Principles and applications of photochemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Chichester
Wiley
2009
|
| Ausgabe: | 1. publ. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV, 250 S. Ill., graph. Darst. |
| ISBN: | 9780470014943 9780470014936 |
Internformat
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| 100 | 1 | |a Wardle, Brian |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Principles and applications of photochemistry |c Brian Wardle |
| 250 | |a 1. publ. | ||
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Datensatz im Suchindex
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| adam_text | CONTENTS PREFACE XIII 1 INTRODUCTORY CONCEPTS 1 AIMS AND OBJECTIVES 1
1.1 THE QUANTUM NATURE OF MATTER AND LIGHT 2 1.2 MODELLING ATOMS: ATOMIC
ORBITALS 6 1.3 MODELLING MOLECULES: MOLECULAR ORBITALS 9 1.4 MODELLING
MOLECULES: ELECTRONIC STATES 13 1.5 LIGHT SOURCES USED IN PHOTOCHEMISTRY
16 1.5.1 THE MERCURY LAMP 17 1.5.2 LASERS 18 1.6 EFFICIENCY OF
PHOTOCHEMICAL PROCESSES: QUANTUM YIELD 25 1.6.1 PRIMARY QUANTUM YIELD
( |)) 25 1.6.2 OVERALL QUANTUM YIELD ( 3 ) 26 2 LIGHT ABSORPTION AND
ELECTRONICALLY-EXCITED STATES 29 AIMS AND OBJECTIVES 29 2.1 INTRODUCTION
29 2.2 THE BEER-LAMBERT LAW 30 2.3 THE PHYSICAL BASIS OF LIGHT
ABSORPTION BY MOLECULES 32 2.4 ABSORPTION OF LIGHT BY ORGANIC MOLECULES
35 2.5 LINEARLY-CONJUGATED MOLECULES 39 2.6 SOME SELECTION RULES 42 2.7
ABSORPTION OF LIGHT BY INORGANIC COMPLEXES 43 VIII CONTENTS 3 THE
PHYSICAL DEACTIVATION OF EXCITED STATES 47 AIMS AND OBJECTIVES 47 3.1
INTRODUCTION 47 3.2 JABLONSKI DIAGRAMS 49 3.2.1 VIBRATIONAL RELAXATION
51 3.2.2 INTERNAL CONVERSION 51 3.2.3 INTERSYSTEM CROSSING 52 3.2.4
FLUORESCENCE 52 3-2.5 PHOSPHORESCENCE 52 3.3 EXCITED-STATE LIFETIMES 53
3.3.1 EXCITED SINGLET-STATE LIFETIME 53 3.3.2 EXCITED SINGLET-STATE
RADIATIVE LIFETIME 55 3.3.3 LIFETIMES OF THE TI EXCITED STATE 57 4
RADIATIVE PROCCSSES OF EXCITED STATES 59 AIMS AND OBJECTIVES 59 4.1
INTRODUCTION 60 4.2 ELUORESCENCE AND FLUORESCENCE SPECTRA 61 4.3 AN
EXCEPTION TO KASHA S RULE 63 4.4 FLUORESCENCE QUANTUM YIELD 64 4.5
FACTORS CONTRIBUTING TO FLUORESCENCE BEHAVIOUR 65 4.5.1 THE NATURE OF SI
65 4.5.2 MOLECULAR RIGIDITY 66 4.5.3 THE EFFECT OF SUBSTITUENT GROUPS 66
4.5.4 THE HEAVY ATOM EFFECT 66 4.6 MOLECULAR FLUORESCENCE IN ANALYTICAL
CHEMISTRY 67 4.7 PHOSPHORESCENCE 70 4.8 DELAYED FLUORESCENCE 73 4.8.1
P-TYPE DELAYED FLUORESCENCE (TRIPLET-TRIPLET ANNIHILATION) 73 4.8.2
E-TYPE DELAYED FLUORESCENCE (THERMALLY- ACTIVATED DELAYED FLUORESCENCE)
73 4.9 LANTHANIDE LUMINESCENCE 74 5 INTRAMOLECULAR RADIATIONLESS
TRANSITIONS OF EXCITED STATES AIMS AND OBJECTIVES 77 5.1 INTRODUCTION 77
5.2 THE ENERGY GAP LAW 79 5.3 THE FRANCK-CONDON FACTOR 79 5.3.1 CASE
(A): SSOTH ELECTRONIC STATES HAVE A SIMILAR GEOMETRY, WITH A LARGE ENERGY
SEPARATION BETWEEN THE STATES 80 CONTENTS 5.3.2 CASE (B): BOTH
ELECTRONIC STATES HAVE A SIMILAR GEOMETRY, WITH A SMALL ENERGY
SEPARATION BETWEEN THE STATES 80 5.3.3 CASE (C): THE ELECTRONIC STATES
HAVE DIFFERENT GEOMETRIES, WITH A LARGE ENERGY SEPARATION BETWEEN THE
STATES 81 5.4 HEAVY ATOM EFFECTS ON INTERSYSTEM CROSSING 82 5.5
