Silicon-containing dendritic polymers:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
[Dordrecht]
Springer
2009
|
| Schriftenreihe: | Advances in silicon science
2 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XV, 428 S. Ill., graph. Darst. |
| ISBN: | 9781402081736 |
Internformat
MARC
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| 016 | 7 | |a 986421693 |2 DE-101 | |
| 020 | |a 9781402081736 |c hbk. |9 978-1-402-08173-6 | ||
| 035 | |a (OCoLC)258090027 | ||
| 035 | |a (DE-599)DNB986421693 | ||
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| 084 | |a VK 8000 |0 (DE-625)147532:253 |2 rvk | ||
| 084 | |a 540 |2 sdnb | ||
| 245 | 1 | 0 | |a Silicon-containing dendritic polymers |c Petar R. Dvornic ; Michael J. Owen, eds. |
| 246 | 1 | 3 | |a Silicon containing dendritic polymers |
| 264 | 1 | |a [Dordrecht] |b Springer |c 2009 | |
| 300 | |a XV, 428 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Advances in silicon science |v 2 | |
| 650 | 4 | |a Dendrimers | |
| 650 | 4 | |a Silicon polymers | |
| 650 | 0 | 7 | |a Silicon-Polymere |0 (DE-588)4456222-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Sternpolymere |0 (DE-588)4245705-1 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Silicon-Polymere |0 (DE-588)4456222-6 |D s |
| 689 | 0 | 1 | |a Sternpolymere |0 (DE-588)4245705-1 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Dvornic, Petar R. |e Sonstige |4 oth | |
| 700 | 1 | |a Owen, Michael J. |e Sonstige |4 oth | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |z 978-1-4020-8174-3 |
| 830 | 0 | |a Advances in silicon science |v 2 |w (DE-604)BV035313944 |9 2 | |
| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992268&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-016992268 | ||
Datensatz im Suchindex
| _version_ | 1804138361027297280 |
|---|---|
| adam_text | Contents
1
The Role of
Silicon
in Dendritic Polymer Chemistry
........................... 1
Petar
R.
Dvornic and Michael J. Owen
1.1
Introduction
....................................................................................... 1
1.2
Dendrimers and Hyperbranched Polymers
....................................... 4
1.2.1
Dendrimers
............................................................................ 4
1.2.2
Hyperbranched Polymers
...................................................... 10
1.3
A Brief Historical Overview of the Main Developments
in Dendrimers and Hyperbranched Polymers
................................... 13
1.4
Silicon in Dendritic Polymers
........................................................... 15
2
Polysiloxane and Siloxane-Based Dendrimers
...................................... 21
Aziz Muzafarov and Evgenij Rebrov
2.1
Introduction: Historical Background
................................................. 21
2.2
Chemistry of Siloxane Dendrimers
................................................... 22
2.3
Peculiarities of Siloxane Dendrimers
................................................ 25
2.4
Prospects for Further Development in the Chemistry
of Siloxane Dendrimers
..................................................................... 28
3
Carbosilane Dendrimers
......................................................................... 31
Jacques Roovers and Jianfu Ding
3.1
Introduction
....................................................................................... 31
3.2
Synthesis of Carbosilane Dendrimers
............................................... 32
3.2.1
Core Molecules
..................................................................... 33
3.2.2
Interior Generations
.............................................................. 38
3.2.3
Peripheral (Corona; End-Groups) Modification
................... 43
3.3
Carbosilane Dendrimer Characterization
.......................................... 60
3.4
Properties of Carbosilane Dendrimers
.............................................. 62
3.4.1
Molecular Dimensions of Carbosilane Dendrimers
.............. 62
3.4.2
Dynamics of Carbosilane Dendrimers
.................................. 66
Contents
viii
4 Polysilane
Dendrimers
.............................................................................
Masato Nanjo and Akira Sekiguchi
4.1
Introduction
.......................................................................................
