Structure of surface adsorbed chains 217
6.3.2. Segmental immobilization of chains in the presence
of solid surfaces 219
6.4. Reinforcement of amorphous nanocomposite
below and above matrix Tg 222
6.5. Strain induced softening of amorphous polymer nanocomposites 228
6.6. Relaxation of chains in the presence of nanoparticles 233
6.7. Conclusions and outlook 235
Acknowledgements 236
References 236
Chapter 7 Interphase Phenomena in Polymer
Micro- and Nanocomposites
J. Jancar
7.1. Introduction 241
7.2. Micro-scale interphase in polymer composites 246
7.3. Nano-scale interphase 250
7.4. Chain immobilization on the nano-scale 252
7.5. Characteristic length-scale in polymer matrix nanocomposites 255
7.6. Conclusions and outlook 257
Acknowledgement 258
References 258
Content xi
PART IV NANO- AND MICROCOMPOSITES:
CHARACTERIZATION
Chapter 8 Deformation Behavior of Nanocomposites
Studied by X-Ray Scattering:
Instrumentation and Methodology
N. Stribeck
8.1. Introduction 269
8.2. Scattering theory and materials structure 272
8.2.1. Relation between a CDF and IDFs 275
8.3. Analysis options derived from scattering theory 276
8.3.1. Completeness - a preliminary note 276
8.3.2. Analysis options 276
8.3.3. Parameters, functions and operations 277
8.4. The experiment 278
8.4.1. Principal design 278
8.4.2. Engineering solutions 279
8.4.3. Scattering data and its evaluation 284
8.5. Techniques: Dynamic vs. stretch-hold 286
8.6. Advanced goal: Identification of mechanisms 286
8.7. Observed promising effects from stretch-hold experiments 289
8.7.1. Orientation of nanofibrils in highly oriented
polymer blends by means of USAXS 289
8.7.2. USAXS studies on undrawn and highly drawn
PP/PET blends 291
8.8. Choosing experiments 293
8.8.1. Experiments with a macrobeam 293
8.8.2. Experiments with a microbeam 294
8.9. Conclusion and outlook 295
References 296
Chapter 9 Creep and Fatigue Behavior
of Polymer Nanocomposites
A. Pegoretti
9.1. Introduction 301
9.2. Generalities on the creep behavior of viscoelastic materials 302
9.3. Generalities on the fatigue resistance of polymeric materials 306
9.4. Creep behavior of polymer nanocomposites 309
9.4.1. Creep response of PNCs containing
one-dimensional nanofillers 309
xii Content
9.4.2. Creep response of PNCs containing
two-dimensional nanofillers 315
9.4.3. Creep response of PNCs containing
three-dimensional nanoparticles 317
9.5. Fatigue resistance of polymer nanocomposites 321
9.5.1. Fatigue behavior of PNCs containing
one-dimensional nanofillers 322
9.5.2. Fatigue behavior of PNCs containing
two-dimensional nanofillers 326
9.5.3. Fatigue behavior of PNCs containing
three-dimensional nanoparticles 332
9.6. Conclusions and outlook 334
References 335
Chapter 10 Deformation Mechanisms
of Functionalized Carbon Nanotube
Reinforced Polymer Nanocomposites
S. C. Tjong
10.1. Introduction 341
10.2. Deformation characteristics 343
10.2.1. CNT/glassy thermoplastic nanocomposites 345
10.2.2. CNT/semicrystalline thermoplastic nanocomposites 356
10.2.3. CNT/epoxy nanocomposites 362
10.2.4. CNT/elastomer nanocomposites 369
10.3. Conclusions 371
References 371
Chapter 11 Fracture Properties and Mechanisms
of Polyamide/Clay Nanocomposites
A. Dasari, S.-H. Lim, Z.-Z. Yu, Y.-W. Mai
11.1. Introduction 377
11.2. Dispersion of clay in polymers 378
11.3. Crystallization behavior 384
11.4. Fracture properties and mechanisms 387
11.4.1. Improved toughness in polymer/clay nanocomposites 387
11.4.2. Brittleness of polymer/clay nanocomposites 393
11.4.3. Approaches to improve fracture toughness
of polymer/clay nanocomposites 399
11.5. Conclusions and future work 414
Acknowledgements 415
References 415
Content xjjj
Chapter 12 On the Toughness of Nanomodified
Polymers and Their Traditional
Polymer Composites
J. Karger-Kocsis
12.1. Introduction 425
12.2. Toughness assessment 427
12.3. Nanomodified thermoplastics 428
12.3.1. Amorphous polymers 428
12.3.2. Semicrystalline polymers 432
12.4. Nanomodified thermosets 444
12.4.1. (Neat) Resins 444
12.4.2. Toughened and hybrid resins 453
12.5. Nanomodified traditional composites 456
12.5.1. Thermoplastic matrices 457
12.5.2. Thermoset matrices 457
