Coordination polymers: design, analysis and application
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Cambridge
RSC Publ.
2009
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | XIII, 424 S. Ill., graph. Darst. |
| ISBN: | 9780854048373 |
Internformat
MARC
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| 100 | 1 | |a Batten, Stuart R. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Coordination polymers |b design, analysis and application |c Stuart R. Batten ; Suzanne M. Neville and David R. Turner |
| 264 | 1 | |a Cambridge |b RSC Publ. |c 2009 | |
| 300 | |a XIII, 424 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
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| 700 | 1 | |a Neville, Suzanne M. |e Verfasser |4 aut | |
| 700 | 1 | |a Turner, David R. |e Verfasser |4 aut | |
| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992257&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992257&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |3 Klappentext |
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Datensatz im Suchindex
| _version_ | 1804138360988499968 |
|---|---|
| adam_text | Contents
Chapter
1
Introduction
1.1
Introduction
1
1.2
Crystal Engineering, Supramolecular Chemistry,
Metallosupramolecules
4
1.3
What is a Coordination Polymer?
6
1.4
Synthetic Techniques
10
1.5
Design, Analysis, Application
12
References
13
Chapter
2
Nets: A Tool for Description and Design
2.1
Introduction
19
2.2
Defining Networks
20
2.3
Identifying and Naming Nets
25
2.4
ID Nets
28
2.5
2D Nets
29
2.6
Common
3D
Nets
36
2.6.1
S-Connected Nets
36
2.6.2
4-Connected Nets
39
2.6.3
5-Connected
Nets
45
2.6.4
ó-Connected
Nets
46
2.6.5
Higher Connected Nets
47
2.6.6
Mixed Connectivity Nets
48
2.7
Rod Packings
52
References
53
Coordination Polymers: Design, Analysis and Application
By Stuart R. Batten, Suzanne M. Neville and David R. Turner
©
Stuart R. Batten, Suzanne M. Neville and David R. Turner,
2009
Published by the Royal Society of Chemistry, www.rsc.org
Contents
Chapter
3
Interpénétration
3.1
Introduction
59
3.2
Nomenclature
67
3.3
ID
Interpénétration
69
3.4
2D Interpénétration
70
3.5 3D
Interpénétration
77
3.6
Interpénétration
of Nets of Different
Composition,
Topology and
Dimensions
84
3.7
Self-penetration
87
3.8
Other Entangled Systems
89
References
89
Chapter
4
Malleability of Coordination Polymers
4.1
Introduction
4.2
Supramolecular Isomerism
4.3
Malleability of Building Blocks
4.4
Synthetic Approach
4.5
Solvent Effects
4.6
Other Guests
4.7
Counterions
4.8
Weaker Interactions
4.9
Conclusion
References
96
98
107
111
115
119
120
124
134
134
Chapter
5
Transition Metal Coordination Polymers
5.1
Introduction
5.2
Pseudohalide Ligands
5.2.1
The Cyanide Ligand
5.2.2
The Azide Ligand
5.2.3
NCX Ligands (X
=
O,
S, Se)
5.2.4
Small Polynitrile Ligands (e.g. dca/tcm)
5.3
Larger Nitrile Donor Ligands
5.3.1
Neutral Ligands
5.3.2
Anionie
Nitrile Ligands
5.4
Pyridyl Donor Ligands
5.4.1
2-Connecting Ligands
5.4.2
3-Connecting Ligands
5.4.3
4-Connecting Ligands
5.5
Five-membered Ring Nitrogen Donor Ligands
5.5.1
2-Connecting Ligands
5.5.2
S-Connecting Ligands
5.5.3
Other Connectors
144
146
146
149
152
153
156
156
158
159
159
164
165
166
167
169
170
Contents
јц
5.6
N-Oxide Ligands
170
5.7
Carboxylate Ligands
172
5.7.1
2-Connecting Ligands
173
5.7.2
S-Connecting Ligands
175
5.7.3
^Connecting
Ligands
177
5.8
Other
Ligands
178
5.9
Mixed Donor Atom
Ligands
180
5.10
Mixed Ligand Coordination Polymers
181
References
183
Chapter
6
Rare Earth Coordination Polymers
6.1
Introduction
191
6.2
Cyanide/Nitrile and Pseudohalide Ligands
192
6.3
Five-membered Ring Donors
195
6.4
Pyridyl Donor Ligands
196
6.5
TV-Oxide Donors
196
