High temperature oxidation and corrosion of metals:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
2008
|
| Ausgabe: | 1. ed. |
| Schriftenreihe: | Elsevier corrosion series
1 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index. - Formerly CIP |
| Beschreibung: | xvii, 574 p. zahlr. Ill. und graph. Darst. |
| ISBN: | 9780080445878 |
Internformat
MARC
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| 245 | 1 | 0 | |a High temperature oxidation and corrosion of metals |c by David John Young |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 2008 | |
| 300 | |a xvii, 574 p. |b zahlr. Ill. und graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Elsevier corrosion series |v 1 | |
| 500 | |a Includes bibliographical references and index. - Formerly CIP | ||
| 650 | 4 | |a Alloys | |
| 650 | 4 | |a Metallic oxides | |
| 650 | 4 | |a Metals |x Effect of high temperatures on | |
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Datensatz im Suchindex
| _version_ | 1804138358046195712 |
|---|---|
| adam_text | Preface
ix
Glossary of Symbols
xiii
Abbreviations and Acronyms
xvii
1.
The Nature of High Temperature Oxidation
1
1.1.
Metal Loss Due to the Scaling of Steel
1
1.2.
Heating Elements
4
1.3.
Protecting Turbine Engine Components
5
1.4.
Hydrocarbon Cracking Furnaces
9
1.5.
Prediction and Measurement
10
1.6.
Rate Equations
15
1.7.
Reaction Morphology: Specimen Examination
22
1.8.
Summary
26
References
26
2.
Enabling Theory
29
2.1.
Chemical Thermodynamics
30
2.2.
Chemical Equilibria Between Solids and Gases
34
2.3.
Alloys and Solid Solutions
42
2.4.
Chemical Equilibria Between Alloys and Gases
46
2.5.
Thermodynamics of Diffusion
51
2.6.
Absolute Rate Theory Applied to Lattice Particle Diffusion
55
2.7.
Diffusion in Alloys
58
2.8.
Diffusion Couples and the Measurement of Diffusion Coefficients
63
2.9.
Interfacial
Processes and Gas Phase Mass Transfer
66
2.10.
Mechanical Effects: Stresses in Oxide Scales
71
References
76
Further Reading
77
3.
Oxidation of Pure Metals
81
3.1.
Experimental Findings
82
3.2.
Use of Phase Diagrams
84
3.3.
Point Defects and Non-Stoichiometry in Ionic Oxides
85
3.4.
Lattice Species and Structural Units in Ionic Oxides
89
3.5.
Gibbs-Duhem Equation for Defective Solid Oxides
91
3.6.
Lattice Diffusion and Oxide Scaling: Wagner s Model
93
3.7.
Validation of Wagner s Model
96
vi
Contents
3.8.
Impurity Effects on Lattice Diffusion
113
3.9.
Microstructural Effects
115
3.10.
Reactions Not Controlled by Solid-State Diffusion
127
3.11.
The Value of Thermodynamic and Kinetic Analysis
133
References
135
4.
Mixed Gas Corrosion of Pure Metals
139
4.1.
Introduction
139
4.2.
Selected Experimental Findings
140
4.3.
Phase Diagrams and Diffusion Paths
147
4.4.
Scale-Gas Interactions
154
4.5.
Transport Processes in Mixed Scales
168
4.6.
Predicting the Outcome of Mixed Gas Reactions
175
References
181
5.
Oxidation of Alloys I: Single Phase Scales
185
5.1.
Introduction
185
5.2.
Selected Experimental Results
187
5.3.
Phase Diagrams and Diffusion Paths
193
5.4.
Selective Oxidation of One Alloy Component
196
5.5.
Selective Oxidation of One Alloy Connponent Under
Non-Steady-State Conditions
202
5.6.
Solid Solution Oxide Scales
206
5.7.
Transient Oxidation
216
5.8.
Microstructural Changes in Subsurface Alloy Regions
226
5.9.
Breakdown of Steady-State Scale
237
5.10.
Other Factors Affecting Scale Growth
241
References
243
6.
Oxidation of Alloys II: Internal Oxidation
247
6.1.
Introduction
247
6.2.
Selected Experimental Results
248
6.3.
Internal Oxidation Kinetics in the Absence of External Scaling
255
6.4.
Experimental Verification of Diffusion Model
260
6.5.
Surface Diffusion Effects in the Precipitation Zone
267
6.6.
Internal Precipitates of Low Stability
273
6.7.
Precipitate Nucleation and Growth
278
6.8.
Cellular Precipitation Morphologies
284
6.9.
Multiple Internal Precipitates
290
6.10.
