Technology of fluoropolymers:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Boca Raton, Fla. [u.a.]
CRC Press
2009
|
| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | XIX, 227 S. Ill., graph. Darst. |
| ISBN: | 9781420063172 1420063170 |
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| 245 | 1 | 0 | |a Technology of fluoropolymers |c Jiri George Drobny |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Boca Raton, Fla. [u.a.] |b CRC Press |c 2009 | |
| 300 | |a XIX, 227 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references and index | ||
| 650 | 7 | |a Fluoropolymères |2 ram | |
| 650 | 4 | |a Fluoropolymers | |
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| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017380435&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |3 Klappentext |
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Datensatz im Suchindex
| _version_ | 1804138915333931008 |
|---|---|
| adam_text | Contents
Preface
to the First Edition
....................................................................................xiii
Preface to the Second Edition
..................................................................................xv
Acknowledgments
..................................................................................................xvii
About the Author
....................................................................................................xix
Chapter
1
Introduction
..........................................................................................1
Chapter
2
Basic Chemistry of Fluoropolymers
.....................................................7
2.1
Polytetrafluoroethylene
...................................................................................7
2.1.1
Industrial Synthesis of Tetrafluoroethylene
........................................7
2.1.2
Properties of Tetrafluoroethylene
.......................................................8
2.1.3
Uses of Tetrafluoroethylene
................................................................9
2.1.4
Polymerization of Tetrafluoroethylene
...............................................9
2.2 Fluorinated
Ethylene
Propylene (FEP)
.........................................................13
2.2.1
Industrial Synthesis of HFP
..............................................................13
2.2.2
Properties of HFP
.............................................................................13
2.2.3
Industrial Process for the Production of FEP
...................................14
2.3
Perfluoroalkoxy (PFA) Resin
........................................................................14
2.3.1
Industrial Synthesis of Perfluoroalkyl Vinyl Ether Monomers
........14
2.3.2
Properties of Perfluoroalkylvinyl Ethers
..........................................15
2.3.3
Industrial Process for the Production of Perfluoroalkoxy Resins
.....15
2.4
PolychlorotrifluoroethyleneiPCTFE)
...........................................................15
2.4.1
Industrial Synthesis of Chlorotrifluoroethylene Monomer
...............15
2.4.2
Properties of CTFE
...........................................................................15
2.4.3
Industrial Process for the Production of PCTFE
..............................16
2.5
Polyvinylidene
Fluoride (PVDF)
..................................................................16
2.5.1
Industrial Synthesis of Vinylidene Fluoride Monomer
....................16
2.5.2
Properties of Vinylidene Fluoride
....................................................17
2.5.3
Industrial Process for the Production of PVDF
................................17
2.6
Polyvinyl Fluoride (PVF)
..............................................................................18
2.6.1
Industrial Synthesis of Vinyl Fluoride
(VF)
Monomer
....................18
2.6.2
Industrial Process for the Production of PVF
...................................18
2.7
Ethylene
Chlorotrifluoroethylene (ECTFE) Copolymer
...............................18
2.7.1
Industrial Process for the Production of ECTFE
..............................18
2.8
Ethylene
Tetrafluoroethylene (ETFE) Copolymer
........................................19
2.8.1
Industrial Process for the Production of ETFE
................................19
2.9
Terpolymers of TFE, HFP, and VDF (THV Fluoroplastic)
..........................19
2.10
Terpolymers of HFP, TFE. and
Ethylene
(Hexafluoropropylene,
Tetrafluoroethylene. and
Ethylene
Fluoroplastic)
..........................................20
VII
viii Technology of Fluoropolymers,
Second Edition
2.11
Fluorocarbon
Elastomers..............................................................................20
2.11.1
Industrial
Process for the Production of Fluorocarbon
Elastomers
.....................................................................................................21
2.12
Fluorosilicones
..............................................................................................21
2.12.1
Industrial Process for the Production of Fluorosilicones
................22
2.13
Phosphazenes
................................................................................................22
Chapter
3
Properties of Commercial Fluoropolymers
........................................29
3.1
Properties as Related to the Structure of the Polymers
................................29
3.1.1
Fluoroplastics
....................................................................................29
3.1.2
Fluoroelastomers
...............................................................................33
3.2
Properties of Individual Commercial Fluoropolymers
.................................34