4.2
Synthetic Approaches to Polysilane Dendrimers
.............................. 76
4.2.1
Convergent Methods
............................................................. 76
4.2.2
Divergent Methods
................................................................ 79
4.2.3
Double-Cored Polysilane Dendrimers
.................................. 81
4.2.4
Functionalized Polysilane Dendrimers
................................. 84
4.3
NMR Spectroscopy of Polysilane Dendrimers
................................. 85
4.4
Crystallography and Conformation of Polysilane Dendrimers
......... 87
4.5
Electronic Spectra
............................................................................. 91
4.6
Conclusions and Future Outlook
....................................................... 94
5
Polycarbosilazane and Related Dendrimers
and Hyperbranched Polymers
................................................................ 97
David Y. Son
5.1
Introduction
....................................................................................... 97
5.2
Polycarbosilazane Dendrimers
.......................................................... 98
5.3
Polysilazane Dendrimers
.................................................................. 99
5.4
Related Dendrimers
.......................................................................... 100
5.5
Hyperbranched Polycarbosilazanes
.................................................. 101
5.6
Concluding Remarks
......................................................................... 102
6
Silyl Ether Containing Dendrimers with Cyclic Siloxane Cores
......... 105
Chungkyun Kim
6.1
Introduction
....................................................................................... 105
6.2
Siloxane Dendrimers with Cyclic Siloxane Core (0G(4)-Vinyl)
...... 106
6.3
Synthesis of Dendrimers with Si-O-C Units from
Cyclic Siloxane Cores
....................................................................... 108
6.3.1
General Synthetic Strategy from 0G(4)-Vinyl Core
............. 108
6.3.2
Dendrimers with Organic Functional End-Groups
............... 108
6.3.3
Dendrimers with Triple Bonds
.............................................. 109
6.3.4
Double-Layered Dendrimers with Conjugated
Branches
.....................................................................
j
¡О
6.3.5
Ferrocenyl-Functionalized Dendrimers
as COGas Sensor
..................................................................
j
12
6.3.6
Water Soluble Dendrimers
..................................................
П2
6.3.7
Dendrimers with Terpyridine Ruthenium
Complex End-Groups
..................................................
j
14
6.3.8
Dendrimers with Farnesyl End-Groups
................................ 114
6.3.9
Diels-Alder Reaction on Dendrimer Periphery
............... 116
6.4
Dendrimers with Silsesquioxane Core
...................................... .......
1
17
6.5
Conclusion
......................
.........................................................................
Ilo
Contents
Polyhedral
Oligomeríc Silsesquioxane Dendrimers
.............................. 121
Katherine
J.
Haxton
and Russell
E.
Morris
7.1
Introduction
....................................................................................... 121
7.2
Synthesis of Silsesquioxanes and Silicates
....................................... 123
7.2.1
Silsesquioxanes
..................................................................... 123
7.2.2
Silicates
................................................................................. 124
7.2.3
Functionalizing Silsesquioxanes and Silicates
...................... 125
7.3
Synthesis of POSS and Silicate Dendrimers
..................................... 126
7.3.1
POSS Dendrimer Synthesis
................................................... 126
7.3.2
Silicate Dendrimer Synthesis
................................................ 129
7.3.3
Characterization
.................................................................... 130
7.4
Applications of POSS and Silicate Dendrimers
................................ 130
7.4.1
Homogeneous Catalysis
........................................................ 130
7.4.2
Electro- and Redox-Active Dendrimers
................................ 133
7.4.3
Liquid Crystals
...................................................................... 133
7.4.4
Transition Metal Binding
...................................................... 134
7.4.5
POSS-PAMAM Nanocomposites
......................................... 135
7.4.6
Gene Transfection
................................................................. 136
7.5
Conclusion
........................................................................................ 137
Organometallic Silicon-Containing Dendrimers
and Their Electrochemical Applications
................................................ 141
Isabel
Cuadrado
8.1
Introduction
....................................................................................... 141
8.2
Synthetic Strategies and
Redox
Properties
of Organometallic Silicon-Containing Dendritic
Macromolecules
................................................................................ 145
8.2.1
Functionalization of Silicon-Based Dendritic Scaffolds
with Electroactive Organometallic Moieties
......................... 147
8.2.2
Silicon-Based Dendrimers from Organometallic
Moieties
................................................................................. 163
8.3
Electrochemical Applications of Ferrocenyl Silicon-Containing
Dendritic Molecules
.......................................................................... 183
8.3.1
Ferrocenyl Dendrimers with Si-NH Linkages
as
Redox
Sensors for Recognition of Inorganic Anions
....... 183
8.3.2
Ferrocenyl Silicon-Containing Dendrimers as
Electron-Transfer Mediators in Amperometric
Biosensors
............................................................................. 186
8.3.3
Electrocatalytic Oxidation of Ascorbic Acid Mediated
by a Ferrocenyl Siloxane-Based Network Polymer
.............. 189
8.4
Concluding Remarks
......................................................................... 191
Contents
9 Carbosilane Dendrimers:
Molecular
Supports
and Containers
for Homogeneous Catalysis
and Organic Synthesis
...........................................................................
