Supramolecular chemistry:
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| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Chichester
Wiley
2009
|
| Edition: | 2. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XXVI, 970 S. Ill., graph. Darst. |
| ISBN: | 9780470512340 9780470512333 |
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| 100 | 1 | |a Steed, Jonathan W. |d 1969- |e Verfasser |0 (DE-588)137209541 |4 aut | |
| 245 | 1 | 0 | |a Supramolecular chemistry |c Jonathan W. Steed ; Jerry L. Atwood |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Chichester |b Wiley |c 2009 | |
| 300 | |a XXVI, 970 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 7 | |a Chelaten |2 gtt | |
| 650 | 7 | |a Fotochemie |2 gtt | |
| 650 | 7 | |a Macrocyclische verbindingen |2 gtt | |
| 650 | 7 | |a Mimetica |2 gtt | |
| 650 | 7 | |a Porfyrinen |2 gtt | |
| 650 | 7 | |a Supramoleculaire systemen |2 gtt | |
| 650 | 7 | |a Viagra |2 gtt | |
| 650 | 4 | |a Supramolecular chemistry | |
| 650 | 0 | 7 | |a Supramolekulare Chemie |0 (DE-588)4306141-2 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Supramolekulare Chemie |0 (DE-588)4306141-2 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Atwood, Jerry L. |d 1942- |e Verfasser |0 (DE-588)134006593 |4 aut | |
| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017053808&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
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| adam_text | Contents
About the Authors
xxi
Preface to the First Edition
xxiii
Preface to the Second Edition
xxv
Acknowledgements
xxvii
ι
Concepts
ι
1.1 Definition and Development of Supramolecular Chemistry
2
1.1.1
What is Supramolecular Chemistry?
2
1.1.2
Host-Guest Chemistry
3
1.1.3
Development
4
1.2
Classification of Supramolecular Host-Guest Compounds
6
1.3
Receptors, Coordination and the Lock and Key Analogy
6
1.4
Binding Constants
9
1.4.1
Definition and Use
9
1.4.2
Measurement of Binding Constants
11
1.5
Cooperativity and the
Chetate
Effect
17
1.6
Preorganisation and Complementarity
22
1.7
Thermodynamic and Kinetic Selectivity, and Discrimination
26
1.8
Nature of Supramolecular Interactions
27
1.8.1
Ion-ion Interactions
27
1.8.2
Ion-Dipole Interactions
27
1.8.3 Dipole-Dipole
Interactions
28
1.8.4
Hydrogen Bonding
28
1.8.5
Cation
-π
Interactions
32
1.8.6
Anion
-π
Interactions
33
1.8.7
κ—η
Interactions
33
1.8.8
Van
der Waals
Forces and Crystal Close Packing
35
1.8.9
Closed Shell Interactions
36
1.9
Solvation and
Hydrophobie
Effects
38
1.9.1 Hydrophobie
Effects
38
1.9.2
Solvation
39
1.10
Supramolecular Concepts and Design
41
1.10.1
Host Design
41
1.10.2
Informed and Emergent Complex Matter
42
1.10.3
Nanochemistry
44
шШт
Contents
Summary
45
Study Problems 45
Suggested Further Reading
46
References
47
2
The Supramolecular Chemistry of Life
49
2.1
Biological Inspiration for Supramolecular Chemistry
50
2.2
Alkali Metal Cations in Biochemistry
50
2.2.1
Membrane Potentials
50
2.2.2
Membrane Transport
53
2.2.3
Rhodopsin: A Supramolecular Photonic Device
60
2.3
Porphyrins and Tetrapyrrole
Macrocycles
61
2.4
Supramolecular Features of Plant Photosynthesis
63
2.4.1
The Role of Magnesium Tetrapyrrole Complexes
