Thermodynamics of surface phenomena:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English Russian |
| Veröffentlicht: |
Cambridge
Cambridge International Science Publishing
2008
|
| Ausgabe: | 1. publ. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | XII, 281 S. Ill. |
| ISBN: | 9781904602774 |
Internformat
MARC
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| 035 | |a (DE-599)HBZHT015698004 | ||
| 040 | |a DE-604 |b ger |e aacr | ||
| 041 | 1 | |a eng |h rus | |
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| 082 | 0 | |a 530.427 |2 22 | |
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| 100 | 1 | |a Dadashev, Raikom K. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Thermodynamics of surface phenomena |c R. Kh. Dadashev |
| 250 | |a 1. publ. | ||
| 264 | 1 | |a Cambridge |b Cambridge International Science Publishing |c 2008 | |
| 300 | |a XII, 281 S. |b Ill. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references and index | ||
| 650 | 4 | |a Chimie des surfaces | |
| 650 | 7 | |a Oppervlakken |2 gtt | |
| 650 | 4 | |a Surfaces (Physique) | |
| 650 | 4 | |a Tension superficielle | |
| 650 | 7 | |a Thermodynamica |2 gtt | |
| 650 | 4 | |a Thermodynamique | |
| 650 | 4 | |a Thermodynamics | |
| 650 | 4 | |a Surfaces (Physics) | |
| 655 | 7 | |0 (DE-588)4006432-3 |a Bibliografie |2 gnd-content | |
| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017079159&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-017079159 | ||
Datensatz im Suchindex
| _version_ | 1804138562625470464 |
|---|---|
| adam_text | CONTENTS
Preface
...............................................................................................ix
Introduction
....................................................................................
xiij
1.
The Gibbs method in the thermodynamics of
surface
phenomena
................................................................................1
1.1.
Dividing surface and excess quantity in Gibbs capillarity theory
................2
1.2.
Excess thermodynamic potential. Gibbs adsorption equation
....................7
1.3.
Dependence of excess thermodynamic quantities on the position of the
dividing surface
..........................................................................................12
1.4.
Adsorption equilibrium in two-phase multicomponent systems
................17
1.5.
Calculation of adsorption in two-component systems
...............................21
1.6.
Adsorption in two-phase systems with a low content of components
in one of the phases
....................................................................................26
1.7.
Calculation of adsorption at the liquid-vacuum interface on the
basis of the concentration dependence of surface tension
.........................31
1.8.
Calculation of adsorption in multicomponent systems
..............................36
1.9.
Calculation of the adsorption of components with the variation of the
composition along lines with a constant content of components, with
the exception of two components
...............................................................42
1.10.
Calculation of adsorption of components for the variation of the
composition by adding one of the components
..........................................44
1.11.
Relationship between the values of adsorption in relation to different
positions of the dividing surface
................................................................50
1.12.
Adsorption method of determination of the molecular mass of surface-
active substances
........................................................................................54
1.13.
Criteria of the surface activity of a component in multicomponent
solutions
.....................................................................................................57
2.
Thermodynamic description of the surface properties
by the method of the finite thickness layer
.......................63
2.1.
Effective thickness of the surface layer of solutions
..................................64
2.2.
Temperature dependence of the thickness of the surface layer of liquid
metals
.........................................................................................................69
2.3.
Calculation of the composition of the surface layer of multicomponent
solutions on the basis of the concentration dependence of surface
tension
........................................................................................................73
2.4.
The molar surface, the thickness of the surface layer and their
dependence on the composition of the multicomponent solution
..............78
2.5.
Partial-molar quantities in multicomponent solutions
...............................83
2.6.
Partial-molar
surfaces
of components
.......................................................86
3.
Method of measurement of the surface tension and
density of metals and alloys
.................................................93
3.1.
Selection of the method of measuring surface tension and density
............95
3.2.
Special features of measurement of the density of liquid metals and
alloys with areometers
...............................................................................99
3.3.
Determination of the concentration dependence of the density of
metallic melts
...........................................................................................105
3.3.1.
Pycnometers for the measurement of the concentration dependence
on the density of melts
[150]....................................................................106
3.2.2.
Areometric method of determination of the concentration dependence
of density
..................................................................................................109
3.4.
Combined measurement of the physical and chemical properties of
liquid metals and their alloys
...................................................................
Ill
3.4.1.
A device for the combined determination of surface tension and
density
......................................................................................................
Ill
3.4.2.
A combined device for detailed examination of the physical-chemical
properties of multicomponent melts
......................................................... 113
3.5.
Combined device for the determination of the concentration
dependence of the surface tension and density of multicomponent
melts
[154]............................................................................................... 116
3.6.
Experimental equipment for the methods of measurement of the
physical-chemical properties of multicomponent metallic melts
............ 119
3.7.
Method of processing measurement results
............................................. 122
3.7.1.
The law of distribution of the error of measurement of surface tension
.. 122
3.7.2.
Error of determination of the composition of the melt prepared
using a dosing apparatus
.......................................................................... 124
3.7.3.
Error of the measurement of the density of liquid metals
........................ 125
3.7.4.
Error of measuring surface tension
.......................................................... 127
4.
Surface properties and molar volumes of pure
metals and binary systems
.................................................129
4.1.
Temperature dependence of the parameters of the surface layer of
low-melting alloys
....................................................................................130
4.2.
Surface tension and density of indium-tin and gallium-lead binary
systems
.....................................................................................................134
4.3.