EL-SAYED S SELECTION RULES FOR INTERSYSTEM CROSSSING 83 INTERMOLECULAR
PHYSICAL PROCESSES OF EXRITED STATES 87 AIMS AND OBJECTIVES 87 6.1
QUENCHING PROCESSES 88 6.2 EXCIMERS 90 6.2.1 EXCIMER EMISSION IN CA 2+
SENSING 93 6.3 EXCIPLEXES 93 6.3.1 EXCIPLEX FLUORESCENCE IMAGING 95 6.4
INTERMOLECULAR ELECTRONIC ENERGY TRANSFER 96 6.5 THE TRIVIAL OR
RADIATIVE MECHANISM OF ENERGY TRANSFER 97 6.6 LONG-RANGE DIPOLE-DIPOLE
(COULOMBIC) ENERGY TRANSFER 98 6.6.1 DYNAMIC PROCESSES WITHIN LIVING
CELLS 101 6.6.2 MOLECULAR RULER 102 6.6.3 MOLECULAR BEACONS 103 6.7
SHORT-RANGE ELECTRON-EXCHANGE ENERGY TRANSFER 105 6.7.1 TRIPLET-TRIPLET
ENERGY TRANSFER AND PHOTOSENSITISATION 106 6.7.2 SINGLET OXYGEN AND
PHOTODYNAMIC THERAPY FOR CANCER TREATMENT 108 6.8 PHOTOINDUCED ELECTRON
TRANSFER (PET) 110 6.8.1 FLUORESCENCE SWITCHING BY PET 111 6.8.2 THE
MARCUS THEORY OF ELECTRON TRANSFER 112 6.8.3 EXPERIMENTAL EVIDENCE
RELATING TO THE MARCUS EQUATION 114 6.8.4 EVIDENCE FOR THE INVERTED
REGION 117 SOME ASPECTS OF THE CHEMICAL PROPERTIES OF EXCITED STATES 119
AIMS AND OBJECTIVES 119 7.1 THE PATHWAY OF PHOTOCHEMICAL REACTIONS 120
7.2 DIFFERENCES BETWEEN PHOTOCHEMICAL AND THERMAL REACTIONS 124 7.3
PHOTOLYSIS 127 CONTENTS 7.3.1 PHOTOHALOGENATION OF HYDROCARBONS 128
7.3.2 THE STRATOSPHERIC OZONE LAYER: ITS PHOTOCHEMICAL FORMATION AND
DEGRADATION 129 7.3.3 RADICALS IN THE POLLUTED TROPOSPHERE 132 7.4 AN
INTRODUCTION TO THE CHEMISTRY OF CARBON-CENTRED RADICALS 133 7.5
PHOTOCHEMISTRY OF THE COMPLEXES AND ORGANOMETALLIC COMPOUNDS OF D-BLOCK
ELEMENTS 135 7.5.1 THE PHOTOCHEMISTRY OF METAL COMPLEXES 135 7.5.2 AN
ASIDE: REDOX POTENTIALS INVOLVED IN PHOTOREDOX REACTIONS 140 7.5.3
ORGANOMETALLIC PHOTOCHEMISTRY 141 THE PHOTOCHEMISTRY OF ALKENES 145 AIMS
AND OBJECTIVES 145 8.1 EXCITED STATES OF ALKENES 146 8.2 GEOMETRICAL
ISOMERISATION BY DIRECT IRRADIATION OF C=C COMPOUNDS 147 8.2.1
PHOTOTHERAPY 148 8.2.2 VISION 148 8.3 PHOTOSENSITISED GEOMETRICAL
ISOMERISATION OF C=C COMPOUNDS 149 8.3.1 SYNTHESIS 150 8.4 CONCERTED
PHOTOREACTIONS 151 8.4.1 ELECTROCYCLIC REACTIONS 152 8.4.2 SIGMATROPIC
SHIFTS 155 8.5 PHOTOCYCLOADDITION REACTIONS 157 8.5.1 SOLAR ENERGY
STORAGE 158 8.6 PHOTOADDITION REACTIONS 159 8.6.1 DNA DAMAGE BY UV 159
THE PHOTOCHEMISTRY OF CARBONYL COMPOUNDS 161 AIMS AND OBJECTIVES 161 9.1
EXCITED STATES OF CARBONYL COMPOUNDS 162 9.2 A-CLEAVAGE REACTIONS 163
9.3 INTERMOLECULAR HYDROGEN-ABSTRACTION REACTIONS 166 9.4 INTRAMOLECULAR
HYDROGEN-ABSTRACTION REACTIONS 167 9.5 PHOTOCYLOADDITION REACTIONS 168
9.6 THE ROLE OF CARBONYL COMPOUNDS IN POLYMER CHEMISTRY 169 9.6.1 VINYL
POLYMERISATION 170 CONTENTS XI 9.6.2 PHOTOCHEMICAL CROSS-LINKING OF
POLYMERS 170 9.6.3 PHOTODEGRADATION OF POLYMERS 172 10 INVESTIGATING
SOME ASPECTS OF PHOTOCHEMICAL REACTION MECHANISMS 173 AIMS AND
OBJECTIVES 173 10.1 INTRODUCTION 174 10.2 INFORMATION FROM ELECTRONIC
SPECTRA 174 10.3 TRIPLET-QUENCHING STUDIES 176 10.4 SENSITISATION 180
10.5 FLASH PHOTOLYSIS STUDIES 182 10.5.1 AN ASIDE: SOME BASIC IDEAS ON
REACTION KINETICS 186 10.5.2 FLASH PHOTOLYSIS STUDIES IN BIMOLECULAR
ELECTRON-TRANSFER PROCESSES 187 10.5.3 PHOTOCHEMISTRY OF SUBSTITUTED