63
2.4.2
Manganese-Catalysed Oxidation of Water to Oxygen
68
2.5
Uptake and Transport of Oxygen by Haemoglobin
70
2.6
Enzymes and Coenzymes
74
2.6.1
Characteristics of Enzymes
74
2.6.2
Mechanism of Enzymatic Catalysis
77
2.6.3
Coenzymes
79
2.6.4
The Example of Coenzyme B12
80
2.7
Neurotransmitters
and Hormones
83
2.8
Semiochemistry in the Natural World
85
2.9 DNA 86
2.9.1 DNA
Structure and Function
86
2.9.2
Site-Directed Mutagenesis
91
2.9.3
The Polymerase Chain Reaction
92
2.9.4
Binding to
DNA 93
2.9.5 DNA
Polymerase:
A Processive
Molecular Machine
97
2.10
Biochemical Self-Assembly
99
Summary
102
Study Problems
102
References
103
3
Cation-Binding Hosts
105
3.1
Introduction to Coordination Chemistry
106
3.1.1
Supramolecular Cation Coordination Chemistry
106
3.1.2
Useful Concepts in Coordination Chemistry
106
3.1.3
EDTA
-
a Classical Supramolecular Host
112
Contents
3.2
The Crown Ethers
114
3.2.1
Discovery and Scope
114
3.2.2
Synthesis
116
3.3
The Lariat Ethers and Podands
118
3.3.1
Podands
118
3.3.2
Lariat Ethers
120
3.3.3
Bibracchial Lariat Ethers
121
3.4
The Cryptands
122
3.5
The Spherands
125
3.6
Nomenclature of Cation-Binding
Macrocycles
127
3.7
Selectivity of Cation Complexation
129
3.7.1
General Considerations
129
3.7.2
Conformational Characteristics of Crown Ethers
130
3.7.3
Donor Group Orientation and Chelate Ring Size Effects
132
3.7.4
Cation Binding by Crown Ethers
135
3.7.5
Cation Binding by Lariat Ethers
140
3.7.6
Cation Binding by Cryptands
142
3.7.7
Preorganisation: Thermodynamic Effects
144
3.7.8
Preorganisation: Kinetic and Dynamic Effects
147
3.8
Solution Behaviour
149
3.8.1
Solubility Properties
149
3.8.2
Solution Applications
149
3.9
Synthesis: The Template Effect and High Dilution
153
3.9.1
The Template Effect
153
3.9.2
High-Dilution Synthesis
157
3.10
Soft Ligands for Soft Metal Ions
160
3.10.1
Nitrogen and Sulfur Analogues of Crown Ethers
160
3.10.2
Nitrogen and Sulfur Analogues of Cryptands
163
3.10.3
Azamacrocycles: Basicity Effects and the Example of Cyclam
164
3.10.4
Phosphorus-Containing
Macrocycles
167
3.10.5
Mixed
Cryptâtes
168
3.10.6 Schiff
Bases
170
3.10.7
Phthalocyanines
172
3.10.8
Torands
173
3.11
Proton Binding: The Simplest Cation
173
3.11.1
Oxonium Ion Binding by
Macrocycles
in the Solid State
174
3.11.2
Solution Chemistry of Proton Complexes
177
3.12
Complexation of Organic Cations
180
3.12.1
Binding of Ammonium Cations by Corands
181
3.12.2
Binding of Ammonium Cations by Three-Dimensional Hosts
183
3.12.3
Ditopic Receptors
184
3.12.4
Chiral Recognition
185
3.12.5
Amphiphilic Receptors
193
3.12.6
Case Study: Herbicide Receptors
194
Contents
3.13 Alkalides and Electrides 195
3.14 The Calixarenes 197
3.14.1
Cation
Complexation
by
Calixarenes 198
3.14.2 Phase Transport
Equilibria
204
3.14.3
Cation
Complexation
by
Hybrid Calixarenes 206
3.15 Carbon
Donor and
ff-acid Ligands 208
3.15.1
Mixed
C-Heteroatom Hosts 209
3.15.2
Hydrocarbon
Hosts 211
3.16 The Siderophores 213
3.16.1
Naturally Occurring
Siderophores 213
3.16.2
Synthetic
Siderophores 215
Summary
217
Study
Problems 217
Thought
Experiment 218
References
219
4
Anion
Binding
223
4.1
Introduction
224
4.1.1