Maaike
Wander, Robertus J.M. Klein Gebbink, and Gerard van
Koten
1Q7
9.1
Introduction
...................................................................................
9.2
Carbosilane Dendrimers with Covalently Bound Catalysts
.......... 201
9.2.1
Synthesis and Structural Aspects
of Phosphine-Based Dendrimer Catalysts
....................... 201
9.2.2
Catalytic Reactivity of Phosphine-Based
Dendrimer Catalysts
........................................................ 203
9.2.3
Synthesis and Structural Aspects of
Non-phosphine-Based Dendrimer Catalysts
................... 213
9.2.4
Catalytic Reactivity of Non-phosphine-Based
Dendrimer Catalysts
........................................................ 214
9.3
Supported Organic Synthesis on Soluble Carbosilanes
................ 228
9.4
Conclusions and Future Outlook
................................................... 230
10
Liquid Crystalline Silicon-Containing Dendrimers
with Terminal Mesogenic Groups
......................................................... 237
Valéry
Shibaev and Natalia Boiko
10.1
Introduction
................................................................................... 237
10.2
Peculiarities of the Molecular Structure
of LC Silicon-Containing Dendrimers
.......................................... 240
10.3
Polyorganosiloxane Dendrimers with Terminal
Mesogenic Groups
........................................................................ 241
10.4
Carbosilane LC Dendrimers
.......................................................... 246
10.4.1
Synthesis of Carbosilane LC Dendrimers
with Different Molecular Architectures
.......................... 249
10.4.2
Structural Organization and Phase Behavior
of Carbosilane LC Dendrimers
....................................... 252
10.5
Chiral Carbosilane LC Dendrimers with Ferroelectric Properties
262
10.6
Photochromic LC Carbosilane Dendrimers
.................................. 269
10.6.1
Phase Behavior and Structure
......................................... 272
10.6.2
Photochemical and Photooptical Properties
.................... 274
10.7
Conclusions and Future Outlook
................................................... 279
11
Silicon-Organic Dendrimers
................................................................. 285
Petar
R.
Dvornic, Michael J. Owen, and Rakesh Sachdeva
11.1
Introduction
........................................... 285
11.2
PAMAMOS:
РАМАМ
Dendrimers with Silicon-Containing
End-Groups
.....................................
2Й7
11.3
PAMAMOS Multi-arm Star Polymers
............. 291
11.4
PAMAMOS Networks
.......................................
ľ.ľZZľ Z
294
11.5
PAMAMOS Networks Nanocomplexes and Nanocomposites
298
11.6
Copolymeric PAMAMOS Dendrimers
.................................... .
302
Contents xj
11.7
Other Silicon-Organic Dendrimers
............................................... 306
11.7.1 Dendrimers
with
Silicon in
the Core...............................
306
11.7.2 Dendrimers
with
Silicon in
Their Interiors.....................
