Structural chemistry of glasses:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
2002 [erschienen] 2007
|
| Ausgabe: | 1. ed., transferred to digital printing |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XV, 568 S. Ill., graph. Darst. |
| ISBN: | 0080439586 |
Internformat
MARC
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| 100 | 1 | |a Rao, K. J. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Structural chemistry of glasses |c by K. J. Rao |
| 250 | |a 1. ed., transferred to digital printing | ||
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 2002 [erschienen] 2007 | |
| 300 | |a XV, 568 S. |b Ill., graph. Darst. | ||
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Datensatz im Suchindex
| _version_ | 1804138642755551232 |
|---|---|
| adam_text | CONTENTS
DEDICATION
v
PREFACE
AND ACKNOWLEDGEMENTS
vii
ACKNOWLEDGEMENTS TO PUBLISHERS
ix
CHAPTER
1
THE WORLD OF INORGANIC GLASSES
1
Natural glasses
1
Glasses through the centuries: a historical perspective
2
Glass in modern times
7
In this book
8
CHAPTER
2
THE GLASSY STATE
13
Preparation of glasses
14
Microwave heating in glass preparation
16
Sol-gel process
17
Chemical nature of glass forming materials
21
Structural approach to glass formation
23
Continuous random network model
26
Random close packing model
31
Bonding theories
36
Thermal behaviour of glasses
43
Tg and experimental time scales
50
Kinetic criteria for glass formation
53
T-T-T diagrams
54
Effect of heating and cooling rates on Tg
58
Constraints model
60
Nucleation and Growth
66
CHAPTER
3
THE GLASS TRANSITION PHENOMENON
77
Free volume and glass transition
77
Entropy theory
82
Significant structures approach
91
Bond-lattice model
92
XI
XII
Theory of potential energy
surfaces
95
Glass transition models based on heterogeneity
100
Structural frustration model
103
Cluster model of glasses and glass transition
105
Boson peak and FSDP
110
Mode Coupling Theory
114
Other viscosity theories
117
Polyamorphism
119
Fragility and glass forming liquids
121
CHAPTER
4
STRUCTURAL TECHNIQUES
137
X-ray diffraction from glass
139
Neutron scattering
144
Inelastic neutron scattering
146
Electron scattering
148
Extended X-ray Absorption Fine Structure
153
X-ray Absorption Near Edge Structure
159
Nuclear Magnetic Resonance
161
Vibrational spectroscopy
170
IR
spectroscopy
173
Raman spectroscopy
175
X-ray Photoelectron Spectroscopy
176
CHAPTER
5
THEORETICAL STUDIES
185
Monte Carlo and Reverse Monte Carlo methods
185
MD simulation
188
Quantum chemical calculations
196
CHAPTER
6
Đ.C.
CONDUCTIVITY
203
Anderson-Stuart model
206
Vacancy model
209
Weak electrolyte models
212
Cluster bypass model
216
Optical basicity and ionic conductivity
216
Mixed Alkali Effect
219
Theories of MAE
223
Mixed ionic effect
229
Simulation
studies of
MAE problem
232
Fast Ion Conduction
236
Decoupling index
240
Chemical approach
243
Ag+ ion conducting glasses
246
Li+ ion conducting glasses
249
Other
FIC
glasses
256
Protonie
FIC
glasses
257
CHAPTER
7
A.C.
CONDUCTIVITY
263
A.c.
conductivity and dielectric quantities
265
Modulus representation
266
Alternate formulation of dielectric data
273
Theoretical models of a.c. conductivity
275
Jump relaxation model
276
Diffusion Controlled Relaxation model
277
Debye-Falkenhagen-Tomozawa effect
281
A.c.
conductivity and NMR relaxation
282
Power law behaviour of a.c. conductivities
288
β
and its relation to other transport parameters
293
Scaling behaviour of a.c. conductivity
295
A.c.
conductivity at very high frequencies
299
Comparison of electrical and mechanical relaxations
302
CHAPTER
8
SEMICONDUCTING GLASSES
307
DOS and energy gaps
309
Characterization of DOS
312
Localization of electron states
314
Minimum metallic conductivity
317
Conductivities
320
Variable Range Hopping
322
Thermoelectric power
324
Hall coefficient
326
Polaronic transport
327
A.c.