Scope
224
4.1.2
Challenges in Anion Receptor Chemistry
225
4.2
Biological Anion Receptors
227
4.2.1
Anion Binding Proteins
228
4.2.2
Arginine
as an Anion Binding Site
229
4.2.3
Main Chain Anion Binding Sites in Proteins: Nests
230
4.2.4
Pyrrole-Based Biomolecules
231
4.3
Concepts in Anion Host Design
232
4.3.1
Preorganisation
232
4.3.2
Entropie
Considerations
233
4.3.3
Considerations Particular to Anions
234
4.4
From Cation Hosts to Anion Hosts
-
a Simple Change in
pH
236
4.4.1
Tetrahedral Receptors
236
4.4.2
Shape Selectivity
238
4.4.3
Ammonium-Based Podands
239
4.4.4
Two-Dimensional Hosts
240
4.4.5
Cyclophane Hosts
246
4.5
Guanidinium-Based Receptors
248
4.6
Neutral Receptors
251
4.6.1 Zwitterions 253
4.6.2
Amide-Based Receptors
253
4.6.3
Urea and Thiourea Derivatives
255
4.6.4
Pyrrole Derivatives
257
4.6.5
Peptide-Based Receptors
258
Contents
4.7 Inert
Metal-Containing Receptors
259
4.7.1 General
Considerations
259
4.7.2 Organometallic
Receptors
261
4.7.3 Hydride
Sponge and Other Lewis Acid Chelates
268
4.7.4
Anticrowns
271
4.8
Common Core Scaffolds
276
4.8.1
The Trialkylbenzene Motif
277
4.8.2
Cholapods
278
Summary
281
Study Problems
281
Thought Experiments
282
References
282
5
Ion Pair Receptors
285
5.1
Simultaneous
Anion
and Cation Binding
286
5.1.1
Concepts
286
5.1.2
Contact Ion Pairs
287
5.1.3
Cascade Complexes
289
5.1.4
Remote
Anion
and Cation Binding Sites
291
5.1.5
Symport and Metals Extraction
295
5.1.6
Dual-Host Salt Extraction
298
5.2
Labile Complexes as
Anion
Hosts
299
5.3
Receptors for
Zwitterions 303
Summary
304
Study Problems
304
References
305
6
Molecular Guests in Solution
307
6.1
Molecular Hosts and Molecular Guests
308
6.1.1
Introduction
308
6.1.2
Some General Considerations
308
6.2
Intrinsic Curvature: Guest Binding by Cavitands
310
6.2.1
Building Blocks
310
6.2.2
Calixarenes and Resorcarenes
311
6.2.3
Dynamics of Guest Exchange in Cavitates
320
6.2.4
Glycoluril-Based Hosts
323
6.2.5
Kohnkene
326
6.3
Cyclodextrins
327
6.3.1
Introduction and Properties
327
6.3.2
Preparation
331
6.3.3
Inclusion Chemistry
331
6.3.4
Industrial Applications
335
6.4
Molecular
Clefts and Tweezers
6.5
Cyclophane Hosts
6.5.1
General Aspects
6.5.2
Cyclophane Nomenclature
6.5.3
Cyclophane Synthesis
6.5.4
Molecular Iron Maidens
6.5.5
From Tweezers to Cyclophanes
6.5.6
The Diphenylmethane Moiety
6.5.7
Guest Inclusion by Hydrogen Bonding
6.5.8
Charge-Transfer Cyclophanes
Contents
336
340
340
341
342
345
346
347
353
357
6.6
Constructing a Solution Host from Clathrate-Forming Building Blocks:
The Cryptophanes
358
6.6.1
Construction of Containers from a Curved Molecular Building Block
358
6.6.2
Complexation of Halocarbons
361
6.6.3
Competition with Solvent
363
6.6.4
Complexes with
Alkyl
Ammonium Ions and Metals
364
6.6.5
Methane and Xenon Complexation
365
6.6.6
An Imploding Cryptophane
366
6.6.7
Hemicryptophanes
367
6.7
Covalent Cavities: Carcerands and Hemicarcerands
370
6.7.1
Definitions and Synthesis
370
6.7.2
Template Effects in Carcerand Synthesis
373
6.7.3
Complexation and Constrictive Binding
373
6.7.4
Carcerism
375
6.7.5
Inclusion Reactions
376
6.7.6
Giant Covalent Cavities
379
Summary
381
Study Problems
381
