Holdings: Gold chemistry :: THWS Bibkatalog

Gold chemistry: highlights and future directions in the life sciences

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Bibliographic Details
Other Authors:	Mohr, Fabian 1975- (Editor)
Format:	Book
Language:	English
Published:	Weinheim WILEY-VCH 2009
Edition:	1. Aufl.
Subjects:	Goldverbindungen
Online Access:	Inhaltstext Inhaltsverzeichnis
Physical Description:	XVI, 408 S. Ill., graph. Darst.
ISBN:	9783527320868

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MARC


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adam_text	IMAGE 1 CONTENTS PREFACE XI FOREWORD XII I LIST OF CONTRIBUTORS XV GOLD(L) NITROGEN CHEMISTRY 1 HANAN E. ABDOU, AHMED A. MOHAMED, ANDJOHN P. FACKLERJR 1.1 INTRODUCTION 1 1.2 TETRA-, TRI-. AND DINUCLEAR GOLD(I) AMIDINATE COMPLEXES 3 1.3 OXIDATIVE-ADDITION REACTIONS TO THE DINUCLEAR GOLD(I) AMIDINATE COMPLEX 9 1.4 MERCURY(II) CYANIDE COORDINATION POLYMER 13 1.5 FORMATION OF MIXED-LIGAND TETRANUCLEAR GOLD(I) NITROGEN CLUSTERS 15 1.6 SOLVENT INFLUENCES ON OXIDATION AND NUCLEARITY OF GOLD GUANIDINATE DERIVATIVES 21 1.7 CYCLIC TRINUCLEAR GOLD(I) NITROGEN COMPOUNDS 24 1.8 OXIDATIVE-ADDITION REACTIONS TO THE CYCLIC TRINUCLEAR GOLD(I)-NITROGEN COMPOUNDS 28 1.9 SUPRAMOLECULAR ENTITIES OF TRINUCLEAR GOLD(I) COMPLEXES SANDWICHING SMALL ORGANIC ACIDS 30 1.10 GOLD(I) AND SILVER(I) MIXED-METAL TRINUCLEAR COMPLEXES 33 1.11 CO OXIDATION OVER AU/TIOZ PREPARED FROM GOLD NITROGEN COMPLEXES 36 1.12 MISCE]]ANEOUS OBSERVATIONS 37 REFERENCES 37 2 CHEMISTRY OFGOLD(LLI) COMPLEXES WITH NITROGEN AND OXYGEN LIGANDS 47 MARIA AGOSTINA CINELLU 2.1 INTRODUCTION 47 2.2 NITROGEN DONOR LIGANDS 47 2.2.1 COMPLEXES WITH NEUTRAL MONODENTATE LIGANDS 47 2.2.2 COMPLEXES WITH ANIONIC MONODENTATE LIGANDS 51 GOLD CHEMISTL}': /\.PPHCATLOLTS AND !-,'UTU.RL' DRRECTLOM IN THE 1 FIE SCIENCES" EDITED BY FABIAN MOHR COPYNGHT 2009 WILEYVCH VERLAG GMBH & CO. KGAA. WEINHCIM ISBN: 97~L527120~G~ IV IMAGE 2 VII CONTENTS 2.2.3 2.2.4 2.2.5 2.3 2.3.1 2.3.2 2.3.3 2.3.4 2.3.5 3 3.1 3.2 3.2.1 3.2.1.1 3.2.1.2 3.2.1.3 3.2.1.4 3.2.2 3.2.2.1 3.2.3 3.2.4 3.2.5 3.2.5.1 3.2.5.2 3.2.5.3 3.2.5.4 3.2.5.5 3.2.5.6 3.2.5.7 3.2.5.8 3.2.5.9 3.2.5.10 3.3 COMPLEXES WITH MULTIDENTATE LIGANDS 53 COMPLEXES WITH MULTIDENTATE LIGANDS CONTAINING ANIONIC N-DONORS 59 COMPLEXES WITH POLYAZAMACROCYCLIC LIGANDS 63 OXYGEN DONOR LIGANDS 65 HYDROXO COMPLEXES 65 OXO COMPLEXES 69 ALKOXO COMPLEXES 72 COMPLEXES WITH OTHER O-DONOR LIGANDS 76 COMPLEXES WITH MIXED N/O LIGANDS 78 REFERENCES 80 PENTAFLUOROPHENYL GOLD COMPLEXES 93 A. LUQUIN, E. CERRADA, AND M. LAGUNA INTRODUCTION 93 PENTAFLUOROPHENYLGOLD(I) DERIVATIVES 94 NEUTRAL PENTAFLUOROPHENYLGOLD(I) DERIVATIVES 95 NEUTRAL PENTAFLUOROPHENYLGOLD(I) DERIVATIVES