Chemistry and application of H-phosphonates:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam[u.a.]
Elsevier
2006
|
| Ausgabe: | 1. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIII, 291 S. Ill., graph. Darst. |
| ISBN: | 0444527370 9780444527370 |
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| 100 | 1 | |a Troev, Kolio Dimov |d 1944- |e Verfasser |0 (DE-588)137584881 |4 aut | |
| 245 | 1 | 0 | |a Chemistry and application of H-phosphonates |c Kolio D. Troev |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a Amsterdam[u.a.] |b Elsevier |c 2006 | |
| 300 | |a XIII, 291 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Phosphonates | |
| 650 | 0 | 7 | |a Hydrogenphosphate |0 (DE-588)4673263-9 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Phosphonate |0 (DE-588)4174406-8 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Hydrogenphosphate |0 (DE-588)4673263-9 |D s |
| 689 | 0 | |5 DE-604 | |
| 689 | 1 | 0 | |a Phosphonate |0 (DE-588)4174406-8 |D s |
| 689 | 1 | |5 DE-604 | |
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| 999 | |a oai:aleph.bib-bvb.de:BVB01-017160827 | ||
Datensatz im Suchindex
| _version_ | 1804138680085905408 |
|---|---|
| adam_text | IMAGE 1
CONTENTS
PREFACE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. VII
ABOUT THE AUTHOR IX-X
METHODS FOR PREPARATION AND PHYSICAL PROPERTIES OF H-PHOSPHONATES 1 1.1
FROM PHOSPHORUS TRICHLORIDE AND ALCOHOLS . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . 1
1.2 FROM H-PHOSPHONIC ACID 3
1.3 FROM WHITE PHOSPHORUS AND ALCOHOLS . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . 4
1.4 OTHERS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . 4
1.5 PHYSICAL PROPERTIES 4
1.6 THERMAL STABILITY . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . 5
APPENDIX 8
2 STRUCTURE AND SPECTRAL CHARACTERISTICS OF H-PHOSPHONATES . . . . . . .
. . . . . . . . . . . . . 11
2.1 ELECTRONIC STRUCTURE OF THE PHOSPHORUS ATOM. . . . . . . . . . . . .
. . . . . . . . . . . . . .. 11
2.2 NATURE OF CHERNICAL BONDS IN THE PHOSPHORYL GROUP 12
2.3 MOLECULAR STRUCTURE OF DIMETHYL H-PHOSPHONATE . . . . . . . . . . .
. . . . . . . . . . . . .. 13
2.4 TAUTOMERIZATION OF DIALKYL H-PHOSPHONATES 15
2.5 SPECTRAL CHARACTERISTICS . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . .. 18
2.5.1 INFRARED SPECTRA 18
2.5.2 IH NMR SPECTRA . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . .. 18
2.5.3 3 1 P NMR SPECTRA 19
2.5.4 I3C NMR SPECTRA .. . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . .. 20
2.5.5 17 0 NMR SPECTRA . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . .. 20
APPENDIX 21
3 REACTIVITY OF H-PHOSPHONATES 23
3.1 ACIDITY OF H-PHOSPHONATE DIESTERS 23
3.2 DISPROPORTIONATION. . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . .. 25
3.3 REDUCTION. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . .. 25
3.4 HYDROLYSIS . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . .. 25
3.5 ACIDOLYSIS. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . .. 29
3.6 SUBSTITUTION REACTIONS AT THE PHOSPHORUS ATOM . . . . . . . . . . .
. . . . . . . . . . . . . .. 29
3.6.1 TRANSESTERIFICATION REACTION 29
3.6.2 SIDE REACTIONS . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . .. 32
3.6.3 SYNTHETIC APPLICATIONS 33
3.7 CHARACTERISTIC REACTIONS OF P-H GROUP . . . . . . . . . . . . . . .
. . . . . . . . . . .. 39
3.7.1 OXIDATION OF P-H GROUP . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . .. 39
3.7.2 ADDITION REACTIONS 53
3.8 REACTIONS WITH THE PARTICIPATION OF THE ET-CARBON ATOM 77
3.8.1 REACTION OF DIALKYL H-PHOSPHONATES WITH AMINES 77
XI
IMAGE 2
XII CONTENTS
3.8.2 REACTION OF DIARYL H-PHOSPHONATES WITH AMINES. . . . . . . . . . .
. . . . . . .. 82 3.8.3 REACTION WITH AMIDES AND URETHANES. . . . . . .