308
11.7.3 Dendrimers
(Other than PAMAMOS) with
Silicon
in
the End-Groups
........................................................... 311
12 Hyperbranched Polycarbosilanes via Nucleophilic
Substitution
Reactions
........................................................................... 315
Leonard
Interrante
and Qionghua Shen
12.1
Introduction
................................................................................... 315
12.2 Hyperbranched Polycarbosilanes
from AB3
Monomers............... 317
12.2.1
From
Chloromethyltrichlorosilane.................................. 317
12.2.2
From
2-Bromo-5-trimethoxysilylthiophene.................... 325
12.2.3
From 2-Bromoethyltrichlorosilane
.................................. 327
12.2.4
From
3-
or 4-Bromophenyltriethoxysilane
..................... 327
12.2.5
From Other Monomers
.................................................... 328
12.3
Hyperbranched Polycarbosilanes from
AB,
Monomers
............... 331
12.3.1
From Chloromethylmethyldichlorosilane
....................... 331
12.3.2
From ClO^CH^HSiMeCl,
and
CH^CíCH^DSiMeCÇ
.......................................... 333
12.3.3
Other Monomers
............................................................. 335
12.4
Hyperbranched Polycarbosilanes from
Α,Β,
-Туре
Monomers
..... 336
12.5
Hyperbranched Co-Polycarbosilanes
............................................ 338
12.5.1
Co-Polycarbosilanes from Phenyltrichlorosilane,
Diphenyldichlorosilane and Dibromomethane
............... 338
12.5.2
Copolymer from
СІСН^ЦОМе),
„Cl,
2¡
and ClCH^iMeCl
....... .................................................... 340
12.5.3
Copolymer from
C^CHSiMeCl,
and COLjSKOMe^Cl, ,5
......*..................................... 341
12.6
Conclusion and Future Outlook
.................................................... 342
13
Hyperbranched Polycarbosilanes and Polycarbosiloxanes
via Hydrosilylation Polymerization
...................................................... 345
Hanna Schule
and
Holger Frey
13.1
Introduction
................................................................................... 345
13.2
Hydrosilylation
.............................................................................. 346
13.3
Synthesis and Characterization of Silicon-Containing
Hyperbranched Polymers
.............................................................. 349
13.4
Polycarbosilanes
............................................................................ 351
13.4.1
General Synthetic Strategy
.............................................. 351
13.4.2
Functionalization
............................................................. 357
13.4.3
Block Copolymers
........................................................... 361
13.5
Polycarbosiloxanes
........................................................................ 363
13.5.1
General Synthetic Strategy
.............................................. 363
13.5.2
Polymer Modification and Application
........................... 367
Contents
xii
13.6 Polyalkoxysilanes.......................................................................... 37°
13.7 Polycarbosilazanes........................................................................
13.8
Summary and Perspectives
............................................................ 372
14
Rearranging
Hyperbranched Silyl
Ether
Polymers 377
Daniel Graiver
14.1
Introduction
................................................................................... 377
14.2
Monomer Synthesis
....................................................................... 379
14.3
Polymerization Reactions
.............................................................. 381
14.4
Rearrangement Reactions
.............................................................. 384
14.5
Possible Applications
.................................................................... 386
15
Cyclization Issues in Silicon-Containing
Hyperbranched Polymers
...................................................................... 391
David Y. Son
15.1
Introduction
................................................................................... 391
15.2
Intramolecular Cyclization of the Monomer
................................. 392
15.3
Intramolecular Cyclization of
Oligomers
...................................... 393
15.4
Controlling Cyclization
................................................................. 396
15.4.1
Controlling Monomer Cyclization
.................................. 396
15.4.2
Controlling Cyclization of
Oligomers
............................. 398
15.5
Concluding Remarks
..................................................................... 399
16
Hyperbranched Silicon-Containing Polymers
via Bimolecular Non-linear Polymerization
........................................ 401
Petar
R.
Dvornic and Dale J. Meier
16.1
Introduction
................................................................................... 401
16.2
Historical Development of Bimolecular
Non-linear Polymerization
............................................................ 402
16.3
Theory of Ax
+
By Bimolecular Non-linear Polymerization
......... 404
16.4
Bimolecular Non-linear Polymerization by Hydrosilylation
........ 407
16.4.1
Hyperbranched Polycarbosilanes
and Polycarbosiloxanes
................................................... 408
16.4.2
Hyperbranched Polymer Networks
................................. 408
16.4.3
Perfluorinated Hyperbranched Polycarbosiloxanes
........ 411
16.4.4
Hyperbranched Polycarbosiloxanes with Latent
Functionalities
.................................... 4P
16.5
Bimolecular Non-linear Polymerization by Nucleophilic
Substitution Reactions
..............................................