WITH C-DONOR LIGANDS 97 NEUTRAL PENTAFLUOROPHENYLGOLD(I) DERIVATIVES WITH N-DONOR LIGANDS 100 NEUTRAL PENTAFLUOROPHENYLGOLD(I) DERIVATIVES WITH P-DONOR LIGANDS 101 NEUTRAL PENTAFLUOROPHENYLGOLD(I) DERIVATIVES WITH S-DONOR LIGANDS 102 ANIONIC PENTAFLUOROPHENYLGOLD(I) DERIVATIVES 103 REACTIVITY OF THE ANIONIC PENTAFLUOROPHENYLGOLD(I) COMPLEXES Q[AU(CC,FS)X] 105 CATIONIC PENTAFLUOROPHENYLGOLD(I) DERIVATIVES 107 DI AND POLYNUCLEAR PENTAFLUOROPHENYLGOLD(I) DERIVATIVES 108 HETERONUCLEAR PENTAFLUOROPHENYLGOLD(I) COMPLEXES 117 HETERONUCLEAR PENTAFLUOROPHENYLGOLD(I) BISMUTH COMPLEXES 117 HETERONUCLEAR PENTAFLUOROPHENYLGOLD(I) TIN COMPLEXES 117 HETERONUCLEAR PENTAFLUOROPHENYLGOLD(I) THALLIUM COMPLEXES 117 HETERONUCLEAR PENTAFLUOROPHENYLGOLD(I) SILVER COMPLEXES 119 HETERONUCLEAR PENTAFLUOROPHENYLGOLD(I) COPPER COMPLEXES 122 HETERONUCLEAR PENTAFLUOROPHENYLGOLD(I) PALLADIUM COMPLEXES 122 HETERONUCLEAR PENTAFLUOROPHENYLGOLD(I) RHODIUM COMPLEXES 123 HETERONUCLEAR PENTAFLUOROPHENYLGOLD(I) IRON COMPLEXES 123 HETERONUCLEAR PENTAFLUOROPHENYLGOLD(I) MANGANESE COMPLEXES 126 HETERONUCLEAR PENTAFLUOROPHENYLGOLD(I) CHROMIUM, GOLD MOLYBDENUM AND GOLD TUNSTEN COMPLEXES 126 PENTAFLUOROPHENYLGOLD(III) DERIVATIVES 127 IMAGE 3 3.3.1 3.3.2 3.3.2.1 3.3.2.2 3.3.2.3 3.3.2.4 3.3.3 3.3.4 3.3.5 3.4 3.5 3.5.1 3.5.2 3.6 CONTENTS I VII MONONUCLEAR PENTAFLUOROPHENYLGOLD (III) DERIVATIVES 130 DI AND POLYNUCLEAR PENTAFLUOROPHENYLGOLD(III) DERIVATIVES 138 C-DONOR LIGANDS 138 DIAMINE AND CARBENE BRIDGES 143 N-, P- AND AS-DONOR LIGANDS 143 S- AND SE-DONOR LIGANDS 147 POLYNUCLEAR PENTAFLUOROPHENYLGOLD DERIVATIVES WITH AU(I)-AU(III) BOND 148 HETEROPOLYNUCLEAR PENTAFLUOROPHENYLGOLD(III) DERIVATIVES 149 PENTAFLUOROPHENYLGOLD(III) DERIVATIVES AS CATALYST 150 GOLD CLUSTERS 155 PENTAFLUOROPHENYLGOLD(II) DERIVATIVES 156 DINUCLEAR PENTAFLUOROPHENYLGOLD(LL) COMPLEXES 156 POLYNUCLEAR PENTAFLUOROPHENYLGOLD(IJ) COMPLEXES 159 OUTLOOK AND FUTURE TRENDS 162 REFERENCES 163 4 THEORETICAL CHEMISTRY OF GOLD - FROM ATOMS TO MOLECULES, CLUSTERS, SURFACES AND THE SOLID STATE 183 PETER SCHWERDTFEGER AND MATTHIAS LEIN 4.1 INTRODUCTION 183 4.2 THE ORIGIN OF THE RELATIVISTIC MAXIMUM AT GOLD ALONG THE 6TH PERIOD OF ELEMENTS IN THE PERIODIC TABLE 186 4.3 CALCULATIONS ON ATOMIC GOLD 189 4.4 RELATIVISTIC METHODS FOR MOLECULAR CALCULATIONS AND DIATOMIC GOLD COMPOUNDS 194 4.5 CALCULATIONS ON INORGANIC AND ORGANOMETALLIC GOLD COMPOUNDS 203 4.6 CALCULATIONS ON GOLD CLUSTERS 212 4.7 CALCULATIONS ON INFINITE SYSTEMS: FROM SURFACES TO THE SOLID STATE OF GOLD 216 4.8 SUMMARY 220 REFERENCES 221 5 LUMINESCENCE AND PHOTOPHYSICS OF GOLD COMPLEXES 249 CHI-MING CHE AND SIU-WAI LAI 5.1 INTRODUCTION 249 5.2 SPECTROSCOPIC PROPERTIES OF GOLD(I) COMPLEXES 