. . . . . . . . . . . . . . . . . . . .. 85
3.8.4 REACTION WITH HYDROGEN HALIDES .... . . . . . . . . . . . . . . .
. . . . . . . . . . .. 87
3.8.5 REACTION WITH METAL SALTS . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . .. 88
3.8.6 REACTION WITH AMMONIUM HALIDES 91
3.8.7 REACTION WITH CHLOROSILANES 92
APPENDIX 102
4 IMPORTANT C1ASSES OF COMPOUNDS 107
4.1 AMINOPHOSPHONATES AND AMINOPHOSPHONIC ACIDS . . . . . . . . . . . .
. . . . . . . . . . .. 107
4.1.1 METHODS FOR THE PREPARATION OF AMINOPHOSPHONATES 108
4.1.2 HYDROLYTIC C1EAVAGE OF PHOSPHORUS-CARBON BOND 138
4.1.3 SYNTHETIC APPLICATION 141
4.2 BISPHOSPHONATES. . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . .. 144
4.2.1 METHODS FOR PREPARATION OF BISPHOSPHONATES 145
4.3 NUCLEOSIDE H-PHOSPHONATES 159
4.3.1 METHODS OFPREPARATION 160
4.3.2 REACTIVITY OF NUCLEOSIDE H-PHOSPHONATES . . . . . . . . . . . . .
. . . . . . . . . .. 166
4.3.3 SYNTHETIC APPLICATION 174
4.4 DIALKYL EPOXYALKYLPHOSPHONATES 180
4.4.1 1,2-EPOXYALKYLPHOSPHONATES 180
4.4.2 2,3-EPOXYALKYLPHOSPHONATES 185
4.4.3 REACTIVITY OF 1,2-EPOXYALKYLPHOSPHONATES 185
4.5 POLY(ALKYLENE H-PHOSPHONATE)S 188
4.5.1 METHODS OF PREPARATION 189
4.5.2 REACTIVITY OF POLY(ALKYLENE H-PHOSPHONATE)S 195
4.5.3 APPLICATION OF POLY(ALKYLENE H-PHOSPHONATE)S . . . . . . . . . . .
. . . . . . . .. 201 4.6 METAL SALTS OF DIALKYL H-PHOSPHONATES .. . . .
. . . . . . . . . . . . . . . . . . . . . . . . . .. 210
4.6.1 PHOSPHITE-TYPE METAL SALTS 211
4.6.2 PHOSPHONATE-TYPE METAL SALTS , 220
4.7 COMPLEXES OF DIALKYL H-PHOSPHONATES 222
4.7.1 MOLECULAR COMPLEXES WITH LEWIS ACIDS 223
4.7.2 COMPLEXES WITH SOME MAIN GROUP AND F-ELEMENTS 224
4.7.3 COMPLEXES WITH TRANSITION METALS . . . . . . . . . . . . . . . . .
. . . . . . . . . . . .. 226
4.7.4 COMPLEXES CONTAINING P(III)-TYPE LIGANDS . . . . . . . . . . . . .
. . . . . . . . . .. 227
APPENDIX 245
5 APPLICATION OF H-PHOSPHONATE DIESTERS AND THEIR DERIVATIVES. . . . . .
. . . . . . . . . . .. 253
5.1 PHYSIOLOGICALLY ACTIVE SUBSTANCES 253
5.1.1 FUNGICIDES AND BACTERICIDES 254
5.1.2 HERBICIDES 256
5.1.3 PLANT-GROWTH REGULATORS 258
5.1.4 INSECTICIDES. . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . .. 260
5.1.5 DRUGS SUPPRESSING THE GROWTH OF CANCER. TUMOR, VIRUS, OR PARASITES
..... 260 5.1.6 ANTI-HIV PRODRUGS . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . .. 261
5.1.7 ANTIRESORPTION DRUGS, CARRIERS OF RADIOACTIVE METALS 263
IMAGE 3
5.2 POLYMER ADDITIVES . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . .. 264
5.2.1 FLAME RETARDANTS AND ANTIOXIDANTS 264
5.3 DEGRADING AND ALKYLATING AGENTS OF POLYMERS. . . . . . . . . . . . .
. . . . . . . . . . . . .. 271
5.4 REAL, LIGHT, AND UV STABILIZERS . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . .. 275
5.5 CATALYSTS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . .. 276
5.6 CORROSION INHIBITORS 278
5.7 SCALE INHIBITORS . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . .. 279
5.8 LUBRICANTS. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . .. 280
SUBJECT INDEX. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 285
|
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| id | DE-604.BV035356766 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:32:02Z |
| institution | BVB |
| isbn | 0444527370 9780444527370 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017160827 |
| oclc_num | 69672036 |
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| owner_facet | DE-19 DE-BY-UBM |
| physical | XIII, 291 S. Ill., graph. Darst. |
| publishDate | 2006 |
| publishDateSearch | 2006 |
| publishDateSort | 2006 |
| publisher | Elsevier |
| record_format | marc |
| spelling | Troev, Kolio Dimov 1944- Verfasser (DE-588)137584881 aut Chemistry and application of H-phosphonates Kolio D. Troev 1. ed. Amsterdam[u.a.] Elsevier 2006 XIII, 291 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Phosphonates Hydrogenphosphate (DE-588)4673263-9 gnd rswk-swf Phosphonate (DE-588)4174406-8 gnd rswk-swf Hydrogenphosphate (DE-588)4673263-9 s DE-604 Phosphonate (DE-588)4174406-8 s OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017160827&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Troev, Kolio Dimov 1944- Chemistry and application of H-phosphonates Phosphonates Hydrogenphosphate (DE-588)4673263-9 gnd Phosphonate (DE-588)4174406-8 gnd |
| subject_GND | (DE-588)4673263-9 (DE-588)4174406-8 |
| title | Chemistry and application of H-phosphonates |
| title_auth | Chemistry and application of H-phosphonates |
| title_exact_search | Chemistry and application of H-phosphonates |
| title_full | Chemistry and application of H-phosphonates Kolio D. Troev |
| title_fullStr | Chemistry and application of H-phosphonates Kolio D. Troev |
| title_full_unstemmed | Chemistry and application of H-phosphonates Kolio D. Troev |
| title_short | Chemistry and application of H-phosphonates |
| title_sort | chemistry and application of h phosphonates |
| topic | Phosphonates Hydrogenphosphate (DE-588)4673263-9 gnd Phosphonate (DE-588)4174406-8 gnd |
| topic_facet | Phosphonates Hydrogenphosphate Phosphonate |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017160827&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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