3.2.1
Polytetrafluoroethylene
.....................................................................34
3.2.2
Copolymers of Tetrafluoroethylene and
Hexafluoropropylene (FEP)
..............................................................38
3.2.3
Copolymers of Tetrafluoroethylene and Perfluoroalkyl Ethers
(PFAandMFA)
................................................................................41
3.2.4
Copolymers of
Ethylene
and Tetrafluoroethylene (ETFE)
...............43
3.2.5
Polyvinylidene Fluoride (PVDF)
......................................................44
3.2.6
Polychlorotrifluoroethylene (PCTFE)
..............................................47
3.2.7
Copolymer of
Ethylene
and Chlorotrifluoroethylene (ECTFE)
.......48
3.2.8
Terpolymer of Tetrafluoroethylene, Hexafluoropropylene, and
Vinylidene (THV) Fluoride (THV Fluoroplastic)
............................48
3.2.9
Terpolymer of Hexafluoropropylene, Tetrafluoroethylene, and
Ethylene (HTE)
Fluoroplastic
...........................................................49
3.2.10
Polyvinyl Fluoride (PVF)
.................................................................50
Chapter
4
Processing and Applications of Commercial Fluoroplastics
..............57
4.1
Processing of Polytetrafluoroethylene (PTFE)
.............................................58
4.1.1
Processing of Granular Resins
.........................................................58
4.1.2
Processing of Fine Powders
..............................................................68
4.2
Applications for PTFE
..................................................................................71
4.3
Processing of Melt-Processible Fluoroplastics
..............................................74
4.3.1
Melt-Processible Perfluoroplastics
....................................................74
4.4
Processing of Other Melt-Processible Fluoroplastics
...................................75
4.4.1
Copolymers of
Ethylene
and Tetrafluoroethylene (ETFE)
...............75
4.4.2
Polyvinylidene Fluoride (PVDF)
......................................................76
4.4.3
Polychlorotrifluoroethylene (PCTFE)
..............................................77
4.4.4
Copolymers of
Ethylene
and Chlorotrifluoroethylene (ECTFE)
......77
4.4.5
THV Fluoroplastics
..........................................................................77
4.5
Applications for Melt-Processible Fluoroplastics
.........................................78
4.5.1
Applications for FEP
........................................................................78
4.5.2
Applications for PFA and MFA
........................................................78
4.5.3
Applications for Copolymers of
Ethylene
and Tetrafluoroethylene..
79
Contents
¡x
4.5.4 Applications
for PVDF
.....................................................................81
4.5.5 Applications
for Polychlorotrifluoroethylene
...................................82
4.5.6 Applications
for ECTFE
...................................................................83
4.5.7 Applications
for THV
Fluorothermoplastics....................................86
4.5.8 Applications
for HTE
Fluorothermoplastics....................................87
4.6 Processing and Applications
of Polyvinylfluoride
........................................87
4.6.1 Processing
of Polyvinyl
Fluoride......................................................87
4.6.2 Applications
for
Polyvinyl Fluoride.................................................88
Chapter
5
Properties,
Processing, and Applications
of
Fluoroelastomers..........93
5.1 Fluorocarbon Elastomers..............................................................................93
5.1.1
Introduction
......................................................................................93
5.1.2
Properties Related to the Polymer Structure
....................................94
5.1.3
Cross-Linking Chemistry
.................................................................98
5.1.4
Formulation of Compounds from Fluorocarbon Elastomers
..........101
5.1.5
Mixing and Processing of Compounds from Fluorocarbon
Elastomers
.......................................................................................108
5.1.6
Solution and Latex Coating
............................................................111
5.1.7
Curing
.............................................................................................112
5.1.8
Physical and Mechanical Properties of Cured Fluorocarbon
Elastomers
.......................................................................................113
5.1.9
Applications of FKM
......................................................................117
5.1.10
Applications of FFKM
...................................................................120
5.1.11
Applications of FKM in Coatings and Sealants
.............................122
5.2
Fluorosilicone Elastomers
...........................................................................122
5.2.1
Introduction
....................................................................................122
5.2.2
Polymerization
................................................................................123
5.2.3
Processing
.......................................................................................123
5.2.4
Properties
........................................................................................124
5.2.5
Applications
....................................................................................128
5.2.6
Toxicity
and Safety
.........................................................................128
Chapter
6
Technology and Applications of Aqueous Fluoropolymer Systems.