6.6
Rare Earth-Carboxylate Polymers
202
6.6.1
Monocarboxylate Ligands
203
6.6.2
Dicarboxylate Ligands
205
6.6.3
Tricarboxylate Ligands
210
6.6.4
Tetracarboxylate Ligands
212
6.7
Other Ligands
212
6.7.1
Oxalate Coordination Polymers
212
6.7.2
Chloranilic Acid and Dihydroxybenzoquinone
215
6.7.3
Polymers with Sulfonate-containing Ligands
217
6.7.4
Amide Ligands
217
6.7.5
Pyridylcarboxylate Ligands
219
6.8
Mixed 3d/4f Coordination Polymers
221
6.8.1
Cyanide-based Bimetallic Polymers
221
6.8.2
Carboxylate-based Bimetallic Polymers
224
6.8.3
Pyridylcarboxylate Ligands
224
6.8.4
Other Mixed O/N Donor Ligands
229
6.9
Actinide Coordination Polymers
229
References
231
Chapter
7
Organometallic Networks
7.1
Introduction
238
7.2
Large Aromatic Ligands
239
7.2.1
Cation
-π
Interactions in Ag(i)-PAH Systems
239
7.2.2
Cation
-π
Interactions with Cyclophanes
241
7.2.3
Non-aromatic
Cation
-π
Interactions
243
7.3
Organometallic Complexes as Ligands
245
7.3.1
Metallocene Bridging Ligands
245
7.3.2
Metal-Quinone Bridging Complexes
246
xii Contents
7.4 Isocarbonyl Polymers 248
7.5 RjSn/RsPb Systems 251
7.5.1 Metal-Cyanide Polymers 251
7.5.2
(Triorganostannyl)tetrazole
Polymers 252
References
254
Chapter
8
Inorganic-Organic Hybrids
8.1
Introduction
257
8.2
OD
Metal-Oxide Substructures
259
8.3
ID Metal-Oxide Substructures
260
8.3.1
2D Polymers with ID Metal-Oxide
Substructures
261
8.3.2 3D
Polymers with ID Metal-Oxide
Substructures
263
8.4
2D Metal-Oxide Substructures (Pillared Layers)
264
References
271
Chapter
9
Magnetism in Coordination Polymers
9.1
Introduction
273
9.2
Long-range Magnetic Ordering
273
9.2.1
Introduction
273
9.2.2
Molecule-based Magnets
275
9.2.3
Single-chain Magnets
293
9.3
Spin Crossover
295
9.3.1
Introduction
295
9.3.2
Five-membered Heterocyclic Ring Bridging
Ligands
297
9.3.3
Six-membered Ring Bridging Ligands
301
9.3.4
Cyanide Bridges in
Hofmann
Phases
305
References
307
Chapter
10
Porous Coordination Polymers
10.1
Introduction
313
10.1.1
Terminology
313
10.2
Designing Permanent Porosity
315
10.2.1
Flexible Porosity
317
10.2.2
Rigid Porosity
322
10.3
Solvent Exchange
326
10.3.1
Flexible Guest Exchange
327
10.3.2
Rigid Guest Exchange
329
10.4
Gas Storage
330
10.4.1
Hydrogen Gas Storage
331
10.4.2
Methane Gas Storage
335
Contents
xjj¡
10.4.3 Carbon Dioxide Gas
Storage
336
10.4.4
Other
Gases 337
10.5 Ion Exchange 338
10.6
Multifunctional Porous
Materials 338
10.7
Conclusion
340
References
341
Chapter
11
Acentric and Chiral Networks
11.1
Introduction
345
11.2
Acentric Networks for Non-linear Optical Behaviour
346
11.3
Chiral Networks
352
11.3.1
ID Helices from Achiral Components
352
11.3.2
2D Chiral Nets from Achiral Components
354
11.3.3 3D
Chiral Nets from Achiral Components
355
11.3.4
Chiral Ligands
361
11.3.5
Applications
367
References
369
Chapter
12
Reactive Coordination Polymers
12.1
Introduction
375
12.2
Topotactic Reactions
375
12.3
Chemically Reactive Ligands
386
12.4
Catalysis
386
References
391
Chapter
13
Other Properties of Coordination Polymers
13.1
Introduction
396
13.2
Luminescence
397
13.3
Redox
Activity
399
13.4
Conductivity
401
13.5
Negative Thermal Expansion
404
13.6
Multifunctional Materials
407
References
408
Subject Index
416
Coordination
Polymers:
Design,
Analysis and Application
¡s
the
first book to provide a broad overview of all the major facets of
coordination polymer research. It combines chapters on nets and
interpénétration
with wide-ranging surveys of transition metal and rare
earth coordination polymers and their properties.The aim is to provide
a flavour of each aspect of coordination polymers whilst introducing the
important concepts and developments using carefully selected examples.
