Alternative solvents for green chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Cambridge
RSC Publ.
2009
|
| Schriftenreihe: | RSC green chemistry series
2 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 226 S. Ill., graph. Darst. |
| ISBN: | 085404163X 9780854041633 |
Internformat
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Datensatz im Suchindex
| _version_ | 1804138809647955968 |
|---|---|
| adam_text | Titel: Alternative solvents for green chemistry
Autor: Kerton, Francesca M.
Jahr: 2009
Contents
Chapter 1 Introduction
1.1 The Need for Alternative Solvents 1
1.2 Safety Considerations, Life Cycle Assessment and
Green Metrics 4
1.2.1 Environmental, Health and Safety (EHS)
Properties 4
1.2.2 Life Cycle Assessment (LCA) 5
1.2.3 Solvents in the Pharmaceutical Industry
and Immediate Alternatives to Common
Laboratory Solvents 12
1.3 Solvent Properties Including Polarity 14
1.4 Summary 20
References 21
Chapter 2 Solvent free Chemistry
2.1 Introduction 23
2.2 Chemical Examples 25
2.2.1 Inorganic and Materials Synthesis 25
2.2.2 Organic Synthesis 27
2.2.2.1 Enantioselective Catalysis 36
2.2.2.2 Microwave assisted Reactions 39
2.2.2.3 Photoreactions 39
2.3 Summary and Outlook for the Future 39
References 41
x Contents
Chapter 3 Water
3.1 Introduction 44
3.1.1 Biphasic Systems 46
3.2 Chemical Examples 49
3.2.1 Extraction 49
3.2.2 Chemical Synthesis 51
3.2.2.1 Metal-mediated and Catalysed
Reactions 54
3.2.2.2 Microwave Assisted Reactions 56
3.2.2.3 Biocatalysis 57
3.2.2.4 Carbon Dioxide Fixation 58
3.2.3 Materials Synthesis 60
3.3 High Temperature, Superheated or Near Critical Water 63
3.4 Summary and Outlook for the Future 64
References 65
Chapter 4 Supercritical Fluids
4.1 Introduction 68
4.2 Chemical Examples 71
4.2.1 Supercritical and Liquid Carbon Dioxide 71
4.2.1.1 Solubility in Supercritical Carbon
Dioxide 71
4.2.1.2 Extraction 74
4.2.1.3 Chemical Synthesis 76
4.2.1.4 Materials Synthesis and Modification 82
4.2.2 Supercritical Water and Near Critical Water 84
4.2.2.1 Extraction and Analytical Chemistry 84
4.2.2.2 Chemical Synthesis 86
4.2.2.3 Materials Synthesis 89
4.2.2.4 Supercritical Water Oxidation
(SCWO) 90
4.3 Summary and Outlook for the Future 91
References 92
Chapter 5 Renewable Solvents
5.1 Introduction 97
5.2 Chemical Examples 100
5.2.1 Alcohols including Glycerol 100
5.2.2 Esters 103
5.2.2.1 Biodiesel 105
5.2.3 2-Methyltetrahydrofuran (2-MeTHF) 108
5.2.4 Terpenes and Plant Oils 109
5.2.5 Renewable Alkanes 113
Contents xj
5.2.6 Ionic Liquids and Eutectic Mixtures Prepared
from Bio-Feedstocks 114
5.3 Summary and Outlook for the Future 115
References 116
Chapter 6 Room Temperature Ionic Liquids and Eutectic Mixtures
6.1 Introduction 118
6.2 Chemical Examples 123
6.2.1 Extractions using RTILS 123
6.2.2 Electrochemistry in RTILS 125
6.2.3 Synthesis in RTILS 126
6.2.3.1 Biocatalysis in RTILs 131
6.2.3.2 Polymer Synthesis and Processing 132
6.2.4 Selected Unconventional Uses of RTILs 136
6.3 Summary and Outlook for the Future 138
References 138
Chapter 7 Fluorous Solvents and Related Systems
7.1 Introduction 143
7.1.1 Overview of Fluorous Approach 143
7.1.2 Fluorous Solvent Polarity Data, Solubility
and Miscibility Data 145
7.1.3 Fluorous Catalysts and Reagents 149
7.2 Chemical Examples 150
7.2.1 Fluorous Extractions and Fluorous Analytical
Chemistry 150
7.2.2 Fluorous Reactions 152
7.2.3 Fluorous Biphase Catalysis 153
7.2.3.1 Continuous Fluorous Biphase
Catalysis 160
7.2.4 Fluorous Biological Chemistry and
Biocatalysis 162
7.2.5 Fluorous Combinatorial Chemistry 164
7.2.6 Fluorous Materials Chemistry 166