Thought Experiment
382
References
382
7
Solid-State Inclusion Compounds
385
7.1
Solid-State Host-Guest Compounds
386
7.2
Clathrate Hydrates
387
7.2.1
Formation
387
7.2.2
Structures and Properties
388
7.2.3
Problems and Applications
391
7.3
Urea and Thiourea Clathrates
393
7.3.1
Structure
393
7.3.2
Guest Order and Disorder
394
7.3.3
Applications of Urea Inclusion Compounds
398
Contents
7.4
Other Channel Clathrates
399
7.4.1 Trimesic
Acid
399
7.4.2
Helical Tubulands and Other Di-ols
401
7.4.3 Perhydrotriphenylene:
Polarity
Formation 403
7.5 Hydroquinone, Phenol,
Dianin s Compound and the
Hexahost
Strategy
406
7.6 Tri-o-thymotide 410
7.6.1
Inclusion Chemistry
410
7.6.2
Synthesis and Derivatives
412
7.6.3
Applications
413
7.7
Cyclotriveratrylene
414
7.7.1
Properties
414
7.7.2
Synthesis
414
7.7.3
Inclusion Chemistry
416
7.7.4
Network Structures
418
7.8
Inclusion Compounds of the Calixarenes
419
7.8.1
Organic-Soluble Calixarenes
419
7.8.2
Fullerene Complexation
423
7.8.3
Water-Soluble
Calixarenes
426
7.9
Solid-Gas and Solid-Liquid Reactions in Molecular Crystals
429
7.9.1
The Importance of
Gas Sorption 429
7.9.2 Gas Sorption
by Calixarenes
431
7.9.3 Gas Sorption
by Channel Hosts
434
7.9.4 Gas Sorption
by Coordination Complex Hosts
435
Summary
437
Study Problems
438
References
438
8
Crystal Engineering
441
8.1
Concepts
442
8.1.1
Introduction
442
8.1.2
Tectons and Synthons
443
8.1.3
The Special Role of Hydrogen Bonding
447
8.1.4
Hydrogen Bond Acidity and Basicity
452
8.2
Crystal Nucleation and Growth
453
8.2.1
Theory of Crystal Nucleation and Growth
453
8.2.2
NMR Spectroscopy as a Tool to Probe Nucleation
455
8.2.3
Crystal Growth at Air-Liquid Interfaces
456
8.2.4
Chirality Induction: The Adam Effect
458
8.2.5
Dyeing Crystal Interfaces
462
8.2.6
Hourglass Inclusions
464
8.2.7
Epitaxy: Engineering Crystals
467
8.2.8
Crystals as Genes?
469
8.2.9
Mechanochemistry and Topochemistry
470
Contents
8.3
Understanding Crystal Structures
476
8.3.1
Graph Set Analysis
476
8.3.2
Etter s Rules
478
8.3.3
Crystal Deconstruction
481
8.3.4
Crystal Engineering Design Strategies
482
8.4
The Cambridge Structural Database
484
8.5
Polymorphism
487
8.5.1
The Importance of Polymorphism
487
8.5.2
Types of Polymorphism
489
8.5.3
Controlling Polymorphism
492
8.6
Co-crystals
493
8.6.1
Scope and Nomenclature
493
8.6.2
Designer Co-crystals
494
8.6.3
Hydrates
497
8.7
Z
> 1 498
8.8
Crystal Structure Prediction
500
8.8.1
Soft vs. Hard Predictions
500
8.8.2
Crystal Structure Calculation
501
8.8.3
The CCDC Blind Tests
504
8.9
Hydrogen Bond Synthons
-
Common and Exotic
505
8.9.1
Hydrogen Bonded Rings
505
8.9.2
Hydrogen Bonds to Halogens
510
8.9.3
Hydrogen Bonds to Cyanometallates
511
8.9.4
Hydrogen Bonds to Carbon Monoxide Ligands
512
8.9.5
Hydrogen Bonds to Metals and Metal Hydrides
514
8.9.6
CH Donor Hydrogen Bonds
517
8.10
Aromatic Rings
519
8.10.1
Edge-to-Face and Face-to-Face Interactions
519
8.10.2
Aryl Embraces
522
8.10.3
Metal
-π
Interactions
523
8.11
Halogen Bonding and Other Interactions
524
8.12
Crystal Engineering of Diamondoid Arrays
526
Summary 530
Study Problems
531
Thought Experiment
532
References
532
9
Network Solids
537
9.1
What Are Network Solids?