conductivity
330
Correlated Barrier Hopping
333
Charged defects
337
Defect controlled properties
343
XIV
High field behaviour of chalcogenide glasses
348
Photostructural
changes in amorphous chalcogenides
354
Chemically controlled carrier type reversal
361
Amorphous silicon and carbon
366
CHAPTER
9
RELAXATION PHENOMENA
375
Secondary or
β-
relaxations
377
The many modes of relaxation in glasses
379
Scaling behaviour of relaxations
381
KWW expression and Ngai s coupling model
384
Thermodynamics in the region of glass transition
387
Two Level States and relaxation
389
Enthalpy relaxation
392
Enthalpy relaxation and a.c. heat capacities
395
WLF equation
397
CHAPTER
10
ELASTIC PROPERTIES AND PRESSURE EFFECTS
401
Elastic constants
401
Measurement of elastic moduli
406
Structure of glasses and elastic constants
411
Microhardness
418
Fracture of glasses
419
Behaviour of glasses under high pressure
423
CHAPTER
11
OPTICAL PROPERTIES
429
Refraction, reflection and absorption of light
430
Measurement of optical constants
437
Stress optical and non-linear optical constants
438
Colour of glasses
441
Colour due to transition metal ions
441
Fluorescence spectra
449
Glass lasers
453
Colour from particle scattering
455
Photosensitive glasses
457
Fibre optics
458
Fine particulates and nano-glasses
461
XV
CHAPTER
12
OXIDE GLASSES
463
Silica and silicate glasses
464
Anomalous properties of silica glass
467
Phase separation and spinodal decomposition
473
SiOx
477
B2O3 and
borate
glasses
478
GeCh and germanate glasses
483
P2O5 and phosphate glasses
484
Bridging, non-bridging and terminal oxygens
487
Complex oxide glasses
488
Glasses with dissolved salts
494
Glasses containing transition metal oxides
496
CHAPTER
13
CHALCOGENIDE GLASSES
513
Chalcogen and inter-chalcogen glasses
515
Group V chalcogenides
518
Chemical ordering
520
Group IV chalcogenides
526
Thioborate glasses
526
Chalcogenide glasses containing halogens
531
CHAPTER
14
OTHER GLASSES
535
Halide glasses
535
Heavy metal fluoride glasses
536
Oxy-halide glasses
540
Glasses of mixed salts: discrete
anion
glasses
544
Oxynitride glasses
547
Metallic glasses
551
Glass-like carbon
554
SUBJECT INDEX
559
|
| any_adam_object | 1 |
| author | Rao, K. J. |
| author_facet | Rao, K. J. |
| author_role | aut |
| author_sort | Rao, K. J. |
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| bvnumber | BV035330696 |
| classification_rvk | UQ 8600 VE 9670 |
| ctrlnum | (OCoLC)635207378 (DE-599)BVBBV035330696 |
| discipline | Chemie / Pharmazie Physik |
| edition | 1. ed., transferred to digital printing |
| format | Book |
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| id | DE-604.BV035330696 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:31:26Z |
| institution | BVB |
| isbn | 0080439586 |
| language | English |
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| owner_facet | DE-703 |
| physical | XV, 568 S. Ill., graph. Darst. |
| publishDate | 2002 |
| publishDateSearch | 2007 |
| publishDateSort | 2007 |
| publisher | Elsevier |
| record_format | marc |
| spelling | Rao, K. J. Verfasser aut Structural chemistry of glasses by K. J. Rao 1. ed., transferred to digital printing Amsterdam [u.a.] Elsevier 2002 [erschienen] 2007 XV, 568 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Strukturchemie (DE-588)4183790-3 gnd rswk-swf Konstruktionswerkstoff (DE-588)4657183-8 gnd rswk-swf Glas (DE-588)4021142-3 gnd rswk-swf Glas (DE-588)4021142-3 s Strukturchemie (DE-588)4183790-3 s DE-604 Konstruktionswerkstoff (DE-588)4657183-8 s 1\p DE-604 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017135138&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Rao, K. J. Structural chemistry of glasses Strukturchemie (DE-588)4183790-3 gnd Konstruktionswerkstoff (DE-588)4657183-8 gnd Glas (DE-588)4021142-3 gnd |
| subject_GND | (DE-588)4183790-3 (DE-588)4657183-8 (DE-588)4021142-3 |
| title | Structural chemistry of glasses |
| title_auth | Structural chemistry of glasses |
| title_exact_search | Structural chemistry of glasses |
| title_full | Structural chemistry of glasses by K. J. Rao |
| title_fullStr | Structural chemistry of glasses by K. J. Rao |
| title_full_unstemmed | Structural chemistry of glasses by K. J. Rao |
| title_short | Structural chemistry of glasses |
| title_sort | structural chemistry of glasses |
| topic | Strukturchemie (DE-588)4183790-3 gnd Konstruktionswerkstoff (DE-588)4657183-8 gnd Glas (DE-588)4021142-3 gnd |
| topic_facet | Strukturchemie Konstruktionswerkstoff Glas |
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