After an introduction, the text is split into three sections:
•Design (nets,
interpénétration,
malleability)
•Analysis (transition metal coordination polymers, rare earth coordination
polymers, organometallic networks, organic-inorganic hybrids)
•Application (magnetic properties, porosity, acentric and chiral networks,
reactive coordination polymers, other properties).
Written in the style of a tutorial review, the book is suitable for both senior
specialists and new postgraduate students taking theirfirst steps in the
field. Coordination Polymers: Design, Analysis and Application also
provides an authoritative and detailed reference source.
|
| adam_txt |
Contents
Chapter
1
Introduction
1.1
Introduction
1
1.2
Crystal Engineering, Supramolecular Chemistry,
Metallosupramolecules
4
1.3
What is a Coordination Polymer?
6
1.4
Synthetic Techniques
10
1.5
Design, Analysis, Application
12
References
13
Chapter
2
Nets: A Tool for Description and Design
2.1
Introduction
19
2.2
Defining Networks
20
2.3
Identifying and Naming Nets
25
2.4
ID Nets
28
2.5
2D Nets
29
2.6
Common
3D
Nets
36
2.6.1
S-Connected Nets
36
2.6.2
4-Connected Nets
39
2.6.3
5-Connected
Nets
45
2.6.4
ó-Connected
Nets
46
2.6.5
Higher Connected Nets
47
2.6.6
Mixed Connectivity Nets
48
2.7
Rod Packings
52
References
53
Coordination Polymers: Design, Analysis and Application
By Stuart R. Batten, Suzanne M. Neville and David R. Turner
©
Stuart R. Batten, Suzanne M. Neville and David R. Turner,
2009
Published by the Royal Society of Chemistry, www.rsc.org
Contents
Chapter
3
Interpénétration
3.1
Introduction
59
3.2
Nomenclature
67
3.3
ID
Interpénétration
69
3.4
2D Interpénétration
70
3.5 3D
Interpénétration
77
3.6
Interpénétration
of Nets of Different
Composition,
Topology and
Dimensions
84
3.7
Self-penetration
87
3.8
Other Entangled Systems
89
References
89
Chapter
4
Malleability of Coordination Polymers
4.1
Introduction
4.2
Supramolecular Isomerism
4.3
Malleability of Building Blocks
4.4
Synthetic Approach
4.5
Solvent Effects
4.6
Other Guests
4.7
Counterions
4.8
Weaker Interactions
4.9
Conclusion
References
96
98
107
111
115
119
120
124
134
134
Chapter
5
Transition Metal Coordination Polymers
5.1
Introduction
5.2
Pseudohalide Ligands
5.2.1
The Cyanide Ligand
5.2.2
The Azide Ligand
5.2.3
NCX Ligands (X
=
O,
S, Se)
5.2.4
Small Polynitrile Ligands (e.g. dca/tcm)
5.3
Larger Nitrile Donor Ligands
5.3.1
Neutral Ligands
5.3.2
Anionie
Nitrile Ligands
5.4
Pyridyl Donor Ligands
5.4.1
2-Connecting Ligands
5.4.2
3-Connecting Ligands
5.4.3
4-Connecting Ligands
5.5
Five-membered Ring Nitrogen Donor Ligands
5.5.1
2-Connecting Ligands
5.5.2
S-Connecting Ligands
5.5.3
Other Connectors
144
146
146
149
152
153
156
156
158
159
159
164
165
166
167
169
170
Contents
јц
5.6
N-Oxide Ligands
170
5.7
Carboxylate Ligands
172
5.7.1
2-Connecting Ligands
173
5.7.2
S-Connecting Ligands
175
5.7.3
^Connecting
Ligands
177
5.8
Other
Ligands
178
5.9
Mixed Donor Atom
Ligands
180
5.10
Mixed Ligand Coordination Polymers
181
References
183
Chapter
6
Rare Earth Coordination Polymers
6.1
Introduction
191
6.2
Cyanide/Nitrile and Pseudohalide Ligands
192
6.3
Five-membered Ring Donors
195
6.4
Pyridyl Donor Ligands
196
6.5
TV-Oxide Donors
196
6.6
Rare Earth-Carboxylate Polymers
202
6.6.1
Monocarboxylate Ligands
203
6.6.2
Dicarboxylate Ligands
205
6.6.3
Tricarboxylate Ligands
210
6.6.4
Tetracarboxylate Ligands
212
6.7
Other Ligands
212
6.7.1
Oxalate Coordination Polymers
212
6.7.2