133
6.1
Introduction
.................................................................................................133
6.2
PTFE Dispersions
.......................................................................................134
6.3
Other Perfluoropolymer Dispersions
...........................................................135
6.3.1
FEP Dispersions
.............................................................................135
6.3.2
PFA and MFA Dispersions
.............................................................135
6.3.3
Dispersions of Modified PTFE
......................................................135
6.3.4
Dispersions of PTFE Micropowders
..............................................136
6.4
Processing of PTFE Dispersions
.................................................................136
6.4.1
Impregnation
................................................................................... 36
6.4.2
Fabric Coating
................................................................................137
6.4.3
Cast Films
.......................................................................................
142
χ
Technology
of Fluoropolymers, Second Edition
6.4.4
Other Applications of PTFE Aqueous Dispersions
........................147
6.5
Processing of Aqueous Dispersions of FEP and PFA/MFA
.......................147
6.5.1
Processing
.......................................................................................147
6.5.2
Applications
....................................................................................148
6.6
Processing of Aqueous Dispersions of Polyvinylidene Fluoride
................148
6.6.1
Processing of PVDF Dispersions
....................................................148
6.6.2
Applications of PVDF Aqueous Dispersions
.................................148
6.7
Aqueous Dispersions of THV Fluoroplastics
.............................................148
6.7.1
Processing of THV Dispersions
.....................................................148
6.7.2
Applications of THV Dispersions
..................................................148
6.8
Fluorocarbon Elastomers in Latex Form, Processing and Applications
.....149
6.9
Health and Safety
........................................................................................149
Chapter
7
Other Fluoropolymers
.......................................................................151
7.1
Amorphous Fluoropolymers
.......................................................................151
7.1.1
Applications of Amorphous Perfluoropolymers
.............................154
7.2 Fluorinated Acrylates..................................................................................154
7.2.1
Applications of
Fluorinated
Acrylates
............................................154
7.3 Fluorinated Polyurethanes..........................................................................156
7.3.1
Applications of
Fluorinated
Polyurethanes
....................................156
7.4 Fluorinated
Thermoplastic Elastomers
.......................................................160
7.4.1
Applications of
Fluorinated
Thermoplastic Elastomers
.................161
7.5
Copolymers of Chlorotrifluoroethylene and Vinyl Ether
............................162
7.5.1
Applications of Copolymers of CTFE and Vinyl Ether
.................162
7.6
Perfluorinated Ionomers
..............................................................................163
7.7
Modified Polytetrafluoroethylene
................................................................164
7.8
PTFE Micropowders
...................................................................................164
Chapter
8
Effects of Heat, Radiation, and Environment on Fluoropolymers
... 171
8.1
Effects of Heat
..................................■..........................................................171
8.1.1
Thermal Degradation of Perfiuoroplastics
...................................... 171
8.1.2
Thermal Degradation of Other Fluoroplastics
................................172
8.1.3
Thermal Degradation of Fluorocarbon Elastomers
........................173
8.1.4
Thermal Degradation of Fluorosilicones
........................................173
8.2
Effects of Ionizing Radiation
......................................................................173
8.2.1
Effects of Ionizing Radiation on PTFE, FEP, and PFA/MFA
(Methyl
fi
uoroalkoxy)
......................................................................174
8.2.2
Effects of Ionizing Radiation on Other Fluoroplastics
...................175
8.2.3
Effects of Ionizing Radiation on Fluorocarbon Elastomers
...........176
8.3
Effects of UV Radiation
..............................................................................176
Chapter
9
Recycling of Fluoropolymers
........................................................... 181
Contents xi
Chapter
10
Safety, Hygiene, and Disposal of Fluoropolymers
...........................183
10.1
Safety and Disposal of Fluoroplastics
.........................................................183
10.1.1
Toxicology of Fluoroplastics
...........................................................183
10.1.2
Thermal Behavior of Fluoroplastics
...............................................183
10.1.3
Medical Applications
......................................................................185
10.1.4
Food Contact
...................................................................................185
10.1.5
Environmental Protection and Disposal Methods for
Fluoroplastics
..................................................................................185
10.2