250 5.2.1 MONONUCLEAR GOLD(I) COMPLEXES 250 5.2.2 DI- AND POLYNUCLEAR GOLD(L) COMPLEXES WITH METAL-METAL INTERACTIONS 252 5.2.3 HIGH-ENERGY L[5DCR', GPCR] EXCITED STATE VERSUS VISIBLE METAL-ANION/SOLVENT EXCIPLEX EMISSION 262 5.2.4 CHEMOSENSORY APPLICATIONS 267 5.3 SPECTROSCOPIC PROPERTIES OF GOLD(III) COMPLEXES 270 5.4 PHOTOINDUCED ELECTRON TRANSFER REACTIONS OF GOLD COMPLEXES 273 IMAGE 4 VIII I CONTENTS 5.5 CONCLUDING REMARKS 274 REFERENCES 276 6 GOLD COMPOUNDS AND THEIR APPLICATIONS IN MEDICINE 283 ELIZABETH A. PACHECO, EDWARD R. T. TIEKINK, AND MICHAEL W. WHITEHOUSE 6.1 INTRODUCTION 283 6.2 THE AQUEOUS CHEMISTRY OF GOLD COMPOUNDS 283 6.2.1 STRUCTURES OF GOLD(I) AND GOLD(III) COMPLEXES 284 6.2.2 OXIDATION-REDUCTION REACTIONS 284 6.2.3 LIGAND EXCHANGE MECHANISMS 285 6.3 MEDICINALLY [MPORTANT GOLD COMPLEXES. THEIR ANALOGS AND REACTIONS 287 6.3.1 OLIGOMERIC GOLD(I) THIOLATES AND ANALOGS 287 6.3.2 BIS(THIOLATO)GOLD(I) SPECIES 290 6.3.3 DITHIOCARBAMATES 291 6.3.4 AURANOFIN AND OTHER PHOSPHINE(THIOLATO)GOLD(I) SPECIES 291 6.3.5 AU-S BOND LENGTH COMPARISONS 292 6.3.6 COMPLEXES OF DIPHOSPHINE LIGANDS 293 6.3.7 GOLD(I) CYANIDE COMPLEXES 294 6.3.8 HETEROCYCLIC CARBENES 295 6.4 GOLD-PROTEIN REACTIONS AND COMPLEXES 295 6.4.1 SERUM ALBUMIN 295 6.4.2 METALLOTHIONEINS 297 6.4.3 SELENIUM-DEPENDENT GLUTATHIONE PEROXIDASE 300 6.4.4 GOLD(III) OXIDATION OF INSULIN AND RIBONUCLEASE 301 6.4.5 ENZYME INHIBITION 301 6.4.6 ZINC FINGER PROTEINS 302 6.4.7 HEMOGLOBIN AND INTERPROTEIN GOLD TRANSFER ("TRANSAURATION") 303 6.4.8 MITOCHONDRIAL THIOREDOXIN REDUCTASE 303 6.5 PHYSIOLOGICAL AND CELLULAR BIOCHEMISTRY 304 6.5.1 BIOLOGICAL LIGAND EXCHANGE 304 6.5.2 THE SULFHYDRYL-SHUTTLE MODEL 305 6.5.3 EQUILIBRATION OF INTRA- AND EXTRACELLULAR GOLD 305 6.5.4 CYTOTOXICITY AND ANTITUMOR ACTIVITY OF GOLD COMPLEXES 306 6.5.5 OXIDATION STATES IN VIVO 307 6.5.6 LMMUNOCHEMICAL CONSEQUENCES OF GOLD(II I) 308 6.5.7 ANTI-HIV ACTIVITY 308 6.5.8 GOLD NANOPARTICLES 309 6.6 CONCLUSIONS 309 REFERENCES 310 7 NANOSCIENCE OF GOLD AND GOLD SURFACES 321 M. B CORTIE AND A. MCDONAGH 7.1 INTRODUCTION 321 7.2 FORMS OF GOLD AT THE NANOSCALE 323 IMAGE 5 7.2.1 7.2.2 7.2.3 7.2.4 7.2.5 7.2.6 7.2.7 7.2.8 7.2.8.1 7.2.8.2 7.3 7.3.1 7.3.1.1 7.3.1.2 7.3.1.3 7.3.2 7.3.2.1 7.3.3 7.3.3.1 7.4 7.4.1 7.4.2 7.4.3 7.4.4 7.4.4.1 7.4.5 7.4.6 7.4.7 7.4.8 7.5 CLUSTERS AND NANOPARTICJES OF LESS THAN 5 NM DIAMETER 323 NANOSPHERES 325 NANOSHELLS 325 NANORODS 327 OTHER NANOPARTICLE SHAPES 327 MESOPOROUS SPONGES 327 THIN FILMS 329 ASSEMBLAGES OF NANOPARTICLES 330 DISORDERED AGGREGATES 330 COLLOIDAL CRYSTALS 330 ONSET OF NEW PHENOMENA 331 OPTICAL 331 THE PLASMON RESONANCE 331 MANIPULATION OF THE PLASMON RESONANCE 332 FLUORESCENCE AND LUMINESCENCE 333 PHYSICAL 334 