12.6. Outlook and future trends 460
Acknowledgements 460
References 461
Chapter 13 Micromechanics of Polymer Blends:
Microhardness of Polymer Systems
Containing a Soft Component and/or Phase
S. Fakirov
13.1. Introduction 471
13.2. The peculiarity of polymer systems containing
a soft component and/or phase 472
13.3. Comparison between measured and computed microhardness
values for various systems 477
13.3.1. Two-component multiphase systems comprising
softphase(s) (blends of semicrystalline homopolymers) 477
13.3.2. One-component multiphase systems
containing soft phase(s) (polyblock copolymers) 478
13.3.3. Two-component one-phase systems
(miscible blends of amorphous polymers) 482
13.3.4. Two-component two-phase amorphous systems
containing a soft phase 484
13.3.5. One-component two-phase systems
(semicrystalline polymers with Tg below room temperature) 487
13.4. Main factors determining the microhardness of polymer systems
containing a soft component and/or phase 489
xiv Content
13.4.1. Importance of the ratio hard/soft components (or phases) 489
13.4.2. Crystalline or amorphous solids 490
13.4.3. Copolymers vs. polymer blends 492
13.4.4. New data on the relationship between H and Tg
of amorphous polymers 493
13.4.5. Modified additivity law for systems
containing soft component and/or phase 495
13.5. Microhardness on the interphase boundaries in polymer blends
and composites and doubly injection molding processing 495
13.5.1. Microhardness on the interphase boundaries
in polymer blends 495
13.5.2. Microhardness on the interphase boundaries
in polymers after double injection molding processing 502
13.6. Conclusions and outlook 510
Acknowledgements 512
References 512
PART V NANOCOMPOSITES: MODELING
Chapter 14 Some Monte Carlo Simulations
on Nanoparticle Reinforcement
of Elastomers
J. E. Mark, T. Z. Sen, A. Kloczkowski
14.1. Introduction 519
14.2. Description of simulations 520
14.2.1. Rotational isomeric state theory
for conformation-dependent properties 520
14.2.2. Distribution functions 520
14.2.3. Applications to unfilled elastomers 521
14.2.4. Applications to filled elastomers 522
14.3. Spherical particles 522
14.3.1. Particle sizes, shapes, concentrations, and arrangements 522
14.3.2. Distributions of chain end-to-end distances 523
14.3.3. Stress-strain isotherms 525
14.3.4. Effects of arbitrary changes in the distributions 526
14.3.5. Some preliminary results on physisorption 528
14.3.6. Relevance of cross linking in solution 530
14.3.7. Detailed descriptions of conformational changes
during chain extension 534
Content xv
14.4. Ellipsoidal particles 534
14.4.1. General features 534
14.4.2. Oblate ellipsoids 536
14.5. Aggregated particles 537
14.5.1. Real systems 537
14.5.2. Types of aggregates for modeling 537
14.5.3. Deformabilities of aggregates 538
14.6. Potential refinements 538
14.7. Conclusions 538
Acknowledgments 538
References 539
Chapter 15 Modeling of Polymer Clay Nanocomposites
for a Multiscale Approach
P. E. Spencer, J. Sweeney
15.1. Introduction 545
15.2. Sequential multiscale modeling 547
15.3. Representative volume element 548
15.3.1. Effective elastic material properties 549
15.3.2. Statistical ensemble 550
15.3.3. Periodic boundary conditions 551
15.4. Generating RVE geometry 553
15.4.1. Number of platelets 553
15.4.2. Generation of platelet configurations 554
15.5. Periodic finite element mesh 556
15.6. Numerical solution process 558
15.6.1. Finite element analysis of boundary value problem 558
15.6.2. Ensemble averaged elastic properties 560
15.6.3. Automation 561
15.7. Elastic RVE numerical results 562
15.7.1. Fully exfoliated straight platelets 565
15.7.2. Effect of platelet orientation 567
15.7.3. Curved platelets 569
15.7.4. Multi-layer stacks of intercalated platelets 572
15.8. Conclusions 574
Acknowledgements 576
References 576
Acknowledgements to previous publishers 579
Author Index 591
Subject Index 597
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV035500005 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:39:00Z |
| institution | BVB |
| isbn | 9783446413238 9781569904350 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017556246 |
| oclc_num | 316736726 |