Chloranilic Acid and Dihydroxybenzoquinone
215
6.7.3
Polymers with Sulfonate-containing Ligands
217
6.7.4
Amide Ligands
217
6.7.5
Pyridylcarboxylate Ligands
219
6.8
Mixed 3d/4f Coordination Polymers
221
6.8.1
Cyanide-based Bimetallic Polymers
221
6.8.2
Carboxylate-based Bimetallic Polymers
224
6.8.3
Pyridylcarboxylate Ligands
224
6.8.4
Other Mixed O/N Donor Ligands
229
6.9
Actinide Coordination Polymers
229
References
231
Chapter
7
Organometallic Networks
7.1
Introduction
238
7.2
Large Aromatic Ligands
239
7.2.1
Cation
-π
Interactions in Ag(i)-PAH Systems
239
7.2.2
Cation
-π
Interactions with Cyclophanes
241
7.2.3
Non-aromatic
Cation
-π
Interactions
243
7.3
Organometallic Complexes as Ligands
245
7.3.1
Metallocene Bridging Ligands
245
7.3.2
Metal-Quinone Bridging Complexes
246
xii Contents
7.4 Isocarbonyl Polymers 248
7.5 RjSn/RsPb Systems 251
7.5.1 Metal-Cyanide Polymers 251
7.5.2
(Triorganostannyl)tetrazole
Polymers 252
References
254
Chapter
8
Inorganic-Organic Hybrids
8.1
Introduction
257
8.2
OD
Metal-Oxide Substructures
259
8.3
ID Metal-Oxide Substructures
260
8.3.1
2D Polymers with ID Metal-Oxide
Substructures
261
8.3.2 3D
Polymers with ID Metal-Oxide
Substructures
263
8.4
2D Metal-Oxide Substructures (Pillared Layers)
264
References
271
Chapter
9
Magnetism in Coordination Polymers
9.1
Introduction
273
9.2
Long-range Magnetic Ordering
273
9.2.1
Introduction
273
9.2.2
Molecule-based Magnets
275
9.2.3
Single-chain Magnets
293
9.3
Spin Crossover
295
9.3.1
Introduction
295
9.3.2
Five-membered Heterocyclic Ring Bridging
Ligands
297
9.3.3
Six-membered Ring Bridging Ligands
301
9.3.4
Cyanide Bridges in
Hofmann
Phases
305
References
307
Chapter
10
Porous Coordination Polymers
10.1
Introduction
313
10.1.1
Terminology
313
10.2
Designing Permanent Porosity
315
10.2.1
Flexible Porosity
317
10.2.2
Rigid Porosity
322
10.3
Solvent Exchange
326
10.3.1
Flexible Guest Exchange
327
10.3.2
Rigid Guest Exchange
329
10.4
Gas Storage
330
10.4.1
Hydrogen Gas Storage
331
10.4.2
Methane Gas Storage
335
Contents
xjj¡
10.4.3 Carbon Dioxide Gas
Storage
336
10.4.4
Other
Gases 337
10.5 Ion Exchange 338
10.6
Multifunctional Porous
Materials 338
10.7
Conclusion
340
References
341
Chapter
11
Acentric and Chiral Networks
11.1
Introduction
345
11.2
Acentric Networks for Non-linear Optical Behaviour
346
11.3
Chiral Networks
352
11.3.1
ID Helices from Achiral Components
352
11.3.2
2D Chiral Nets from Achiral Components
354
11.3.3 3D
Chiral Nets from Achiral Components
355
11.3.4
Chiral Ligands
361
11.3.5
Applications
367
References
369
Chapter
12
Reactive Coordination Polymers
12.1
Introduction
375
12.2
Topotactic Reactions
375
12.3
Chemically Reactive Ligands
386
12.4
Catalysis
386
References
391
Chapter
13
Other Properties of Coordination Polymers
13.1
Introduction
396
13.2
Luminescence
397
13.3
Redox
Activity
399
13.4
Conductivity
401
13.5
Negative Thermal Expansion
404
13.6
Multifunctional Materials
407
References
408
Subject Index
416
Coordination
Polymers:
Design,
Analysis and Application
¡s
the
first book to provide a broad overview of all the major facets of
coordination polymer research. It combines chapters on nets and
interpénétration
with wide-ranging surveys of transition metal and rare
earth coordination polymers and their properties.The aim is to provide
a flavour of each aspect of coordination polymers whilst introducing the
important concepts and developments using carefully selected examples.