DEPRESSION OF THE MELTING POINT 334 CHEMICAL 334 HETEROGENEOUS CATALYSIS 334 SURFACE CHEMISTRY OF GOLD 335 HYDROGEN 335 HALOGENS 336 OXYGEN 337 SULFUR 338 ISOTHIOCYANATES 339 SELENIUM AND TELLURIUM 339 NITROGEN 340 PHOSPHORUS, ARSENIC, ANTIMONY 341 CARBON 342 CONCLUSIONS 342 REFERENCES 343 CONTENTS IIX 8 LIQUID CRYSTALS BASED ON GOLD COMPOUNDS 357 SILVERIO COCO AND PABLO ESPINET 8.1 INTRODUCTION 357 8.1.1 A FEW GENERAL CONCEPTS IN LIQUID CRYSTALS 357 8.1.2 GOLD, AN IDEAL METAL FOR LC STUDIES 360 8.2 PYRIDINE COMPLEXES 361 8.3 DITHIOBENZOATE COMPLEXES 361 8.4 ISOCYANIDE COMPLEXES 362 8.4.1 ISOCYANIDE-HALIDE COMPLEXES 362 8.4.2 [SOCYANIDE-ALKYNYL COMPLEXES 370 8.4.3 ISOCYANIDE-FLUOROPHENYL DERIVATIVES 372 8.4.4 IONIC BIS(ISOCYANIDE) DERIVATIVES 379 8.4.5 MIXTURES: LIQUID CRYSTALLINE "MOLECULAR ALLOYS" 383 IMAGE 6 X I CONTENTS 8.5 CARBENE COMPLEXES 384 8.6 COMPLEXES CONTAINING PYRAZOLE-TYPE LIGANDS 387 8.6.1 TRINUCLEAR GOLD PYRAZOLATE RINGS: METALLACROWNS 387 8.6.2 "MONONUCLEAR" COMPLEXES 388 8.7 IONIC IMIDAZOLIUM DERIVATIVES 388 8.8 LIQUID CRYSTALLINE GOLD NANOPARTICLES 388 8.9 CONCLUSIONS 390 REFERENCES 392 INDEX 397
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spelling	Gold chemistry highlights and future directions in the life sciences ed. by Fabian Mohr 1. Aufl. Weinheim WILEY-VCH 2009 XVI, 408 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Goldverbindungen (DE-588)4157895-8 gnd rswk-swf Goldverbindungen (DE-588)4157895-8 s DE-604 Mohr, Fabian 1975- (DE-588)137759819 edt text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3113107&prov=M&dok_var=1&dok_ext=htm Inhaltstext OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017322558&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Gold chemistry highlights and future directions in the life sciences Goldverbindungen (DE-588)4157895-8 gnd
subject_GND	(DE-588)4157895-8
title	Gold chemistry highlights and future directions in the life sciences
title_auth	Gold chemistry highlights and future directions in the life sciences
title_exact_search	Gold chemistry highlights and future directions in the life sciences
title_full	Gold chemistry highlights and future directions in the life sciences ed. by Fabian Mohr
title_fullStr	Gold chemistry highlights and future directions in the life sciences ed. by Fabian Mohr
title_full_unstemmed	Gold chemistry highlights and future directions in the life sciences ed. by Fabian Mohr
title_short	Gold chemistry
title_sort	gold chemistry highlights and future directions in the life sciences
title_sub	highlights and future directions in the life sciences
topic	Goldverbindungen (DE-588)4157895-8 gnd
topic_facet	Goldverbindungen
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