| open_access_boolean | |
| owner | DE-12 DE-91G DE-BY-TUM DE-29T DE-210 DE-703 DE-83 DE-92 |
| owner_facet | DE-12 DE-91G DE-BY-TUM DE-29T DE-210 DE-703 DE-83 DE-92 |
| physical | XX, 604 S. Ill., graph. Darst. 25 cm |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | Hanser |
| record_format | marc |
| spelling | Nano- and micro-mechanics of polymer blends and composites József Karger-Kocsis ; Stoyko Fakirov Munich [u.a.] Hanser 2009 XX, 604 S. Ill., graph. Darst. 25 cm txt rdacontent n rdamedia nc rdacarrier Literaturangaben "The aim of this book is to give a state-of-art overview on aspects of micro- and nanomechanics of polymers, polymeric blends and composites"--Provided by publisher. Nanokomposit - Polymere - Nanostruktur - Mechanische Eigenschaft Polymergemisch - Mikrostruktur - Mikromechanik Micromechanics Microstructure Nanostructured materials Polymeric composites Mechanical properties Polymere (DE-588)4046699-1 gnd rswk-swf Mechanische Eigenschaft (DE-588)4217961-0 gnd rswk-swf Polymergemisch (DE-588)4175243-0 gnd rswk-swf Nanokomposit (DE-588)4768127-5 gnd rswk-swf Mikrostruktur (DE-588)4131028-7 gnd rswk-swf Nanostruktur (DE-588)4204530-7 gnd rswk-swf Mikromechanik (DE-588)4205811-9 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Nanokomposit (DE-588)4768127-5 s Polymere (DE-588)4046699-1 s Nanostruktur (DE-588)4204530-7 s Mechanische Eigenschaft (DE-588)4217961-0 s DE-604 Polymergemisch (DE-588)4175243-0 s Mikrostruktur (DE-588)4131028-7 s Mikromechanik (DE-588)4205811-9 s b DE-604 Karger-Kocsis, József 1950-2018 Sonstige (DE-588)138157960 oth Fakirov, Stoyko 1936- Sonstige (DE-588)115146210 oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017556246&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Nano- and micro-mechanics of polymer blends and composites Nanokomposit - Polymere - Nanostruktur - Mechanische Eigenschaft Polymergemisch - Mikrostruktur - Mikromechanik Micromechanics Microstructure Nanostructured materials Polymeric composites Mechanical properties Polymere (DE-588)4046699-1 gnd Mechanische Eigenschaft (DE-588)4217961-0 gnd Polymergemisch (DE-588)4175243-0 gnd Nanokomposit (DE-588)4768127-5 gnd Mikrostruktur (DE-588)4131028-7 gnd Nanostruktur (DE-588)4204530-7 gnd Mikromechanik (DE-588)4205811-9 gnd |
| subject_GND | (DE-588)4046699-1 (DE-588)4217961-0 (DE-588)4175243-0 (DE-588)4768127-5 (DE-588)4131028-7 (DE-588)4204530-7 (DE-588)4205811-9 (DE-588)4143413-4 |
| title | Nano- and micro-mechanics of polymer blends and composites |
| title_auth | Nano- and micro-mechanics of polymer blends and composites |
| title_exact_search | Nano- and micro-mechanics of polymer blends and composites |
| title_full | Nano- and micro-mechanics of polymer blends and composites József Karger-Kocsis ; Stoyko Fakirov |
| title_fullStr | Nano- and micro-mechanics of polymer blends and composites József Karger-Kocsis ; Stoyko Fakirov |
| title_full_unstemmed | Nano- and micro-mechanics of polymer blends and composites József Karger-Kocsis ; Stoyko Fakirov |
| title_short | Nano- and micro-mechanics of polymer blends and composites |
| title_sort | nano and micro mechanics of polymer blends and composites |
| topic | Nanokomposit - Polymere - Nanostruktur - Mechanische Eigenschaft Polymergemisch - Mikrostruktur - Mikromechanik Micromechanics Microstructure Nanostructured materials Polymeric composites Mechanical properties Polymere (DE-588)4046699-1 gnd Mechanische Eigenschaft (DE-588)4217961-0 gnd Polymergemisch (DE-588)4175243-0 gnd Nanokomposit (DE-588)4768127-5 gnd Mikrostruktur (DE-588)4131028-7 gnd Nanostruktur (DE-588)4204530-7 gnd Mikromechanik (DE-588)4205811-9 gnd |
| topic_facet | Nanokomposit - Polymere - Nanostruktur - Mechanische Eigenschaft Polymergemisch - Mikrostruktur - Mikromechanik Micromechanics Microstructure Nanostructured materials Polymeric composites Mechanical properties Polymere Mechanische Eigenschaft Polymergemisch Nanokomposit Mikrostruktur Nanostruktur Mikromechanik Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017556246&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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