7.3 Summary and Outlook for the Future 167
References 167
Chapter 8 Liquid Polymers
8.1 Introduction 170
8.1.1 Properties of Aqueous PEG Solutions 170
8.2 Chemical Examples 173
8.2.1 PEG and PPG as Non-volatile Reaction Media 173
8.2.1.1 PEG as a Reaction Solvent 174
xii Contents
8.2.2 Poly(dimethylsiloxane) as a Non-volatile
Reaction Medium 182
8.3 Summary and Outlook for the Future 185
References 186
Chapter 9 Tunable and Switchable Solvent Systems
9.1 Introduction 188
9.2 Chemical Examples 189
9.2.1 Gas Expanded Liquids 189
9.2.1.1 Solvent Properties of CXLs 190
9.2.1.2 Applications of CXLs 191
9.2.2 Solvents of Switchable Polarity 193
9.2.3 Switchable Surfactants 197
9.2.4 Solvents of Switchable Volatility 199
9.2.5 Thermomorphic and Related Biphasic
Catalysis 201
9.3 Summary and Outlook for the Future 202
References 202
Chapter 10 Industrial Case Studies
10.1 Introduction 204
10.2 Selected Applications: Examples 205
10.2.1 Water as a Solvent and Reaction Medium 206
10.2.2 Carbon Dioxide as a Solvent and
Reaction Medium 210
10.2.3 RTILs in Industry 214
10.3 Summary and Outlook 215
References 216
Subject Index 218
|
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| indexdate | 2024-07-09T21:34:05Z |
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| language | English |
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| physical | XII, 226 S. Ill., graph. Darst. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
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| series | RSC green chemistry series |
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| spelling | Kerton, Francesca M. Verfasser aut Alternative solvents for green chemistry Francesca M. Kerton Cambridge RSC Publ. 2009 XII, 226 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier RSC green chemistry series 2 Umwelt Solvents Solvents Environmental aspects Organische Chemie (DE-588)4043793-0 gnd rswk-swf Lösungsmittel (DE-588)4036160-3 gnd rswk-swf Grüne Chemie (DE-588)7563215-9 gnd rswk-swf Lösungsmittel (DE-588)4036160-3 s Organische Chemie (DE-588)4043793-0 s DE-604 Grüne Chemie (DE-588)7563215-9 s RSC green chemistry series 2 (DE-604)BV036009328 2 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017309015&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kerton, Francesca M. Alternative solvents for green chemistry RSC green chemistry series Umwelt Solvents Solvents Environmental aspects Organische Chemie (DE-588)4043793-0 gnd Lösungsmittel (DE-588)4036160-3 gnd Grüne Chemie (DE-588)7563215-9 gnd |
| subject_GND | (DE-588)4043793-0 (DE-588)4036160-3 (DE-588)7563215-9 |
| title | Alternative solvents for green chemistry |
| title_auth | Alternative solvents for green chemistry |
| title_exact_search | Alternative solvents for green chemistry |
| title_full | Alternative solvents for green chemistry Francesca M. Kerton |
| title_fullStr | Alternative solvents for green chemistry Francesca M. Kerton |
| title_full_unstemmed | Alternative solvents for green chemistry Francesca M. Kerton |
| title_short | Alternative solvents for green chemistry |
| title_sort | alternative solvents for green chemistry |
| topic | Umwelt Solvents Solvents Environmental aspects Organische Chemie (DE-588)4043793-0 gnd Lösungsmittel (DE-588)4036160-3 gnd Grüne Chemie (DE-588)7563215-9 gnd |
| topic_facet | Umwelt Solvents Solvents Environmental aspects Organische Chemie Lösungsmittel Grüne Chemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017309015&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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