Holdings: Chemistry and application of H-phosphonates

Chemistry and application of H-phosphonates:

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Bibliographic Details
Main Author:	Troev, Kolio Dimov 1944- (Author)
Format:	Book
Language:	English
Published:	Amsterdam[u.a.] Elsevier 2006
Edition:	1. ed.
Subjects:	Phosphonates Hydrogenphosphate Phosphonate
Online Access:	Inhaltsverzeichnis
Physical Description:	XIII, 291 S. Ill., graph. Darst.
ISBN:	0444527370 9780444527370

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MARC


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264		1	\|a Amsterdam[u.a.] \|b Elsevier \|c 2006
300			\|a XIII, 291 S. \|b Ill., graph. Darst.
336			\|b txt \|2 rdacontent
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650		4	\|a Phosphonates
650	0	7	\|a Hydrogenphosphate \|0 (DE-588)4673263-9 \|2 gnd \|9 rswk-swf
650	0	7	\|a Phosphonate \|0 (DE-588)4174406-8 \|2 gnd \|9 rswk-swf
689	0	0	\|a Hydrogenphosphate \|0 (DE-588)4673263-9 \|D s
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689	1	0	\|a Phosphonate \|0 (DE-588)4174406-8 \|D s
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adam_text	IMAGE 1 CONTENTS PREFACE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. VII ABOUT THE AUTHOR IX-X METHODS FOR PREPARATION AND PHYSICAL PROPERTIES OF H-PHOSPHONATES 1 1.1 FROM PHOSPHORUS TRICHLORIDE AND ALCOHOLS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.2 FROM H-PHOSPHONIC ACID 3 1.3 FROM WHITE PHOSPHORUS AND ALCOHOLS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1.4 OTHERS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1.5 PHYSICAL PROPERTIES 4 1.6 THERMAL STABILITY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 APPENDIX 8 2 STRUCTURE AND SPECTRAL CHARACTERISTICS OF H-PHOSPHONATES . . . . . . . . . . . . . . . . . . . . 11 2.1 ELECTRONIC STRUCTURE OF THE PHOSPHORUS ATOM. . . . . . . . . . . . . . . . . . . . . . . . . . .. 11 2.2 NATURE OF CHERNICAL BONDS IN THE PHOSPHORYL GROUP 12 2.3 MOLECULAR STRUCTURE OF DIMETHYL H-PHOSPHONATE . . . . . . . . . . . . . . . . . . . . . . . .. 13 2.4 TAUTOMERIZATION OF DIALKYL H-PHOSPHONATES 15 2.5 SPECTRAL CHARACTERISTICS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 18 2.5.1 INFRARED SPECTRA 18 2.5.2 IH NMR SPECTRA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 18 2.5.3 3 1 P NMR SPECTRA 19 2.5.4 I3C NMR SPECTRA .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 20 2.5.5 17 0 NMR SPECTRA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 20 APPENDIX 21 3 REACTIVITY OF H-PHOSPHONATES 23 3.1 ACIDITY OF H-PHOSPHONATE DIESTERS 23 3.2 DISPROPORTIONATION. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 25 3.3 REDUCTION. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 25 3.4 HYDROLYSIS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 25 3.5 ACIDOLYSIS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 29 3.6 SUBSTITUTION REACTIONS AT THE PHOSPHORUS ATOM . . . . . . . . . . . . . . . . . . . . . . . . .. 29 3.6.1 TRANSESTERIFICATION REACTION 29 3.6.2 SIDE REACTIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 32 3.6.3 SYNTHETIC APPLICATIONS 33 3.7 CHARACTERISTIC REACTIONS OF P-H GROUP . . . . . . . . . . . . . . . . . . . . . . . . . .. 39 3.7.1 OXIDATION OF P-H GROUP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 39 3.7.2 ADDITION REACTIONS 53 3.8 REACTIONS WITH THE PARTICIPATION OF THE ET-CARBON ATOM 77 3.8.1 REACTION OF DIALKYL H-PHOSPHONATES WITH AMINES 77 XI IMAGE 2 XII CONTENTS 3.8.2 REACTION OF DIARYL H-PHOSPHONATES WITH AMINES. . . . . . . . . . . . . . . . . .. 82 3.8.3 REACTION WITH AMIDES AND URETHANES. . . . . . . . . . . . . . . . . . . . . . . . . . .. 85 3.8.4 REACTION WITH HYDROGEN HALIDES .... . . . . . . . . . . . . . . . . . . . . . . . . . .. 87 3.8.5 REACTION WITH METAL SALTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 88 3.8.6 REACTION WITH AMMONIUM HALIDES 91 3.8.7 REACTION WITH CHLOROSILANES 92 APPENDIX 102 4 IMPORTANT C1ASSES OF COMPOUNDS 107 4.1 AMINOPHOSPHONATES AND AMINOPHOSPHONIC ACIDS . . . . . . . . . . . . . . . . . . . . . . .. 107 4.1.1 METHODS FOR THE PREPARATION OF AMINOPHOSPHONATES 108 4.1.2 HYDROLYTIC C1EAVAGE OF PHOSPHORUS-CARBON BOND 138 4.1.3 SYNTHETIC APPLICATION 141 4.2 BISPHOSPHONATES. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 144 4.2.1 METHODS FOR PREPARATION OF BISPHOSPHONATES 145 4.3 NUCLEOSIDE H-PHOSPHONATES 159 4.3.1 METHODS OFPREPARATION 160 4.3.2 REACTIVITY OF NUCLEOSIDE H-PHOSPHONATES . . . . . . . . . . . . . . . . . . . . . . .. 166 4.3.3 SYNTHETIC APPLICATION 174 4.4 DIALKYL EPOXYALKYLPHOSPHONATES 180 4.4.1 1,2-EPOXYALKYLPHOSPHONATES 180 4.4.2 2,3-EPOXYALKYLPHOSPHONATES 185 4.4.3 REACTIVITY OF 1,2-EPOXYALKYLPHOSPHONATES 185 4.5 POLY(ALKYLENE H-PHOSPHONATE)S 188 4.5.1 METHODS OF PREPARATION 189 4.5.2 REACTIVITY OF POLY(ALKYLENE H-PHOSPHONATE)S 195 4.5.3 APPLICATION OF POLY(ALKYLENE H-PHOSPHONATE)S . . . . . . . . . . . . . . . . . . .. 201 4.6 METAL SALTS OF DIALKYL H-PHOSPHONATES .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 210 4.6.1 PHOSPHITE-TYPE METAL SALTS 211 4.6.2 PHOSPHONATE-TYPE METAL SALTS , 220 4.7 COMPLEXES OF DIALKYL H-PHOSPHONATES 222 4.7.1 MOLECULAR COMPLEXES WITH LEWIS ACIDS 223 4.7.2 COMPLEXES WITH SOME MAIN GROUP AND F-ELEMENTS 224 4.7.3 COMPLEXES WITH TRANSITION METALS . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 226 4.7.4 COMPLEXES CONTAINING P(III)-TYPE LIGANDS . . . . . . . . . . . . . . . . . . . . . . .. 227 APPENDIX 245 5 APPLICATION OF H-PHOSPHONATE DIESTERS AND THEIR DERIVATIVES. . . . . . . . . . . . . . . . .. 253 5.1 PHYSIOLOGICALLY ACTIVE SUBSTANCES 253 5.1.1 FUNGICIDES AND BACTERICIDES 254 5.1.2 HERBICIDES 256 5.1.3 PLANT-GROWTH REGULATORS 258 5.1.4 INSECTICIDES. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 260 5.1.5 DRUGS SUPPRESSING THE GROWTH OF CANCER. TUMOR, VIRUS, OR PARASITES ..... 260 5.1.6 ANTI-HIV PRODRUGS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 261 5.1.7 ANTIRESORPTION DRUGS, CARRIERS OF RADIOACTIVE METALS 263 IMAGE 3 5.2 POLYMER ADDITIVES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 264 5.2.1 FLAME RETARDANTS AND ANTIOXIDANTS 264 5.3 DEGRADING AND ALKYLATING AGENTS OF POLYMERS. . . . . . . . . . . . . . . . . . . . . . . . . .. 271 5.4 REAL, LIGHT, AND UV STABILIZERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 275 5.5 CATALYSTS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 276 5.6 CORROSION INHIBITORS 278 5.7 SCALE INHIBITORS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 279 5.8 LUBRICANTS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 280 SUBJECT INDEX. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 285
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author	Troev, Kolio Dimov 1944-
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dewey-hundreds	500 - Natural sciences and mathematics
dewey-ones	547 - Organic chemistry
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dewey-tens	540 - Chemistry and allied sciences
discipline	Chemie / Pharmazie
edition	1. ed.
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spelling	Troev, Kolio Dimov 1944- Verfasser (DE-588)137584881 aut Chemistry and application of H-phosphonates Kolio D. Troev 1. ed. Amsterdam[u.a.] Elsevier 2006 XIII, 291 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Phosphonates Hydrogenphosphate (DE-588)4673263-9 gnd rswk-swf Phosphonate (DE-588)4174406-8 gnd rswk-swf Hydrogenphosphate (DE-588)4673263-9 s DE-604 Phosphonate (DE-588)4174406-8 s OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017160827&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Troev, Kolio Dimov 1944- Chemistry and application of H-phosphonates Phosphonates Hydrogenphosphate (DE-588)4673263-9 gnd Phosphonate (DE-588)4174406-8 gnd
subject_GND	(DE-588)4673263-9 (DE-588)4174406-8
title	Chemistry and application of H-phosphonates
title_auth	Chemistry and application of H-phosphonates
title_exact_search	Chemistry and application of H-phosphonates
title_full	Chemistry and application of H-phosphonates Kolio D. Troev
title_fullStr	Chemistry and application of H-phosphonates Kolio D. Troev
title_full_unstemmed	Chemistry and application of H-phosphonates Kolio D. Troev
title_short	Chemistry and application of H-phosphonates
title_sort	chemistry and application of h phosphonates
topic	Phosphonates Hydrogenphosphate (DE-588)4673263-9 gnd Phosphonate (DE-588)4174406-8 gnd
topic_facet	Phosphonates Hydrogenphosphate Phosphonate
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017160827&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT troevkoliodimov chemistryandapplicationofhphosphonates

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