Solute Interactions in the Precipitation Zone
299
6.11.
Transition from Internal to External Oxidation
301
6.12.
Internal Oxidation Beneath a Corroding Alloy Surface
305
6.13.
Volume Expansion in the Internal Precipitation Zone
306
6.14.
Success of Internal Oxidation Theory
311
References
312
Contents
VM
7.
Alloy Oxidation III: Multiphase Scales
315
7.1.
Introduction
315
7.2.
Binary Alumina Formers
316
7.3.
Binary Chromia Formers
326
7.4.
Ternary Alloy Oxidation
330
7.5.
Scale Spallation
341
7.6.
Effects of Minor Alloying Additions
347
7.7.
Effects of Secondary Oxidants
352
7.8.
Status of Multiphase Scale Growth Theory
355
References
356
8.
Corrosion by Sulfur
361
8.1.
Introduction
361
8.2.
Sulfidation of Pure Metals
362
8.3.
Alloying for Sulfidation Protection
367
8.4.
Sulfidation in
H2/H2S
378
8.5.
Effects of Temperature and Sulfur Partial Pressure
381
8.6.
The Role of Oxygen
382
8.7.
Internal Sulfidation
383
8.8.
Hot Corrosion
383
8.9.
Achieving Sulfidation Resistance
391
References
392
9.
Corrosion by Carbon
397
9.1.
Introduction
398
9.2.
Gaseous Carbon Activities
400
9.3.
Carburization
402
9.4.
Internal Carburization of Model Alloys
403
9.5.
Internal Carburization of Heat Resisting Alloys
415
9.6.
Metal Dusting of Iron and Ferritic Alloys
421
9.7.
Dusting of Nickel and Austenitic Alloys
435
9.8.
Protection by Oxide Scaling
444
9.9.
Controlling Carbon Corrosion
449
References
450
10.
Effects of Water Vapour on Oxidation
455
10.1.
Introduction
455
10.2.
Volatile Metal Hydroxide Formation
458
10.3.
Scale-Gas
Interfacial
Processes
468
10.4.
Scale Transport Properties
472
10.5.
Water Vapour Effects on Alumina Growth
488
10.6.
Void Development in Growing Scales
489
10.7.
Understanding and Controlling Water Vapour Effects
490
References
492
VIU
Contents
11.
Cyclic Oxidation
497
11.1.
Introduction
497
11.2.
Alloy Depletion and Scale Rehealing
502
11.3.
Spallation Models
506
11.4.
Combination of Spalling and Depletion Models
514
11.5.
Effects of Experimental Variables
517
11.6.
Describing and Predicting Cyclic Oxidation
527
References
530
12.
Alloy Design
533
12.1.
Introduction
533
12.2.
Alloy Design for Resistance to Oxygen
534
12.3.
Design Against Oxide Scale Spallation
537
12.4.
Design for Resistance to Other Corrodents and Mixed Gases
538
12.5.
Future Research
539
12.6.
Fundamental Research
544
12.7.
Conclusion
547
References
547
Appendix A: High Temperature Alloys
549
Appendix B: Cation Diffusion Kinetics in Ionic Solids
553
Appendix C: The Error Function
561
Appendix D: Self-Diffusion Coefficients
565
Index
567
|
| adam_txt |
Preface
ix
Glossary of Symbols
xiii
Abbreviations and Acronyms
xvii
1.
The Nature of High Temperature Oxidation
1
1.1.
Metal Loss Due to the Scaling of Steel
1
1.2.
Heating Elements
4
1.3.
Protecting Turbine Engine Components
5
1.4.
Hydrocarbon Cracking Furnaces
9
1.5.
Prediction and Measurement
10
1.6.
Rate Equations
15
1.7.
Reaction Morphology: Specimen Examination
22
1.8.
Summary
26
References
26
2.
Enabling Theory
29
2.1.
Chemical Thermodynamics
30
2.2.
Chemical Equilibria Between Solids and Gases
34
2.3.
Alloys and Solid Solutions
42
2.4.
Chemical Equilibria Between Alloys and Gases
46
2.5.
Thermodynamics of Diffusion
51
2.6.
Absolute Rate Theory Applied to Lattice Particle Diffusion
55
2.7.
Diffusion in Alloys
58
2.8.
Diffusion Couples and the Measurement of Diffusion Coefficients
63
2.9.
Interfacial
Processes and Gas Phase Mass Transfer
66
2.10.
Mechanical Effects: Stresses in Oxide Scales
71
References
76
Further Reading
77
3.
Oxidation of Pure Metals
81
3.1.
Experimental Findings
82
3.2.