After an introduction, the text is split into three sections:
•Design (nets,
interpénétration,
malleability)
•Analysis (transition metal coordination polymers, rare earth coordination
polymers, organometallic networks, organic-inorganic hybrids)
•Application (magnetic properties, porosity, acentric and chiral networks,
reactive coordination polymers, other properties).
Written in the style of a tutorial review, the book is suitable for both senior
specialists and new postgraduate students taking theirfirst steps in the
field. Coordination Polymers: Design, Analysis and Application also
provides an authoritative and detailed reference source. |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Batten, Stuart R. Neville, Suzanne M. Turner, David R. |
| author_facet | Batten, Stuart R. Neville, Suzanne M. Turner, David R. |
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| author_sort | Batten, Stuart R. |
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| discipline_str_mv | Chemie / Pharmazie Physik Chemie |
| format | Book |
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| id | DE-604.BV035185563 |
| illustrated | Illustrated |
| index_date | 2024-07-02T22:59:32Z |
| indexdate | 2024-07-09T21:26:58Z |
| institution | BVB |
| isbn | 9780854048373 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016992257 |
| oclc_num | 463630985 |
| open_access_boolean | |
| owner | DE-703 DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-11 DE-20 |
| owner_facet | DE-703 DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-11 DE-20 |
| physical | XIII, 424 S. Ill., graph. Darst. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | RSC Publ. |
| record_format | marc |
| spelling | Batten, Stuart R. Verfasser aut Coordination polymers design, analysis and application Stuart R. Batten ; Suzanne M. Neville and David R. Turner Cambridge RSC Publ. 2009 XIII, 424 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Polymerkomplexe (DE-588)4137334-0 gnd rswk-swf Supramolekulare Struktur (DE-588)4208977-3 gnd rswk-swf Polymerkomplexe (DE-588)4137334-0 s Supramolekulare Struktur (DE-588)4208977-3 s DE-604 Neville, Suzanne M. Verfasser aut Turner, David R. Verfasser aut Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992257&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992257&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Batten, Stuart R. Neville, Suzanne M. Turner, David R. Coordination polymers design, analysis and application Polymerkomplexe (DE-588)4137334-0 gnd Supramolekulare Struktur (DE-588)4208977-3 gnd |
| subject_GND | (DE-588)4137334-0 (DE-588)4208977-3 |
| title | Coordination polymers design, analysis and application |
| title_auth | Coordination polymers design, analysis and application |
| title_exact_search | Coordination polymers design, analysis and application |
| title_exact_search_txtP | Coordination polymers design, analysis and application |
| title_full | Coordination polymers design, analysis and application Stuart R. Batten ; Suzanne M. Neville and David R. Turner |
| title_fullStr | Coordination polymers design, analysis and application Stuart R. Batten ; Suzanne M. Neville and David R. Turner |
| title_full_unstemmed | Coordination polymers design, analysis and application Stuart R. Batten ; Suzanne M. Neville and David R. Turner |
| title_short | Coordination polymers |
| title_sort | coordination polymers design analysis and application |
| title_sub | design, analysis and application |
| topic | Polymerkomplexe (DE-588)4137334-0 gnd Supramolekulare Struktur (DE-588)4208977-3 gnd |
| topic_facet | Polymerkomplexe Supramolekulare Struktur |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992257&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992257&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT battenstuartr coordinationpolymersdesignanalysisandapplication AT nevillesuzannem coordinationpolymersdesignanalysisandapplication AT turnerdavidr coordinationpolymersdesignanalysisandapplication |