538
9.1.1
Concepts and Classification
538
9.1.2
Network Topology
539
9.1.3
Porosity
542
Contents
9.2
Zeolites
543
9.2.1
Composition and Structure
543
9.2.2
Synthesis
547
9.2.3
MFI Zeolites in the Petroleum Industry
548
9.3
Layered Solids and Intercalates
550
9.3.1
General Characteristics
550
9.3.2
Graphite Intercalates
553
9.3.3
Controlling the Layers: Guanidinium Sulfonates
554
9.4
In the Beginning: Hoffman Inclusion Compounds and Werner Clathrates
556
9.5
Coordination Polymers
561
9.5.1
Coordination Polymers, MOFs and Other Terminology
561
9.5.2
OD
Coordination Clusters
562
9.5.3
ID, 2D and
3D
Structures
564
9.5.4
Magnetism
568
9.5.5
Negative Thermal Expansion
570
9.5.6
Interpenetrated Structures
571
9.5.7
Porous and Cavity-Containing Structures
575
9.5.8
Metal-Organic Frameworks
578
9.5.9
Catalysis by MOFs
583
9.5.10
Hydrogen Storage by MOFs
583
Summary
586
Study Problem
587
References
587
10
Self-Assembly
591
10.1
Introduction
592
10.1.1
Scope and Goals
592
10.1.2
Concepts and Classification
594
10.2
Proteins and Foldamers: Single Molecule Self-Assembly
598
10.2.1
Protein Self-Assembly
598
10.2.2
Foldamers
599
10.3
Biochemical Self-Assembly
600
10.3.1
Strict Self-Assembly: The Tobacco Mosaic Virus and
DNA 600
10.3.2
Self-Assembly with Covalent Modification
602
10.4
Self-Assembly in Synthetic Systems: Kinetic
and Thermodynamic Considerations
604
10.4.1
Template Effects in Synthesis
604
10.4.2
A Thermodynamic Model: Self-Assembly of Zinc
Porphyrin
Complexes
606
10.4.3
Cooperativity and the Extended Site Binding Model
610
10.4.4
Double Mutant Cycles
-
Quantifying Weak Interactions
615
10.4.5
Probability of Self-Assembly
616
Contents
10.5
Self-Assembling Coordination Compounds
620
10.5.1
Design and Notation
620
10.5.2
A Supramolecular Cube
621
10.5.3
Molecular Squares and Boxes
624
10.5.4
Self-Assembly of Metal Arrays
637
10.6
Self-Assembly of Closed Complexes
by Hydrogen Bonding
641
10.6.1
Tennis Balls and
Softballs:
Self-Complementary
Assemblies
641
10.6.2
Heterodimeric Capsules
646
10.6.3
Giant Self-Assembling Capsules
646
10.6.4
Rosettes
651
10.7
Catenanes and Rotaxanes
653
10.7.1
Overview
653
10.7.2
Statistical Approaches to Catenanes and Rotaxanes
655
10.7.3
Rotaxanes and Catenanes Involving
π-π
Stacking Interactions
656
10.7.4
Hydrogen Bonded Rotaxanes and Catenanes
666
10.7.5
Metal and Auxiliary Linkage Approaches to
Catenanes and Rotaxanes
669
10.7.6
Molecular Necklaces
677
10.8
Helicates and Helical Assemblies
678
10.8.1
Introduction
678
10.8.2
Synthetic Considerations
681
10.8.3 [4 + 4]
Helicates
682
10.8.4 [6 + 6]
Helicates
683
10.8.5
Self-Recognition and Positive Cooperativity
684
10.8.6
Cyclic Helicates
686
10.8.7
Anion-Based Helices
687
10.8.8
Hydrogen-Bonded Helices
687
10.9
Molecular Knots
691
10.9.1
The Topology of Knots
691
10.9.2
Trefoil Knots
693
10.9.3
Other Knots
696
10.9.4
Borromean Rings
697
Summary
700
Study Problems
701
Thought Experiment
702
References
702
11
Molecular Devices
707
11.1
Introduction
708
11.1.1
Philosophy of Molecular Devices
708
11.1.2
When Is a Device Supramolecular?
708
Contents
МрЈ!»