413
16.5.1
Hyperbranched Silarylenesiloxanes
................................ 413
16.5.2
Hyperbranched Polysiloxanes
............................... ....... 414
16.6
Siliconized Hyperbranched Polymers by BMNLP
......
ZZZZZ.
...... 415
16.7
Conclusions and Future Outlook
..................................... ........
417
Index
............
.................................................................................................. 421
|
| adam_txt |
Contents
1
The Role of
Silicon
in Dendritic Polymer Chemistry
. 1
Petar
R.
Dvornic and Michael J. Owen
1.1
Introduction
. 1
1.2
Dendrimers and Hyperbranched Polymers
. 4
1.2.1
Dendrimers
. 4
1.2.2
Hyperbranched Polymers
. 10
1.3
A Brief Historical Overview of the Main Developments
in Dendrimers and Hyperbranched Polymers
. 13
1.4
Silicon in Dendritic Polymers
. 15
2
Polysiloxane and Siloxane-Based Dendrimers
. 21
Aziz Muzafarov and Evgenij Rebrov
2.1
Introduction: Historical Background
. 21
2.2
Chemistry of Siloxane Dendrimers
. 22
2.3
Peculiarities of Siloxane Dendrimers
. 25
2.4
Prospects for Further Development in the Chemistry
of Siloxane Dendrimers
. 28
3
Carbosilane Dendrimers
. 31
Jacques Roovers and Jianfu Ding
3.1
Introduction
. 31
3.2
Synthesis of Carbosilane Dendrimers
. 32
3.2.1
Core Molecules
. 33
3.2.2
Interior Generations
. 38
3.2.3
Peripheral (Corona; End-Groups) Modification
. 43
3.3
Carbosilane Dendrimer Characterization
. 60
3.4
Properties of Carbosilane Dendrimers
. 62
3.4.1
Molecular Dimensions of Carbosilane Dendrimers
. 62
3.4.2
Dynamics of Carbosilane Dendrimers
. 66
Contents
viii
4 Polysilane
Dendrimers
.
Masato Nanjo and Akira Sekiguchi
4.1
Introduction
.
4.2
Synthetic Approaches to Polysilane Dendrimers
. 76
4.2.1
Convergent Methods
. 76
4.2.2
Divergent Methods
. 79
4.2.3
Double-Cored Polysilane Dendrimers
. 81
4.2.4
Functionalized Polysilane Dendrimers
. 84
4.3
NMR Spectroscopy of Polysilane Dendrimers
. 85
4.4
Crystallography and Conformation of Polysilane Dendrimers
. 87
4.5
Electronic Spectra
. 91
4.6
Conclusions and Future Outlook
. 94
5
Polycarbosilazane and Related Dendrimers
and Hyperbranched Polymers
. 97
David Y. Son
5.1
Introduction
. 97
5.2
Polycarbosilazane Dendrimers
. 98
5.3
Polysilazane Dendrimers
. 99
5.4
Related Dendrimers
. 100
5.5
Hyperbranched Polycarbosilazanes
. 101
5.6
Concluding Remarks
. 102
6
Silyl Ether Containing Dendrimers with Cyclic Siloxane Cores
. 105
Chungkyun Kim
6.1
Introduction
. 105
6.2
Siloxane Dendrimers with Cyclic Siloxane Core (0G(4)-Vinyl)
. 106
6.3
Synthesis of Dendrimers with Si-O-C Units from
Cyclic Siloxane Cores
. 108
6.3.1
General Synthetic Strategy from 0G(4)-Vinyl Core
. 108
6.3.2
Dendrimers with Organic Functional End-Groups
. 108
6.3.3
Dendrimers with Triple Bonds
. 109
6.3.4
"Double-Layered" Dendrimers with Conjugated
Branches
.
j
¡О
6.3.5
Ferrocenyl-Functionalized Dendrimers
as COGas Sensor
.
j
12
6.3.6
Water Soluble Dendrimers
.
П2
6.3.7
Dendrimers with Terpyridine Ruthenium
Complex End-Groups
.
j
14
6.3.8
Dendrimers with Farnesyl End-Groups
. 114
6.3.9
Diels-Alder Reaction on Dendrimer Periphery
. 116
6.4
Dendrimers with Silsesquioxane Core
. .