BENZOQUINONES IN ETHANOL/WATER 190 10.5.4 TIME-RESOLVED INFRARED
SPECTROSCOPY 192 10.5.5 FEMTOCHEMISTRY 193 10.6 LOW-TEMPERATURE STUDIES
195 FURTHER READING 196 11 SEMICONDUCTOR PHOTOCHEMISTRY 197 AIMS AND
OBJECTIVES 197 11.1 INTRODUCTION TO SEMICONDUCTOR PHOTOCHEMISTRY 198
11.2 SOLAR-ENERGY CONVERSION BY PHOTOVOLTAIC CELLS 199 11.2.1
DYE-SENSITISED PHOTOVOLTAIC CELLS 201 11.3 SEMICONDUCTORS AS SENSITISERS
FOR WATER SPLITTING 204 11.4 SEMICONDUCTOR PHOTOCATALYSIS 208 11.5
SEMICONDUCTOR-PHOTOINDUCED SUPERHYDROPHILICITY 211 FURTHER READING 212
12 AN INTRODUCTION TO SUPRAMOLECULAR PHOTOCHEMISTRY 213 AIMS AND
OBJECTIVES 213 12.1 SOME BASIC IDEAS 214 12.2 HOST-GUEST SUPRAMOLECULAR
PHOTOCHEMISTRY 215 12.2.1 MICELLES 215 12.2.2 ZEOLITES AS SUPRAMOLECULAR
HOSTS FOR PHOTOCHEMICAL TRANSFORMATIONS 217 12.2.3 CYCLODEXTRINS AS
SUPRAMOLECULAR HOSTS 220 12.3 SUPRAMOLECULAR PHOTOCHEMISTRY IN NATURAL
SYSTEMS 221 XII CONTENTS 12.3.1 VISION 221 12.3.2 PHOTOSYNTHESIS 222
12.3.3 SSACTERIAL PHOTOSYNTHESIS 227 12.4 ARTIFICIAL PHOTOSYNTHESIS 229
12.5 PHOTOCHEMICAL SUPRAMOLECULAR DEVICES 233 12.5.1 DEVICES FOR
PHOTOINDUCED ENERGY OR ELECTRON TRANSFER 233 12.5.2 DEVICES FOR
INFORMATION PROCESSING BASED ON PHOTOCHEMICAL OR PHOTOPHYSICAL PROCESSES
234 12.5.3 DEVICES DESIGNED TO UNDERGO EXTENSIVE CONFORMATIONAL CHANGES
ON PHOTOEXCITATION: PHOTOCHEMICALLY-DRIVEN MOLECULAR MACHINES 235
FURTHER READING 238 INDEX 241
|
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| discipline | Chemie / Pharmazie |
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| indexdate | 2024-07-09T21:35:07Z |
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| isbn | 9780470014943 9780470014936 |
| language | English |
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| spelling | Wardle, Brian Verfasser aut Principles and applications of photochemistry Brian Wardle 1. publ. Chichester Wiley 2009 XIV, 250 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Photochemistry Fotochemie (DE-588)4045873-8 gnd rswk-swf Fotochemie (DE-588)4045873-8 s DE-604 OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017351898&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Wardle, Brian Principles and applications of photochemistry Photochemistry Fotochemie (DE-588)4045873-8 gnd |
| subject_GND | (DE-588)4045873-8 |
| title | Principles and applications of photochemistry |
| title_auth | Principles and applications of photochemistry |
| title_exact_search | Principles and applications of photochemistry |
| title_full | Principles and applications of photochemistry Brian Wardle |
| title_fullStr | Principles and applications of photochemistry Brian Wardle |
| title_full_unstemmed | Principles and applications of photochemistry Brian Wardle |
| title_short | Principles and applications of photochemistry |
| title_sort | principles and applications of photochemistry |
| topic | Photochemistry Fotochemie (DE-588)4045873-8 gnd |
| topic_facet | Photochemistry Fotochemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017351898&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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