11.2
Supramolecular Photochemistry
710
11.2.1
Photophysical Fundamentals
710
11.2.2
Mechanisms of Energy and Electron Transfer
713
11.2.3
Bimetallic Systems and Mixed Valence
715
11.2.4
Bipyridine and Friends as Device Components
716
11.2.5
Bipyridyl-Type Light Harvesting Devices
718
11.2.6
Light-Conversion Devices
725
11.2.7
Non-Covalently Bonded Systems
726
11.3
Information and Signals: Semiochemistry and Sensing
730
11.3.1
Supramolecular Semiochemistry
730
11.3.2
Photophysical Sensing and Imaging
731
11.3.3
Colorimetrie
Sensors and the Indicator
Displacement Assay
738
11.3.4
Electrochemical Sensors
742
11.4
Molecule-Based Electronics
746
11.4.1
Molecular Electronic Devices
746
11.4.2
Molecular Wires
746
11.4.3
Molecular Rectifiers
750
11.4.4
Molecular Switches
752
11.4.5
Molecular Logic
756
11.4.6
Towards Addressable Molecular Devices
760
11.5
Molecular Analogues of Mechanical Machines
762
11.6
Nonlinear Optical Materials
765
11.6.1
Origins of Nonlinear Optical Effects
765
11.6.2
Second-Order Nonlinear Optical Materials
768
11.6.3
Third Harmonic Generation Nonlinear
Optical Materials
771
Summary
771
Study Problems
771
References
772
12
Biological Mimics and Supramolecular Catalysis
777
12.1
Introduction
778
12.1.1
Understanding and Learning from Biochemistry
778
12.1.2
Characteristics of Biological Models
779
12.2
Cyclodextrins as Enzyme Mimics
780
12.2.1
Enzyme Modelling Using an Artificial
Host Framework
780
12.2.2
Cyclodextrins as
Esterase
Mimics
782
12.2.3
Functionalised Cyclodextrins
783
12.3
Corands as ATPase Mimics
785
Contents
12.4
Cation-Binding
Hosts
as Transacylase
Mimics
788
12.4.1
Olirai Corands
788
12.4.2
A
Structure and Function Mimic
790
12.5
Metallobiosites
792
12.5.1
Haemocyanin Models
793
12.5.2
Zinc-Containing Enzymes
795
12.6
Haem Analogues
798
12.6.1
Models of Oxygen Uptake and Transport
798
12.6.2
Cytochrome P-450 Models
803
12.6.3
Cytochrome
с
Oxidase
Models
807
12.7
Vitamin B12 Models
808
12.8
Ion Channel Mimics
809
12.9
Supramolecular Catalysis
813
12.9.1
Abiotic Supramolecular Catalysis
813
12.9.2
Dynamic Combinatorial Libraries
817
12.9.3
Self-Replicating Systems
819
12.9.4
Emergence of Life
823
Summary
825
Study Problems
825
Thought Experiment
826
References
826
13
Interfaces and Liquid Assemblies
829
13.1
Order in Liquids
830
13.2
Surfactants and
Interfacial
Ordering
831
13.2.1
Surfactants, Micelles and Vesicles
831
13.2.2
Surface Self-Assembled Monolayers
837
13.3
Liquid Crystals
839
13.3.1
Nature and Structure
839
13.3.2
Design of Liquid Crystalline Materials
846
13.3.3
Supramolecular Liquid Crystals
848
13.3.4
Liquid Crystal Displays
851
13.4
Ionic Liquids
852
13.5
Liquid Clathrates
854
Summary
858
Study Problems
858
References
859
Contents
14 Supramolecular Polymers, Gels and
Fibres
ббі
14.1
Introduction
862
14.2 Dendrimers 862
14.2.1
Structure
and Nomenclature
862
14.2.2
Preparation and Properties of Molecular Dendrimers
866
14.2.3
Dendrimer Host-Guest Chemistry
869
14.2.4
Supramolecular Dendrimer Assemblies
872
14.2.5
Dendritic Nanodevices
874
14.3
Covalent Polymers with Supramolecular Properties
876
14.3.1
Amphiphilic Block Copolymers
876
14.3.2
Molecular Imprinted Polymers
879
14.4
Self-Assembled Supramolecular Polymers
880
14.5
Polycatenanes and Polyrotaxanes
883
14.6
Biological Self-Assembled Fibres and Layers
885
14.6.1
Amyloids, Actins and Fibrin
885
14.6.2
Bacterial S-Layers
887
14.7
Supramolecular Gels
888
14.8
Polymeric Liquid Crystals
893
Summary
894
Study Problems
895
References
895
15
Nanochemistry
899
15.1
When Is
Nano
Really
Nano?