1
17
6.5
Conclusion
.
.
Ilo
Contents
Polyhedral
Oligomeríc Silsesquioxane Dendrimers
. 121
Katherine
J.
Haxton
and Russell
E.
Morris
7.1
Introduction
. 121
7.2
Synthesis of Silsesquioxanes and Silicates
. 123
7.2.1
Silsesquioxanes
. 123
7.2.2
Silicates
. 124
7.2.3
Functionalizing Silsesquioxanes and Silicates
. 125
7.3
Synthesis of POSS and Silicate Dendrimers
. 126
7.3.1
POSS Dendrimer Synthesis
. 126
7.3.2
Silicate Dendrimer Synthesis
. 129
7.3.3
Characterization
. 130
7.4
Applications of POSS and Silicate Dendrimers
. 130
7.4.1
Homogeneous Catalysis
. 130
7.4.2
Electro- and Redox-Active Dendrimers
. 133
7.4.3
Liquid Crystals
. 133
7.4.4
Transition Metal Binding
. 134
7.4.5
POSS-PAMAM Nanocomposites
. 135
7.4.6
Gene Transfection
. 136
7.5
Conclusion
. 137
Organometallic Silicon-Containing Dendrimers
and Their Electrochemical Applications
. 141
Isabel
Cuadrado
8.1
Introduction
. 141
8.2
Synthetic Strategies and
Redox
Properties
of Organometallic Silicon-Containing Dendritic
Macromolecules
. 145
8.2.1
Functionalization of Silicon-Based Dendritic Scaffolds
with Electroactive Organometallic Moieties
. 147
8.2.2
Silicon-Based Dendrimers from Organometallic
Moieties
. 163
8.3
Electrochemical Applications of Ferrocenyl Silicon-Containing
Dendritic Molecules
. 183
8.3.1
Ferrocenyl Dendrimers with Si-NH Linkages
as
Redox
Sensors for Recognition of Inorganic Anions
. 183
8.3.2
Ferrocenyl Silicon-Containing Dendrimers as
Electron-Transfer Mediators in Amperometric
Biosensors
. 186
8.3.3
Electrocatalytic Oxidation of Ascorbic Acid Mediated
by a Ferrocenyl Siloxane-Based Network Polymer
. 189
8.4
Concluding Remarks
. 191
Contents
9 Carbosilane Dendrimers:
Molecular
Supports
and Containers
for Homogeneous Catalysis
and Organic Synthesis
.
Maaike
Wander, Robertus J.M. Klein Gebbink, and Gerard van
Koten
1Q7
9.1
Introduction
.
9.2
Carbosilane Dendrimers with Covalently Bound Catalysts
. 201
9.2.1
Synthesis and Structural Aspects
of Phosphine-Based Dendrimer Catalysts
. 201
9.2.2
Catalytic Reactivity of Phosphine-Based
Dendrimer Catalysts
. 203
9.2.3
Synthesis and Structural Aspects of
Non-phosphine-Based Dendrimer Catalysts
. 213
9.2.4
Catalytic Reactivity of Non-phosphine-Based
Dendrimer Catalysts
. 214
9.3
Supported Organic Synthesis on Soluble Carbosilanes
. 228
9.4
Conclusions and Future Outlook
. 230
10
Liquid Crystalline Silicon-Containing Dendrimers
with Terminal Mesogenic Groups
. 237
Valéry
Shibaev and Natalia Boiko
10.1
Introduction
. 237
10.2
Peculiarities of the Molecular Structure
of LC Silicon-Containing Dendrimers
. 240
10.3
Polyorganosiloxane Dendrimers with Terminal
Mesogenic Groups
. 241
10.4
Carbosilane LC Dendrimers
. 246
10.4.1
Synthesis of Carbosilane LC Dendrimers
with Different Molecular Architectures
. 249
10.4.2
Structural Organization and Phase Behavior
of Carbosilane LC Dendrimers
. 252
10.5
Chiral Carbosilane LC Dendrimers with Ferroelectric Properties
262
10.6
Photochromic LC Carbosilane Dendrimers
. 269
10.6.1
Phase Behavior and Structure
. 272
10.6.2
Photochemical and Photooptical Properties
. 274
10.7
Conclusions and Future Outlook
. 279
11
Silicon-Organic Dendrimers
. 285
Petar
R.
