Modern heterogeneous oxidation catalysis: design, reactions and characterization
Gespeichert in:
Format: | Buch |
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Sprache: | English |
Veröffentlicht: |
Weinheim
WILEY-VCH
2009
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Schlagworte: | |
Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
Beschreibung: | XV, 341 S. Ill., graph. Darst. |
ISBN: | 9783527318599 |
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Titel: Modern heterogeneous oxidation catalysis
Autor: Mizuno, Noritaka
Jahr: 2009
Contents
Preface XI
List of Contributors XIII
1 Concepts in Selective Oxidation of Small Alkane Molecules 1
Robert Schlogl
1.1 Introduction 1
1.2 The Research Field 4
1.3 Substrate Activation 7
1.4 Active Oxygen Species 35
1.5 Catalyst Material Science 22
1.6 Conclusion 34
References 35
2 Active Ensemble Structures for Selective Oxidation Catalyses
at Surfaces 43
Mizuki Tada and Yasuhiro Iwasawa
2.1 Introduction 43
2.2 Chiral Self-Dimerization of Vanadium Schiff-Base Complexes on
SiO2 and Their Catalytic Performances for Asymmetric Oxidative
Coupling of 2-Naphthol 44
2.2.1 Asymmetric Heterogeneous Catalysis Using Supported Metal
Complexes 44
2.2.2 Chiral V-Dimer Structure on a SiO2 Surface 45
2.2.3 AsymmetricCatalysisforOxidativeCouplingof2-NaphtholtoBINOL 49
2.3 Low-Temperature Preferential Oxidation of CO in Excess H2 on
Cu-Clusters Dispersed on CeO2 51
2.3.1 Preferential Oxidation (PROX) of CO in Excess H2 on Novel
Metal Catalysts 51
2.3.2 Characterization and Performance of a Novel Cu Cluster/CeO2
Catalyst 52
Modem Heterogeneous Oxidation Catalysis: Design, Reactions and Characterization
Edited by Noritaka Mizuno
Copyright © 2009 W1LEY-VCH Verlag GmbH Co. KGaA, Weinheim
ISBN: 978-3-527-31859-9
2.4 Direct Phenol Synthesis from Benzene and Molecular Oxygen
on a Novel N-Interstitial Re10-Cluster/HZSM-5 Catalyst 57
2.4.1 Phenol Production from Benzene with N2O, H2 + O2, and O2 57
2.4.1.1 Benzene to Phenol with N2O 58
2.4.1.2 Benzene to Phenol with H2 + O2 60
2.4.1.3 Benzene to Phenol with O2 62
2.4.2 Novel Re/HZSM-5 Catalyst for Direct Benzene-to-Phenol Synthesis
with O2 64
2.4.3 Active Re Clusters Entrapped in ZSM-5 Pores 66
2.4.4 Structural Dynamics of the Active Re10 Cluster 68
2.5 Conclusion 71
References 71
3 Unique Catalytic Performance of Supported Cold Nanoparticles
in Oxidation 77
Yunbo Yu,Jiahui Huang, Tamao Ishida, and Masatake Haruta
3.1 Introduction 77
3.2 Low-Temperature CO Oxidation 79
3.2.1 Low-Temperature CO Oxidation in Air 79
3.2.1.1 Junction Perimeter Between Au Particles and the Support 79
3.2.1.2 Selection of Suitable Supports 81
3.2.1.3 Sensitivity to the Size of the Gold Particles 82
3.2.2 Low-Temperature CO Oxidation in H2 84
3.2.3 Mechanism for CO Oxidation Over Supported Gold Nanoparticles 87
3.2.3.1 Mechanisms Involving Junction Perimeter Between Gold and
the Metal-Oxide Supports 87
3.2.3.2 Mechanisms Involving Specific Size or Thickness of Gold Clusters
or Thin Layers 90
3.2.3.3 Mechanisms Involving Cationic Gold 92
3.3 Complete Oxidation of Volatile Organic Compounds 92
3.4 Gas-Phase Selective Oxidation of Organic Compounds 97
3.4.1 Gas-Phase Selective Oxidation of Aliphatic Alkanes 97
3.4.2 Gas-Phase Selective Oxidation of Alcohols 98
3.4.3 Gas-Phase Propylene Epoxidation 100
3.4.3.1 Introduction 100
3.4.3.2 Gas-Phase Propylene Epoxidation with Hydrogen-Oxygen Mixtures
onAu/TiO2 101
3.4.3.3 Gas-Phase Propylene Epoxidation with Hydrogen-Oxygen Mixtures
onAu/Ti-SiO2 103
3.5 liquid-Phase Selective Oxidation of Organic Compounds 106