Safety and Disposal of Fluoroelastomers
....................................................186
10.2.1
Safety and Hygiene in the Processing of Fluoroelastomers
...........186
10.2.2
Safety and Hygiene in the Use of Fluoroelastomers
.......................186
10.2.3
Disposal of Production and Post-Consumer
Fluoroelastomer Scrap
....................................................................186
Chapter
11
New Developments and Current Trends
...........................................187
11.1
New Developments and Trends in Chemistry and Processing
...................187
11.1.1
New Developments in Polymerization
............................................187
11.1.2
New Developments in Processing
..................................................189
11.2
New Developments and Trends in Applications
.........................................190
11.2.1
Automotive Industry
.......................................................................190
11.2.2
Aerospace Industry
.........................................................................191
11.2.3
Telecommunications
.......................................................................191
11.2.4
Other Applications
..........................................................................191
11.3
Environmental Issues Regarding
Fluorinated
Substances
..........................191
Appendix
1:
Environmental Issues Involving Perfluorooctanoic Acid
...........193
Appendix
2:
Trade Names of Common Commercial Fluoropolymers
...........195
Appendix
3:
Acronyms and Abbreviations
197
Appendix
4:
Glossary of Terms
..........................................................................199
Appendix
5:
Fluoropolymer Bibliography
.........................................................205
Appendix
6:
Properties of PTFE Resins
207
Appendix
7:
Properties of Melt-Processible Fluoropolymers
213
Appendix
8:
Recent U.S. Patents
........................................................................217
Index
......................................................................................................................219
.ι
FLUOROPOLYMERS
Second Edition
The first edition of Technology of
Fluorpolymers was
developed to provide systematic
fundamental information to professionals working in industrial practice. However,
since its publication almost eight years ago, the industry has changed. The development
of new technologies and applications, coupled with environmental issues such as
the
toxicity
of certain additives and products of thermal decomposition of certain
fluoropolymers, has influenced the field.
Features
Reflects recent developments, such as melt-processable polytetrafluoroethylene
(PTFE) and other novel polymers
•
Highlights new industrial, military, medical, and consumer goods applications
•
Incorporates new knowledge on properties-structure correlation
Adds more detailed information on equipment and processing conditions
•
Discusses the effects of heat and radiation on fluoropolymers
Addresses critical environment issues and health concerns, particularly for
certain fluorosurfactants
Fully revised and updated, this second edition continues to provide industrial chemists,
technologists, and engineers with the most accurate, compact, and practical source
on fluoropolymers (such as Teflon®). In keeping with the focus of the first edition,
the book stresses the practical aspects of fluoropolymers and their industrial application.
Written by an industry veteran, the handbook systematically covers the field, providing
a complete overview of current technology. Using clear and concise language, the
book brings together information from a wide variety of sources to make a compact,
well-organized resource. The practical approach provides an accessible introduction
to fluoropolymers for those just entering the field, and a solid reference for those
already working in the industry.
|
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| id | DE-604.BV035460589 |
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| indexdate | 2024-07-09T21:35:46Z |
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| publisher | CRC Press |
| record_format | marc |
| spelling | Drobny, Jiri G. Verfasser (DE-588)1050691377 aut Technology of fluoropolymers Jiri George Drobny 2. ed. Boca Raton, Fla. [u.a.] CRC Press 2009 XIX, 227 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Fluoropolymères ram Fluoropolymers Fluorpolymere (DE-588)4154866-8 gnd rswk-swf Fluorpolymere (DE-588)4154866-8 s DE-604 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017380435&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017380435&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Drobny, Jiri G. Technology of fluoropolymers Fluoropolymères ram Fluoropolymers Fluorpolymere (DE-588)4154866-8 gnd |
| subject_GND | (DE-588)4154866-8 |
| title | Technology of fluoropolymers |
| title_auth | Technology of fluoropolymers |
| title_exact_search | Technology of fluoropolymers |
| title_full | Technology of fluoropolymers Jiri George Drobny |
| title_fullStr | Technology of fluoropolymers Jiri George Drobny |
| title_full_unstemmed | Technology of fluoropolymers Jiri George Drobny |
| title_short | Technology of fluoropolymers |
| title_sort | technology of fluoropolymers |
| topic | Fluoropolymères ram Fluoropolymers Fluorpolymere (DE-588)4154866-8 gnd |
| topic_facet | Fluoropolymères Fluoropolymers Fluorpolymere |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017380435&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017380435&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT drobnyjirig technologyoffluoropolymers |