Catalysis in asymmetric synthesis:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Hoboken, NJ
Wiley
2009
|
| Edition: | 2. ed. |
| Series: | Postgraduate chemistry series
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Includes bibliographical references and index |
| Physical Description: | XIII, 393 S. graph. Darst. |
| ISBN: | 9781405190916 9781405175197 |
Staff View
MARC
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| 100 | 1 | |a Caprio, Vittorio |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Catalysis in asymmetric synthesis |c Vittorio Caprio and Jonathan M.J. Williams |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Hoboken, NJ |b Wiley |c 2009 | |
| 300 | |a XIII, 393 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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| 490 | 0 | |a Postgraduate chemistry series | |
| 500 | |a Includes bibliographical references and index | ||
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| 650 | 4 | |a Catalysis | |
| 650 | 4 | |a Asymmetric synthesis | |
| 650 | 4 | |a Catalysis | |
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Record in the Search Index
| _version_ | 1804138621032202241 |
|---|---|
| adam_text | Contents
Preface
to the Second Edition
xi
Preface to the First Edition
xiii
1
Introduction
1
1.1
Reactions Amenable to Asymmetric Catalysis
1
1.2
Assignment of (JR) and (S) Stereochemical Descriptors
2
Futher Reading
6
References
7
2
Reduction of Alkenes
9
2.1
Asymmetric
Hydrogénation
with Rhodium Complexes
9
2.2
Asymmetric
Hydrogénation
with Ruthenium Catalysts
18
2.3
Alkene
Hydrogénation
with Titanium and
Zirconium Catalysts
24
2.4
Alkene
Hydrogénation
with Iridium Catalysts
25
2.5
Alkene
Hydrogénation
with Organocatalysts
28
2.6
Alkene Hydrosilylation
29
2.7
Alkene Hydroboration
32
2.8
Hydroamination
34
2.9
Hydroformylation
36
2.10
Hydroacylation of Alkenes
39
2.11
Hydrocyanation of Alkenes
40
References
40
3
Reduction of Ketones and Imines
47
3.1
Hydrogénation
of Ketones
47
3.2
Hydrogénation
and Transfer
Hydrogénation
of Imines
and Related Compounds
53
3.3
Transfer
Hydrogénation
of Ketones
56
3.4
Heterogeneous
Hydrogénation
59
3.5
Reduction of Ketones Using Enantioselective
Borohydride Reagents
63
3.6
Hydrosilylation of Ketones
68
3.7
Hydrosilylation of Imines and Nitrones
73
References 75
vii
viii Contents
4 Epoxidation 81
4.1 Epoxidation
of Allylic
Alcohols
81
4.2 Epoxidation
with
Meta^salen)
Complexes
88
4.3 Epoxidation
Using Metal-Porphyrin-Based Catalysts
94
4.4
Other Metal-Catalysed Epoxidations of
Unfunctionalised Olefins
95
4.5
Epoxidation of Electron-Deficient Alkenes
96
4.6
Epoxidation with Iminium Salts
101
4.7
Epoxidation with
Ketone
Catalysts
102
4.8
Epoxidation of Aldehydes
105
4.9
Aziridination of Alkenes
106
4.10
Aziridination of Imines
108
References
109
5
Further Oxidation Reactions
117
5.1
Dihydroxylation
117
5.2
Aminohydroxylation
126
5.3
a-Heterofunctionalisation of Aldehydes and Ketones
130
5.4
Oxidation of C-H
136
5.5
Baeyer-
Villiger
Oxidation
138
5.6
Oxidation of
Sulfides 139
References
142
6
Nudeophilic Addition to Carbonyl Compounds
147
6.1
Addition of Organozincs to Carbonyl Compounds
147
6.2
Addition of Cyanide to Aldehydes and Ketones
153
6.3
Allylation of Aldehydes
160
6.4
Hydrophosphonylation of Aldehydes
165
6.5
Nudeophilic Additions to Imines
166
References
173
7
The Aldol and Related Reactions
179
7.1
The Aldol Reaction
180
7.2
Isocyanide and Related Aldol Reactions
191
7.3
The Nitroaldol Reaction
193
7.4
Addition of Enolates to Imines
195
7.5
Darzens Condensation
200
7.6
Morita-Baylis-Hillman Reaction
201
7.7
Carbonyl-Ene Reactions
203
References
208
8
Cycloadditions
213
8.1
Diels-Alder Reactions
213
8.2
Inverse Electron Demand Diels-Alder Reactions
231
Contents ix
8.3 Hetero-Diels-Alder
Reactions
232
8.4
1,3-Dipolar
Cycloaddition
Reactions
240
8.5 [2+2]
Cycloadditions