Use of Phase Diagrams
84
3.3.
Point Defects and Non-Stoichiometry in Ionic Oxides
85
3.4.
Lattice Species and Structural Units in Ionic Oxides
89
3.5.
Gibbs-Duhem Equation for Defective Solid Oxides
91
3.6.
Lattice Diffusion and Oxide Scaling: Wagner's Model
93
3.7.
Validation of Wagner's Model
96
vi
Contents
3.8.
Impurity Effects on Lattice Diffusion
113
3.9.
Microstructural Effects
115
3.10.
Reactions Not Controlled by Solid-State Diffusion
127
3.11.
The Value of Thermodynamic and Kinetic Analysis
133
References
135
4.
Mixed Gas Corrosion of Pure Metals
139
4.1.
Introduction
139
4.2.
Selected Experimental Findings
140
4.3.
Phase Diagrams and Diffusion Paths
147
4.4.
Scale-Gas Interactions
154
4.5.
Transport Processes in Mixed Scales
168
4.6.
Predicting the Outcome of Mixed Gas Reactions
175
References
181
5.
Oxidation of Alloys I: Single Phase Scales
185
5.1.
Introduction
185
5.2.
Selected Experimental Results
187
5.3.
Phase Diagrams and Diffusion Paths
193
5.4.
Selective Oxidation of One Alloy Component
196
5.5.
Selective Oxidation of One Alloy Connponent Under
Non-Steady-State Conditions
202
5.6.
Solid Solution Oxide Scales
206
5.7.
Transient Oxidation
216
5.8.
Microstructural Changes in Subsurface Alloy Regions
226
5.9.
Breakdown of Steady-State Scale
237
5.10.
Other Factors Affecting Scale Growth
241
References
243
6.
Oxidation of Alloys II: Internal Oxidation
247
6.1.
Introduction
247
6.2.
Selected Experimental Results
248
6.3.
Internal Oxidation Kinetics in the Absence of External Scaling
255
6.4.
Experimental Verification of Diffusion Model
260
6.5.
Surface Diffusion Effects in the Precipitation Zone
267
6.6.
Internal Precipitates of Low Stability
273
6.7.
Precipitate Nucleation and Growth
278
6.8.
Cellular Precipitation Morphologies
284
6.9.
Multiple Internal Precipitates
290
6.10.
Solute Interactions in the Precipitation Zone
299
6.11.
Transition from Internal to External Oxidation
301
6.12.
Internal Oxidation Beneath a Corroding Alloy Surface
305
6.13.
Volume Expansion in the Internal Precipitation Zone
306
6.14.
Success of Internal Oxidation Theory
311
References
312
Contents
VM
7.
Alloy Oxidation III: Multiphase Scales
315
7.1.
Introduction
315
7.2.
Binary Alumina Formers
316
7.3.
Binary Chromia Formers
326
7.4.
Ternary Alloy Oxidation
330
7.5.
Scale Spallation
341
7.6.
Effects of Minor Alloying Additions
347
7.7.
Effects of Secondary Oxidants
352
7.8.
Status of Multiphase Scale Growth Theory
355
References
356
8.
Corrosion by Sulfur
361
8.1.
Introduction
361
8.2.
Sulfidation of Pure Metals
362
8.3.
Alloying for Sulfidation Protection
367
8.4.
Sulfidation in
H2/H2S
378
8.5.
Effects of Temperature and Sulfur Partial Pressure
381
8.6.
The Role of Oxygen
382
8.7.
Internal Sulfidation
383
8.8.
Hot Corrosion
383
8.9.
Achieving Sulfidation Resistance
391
References
392
9.
Corrosion by Carbon
397
9.1.
Introduction
398
9.2.
Gaseous Carbon Activities
400
9.3.
Carburization
402
9.4.
Internal Carburization of Model Alloys
403
9.5.
Internal Carburization of Heat Resisting Alloys
415
9.6.
Metal Dusting of Iron and Ferritic Alloys
421
9.7.
Dusting of Nickel and Austenitic Alloys
435
9.8.
Protection by Oxide Scaling
444
9.9.
Controlling Carbon Corrosion
449
References
450
10.
Effects of Water Vapour on Oxidation
455
10.1.
Introduction
455
10.2.
Volatile Metal Hydroxide Formation
458
10.3.
Scale-Gas
Interfacial
Processes
468
10.4.
Scale Transport Properties
472
10.5.
Water Vapour Effects on Alumina Growth
488
10.6.
Void Development in Growing Scales
489
10.7.
Understanding and Controlling Water Vapour Effects
490
References
492
VIU
Contents
11.