Dvornic, Michael J. Owen, and Rakesh Sachdeva
11.1
Introduction
. 285
11.2
PAMAMOS:
РАМАМ
Dendrimers with Silicon-Containing
End-Groups
.
2Й7
11.3
PAMAMOS Multi-arm Star Polymers
. 291
11.4
PAMAMOS Networks
.
ľ.ľZZľ'Z"
294
11.5
PAMAMOS Networks Nanocomplexes and Nanocomposites
298
11.6
Copolymeric PAMAMOS Dendrimers
.'. "
302
Contents xj
11.7
Other Silicon-Organic Dendrimers
. 306
11.7.1 Dendrimers
with
Silicon in
the Core.
306
11.7.2 Dendrimers
with
Silicon in
Their Interiors.
308
11.7.3 Dendrimers
(Other than PAMAMOS) with
Silicon
in
the End-Groups
. 311
12 Hyperbranched Polycarbosilanes via Nucleophilic
Substitution
Reactions
. 315
Leonard
Interrante
and Qionghua Shen
12.1
Introduction
. 315
12.2 Hyperbranched Polycarbosilanes
from AB3
Monomers. 317
12.2.1
From
Chloromethyltrichlorosilane. 317
12.2.2
From
2-Bromo-5-trimethoxysilylthiophene. 325
12.2.3
From 2-Bromoethyltrichlorosilane
. 327
12.2.4
From
3-
or 4-Bromophenyltriethoxysilane
. 327
12.2.5
From Other Monomers
. 328
12.3
Hyperbranched Polycarbosilanes from
AB,
Monomers
. 331
12.3.1
From Chloromethylmethyldichlorosilane
. 331
12.3.2
From ClO^CH^HSiMeCl,
and
CH^CíCH^DSiMeCÇ
. 333
12.3.3
Other Monomers
. 335
12.4
Hyperbranched Polycarbosilanes from
Α,Β,
-Туре
Monomers
. 336
12.5
Hyperbranched Co-Polycarbosilanes
. 338
12.5.1
Co-Polycarbosilanes from Phenyltrichlorosilane,
Diphenyldichlorosilane and Dibromomethane
. 338
12.5.2
Copolymer from
СІСН^ЦОМе),
„Cl,
2¡
and ClCH^iMeCl
.'. 340
12.5.3
Copolymer from
C^CHSiMeCl,
and COLjSKOMe^Cl, ,5
.*. 341
12.6
Conclusion and Future Outlook
. 342
13
Hyperbranched Polycarbosilanes and Polycarbosiloxanes
via Hydrosilylation Polymerization
. 345
Hanna Schule
and
Holger Frey
13.1
Introduction
. 345
13.2
Hydrosilylation
. 346
13.3
Synthesis and Characterization of Silicon-Containing
Hyperbranched Polymers
. 349
13.4
Polycarbosilanes
. 351
13.4.1
General Synthetic Strategy
. 351
13.4.2
Functionalization
. 357
13.4.3
Block Copolymers
. 361
13.5
Polycarbosiloxanes
. 363
13.5.1
General Synthetic Strategy
. 363
13.5.2
Polymer Modification and Application
. 367
Contents
xii
13.6 Polyalkoxysilanes. 37°
13.7 Polycarbosilazanes.
13.8
Summary and Perspectives
. 372
14
Rearranging
Hyperbranched Silyl
Ether
Polymers 377
Daniel Graiver
14.1
Introduction
. 377
14.2
Monomer Synthesis
. 379
14.3
Polymerization Reactions
. 381
14.4
Rearrangement Reactions
. 384
14.5
Possible Applications
. 386
15
Cyclization Issues in Silicon-Containing
Hyperbranched Polymers
. 391
David Y. Son
15.1
Introduction
. 391
15.2
Intramolecular Cyclization of the Monomer
. 392
15.3
Intramolecular Cyclization of
Oligomers
. 393
15.4
Controlling Cyclization
. 396
15.4.1
Controlling Monomer Cyclization
. 396
15.4.2
Controlling Cyclization of
Oligomers
. 398
15.5
Concluding Remarks
. 399
16
Hyperbranched Silicon-Containing Polymers
via Bimolecular Non-linear Polymerization
. 401
Petar
R.
