Chemistry and physics of mechanical hardness:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, NJ
Wiley
2009
|
| Schriftenreihe: | Wiley series on processing of engineering materials
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | XII, 214 S. graph. Darst. |
| ISBN: | 0470226528 9780470226520 |
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Datensatz im Suchindex
| _version_ | 1804138913520943104 |
|---|---|
| adam_text | TABLE
OF
CONTENTS
Preface
xi
1
Introduction
1
1.1
Why Hardness Matters (A Short History)
1
1.2
Purpose of This Book
5
1.3
The Nature of Hardness
7
References
10
2
Indentation
11
2.1
Introduction
11
2.2
The Chin-Gilman Parameter
14
2.3
What Does Indentation Hardness Measure?
14
2.4
Indentation Size Effect
20
2.5
Indentation Size (From Macro to
Nano)
22
2.6
Indentation vs. Scratch Hardness
23
2.7
Blunt or Soft Indenters
24
2.8
Anisotropy
24
2.9
Indenter and Specimen Surfaces
25
References
25
3
Chemical Bonding
27
3.1
Forms of Bonding
27
3.2
Atoms
28
3.3
State Symmetries
29
3.4
Molecular Bonding (Hydrogen)
31
3.5
Covalent Bonds
36
3.6
Bonding in Solids
41
3.6.1
Ionic Bonding
41
3.6.2
Metallic Bonding
43
3.6.3
Covalent Crystals
44
3.7
Electrodynamic Bonding
45
3.8
Polarizability
47
References
48
vi
TABLE OF CONTENTS
4
Plastic Deformation
51
4.1
Introduction
51
4.2
Dislocation Movement
52
4.3
Importance of Symmetry
55
4.4
Local Inelastic Shearing of Atoms
56
4.5
Dislocation Multiplication
57
4.6
Individual Dislocation Velocities
(Microscopic Distances)
59
4.7
Viscous Drag
60
4.7.1
Pure Metals
61
4.7.2
Covalent Crystals
62
4.8
Deformation-Softening and Elastic Relaxation
62
4.9
Macroscopic Plastic Deformation
63
References
64
5
Covalent Semiconductors
67
5.1
Introduction
67
5.2
Octahedral Shear Stiffness
69
5.3
Chemical Bonds and Dislocation Mobility
71
5.4
Behavior of Kinks
75
5.5
Effect of Polarity
77
5.6
Photoplasticity
79
5.7
Surface Environments
80
5.8
Effect of Temperature
80
5.9
Doping Effects
80
References
81
6
Simple Metals and Alloys
83
6.1
Intrinsic Behavior
83
6.2
Extrinsic Sources of Plastic Resistance
85
6.2.1
Deformation-Hardening
85
6.2.2
Impurity Atoms (Alloying)
87
6.2.3
Precipitates (Clusters, Needles, and Platelets)
89
6.2.4
Grain-Boundaries
90
6.2.5
Surface Films (Such as Oxides)
94
6.2.6
Magnetic Domain Walls
95
6.2.7
Ferroelectric Domain-Walls
%
6.2.8
Twin Boundaries
%
References
96
7
Transition Metals
99
7.1
Introduction
99
7.2
Rare Earth Metals
101
References
101
TABLE
OF
CONTENTS
vii
8
Intermetallic
Compounds
103
8.1
Introduction
103
8.2
Crystal Structures
104
8.2.1
Sigma Phase
104
8.2.2
Laves Phases
105
8.2.3
NÌ3AI
107
8.3
Calculated Hardness of NiAl
112
8.4
Superconducting Intermetallic Compounds
113
8.5
Transition Metal Compounds
115
References
116
9
Ionic Crystals
119
9.1
Alkali Halides
119
9.2
Glide in the NaCl Structure
120
9.3
Alkali Halide Alloys
123
9.4
Glide in CsCl Structure
124
9.5
Effect of Imputities
124
9.6
Alkaline Earth Fluorides
126
9.7
Alkaline Earth
Sulfides 128
9.8
Photomechanical Effects
128
9.9
Effects of Applied Electric Fields
129
9.10
Magneto-Plasticity
129
References
129
10
Metal-Metalloids (Hard Metals)
131
10.1
Introduction
131
10.2
Carbides
132
10.3
Tungsten Carbide
134
10.4
Borides
136
10.5
Titanium Diboride
137
10.6
Rare Metal Diborides
138
10.7
Hexaborides
138
10.8
Boron Carbide (Carbon Quasi-Hexaboride)
140
10.9
Nitrides
141
References
141
11
Oxides
143
11.1
Introduction
143
11.2
Silicates
143
11.2.1
Quartz
144
11.2.2
Hydrolytic Catalysis
146
11.2.3
Talc
146
11.3
Cubic Oxides
147
11.3.1
Alkaline Earth Oxides
147
vüi
TABLE OF CONTENTS
11.3.2
Perovskites
148
11.3.3
Garnets
150
11.3.3.1
(YsAlsOn)—YAG
151
11.4
Hexagonal (Rhombohedral) Oxides
152
11.4.1
Aluminum Oxide (Sapphire)
152
11.4.2
Hexaboron Oxide
153
11.5
Comparison of Transition Metal Oxides with
Hard Metals
155
References
156
12
Molecular Crystals
157
12.1
Introduction
157
12.2
Anthracene
158
12.3
Sucrose
159
12.4
Amino
Acids
159
12.5
Protein Crystals
160
12.6
Energetic Crystals (Explosives)
161
12.7
Commentary
161
References
161
13
Polymers
163
13.1
Introduction
163
13.2
Thermosetting Resins (Phenolic and
Epoxide)
164
13.3
Thermoplastic Polymers
165
13.4
Mechanisms of Inelastic Plasticity
166
13.5
Natural Polymers (Plants)
166
13.6
Natural Polymers (Animals)
168
References
168
14
Glasses
171
14.1
Introduction
171
14.2
Inorganic Glasses
172
14.3
Metallic Glasses
176
14.3.1
Hardness
—
Shear Modulus Relationship
177
14.3.2
Stable Compositions
180
References
180
15 Hot Hardness
183
15.1
Introduction
183
15.2
Nickel Aluminide versus Oxides
184
15.3
Other Hard Compounds
184
15.4
Metals
185
TABLE
OF
CONTENTS
ix
15.5
Intermetallic
Compounds
187
References
187
16
Chemical
Hardness
189
16.1
Introduction
189
16.2
Definition of Chemical Hardness
190
16.3
Physical (Mechanical) Hardness
192
16.4
Hardness and Electronic Stability
193
16.5
Chemical and Elastic Hardness (Stiffness)
194
16.6
Band Gap Density and Polarizability
194
16.7
Compression Induced Structure Changes
195
16.8
Summary
196
References
196
17
Superhard Materials
197
17.1
Introduction
197
17.2
Principles for High Hardness
197
17.3
Friction at High Loads
198
17.4
Superhard Materials
199
References
200
Index
203
THE CHEMISTRY AND PHYSICS
OF MECHANICAL HARDNESS
Chemistry and Physics of Mechanical Hardness presents a general introduction to
hardness measurement and the connections between hardness and fundamental
materials properties.