900
15.2
Nanotechnology: The Top Down and Bottom Up Approaches
900
15.3
Templated and Biomimetic Morphosynthesis
902
15.4
Nanoscale Photonics
905
15.5
Microfabrication, Nanofabrication
and Soft Lithography
907
15.6
Assembly and Manipulation on the Nanoscale
912
15.6.1
Chemistry with a Microscope Tip
912
15.6.2
Self-Assembly on Surfaces
914
15.6.3
Addressing Single Molecules
918
15.6.4
Atomic-Level Assembly of Materials
920
15.7
Nanoparticles
921
15.7.1
Nanoparticles and Colloids: Definition and Description
921
15.7.2
Gold Nanoparticles
922
15.7.3
Quantum Dots
925
15.7.4
Non-Spherical Nanoparticles
927
Contents
15.8 Endohedral
Fullerenes,
Nanotubes and Graphene 927
15.8.1
Fullerenes
as
Hosts 928
15.8.2 Carbon Nanotubes 931
15.8.3 Graphene 935
15.8.4 Afterword -
Damascus
Steel 935
Summary
936
Thought
Experiment 937
References
937
Index 941
|
| any_adam_object | 1 |
| author | Steed, Jonathan W. 1969- Atwood, Jerry L. 1942- |
| author_GND | (DE-588)137209541 (DE-588)134006593 |
| author_facet | Steed, Jonathan W. 1969- Atwood, Jerry L. 1942- |
| author_role | aut aut |
| author_sort | Steed, Jonathan W. 1969- |
| author_variant | j w s jw jws j l a jl jla |
| building | Verbundindex |
| bvnumber | BV035248122 |
| callnumber-first | Q - Science |
| callnumber-label | QD878 |
| callnumber-raw | QD878 |
| callnumber-search | QD878 |
| callnumber-sort | QD 3878 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VK 7150 VK 7151 |
| classification_tum | CHE 780f |
| ctrlnum | (OCoLC)251208094 (DE-599)BVBBV035248122 |
| dewey-full | 547/.1226 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547/.1226 |
| dewey-search | 547/.1226 |
| dewey-sort | 3547 41226 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| edition | 2. ed. |
| format | Book |
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| id | DE-604.BV035248122 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:29:35Z |
| institution | BVB |
| isbn | 9780470512340 9780470512333 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017053808 |
| oclc_num | 251208094 |
| open_access_boolean | |
| owner | DE-20 DE-703 DE-91G DE-BY-TUM DE-29T DE-19 DE-BY-UBM DE-11 |
| owner_facet | DE-20 DE-703 DE-91G DE-BY-TUM DE-29T DE-19 DE-BY-UBM DE-11 |
| physical | XXVI, 970 S. Ill., graph. Darst. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | Wiley |
| record_format | marc |
| spelling | Steed, Jonathan W. 1969- Verfasser (DE-588)137209541 aut Supramolecular chemistry Jonathan W. Steed ; Jerry L. Atwood 2. ed. Chichester Wiley 2009 XXVI, 970 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chelaten gtt Fotochemie gtt Macrocyclische verbindingen gtt Mimetica gtt Porfyrinen gtt Supramoleculaire systemen gtt Viagra gtt Supramolecular chemistry Supramolekulare Chemie (DE-588)4306141-2 gnd rswk-swf Supramolekulare Chemie (DE-588)4306141-2 s DE-604 Atwood, Jerry L. 1942- Verfasser (DE-588)134006593 aut Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017053808&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Steed, Jonathan W. 1969- Atwood, Jerry L. 1942- Supramolecular chemistry Chelaten gtt Fotochemie gtt Macrocyclische verbindingen gtt Mimetica gtt Porfyrinen gtt Supramoleculaire systemen gtt Viagra gtt Supramolecular chemistry Supramolekulare Chemie (DE-588)4306141-2 gnd |
| subject_GND | (DE-588)4306141-2 |
| title | Supramolecular chemistry |
| title_auth | Supramolecular chemistry |
| title_exact_search | Supramolecular chemistry |
| title_full | Supramolecular chemistry Jonathan W. Steed ; Jerry L. Atwood |
| title_fullStr | Supramolecular chemistry Jonathan W. Steed ; Jerry L. Atwood |
| title_full_unstemmed | Supramolecular chemistry Jonathan W. Steed ; Jerry L. Atwood |
| title_short | Supramolecular chemistry |
| title_sort | supramolecular chemistry |
| topic | Chelaten gtt Fotochemie gtt Macrocyclische verbindingen gtt Mimetica gtt Porfyrinen gtt Supramoleculaire systemen gtt Viagra gtt Supramolecular chemistry Supramolekulare Chemie (DE-588)4306141-2 gnd |
| topic_facet | Chelaten Fotochemie Macrocyclische verbindingen Mimetica Porfyrinen Supramoleculaire systemen Viagra Supramolecular chemistry Supramolekulare Chemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017053808&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT steedjonathanw supramolecularchemistry AT atwoodjerryl supramolecularchemistry |