Dvornic and Dale J. Meier
16.1
Introduction
. 401
16.2
Historical Development of Bimolecular
Non-linear Polymerization
. 402
16.3
Theory of Ax
+
By Bimolecular Non-linear Polymerization
. 404
16.4
Bimolecular Non-linear Polymerization by Hydrosilylation
. 407
16.4.1
Hyperbranched Polycarbosilanes
and Polycarbosiloxanes
. 408
16.4.2
Hyperbranched Polymer Networks
. 408
16.4.3
Perfluorinated Hyperbranched Polycarbosiloxanes
. 411
16.4.4
Hyperbranched Polycarbosiloxanes with Latent
Functionalities
. 4P
16.5
Bimolecular Non-linear Polymerization by Nucleophilic
Substitution Reactions
.
413
16.5.1
Hyperbranched Silarylenesiloxanes
. 413
16.5.2
Hyperbranched Polysiloxanes
. . 414
16.6
Siliconized Hyperbranched Polymers by BMNLP
.
ZZZZZ.
. 415
16.7
Conclusions and Future Outlook
. .
417
Index
.
. 421 |
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| id | DE-604.BV035185575 |
| illustrated | Illustrated |
| index_date | 2024-07-02T22:59:32Z |
| indexdate | 2024-07-09T21:26:58Z |
| institution | BVB |
| isbn | 9781402081736 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016992268 |
| oclc_num | 258090027 |
| open_access_boolean | |
| owner | DE-703 DE-11 |
| owner_facet | DE-703 DE-11 |
| physical | XV, 428 S. Ill., graph. Darst. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | Springer |
| record_format | marc |
| series | Advances in silicon science |
| series2 | Advances in silicon science |
| spelling | Silicon-containing dendritic polymers Petar R. Dvornic ; Michael J. Owen, eds. Silicon containing dendritic polymers [Dordrecht] Springer 2009 XV, 428 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Advances in silicon science 2 Dendrimers Silicon polymers Silicon-Polymere (DE-588)4456222-6 gnd rswk-swf Sternpolymere (DE-588)4245705-1 gnd rswk-swf Silicon-Polymere (DE-588)4456222-6 s Sternpolymere (DE-588)4245705-1 s DE-604 Dvornic, Petar R. Sonstige oth Owen, Michael J. Sonstige oth Erscheint auch als Online-Ausgabe 978-1-4020-8174-3 Advances in silicon science 2 (DE-604)BV035313944 2 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992268&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Silicon-containing dendritic polymers Advances in silicon science Dendrimers Silicon polymers Silicon-Polymere (DE-588)4456222-6 gnd Sternpolymere (DE-588)4245705-1 gnd |
| subject_GND | (DE-588)4456222-6 (DE-588)4245705-1 |
| title | Silicon-containing dendritic polymers |
| title_alt | Silicon containing dendritic polymers |
| title_auth | Silicon-containing dendritic polymers |
| title_exact_search | Silicon-containing dendritic polymers |
| title_exact_search_txtP | Silicon-containing dendritic polymers |
| title_full | Silicon-containing dendritic polymers Petar R. Dvornic ; Michael J. Owen, eds. |
| title_fullStr | Silicon-containing dendritic polymers Petar R. Dvornic ; Michael J. Owen, eds. |
| title_full_unstemmed | Silicon-containing dendritic polymers Petar R. Dvornic ; Michael J. Owen, eds. |
| title_short | Silicon-containing dendritic polymers |
| title_sort | silicon containing dendritic polymers |
| topic | Dendrimers Silicon polymers Silicon-Polymere (DE-588)4456222-6 gnd Sternpolymere (DE-588)4245705-1 gnd |
| topic_facet | Dendrimers Silicon polymers Silicon-Polymere Sternpolymere |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992268&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV035313944 |
| work_keys_str_mv | AT dvornicpetarr siliconcontainingdendriticpolymers AT owenmichaelj siliconcontainingdendriticpolymers |