3.5.1 Oxidation of Mono-Alcohols 107
3.5.2 Oxidation of Diols 112
3.5.3 Oxidationof Glycerol 113
3.5.4 Aerobic Oxidation of Glucose 115
3.5.5 Oxidation of Alkanes and Alkenes 116
3.6 Conclusions 116
References 118
4 Metal-Substituted Zeolites as Heterogeneous Oxidation Catalysts 125
Takashi Tatsumi
4.1 Introduction - Two Ways to Introduce Hetero-Metals into Zeolites 125
4.2 Titanium-Containing Zeolites 126
4.2.1 TS-1 126
4.2.2 Ti-Beta 136
4.2.3 Ti-MWW 137
4.2.4 Other Titanium-Containing Zeolites 145
4.2.5 Solvent Effects and Reaction Intermediate 145
4.3 Other Metal-Containing Zeolites 150
4.4 Conclusion 151
References 151
5 Design of Well-Defined Active Sites on Crystalline Materials
for Liquid-Phase Oxidations 157
Kiyotomi Kaneda and Takato Mhsudome
5.1 Introduction 157
5.2 Oxidation of Alcohols 157
5.2.1 Ru Catalyst 158
5.2.2 Pd Catalyst 163
5.2.3 Au Catalyst 164
5.2.4 Au-Pd Catalyst 166
5.3 Epoxidation of Olefins 166
5.3.1 Epoxidation with Hydrogen Peroxide 167
5.3.1.1 Titanium-Based Catalysts 167
5.3.1.2 Tungsten-Based Catalysts 167
5.3.1.3 Base Catalyst 169
5.3.2 Epoxidation with Molecular Oxygen 172
5.4 Cis-Dihydroxylation 173
5.5 Baeyer-Villiger Oxidation 175
5.6 C-H Activation Using Molecular Oxygen 177
5.7 Conclusions 178
References 178
6 Liquid-Phase Oxidations with Hydrogen Peroxide and Molecular
Oxygen Catalyzed by Polyoxometalate-Based Compounds 185
Noritaka Mizuno, Keigo Kamata, Sayaka Uchida, and
Kazuya Yamaguchi
6.1 Introduction 185
6.2 Molecular Design of Polyoxometalates for H2O2- and O2-Based
Oxidations 186
6.2.1 Isopoly- and Heteropolyoxometalates 188
6.2.2 Peroxometalates 189
6.2.3 Lacunary Polyoxometalates 190
6.2A Transition-Metal-Substituted Polyoxometalates 192
6.3 Heterogenization of Polyoxometalates 193
6.3.1 Solidification of Polyoxometalates with Appropriate Cations 200
6.3.1.1 Metal and Alkylammonium Cations 200
6.3.1.2 Polycations 201
6.3.1.3 Canonic Organometallic Complexes 203
6.3.2 Immobilization of Polyoxometalate-Based Compounds 205
6.3.2.1 Wet Impregnation 205
6.3.2.2 Solvent-Anchoring and Covalent Linkage 207
6.3.2.3 Anion Exchange 208
6.4 Conclusion 210
References 211
7 Nitrous Oxide as an Oxygen Donor in Oxidation Chemistry
and Catalysis 217
Gennady L Panov, Konstantin A. Dubkov, and Alexander S. Kharitonov
7.1 Introduction 217
7.2 Molecular Structure and Physical Properties of Nitrous Oxide 218
7.3 Catalytic Oxidation by Nitrous Oxide in the Gas Phase 220
7.3.1 Oxidation of Lower Alkanes Over Oxide Catalysts 220
7.3.2 Oxidation Over Zeolites 222
7.3.2.1 Oxidation by Dioxygen 222
7.3.2.2 Oxidation of Benzene to Phenol by N2O 223
7.3.2.3 Nature of Zeolite Activity, a-Sites 224
7.3.2.4 N2O specificity, oc-Oxygen and its Stoichiometric Reactions 227
7.3.2.5 Hydroxylation of Alkanes and Benzene Derivatives 229
7.3.2.6 Other Types of Oxidation Reactions 230
7.4 Catalytic Oxidation by N2O in the Liquid Phase 230
7.5 Non-Catalytic Oxidations by N2O 231
7.5.1 Liquid-Phase Oxidation of Alkenes 231
7.5.1.1 Linear Alkenes 232
7.5.1.2 Cyclic Alkenes 234
7.5.1.3 Cydodienes 237
7.5.1.4 Bicyclic Alkenes 238
7.5.1.5 Heterocyclic Alkenes 238
7.5.2 Carboxidation of Polymers 240
7.5.2.1 Carboxidation of Polyethylene 240
7.5.2.2 Carboxidation of Polybutadiene Rubber 241
7.6 Economic Aspects of N2O as Oxidant 244
7.6.1 Recovery of N2O From Off-Gases 244
7.6.2 Deliberate Preparation of N2O 245
7.7 Conclusion 246
References 247
8 Direct Synthesis of Hydrogen Peroxide: Recent Advances 253
Gabriele Centi, Siglinda Perathoner, and Salvatore Abate
8.1 Introduction 253
8.1.1 Industrial Production 253
8.1.2 Outlook for H2O2 Production 254