246
8.6
Pauson-Khand-Type Reactions
249
References
251
9
Catalytic Reactions Involving Carbenes and Ylides
257
9.1
Cyclopropanation
257
9.2
Insertion Reactions
268
9.3
Asymmetric Ylide Reactions
273
References
275
10
Catalytic Carbon-Carbon Bond-Forming Reactions
281
10.1
Cross-Coupling Reactions
282
10.2
Metal-Catalysed Allylic Substitution
284
10.3
Heck Reactions
296
10.4
Alkylmetalation of Alkenes
302
References
305
11
Conjugate Addition Reactions
311
11.1
Conjugate Addition of Enolates
311
11.2
Conjugate Addition of Sulfur Nudeophiles
317
11.3
Conjugate Addition of Nonstabilised Nudeophiles
320
11.4
Conjugate Addition with Nitrogen-Based Nudeophiles
and Electrophiles
325
References
328
12
Further Catalytic Reactions
333
12.1
Isomerisations and Rearrangements
333
12.2
Deprotonation Reactions
336
12.3
Protonation
Reactions
336
12.4
Alleviation and Allylation of Enolates
338
12.5
Formation of Alkenes
342
12.6
Oxyselenylation-Elimination Reactions
344
12.7
The Benzoin Condensation
344
12.8
Ester Formation and Hydrolysis
345
12.9
Ring-Opening of Epoxides
349
References
355
Index
361
|
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| ctrlnum | (OCoLC)474716271 (DE-599)BVBBV035314989 |
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| dewey-sort | 3541 239 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| edition | 2. ed. |
| format | Book |
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| id | DE-604.BV035314989 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:31:06Z |
| institution | BVB |
| isbn | 9781405190916 9781405175197 |
| language | English |
| lccn | 2008045023 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017119669 |
| oclc_num | 474716271 |
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| owner | DE-703 DE-634 DE-11 DE-91G DE-BY-TUM |
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| physical | XIII, 393 S. graph. Darst. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | Wiley |
| record_format | marc |
| series2 | Postgraduate chemistry series |
| spelling | Caprio, Vittorio Verfasser aut Catalysis in asymmetric synthesis Vittorio Caprio and Jonathan M.J. Williams 2. ed. Hoboken, NJ Wiley 2009 XIII, 393 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Postgraduate chemistry series Includes bibliographical references and index Asymmetric synthesis Catalysis Katalyse (DE-588)4029921-1 gnd rswk-swf Asymmetrische Synthese (DE-588)4135603-2 gnd rswk-swf Asymmetrische Synthese (DE-588)4135603-2 s Katalyse (DE-588)4029921-1 s DE-604 Williams, Jonathan M. J. Sonstige oth Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017119669&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Caprio, Vittorio Catalysis in asymmetric synthesis Asymmetric synthesis Catalysis Katalyse (DE-588)4029921-1 gnd Asymmetrische Synthese (DE-588)4135603-2 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4135603-2 |
| title | Catalysis in asymmetric synthesis |
| title_auth | Catalysis in asymmetric synthesis |
| title_exact_search | Catalysis in asymmetric synthesis |
| title_full | Catalysis in asymmetric synthesis Vittorio Caprio and Jonathan M.J. Williams |
| title_fullStr | Catalysis in asymmetric synthesis Vittorio Caprio and Jonathan M.J. Williams |
| title_full_unstemmed | Catalysis in asymmetric synthesis Vittorio Caprio and Jonathan M.J. Williams |
| title_short | Catalysis in asymmetric synthesis |
| title_sort | catalysis in asymmetric synthesis |
| topic | Asymmetric synthesis Catalysis Katalyse (DE-588)4029921-1 gnd Asymmetrische Synthese (DE-588)4135603-2 gnd |
| topic_facet | Asymmetric synthesis Catalysis Katalyse Asymmetrische Synthese |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017119669&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT capriovittorio catalysisinasymmetricsynthesis AT williamsjonathanmj catalysisinasymmetricsynthesis |