Cyclic Oxidation
497
11.1.
Introduction
497
11.2.
Alloy Depletion and Scale Rehealing
502
11.3.
Spallation Models
506
11.4.
Combination of Spalling and Depletion Models
514
11.5.
Effects of Experimental Variables
517
11.6.
Describing and Predicting Cyclic Oxidation
527
References
530
12.
Alloy Design
533
12.1.
Introduction
533
12.2.
Alloy Design for Resistance to Oxygen
534
12.3.
Design Against Oxide Scale Spallation
537
12.4.
Design for Resistance to Other Corrodents and Mixed Gases
538
12.5.
Future Research
539
12.6.
Fundamental Research
544
12.7.
Conclusion
547
References
547
Appendix A: High Temperature Alloys
549
Appendix B: Cation Diffusion Kinetics in Ionic Solids
553
Appendix C: The Error Function
561
Appendix D: Self-Diffusion Coefficients
565
Index
567 |
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| id | DE-604.BV035183659 |
| illustrated | Illustrated |
| index_date | 2024-07-02T22:58:55Z |
| indexdate | 2024-07-09T21:26:55Z |
| institution | BVB |
| isbn | 9780080445878 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016990374 |
| oclc_num | 212894774 |
| open_access_boolean | |
| owner | DE-703 |
| owner_facet | DE-703 |
| physical | xvii, 574 p. zahlr. Ill. und graph. Darst. |
| publishDate | 2008 |
| publishDateSearch | 2008 |
| publishDateSort | 2008 |
| publisher | Elsevier |
| record_format | marc |
| series | Elsevier corrosion series |
| series2 | Elsevier corrosion series |
| spelling | Young, David John Verfasser aut High temperature oxidation and corrosion of metals by David John Young 1. ed. Amsterdam [u.a.] Elsevier 2008 xvii, 574 p. zahlr. Ill. und graph. Darst. txt rdacontent n rdamedia nc rdacarrier Elsevier corrosion series 1 Includes bibliographical references and index. - Formerly CIP Alloys Metallic oxides Metals Effect of high temperatures on Oxidation (DE-588)4137187-2 gnd rswk-swf Metall (DE-588)4038860-8 gnd rswk-swf Korrosion (DE-588)4032518-0 gnd rswk-swf Metalloxide (DE-588)4169619-0 gnd rswk-swf Hochtemperatur (DE-588)4282597-0 gnd rswk-swf Metall (DE-588)4038860-8 s Korrosion (DE-588)4032518-0 s Oxidation (DE-588)4137187-2 s 1\p DE-604 Hochtemperatur (DE-588)4282597-0 s 2\p DE-604 Metalloxide (DE-588)4169619-0 s 3\p DE-604 Elsevier corrosion series 1 (DE-604)BV035344244 1 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016990374&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Young, David John High temperature oxidation and corrosion of metals Elsevier corrosion series Alloys Metallic oxides Metals Effect of high temperatures on Oxidation (DE-588)4137187-2 gnd Metall (DE-588)4038860-8 gnd Korrosion (DE-588)4032518-0 gnd Metalloxide (DE-588)4169619-0 gnd Hochtemperatur (DE-588)4282597-0 gnd |
| subject_GND | (DE-588)4137187-2 (DE-588)4038860-8 (DE-588)4032518-0 (DE-588)4169619-0 (DE-588)4282597-0 |
| title | High temperature oxidation and corrosion of metals |
| title_auth | High temperature oxidation and corrosion of metals |
| title_exact_search | High temperature oxidation and corrosion of metals |
| title_exact_search_txtP | High temperature oxidation and corrosion of metals |
| title_full | High temperature oxidation and corrosion of metals by David John Young |
| title_fullStr | High temperature oxidation and corrosion of metals by David John Young |
| title_full_unstemmed | High temperature oxidation and corrosion of metals by David John Young |
| title_short | High temperature oxidation and corrosion of metals |
| title_sort | high temperature oxidation and corrosion of metals |
| topic | Alloys Metallic oxides Metals Effect of high temperatures on Oxidation (DE-588)4137187-2 gnd Metall (DE-588)4038860-8 gnd Korrosion (DE-588)4032518-0 gnd Metalloxide (DE-588)4169619-0 gnd Hochtemperatur (DE-588)4282597-0 gnd |
| topic_facet | Alloys Metallic oxides Metals Effect of high temperatures on Oxidation Metall Korrosion Metalloxide Hochtemperatur |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016990374&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV035344244 |
| work_keys_str_mv | AT youngdavidjohn hightemperatureoxidationandcorrosionofmetals |