8.1.3 Uses of Hydrogen Peroxide 255
8.2 Direct Synthesis of H2O2 from an Industrial Perspective 257
8.2.1 Status of Development and Perspectives of Industrial Production 257
8.2.2 Recent Patents on the Direct Synthesis of H2O2 262
8.3 Fundamental Studies 270
8.3.1 Intrinsically Safe Operations and Microreactors 271
8.3.2 Nature of the Catalyst and Reaction Network 275
8.3.3 Role of the S olvent and of Promoters 281
8.4 Conclusion 282
References 283
9 Recent Achievements and Challenges for a Greener Chemical
Industry 289
Fabrizio Cavani and Nicola Ballarini
9.1 Introduction: Old and New Challenges for Oxidation Catalysis in
Industry 289
9.2 Recent Successful Examples of Alkanes Oxidation 290
9.2.1 Oxidation of Ethane to Acetic Acid 290
9.2.2 Ammoxidation of Propane to Acrylonitrile 294
9.3 New Oxidation Technologies: Oxidative Desulfurization (ODS) of
Gas Oil 301
9.4 Process Intensification in Catalytic Oxidation 304
9.5 An Alternative Approach: Anaerobic Oxidation with Metal Oxides
in a Cycle Process (from an Oxidation Catalyst to a Reusable
Stoichiometric Oxidant) 306
9.5.1 Anaerobic Oxidation of Propene to Acrolein in a CFBR Reactor 309
9.5.2 Anaerobic Synthesis of 2-Methyl-l,4-Naphthoquinone (Menadione) 310
9.5.3 Anaerobic Oxidative Dehydrogenation of Propane to Propene 311
9.5.4 Production of Hydrogen from Methane with Oxide Materials and
Inherent Segregation of Carbon Dioxide 313
9.6 Current and Developing Processes for the Transformation of
Bioplatform Molecules into Chemicals by Catalytic Oxidation 316
9.6.1 Glycerol: A Versatile Building Block 320
9.7 Conclusion 321
References 323
Index 333 |
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spelling | Modern heterogeneous oxidation catalysis design, reactions and characterization ed. by Noritaka Mizuno Weinheim WILEY-VCH 2009 XV, 341 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Heterogene Katalyse (DE-588)4123377-3 gnd rswk-swf Oxidation (DE-588)4137187-2 gnd rswk-swf Oxidation (DE-588)4137187-2 s Heterogene Katalyse (DE-588)4123377-3 s DE-604 Mizuno, Noritaka Sonstige (DE-588)138041695 oth text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3112913&prov=M&dok_var=1&dok_ext=htm Inhaltstext HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017546138&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Modern heterogeneous oxidation catalysis design, reactions and characterization Heterogene Katalyse (DE-588)4123377-3 gnd Oxidation (DE-588)4137187-2 gnd |
subject_GND | (DE-588)4123377-3 (DE-588)4137187-2 |
title | Modern heterogeneous oxidation catalysis design, reactions and characterization |
title_auth | Modern heterogeneous oxidation catalysis design, reactions and characterization |
title_exact_search | Modern heterogeneous oxidation catalysis design, reactions and characterization |
title_full | Modern heterogeneous oxidation catalysis design, reactions and characterization ed. by Noritaka Mizuno |
title_fullStr | Modern heterogeneous oxidation catalysis design, reactions and characterization ed. by Noritaka Mizuno |
title_full_unstemmed | Modern heterogeneous oxidation catalysis design, reactions and characterization ed. by Noritaka Mizuno |
title_short | Modern heterogeneous oxidation catalysis |
title_sort | modern heterogeneous oxidation catalysis design reactions and characterization |
title_sub | design, reactions and characterization |
topic | Heterogene Katalyse (DE-588)4123377-3 gnd Oxidation (DE-588)4137187-2 gnd |
topic_facet | Heterogene Katalyse Oxidation |
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