Beginning with an introduction on the importance of hardness in the development of
technology, the book systematically covers:
Indentation
Chemical bonding
Plastic deformation
Covalent semiconductors
Simple metals and alloys
Transition metals
Intermetallic compounds
Ionic crystals
Metal-metalloids
Oxides
Molecular crystals
Polymers
Glasses
Hot hardness
Chemical hardness
Super-hard materials
Chemistry and Physics of Mechanical Hardness is essential reading for materials scien¬
tists, mechanical engineers, metallurgists, ceramists, chemists, and physicists who are
interested in learning how hardness is related to other properties and to the building
blocks of everyday matter.
is Research Professor in the Department of Materials Sci¬
ence and Engineering at UCLA. He has been contributing to the scientific literature
of mechanical hardness for almost fifty years. Dr.
Gilman
is the author of three other
books and
325
technical papers, and the owner of six patents. He has been an editor
for various books and magazines.
|
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| discipline | Physik Chemie Werkstoffwissenschaften |
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| id | DE-604.BV035459193 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:35:45Z |
| institution | BVB |
| isbn | 0470226528 9780470226520 |
| language | English |
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| record_format | marc |
| series2 | Wiley series on processing of engineering materials |
| spelling | Gilman, John J. Verfasser aut Chemistry and physics of mechanical hardness John J. Gilman Hoboken, NJ Wiley 2009 XII, 214 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wiley series on processing of engineering materials Hardness Strength of materials Festigkeit (DE-588)4016916-9 gnd rswk-swf Physikalische Eigenschaft (DE-588)4134738-9 gnd rswk-swf Werkstoff (DE-588)4065579-9 gnd rswk-swf Härte (DE-588)4158703-0 gnd rswk-swf Härteprüfung (DE-588)4022844-7 gnd rswk-swf Chemische Eigenschaft (DE-588)4371174-1 gnd rswk-swf Härte (DE-588)4158703-0 s Werkstoff (DE-588)4065579-9 s Chemische Eigenschaft (DE-588)4371174-1 s Physikalische Eigenschaft (DE-588)4134738-9 s DE-604 Härteprüfung (DE-588)4022844-7 s Festigkeit (DE-588)4016916-9 s Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017379068&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017379068&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Gilman, John J. Chemistry and physics of mechanical hardness Hardness Strength of materials Festigkeit (DE-588)4016916-9 gnd Physikalische Eigenschaft (DE-588)4134738-9 gnd Werkstoff (DE-588)4065579-9 gnd Härte (DE-588)4158703-0 gnd Härteprüfung (DE-588)4022844-7 gnd Chemische Eigenschaft (DE-588)4371174-1 gnd |
| subject_GND | (DE-588)4016916-9 (DE-588)4134738-9 (DE-588)4065579-9 (DE-588)4158703-0 (DE-588)4022844-7 (DE-588)4371174-1 |
| title | Chemistry and physics of mechanical hardness |
| title_auth | Chemistry and physics of mechanical hardness |
| title_exact_search | Chemistry and physics of mechanical hardness |
| title_full | Chemistry and physics of mechanical hardness John J. Gilman |
| title_fullStr | Chemistry and physics of mechanical hardness John J. Gilman |
| title_full_unstemmed | Chemistry and physics of mechanical hardness John J. Gilman |
| title_short | Chemistry and physics of mechanical hardness |
| title_sort | chemistry and physics of mechanical hardness |
| topic | Hardness Strength of materials Festigkeit (DE-588)4016916-9 gnd Physikalische Eigenschaft (DE-588)4134738-9 gnd Werkstoff (DE-588)4065579-9 gnd Härte (DE-588)4158703-0 gnd Härteprüfung (DE-588)4022844-7 gnd Chemische Eigenschaft (DE-588)4371174-1 gnd |
| topic_facet | Hardness Strength of materials Festigkeit Physikalische Eigenschaft Werkstoff Härte Härteprüfung Chemische Eigenschaft |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017379068&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017379068&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT gilmanjohnj chemistryandphysicsofmechanicalhardness |