Special features of the concentration dependence of the
thermodynamic parameters of the surface layer of indium-tin and
thallium-lead melts
..................................................................................138
4.4.
Surface properties of binary systems: bismuth-thallium, tin-
thallium and indium-thallium
..................................................................144
4.5.
Surface tension and molar volumes in gallium-bismuth melts
................ 152
5.
Surface tension
and density of multicomponent melts .
156
5.1.
Surface tension and
molar
volumes
of ternary systems
...........................157
5.1.1.
The indium-tin-lead system
....................................................................157
5.1.2.
The thallium-lead-bismuth system
..........................................................161
5.1.3.
The indium-tin-gallium system
...............................................................163
5.2.
Application of the methods of mathematical experimental design in
examination of the surface properties of multicomponent systems
.........168
5.3.
Investigation of the surface tension and density of ternary systems
using experiment design methods
............................................................170
5.3.1.
Concentration dependence of the surface tension of ternary systems
......170
5.4.
Surface tension of four-component systems
............................................177
5.4.1.
The indium-tin-lead-bismuth system
.....................................................178
5.4.2.
The indium-lead-tin-bismuth-thallium system
......................................182
5.5.
Special features of the variation of the physical and chemical
properties with the composition of the multicomponent melt.
Concentration buffering of surface tension
..............................................185
6.
Thermodynamic parameters of the surface layer of
multicomponent melts and methods of predicting the
parameters
............................................................................191
6.1.
Adsorption phenomena in multicomponent metallic melts
......................192
6.1.1.
Effect of the surface-active component on the adsorption processes in
binary melts
..............................................................................................193
6.1.2.
Adsorption behaviour of the inactive component in In-Sn-Ga,
Tl-Pb-ln, Tl-Pb-Sn and Tl-Bi-In ternary melts
....................................196
6.1.3.
Adsorption phenomena in indium-tin-lead-bismuth and
indium-lead-gallium-bismuth four-component solutions
.......................200
6.2.
Composition and thickness of the surface layer of multicomponent
melts
.........................................................................................................202
6.3.
The current state of experimental examination of the surface
properties and molar volumes of multicomponent metallic systems
.......211
6.4.
Methods of predicting the surface properties of multicomponent
melts
.........................................................................................................217
6.5.
Prediction of surface tension and excess molar volume on the basis
of the properties of melts of lateral binary systems
.................................220
6.6.
Theoretical description of the concentration dependence of the
surface tension of multicomponent solutions
...........................................226
6.7.
Equation of surface tension isotherms of binary and ternary systems
.....232
Conclusions
............................................................................................................241
Appendix
................................................................................................................247
References
..............................................................................................................269
Index
.................................................................................................................281
VII
|
| any_adam_object | 1 |
| author | Dadashev, Raikom K. |
| author_facet | Dadashev, Raikom K. |
| author_role | aut |
| author_sort | Dadashev, Raikom K. |
| author_variant | r k d rk rkd |
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| ctrlnum | (OCoLC)191759890 (DE-599)HBZHT015698004 |
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| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 530 - Physics |
| dewey-raw | 530.427 |
| dewey-search | 530.427 |
| dewey-sort | 3530.427 |
| dewey-tens | 530 - Physics |
| discipline | Physik |
| edition | 1. publ. |
| format | Book |
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| genre_facet | Bibliografie |
| id | DE-604.BV035273831 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:30:10Z |
| institution | BVB |
| isbn | 9781904602774 |
| language | English Russian |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017079159 |
| oclc_num | 191759890 |
| open_access_boolean | |
| owner | DE-703 |
| owner_facet | DE-703 |
| physical | XII, 281 S. Ill. |
| publishDate | 2008 |
| publishDateSearch | 2008 |
| publishDateSort | 2008 |
| publisher | Cambridge International Science Publishing |
| record_format | marc |
| spelling | Dadashev, Raikom K. Verfasser aut Thermodynamics of surface phenomena R. Kh. Dadashev 1. publ. Cambridge Cambridge International Science Publishing 2008 XII, 281 S. Ill. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Chimie des surfaces Oppervlakken gtt Surfaces (Physique) Tension superficielle Thermodynamica gtt Thermodynamique Thermodynamics Surfaces (Physics) (DE-588)4006432-3 Bibliografie gnd-content Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017079159&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Dadashev, Raikom K. Thermodynamics of surface phenomena Chimie des surfaces Oppervlakken gtt Surfaces (Physique) Tension superficielle Thermodynamica gtt Thermodynamique Thermodynamics Surfaces (Physics) |
| subject_GND | (DE-588)4006432-3 |
| title | Thermodynamics of surface phenomena |
| title_auth | Thermodynamics of surface phenomena |
| title_exact_search | Thermodynamics of surface phenomena |
| title_full | Thermodynamics of surface phenomena R. Kh. Dadashev |
| title_fullStr | Thermodynamics of surface phenomena R. Kh. Dadashev |
| title_full_unstemmed | Thermodynamics of surface phenomena R. Kh. Dadashev |
| title_short | Thermodynamics of surface phenomena |
| title_sort | thermodynamics of surface phenomena |
| topic | Chimie des surfaces Oppervlakken gtt Surfaces (Physique) Tension superficielle Thermodynamica gtt Thermodynamique Thermodynamics Surfaces (Physics) |
| topic_facet | Chimie des surfaces Oppervlakken Surfaces (Physique) Tension superficielle Thermodynamica Thermodynamique Thermodynamics Surfaces (Physics) Bibliografie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017079159&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT dadashevraikomk thermodynamicsofsurfacephenomena |